RU2632197C2 - Способ получения катализатора для риформинга и риформинг метана - Google Patents

Способ получения катализатора для риформинга и риформинг метана Download PDF

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RU2632197C2
RU2632197C2 RU2014123056A RU2014123056A RU2632197C2 RU 2632197 C2 RU2632197 C2 RU 2632197C2 RU 2014123056 A RU2014123056 A RU 2014123056A RU 2014123056 A RU2014123056 A RU 2014123056A RU 2632197 C2 RU2632197 C2 RU 2632197C2
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range
catalyst
metal salt
temperature
hydrotalcite
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RU2014123056A (ru
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Эккехард Шваб
Андриан МИЛАНОВ
Штефан ШУНК
Томас РУССЬЕР
Гвидо ВАССЕРШАФФ
Андреас ШТРАССЕР
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Басф Се
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    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
    • C01B2203/1241Natural gas or methane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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  • Chemical & Material Sciences (AREA)
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  • Thermal Sciences (AREA)
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  • Combustion & Propulsion (AREA)
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RU2014123056A 2011-11-08 2012-11-05 Способ получения катализатора для риформинга и риформинг метана RU2632197C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11188237.9 2011-11-08
EP11188237 2011-11-08
PCT/IB2012/056158 WO2013068905A1 (en) 2011-11-08 2012-11-05 Process for producing reforming catalyst and reforming of methane

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RU2014123056A RU2014123056A (ru) 2015-12-20
RU2632197C2 true RU2632197C2 (ru) 2017-10-03

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EP (1) EP2776157B1 (enExample)
JP (1) JP6296990B2 (enExample)
KR (1) KR20140099475A (enExample)
CN (1) CN104039445B (enExample)
CA (1) CA2854863A1 (enExample)
DK (1) DK2776157T3 (enExample)
RU (1) RU2632197C2 (enExample)
WO (1) WO2013068905A1 (enExample)
ZA (1) ZA201404090B (enExample)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103917291A (zh) * 2011-11-09 2014-07-09 巴斯夫欧洲公司 用于在燃料电池中蒸汽转化甲烷的催化剂组合物
CN103611541B (zh) * 2013-12-06 2016-03-30 新奥科技发展有限公司 一种低温甲烷水蒸汽重整催化剂及其制备方法
EP2886514A1 (de) 2013-12-20 2015-06-24 Basf Se Verfahren zur Reformierung von Gemischen aus Kohlenwasserstoffen und Kohlendioxid
KR20160133490A (ko) * 2014-03-14 2016-11-22 바스프 에스이 고온 이산화탄소 수소화, 조합된 고온 이산화탄소 수소화 및 개질, 및/또는 개질을 위한 이트륨 함유 촉매, 및 고온 이산화탄소 수소화, 조합된 고온 이산화탄소 수소화 및 개질, 및/또는 개질을 위한 방법
FR3020356A1 (fr) 2014-04-29 2015-10-30 Univ Lille Sciences Tech Procede de reformage sec d'au moins un alcane.
CN103962145B (zh) * 2014-04-30 2016-08-24 上海倍能化工技术有限公司 一种高温型甲烷合成用催化剂、制备方法及甲烷合成方法
EP3169433A4 (en) 2014-07-17 2018-06-27 SABIC Global Technologies B.V. Use of olivine catalysts for carbon dioxide reforming of methane
DE102014011213A1 (de) 2014-07-29 2016-02-04 Linde Aktiengesellschaft Verfahren zur Synthesegasherstellung
DK201400705A1 (en) * 2014-12-03 2016-04-18 Haldor Topsoe As A catalyst for prereforming and/or steam reforming
US11104575B2 (en) 2016-05-12 2021-08-31 Fujian Institute Of Research On The Structure Of Matter, Chinese Academy Of Science Nanocatalysts, preparation methods and applications for reforming carbon dioxide and methane to syngas
CN106622321B (zh) * 2016-09-06 2019-07-12 中国海洋石油集团有限公司 一种甲烷化催化剂及其制备方法与应用
EP3574994A1 (en) 2018-05-30 2019-12-04 Basf Se Method for producing catalyst monoliths for the reforming of hydrocarbons
FR3104462B1 (fr) * 2019-12-17 2022-06-10 Ifp Energies Now Catalyseur pour l’hydrogenation de composes aromatiques obtenu a partir de sels fondus et d’un additif organique
US20230095488A1 (en) 2020-01-31 2023-03-30 Basf Se A process for preparing a molding, a molding and use thereof as methane reforming catalyst
KR20220052099A (ko) * 2020-10-20 2022-04-27 한국화학연구원 메탄의 수증기 개질용 니켈계 촉매 및 이를 이용한 메탄의 수증기 개질 반응
WO2022184892A1 (en) 2021-03-04 2022-09-09 Basf Se Process for the preparation of a mixed metal oxide
WO2023111017A1 (en) 2021-12-15 2023-06-22 Basf Se High pressure nh3-reforming and combined reforming of nh3 as co-feed for hydrocarbon/co2-reforming
JP2025513003A (ja) 2022-04-08 2025-04-22 ビーエーエスエフ ソシエタス・ヨーロピア Nh3の改質のためのゾーン分割反応器
WO2023227605A1 (en) 2022-05-24 2023-11-30 Basf Se Method for the preparation of a supported mixed metal oxide
CN115282975B (zh) * 2022-07-29 2024-02-20 东南大学 适用于甲烷湿重整的催化剂、制备、还原及应用方法
JP2025531118A (ja) 2022-09-12 2025-09-19 ビーエーエスエフ ソシエタス・ヨーロピア NH3改質用途のNiベース触媒
EP4587373A1 (en) 2022-09-12 2025-07-23 Basf Se Process for nh3 reforming

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3926583A (en) * 1967-06-12 1975-12-16 Haldor Topsoe As Process for the catalytic steam reforming of hydrocarbons
WO2007046591A1 (en) * 2005-10-20 2007-04-26 Sk Energy Co., Ltd Nickel based catalyst using hydrotalcite-like precursor and steam reforming reaction of lpg
RU2383388C2 (ru) * 2004-12-17 2010-03-10 Энститю Франсэ Дю Петроль Катализатор на основе кобальта для синтеза фишера-тропша
EP2308594A2 (en) * 2008-08-01 2011-04-13 Hyundai Heavy Industries Co., Ltd. Catalyst for preparing synthesis gas from natural gas and carbon dioxide, and preparation method thereof

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL302476A (enExample) * 1962-12-29
GB1182829A (en) * 1967-06-12 1970-03-04 Haldor Frederik Axel Topsoe Improvements in or relating to Nickel Catalysts.
US6242380B1 (en) * 1993-08-25 2001-06-05 Korea Research Institute Of Chemical Technology Process for preparing supported nickel catalyst for reforming hydrocarbons
WO2001025142A1 (en) * 1999-10-01 2001-04-12 Bp Amoco Corporation Preparing synthesis gas using hydrotalcite-derived nickel catalysts
KR100398058B1 (ko) * 2001-05-18 2003-09-19 주식회사 경동도시가스 수식된 θ-알루미나에 담지되어 이루어진 니켈계 개질촉매및 이를 이용한 천연가스로부터 합성가스의 제조방법
JP4013689B2 (ja) * 2002-07-30 2007-11-28 宇部興産株式会社 炭化水素改質用触媒、炭化水素分解装置、及び燃料電池用改質器
US20080260628A1 (en) * 2007-04-17 2008-10-23 Korea Institute Of Science And Technology Ni-based catalyst for tri-reforming of methane and its catalysis application for the production of syngas
KR100892033B1 (ko) * 2007-10-08 2009-04-07 한국에너지기술연구원 고표면적 스핀넬 구조의 나노크기 결정을 가지는yMgO(1-y)Al₂O₃에 나노크기로 담지된 니켈계개질촉매 및 이를 이용한 수증기-이산화탄소 복합개질에의한 천연가스로부터 합성가스의 제조방법
CN101391218B (zh) * 2008-10-31 2010-08-11 西南化工研究设计院 一种焦炉气甲烷化催化剂的制备方法
ES2342814B1 (es) * 2009-01-13 2011-05-23 Hynergreen Technologies, S.A Catalizador para un proceso para la obtencion de hidrogeno mediante reformado de hidrocarburos con vapor de agua, proceso de preparacion del catalizador y uso del mismo en el proceso.
JP5477561B2 (ja) * 2009-09-09 2014-04-23 戸田工業株式会社 炭化水素を分解する多孔質触媒体及びその製造方法、炭化水素から水素を含む混合改質ガスを製造する方法、並びに燃料電池システム
CA2817490C (en) * 2010-11-16 2019-02-12 Stichting Energieonderzoek Centrum Nederland Catalyst for hydrogen production
EP2776164A4 (de) * 2011-11-08 2015-08-19 Basf Se Verfahren zur herstellung eines methanisierungs-katalysators sowie ein verfahren zur methanisierung von synthesegas

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3926583A (en) * 1967-06-12 1975-12-16 Haldor Topsoe As Process for the catalytic steam reforming of hydrocarbons
RU2383388C2 (ru) * 2004-12-17 2010-03-10 Энститю Франсэ Дю Петроль Катализатор на основе кобальта для синтеза фишера-тропша
WO2007046591A1 (en) * 2005-10-20 2007-04-26 Sk Energy Co., Ltd Nickel based catalyst using hydrotalcite-like precursor and steam reforming reaction of lpg
EP2308594A2 (en) * 2008-08-01 2011-04-13 Hyundai Heavy Industries Co., Ltd. Catalyst for preparing synthesis gas from natural gas and carbon dioxide, and preparation method thereof

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