CN104039445B - 制备重整催化剂和重整甲烷的方法 - Google Patents

制备重整催化剂和重整甲烷的方法 Download PDF

Info

Publication number
CN104039445B
CN104039445B CN201280066204.4A CN201280066204A CN104039445B CN 104039445 B CN104039445 B CN 104039445B CN 201280066204 A CN201280066204 A CN 201280066204A CN 104039445 B CN104039445 B CN 104039445B
Authority
CN
China
Prior art keywords
catalyst
reforming
temperature
synthesis gas
hydrocarbon compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201280066204.4A
Other languages
English (en)
Chinese (zh)
Other versions
CN104039445A (zh
Inventor
E·施瓦布
A·米拉诺夫
S·顺克
T·鲁西埃
G·瓦塞尔沙夫
A·斯特拉瑟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CN104039445A publication Critical patent/CN104039445A/zh
Application granted granted Critical
Publication of CN104039445B publication Critical patent/CN104039445B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B01J27/232—Carbonates
    • B01J27/236—Hydroxy carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/653—500-1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/695—Pore distribution polymodal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B01J35/73—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline having a two-dimensional layered crystalline structure, e.g. layered double hydroxide [LDH]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B01J35/77—Compounds characterised by their crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0081—Preparation by melting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0238—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a carbon dioxide reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C01B2203/1058—Nickel catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1094—Promotors or activators
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
CN201280066204.4A 2011-11-08 2012-11-05 制备重整催化剂和重整甲烷的方法 Active CN104039445B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11188237 2011-11-08
EP11188237.9 2011-11-08
PCT/IB2012/056158 WO2013068905A1 (en) 2011-11-08 2012-11-05 Process for producing reforming catalyst and reforming of methane

Publications (2)

Publication Number Publication Date
CN104039445A CN104039445A (zh) 2014-09-10
CN104039445B true CN104039445B (zh) 2017-05-31

Family

ID=48288609

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280066204.4A Active CN104039445B (zh) 2011-11-08 2012-11-05 制备重整催化剂和重整甲烷的方法

Country Status (9)

Country Link
EP (1) EP2776157B1 (enExample)
JP (1) JP6296990B2 (enExample)
KR (1) KR20140099475A (enExample)
CN (1) CN104039445B (enExample)
CA (1) CA2854863A1 (enExample)
DK (1) DK2776157T3 (enExample)
RU (1) RU2632197C2 (enExample)
WO (1) WO2013068905A1 (enExample)
ZA (1) ZA201404090B (enExample)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6305341B2 (ja) 2011-11-09 2018-04-04 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 燃料電池中でのメタン水蒸気改質用の触媒組成物
CN103611541B (zh) * 2013-12-06 2016-03-30 新奥科技发展有限公司 一种低温甲烷水蒸汽重整催化剂及其制备方法
EP2886514A1 (de) 2013-12-20 2015-06-24 Basf Se Verfahren zur Reformierung von Gemischen aus Kohlenwasserstoffen und Kohlendioxid
WO2015135968A1 (de) * 2014-03-14 2015-09-17 Basf Se Yttriumhaltiger katalysator zur hochtemperatur kohlendioxidhydrierung, kombinierten hochtemperatur kohlendioxidhydrierung und reformierung und/oder reformierung sowie ein verfahren zur hochtemperatur kohlendioxidhydrierung, kombinierten hochtemperatur kohlendioxidhydrierung und reformierung und/oder reformierung
FR3020356A1 (fr) 2014-04-29 2015-10-30 Univ Lille Sciences Tech Procede de reformage sec d'au moins un alcane.
CN103962145B (zh) * 2014-04-30 2016-08-24 上海倍能化工技术有限公司 一种高温型甲烷合成用催化剂、制备方法及甲烷合成方法
WO2016011240A1 (en) 2014-07-17 2016-01-21 Sabic Global Technologies B.V. Use of olivine catalysts for carbon dioxide reforming of methane
DE102014011213A1 (de) 2014-07-29 2016-02-04 Linde Aktiengesellschaft Verfahren zur Synthesegasherstellung
DK201400705A1 (en) * 2014-12-03 2016-04-18 Haldor Topsoe As A catalyst for prereforming and/or steam reforming
US11104575B2 (en) 2016-05-12 2021-08-31 Fujian Institute Of Research On The Structure Of Matter, Chinese Academy Of Science Nanocatalysts, preparation methods and applications for reforming carbon dioxide and methane to syngas
CN106622321B (zh) * 2016-09-06 2019-07-12 中国海洋石油集团有限公司 一种甲烷化催化剂及其制备方法与应用
EP3574994A1 (en) 2018-05-30 2019-12-04 Basf Se Method for producing catalyst monoliths for the reforming of hydrocarbons
FR3104462B1 (fr) * 2019-12-17 2022-06-10 Ifp Energies Now Catalyseur pour l’hydrogenation de composes aromatiques obtenu a partir de sels fondus et d’un additif organique
EP4096824A1 (en) 2020-01-31 2022-12-07 Basf Se A process for preparing a molding, a molding and use thereof as methane reforming catalyst
KR20220052099A (ko) * 2020-10-20 2022-04-27 한국화학연구원 메탄의 수증기 개질용 니켈계 촉매 및 이를 이용한 메탄의 수증기 개질 반응
WO2022184892A1 (en) 2021-03-04 2022-09-09 Basf Se Process for the preparation of a mixed metal oxide
KR20240124964A (ko) 2021-12-15 2024-08-19 바스프 에스이 고압 nh3-개질, 및 탄화수소 및또는 co2-개질을 위한 공동-공급물로서의 nh3의 조합 개질
HUE072610T2 (hu) 2022-04-08 2025-11-28 Basf Se Zónás reaktor NH3 átalakítására
WO2023227605A1 (en) 2022-05-24 2023-11-30 Basf Se Method for the preparation of a supported mixed metal oxide
CN115282975B (zh) * 2022-07-29 2024-02-20 东南大学 适用于甲烷湿重整的催化剂、制备、还原及应用方法
KR20250071249A (ko) 2022-09-12 2025-05-21 바스프 에스이 Nh₃ 개질 방법
CN119894810A (zh) 2022-09-12 2025-04-25 巴斯夫欧洲公司 用于NH3重整应用的Ni基催化剂

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030172590A1 (en) * 1999-10-01 2003-09-18 Alakananda Bhattacharyya Preparing synthesis gas using hydrotalcite-derived nickel catalysts
WO2010081916A1 (es) * 2009-01-13 2010-07-22 Hynergreen Technology, S.A. Catalizador para un proceso para la obtención de hidrógeno mediante reformado de hidrocarburos con vapor de agua, proceso de preparación del catalizador y uso del mismo en el proceso
WO2011030800A1 (ja) * 2009-09-09 2011-03-17 戸田工業株式会社 炭化水素を分解する多孔質触媒体及びその製造方法、炭化水素から水素を含む混合改質ガスを製造する方法、並びに燃料電池システム
CN102112227A (zh) * 2008-08-01 2011-06-29 现代重工业株式会社 用于从天然气和二氧化碳制备合成气的催化剂及其制备方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL302476A (enExample) * 1962-12-29
US3926583A (en) * 1967-06-12 1975-12-16 Haldor Topsoe As Process for the catalytic steam reforming of hydrocarbons
GB1182829A (en) * 1967-06-12 1970-03-04 Haldor Frederik Axel Topsoe Improvements in or relating to Nickel Catalysts.
US6242380B1 (en) * 1993-08-25 2001-06-05 Korea Research Institute Of Chemical Technology Process for preparing supported nickel catalyst for reforming hydrocarbons
KR100398058B1 (ko) * 2001-05-18 2003-09-19 주식회사 경동도시가스 수식된 θ-알루미나에 담지되어 이루어진 니켈계 개질촉매및 이를 이용한 천연가스로부터 합성가스의 제조방법
JP4013689B2 (ja) * 2002-07-30 2007-11-28 宇部興産株式会社 炭化水素改質用触媒、炭化水素分解装置、及び燃料電池用改質器
FR2879478B1 (fr) * 2004-12-17 2007-10-26 Inst Francais Du Petrole Catalyseur a base de cobalt pour la synthese fisher-tropsch
KR101300501B1 (ko) * 2005-10-20 2013-08-26 에스케이이노베이션 주식회사 유사 하이드로탈사이트 전구체를 이용한 니켈계 촉매와이를 이용한 액화석유가스의 수증기 개질반응
US20080260628A1 (en) * 2007-04-17 2008-10-23 Korea Institute Of Science And Technology Ni-based catalyst for tri-reforming of methane and its catalysis application for the production of syngas
KR100892033B1 (ko) * 2007-10-08 2009-04-07 한국에너지기술연구원 고표면적 스핀넬 구조의 나노크기 결정을 가지는ｙＭｇＯ(1-ｙ)Ａｌ₂Ｏ₃에 나노크기로 담지된 니켈계개질촉매 및 이를 이용한 수증기-이산화탄소 복합개질에의한 천연가스로부터 합성가스의 제조방법
CN101391218B (zh) * 2008-10-31 2010-08-11 西南化工研究设计院 一种焦炉气甲烷化催化剂的制备方法
AU2011329937B2 (en) * 2010-11-16 2017-02-02 Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno Catalyst for hydrogen production
JP6125518B2 (ja) * 2011-11-08 2017-05-10 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ メタン化触媒を製造するための方法および合成ガスのメタン化のための方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030172590A1 (en) * 1999-10-01 2003-09-18 Alakananda Bhattacharyya Preparing synthesis gas using hydrotalcite-derived nickel catalysts
CN102112227A (zh) * 2008-08-01 2011-06-29 现代重工业株式会社 用于从天然气和二氧化碳制备合成气的催化剂及其制备方法
WO2010081916A1 (es) * 2009-01-13 2010-07-22 Hynergreen Technology, S.A. Catalizador para un proceso para la obtención de hidrógeno mediante reformado de hidrocarburos con vapor de agua, proceso de preparación del catalizador y uso del mismo en el proceso
WO2011030800A1 (ja) * 2009-09-09 2011-03-17 戸田工業株式会社 炭化水素を分解する多孔質触媒体及びその製造方法、炭化水素から水素を含む混合改質ガスを製造する方法、並びに燃料電池システム

Also Published As

Publication number Publication date
ZA201404090B (en) 2017-05-31
EP2776157A4 (en) 2015-08-12
CA2854863A1 (en) 2013-05-16
EP2776157A1 (en) 2014-09-17
EP2776157B1 (en) 2021-01-06
CN104039445A (zh) 2014-09-10
KR20140099475A (ko) 2014-08-12
JP6296990B2 (ja) 2018-03-20
RU2632197C2 (ru) 2017-10-03
DK2776157T3 (da) 2021-03-29
WO2013068905A1 (en) 2013-05-16
JP2014532559A (ja) 2014-12-08
RU2014123056A (ru) 2015-12-20

Similar Documents

Publication Publication Date Title
CN104039445B (zh) 制备重整催化剂和重整甲烷的方法
US9259712B2 (en) Process for producing a reforming catalyst and the reforming of methane
US8916491B2 (en) Process for producing a methanation catalyst and a process for the methanation of synthesis gas
CN104039452B (zh) 生产甲烷化催化剂的方法及合成气甲烷化的方法
CN104080530B (zh) 用于重整烃的含六铝酸盐的催化剂和重整方法
CN102112227B (zh) 用于从天然气和二氧化碳制备合成气的催化剂及其制备方法
Chatla et al. Dry (CO2) reforming of methane over zirconium promoted Ni-MgO mixed oxide catalyst: Effect of Zr addition
EP3685916A1 (en) Perovskite metal oxide catalyst, in which metal ion is substituted, for reducing carbon deposition, preparation method therefor, and methane reforming reaction method using same
CN106102905A (zh) 用于高温二氧化碳氢化、用于组合高温二氧化碳氢化和重整和/或用于重整的含钇催化剂，和用于高温二氧化碳氢化，用于组合高温二氧化碳氢化和重整和/或用于重整的方法
EP3801885B1 (en) Method for producing catalyst monoliths for the reforming of hydrocarbons
EP2251080A1 (en) A porous catalytic body that decomposes hydrocarbons and a manufacturing method thereof, a method for manufacturing mixed reformed gas that comprises hydrogen from hydrocarbon, and a fuel cell system
US10987660B2 (en) Hexaaluminate-comprising catalyst for the reforming of hydrocarbons and a reforming process
CA2846994C (en) Catalysts for producing hydrogen and synthesis gas
Jin et al. Ni/MgOAl2O3 catalyst derived from modified [Ni, Mg, Al]-LDH with NaOH for CO2 reforming of methane
JP2025025023A (ja) 二酸化炭素をメタン化するメタン化触媒及びその製造方法、並びに二酸化炭素をメタン化する方法
CN116272955B (zh) 逆水汽变换催化剂及其制备方法和应用

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant