KR20140099475A - 개질 촉매의 제조 방법 및 메탄의 개질 - Google Patents

개질 촉매의 제조 방법 및 메탄의 개질 Download PDF

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KR20140099475A
KR20140099475A KR1020147015234A KR20147015234A KR20140099475A KR 20140099475 A KR20140099475 A KR 20140099475A KR 1020147015234 A KR1020147015234 A KR 1020147015234A KR 20147015234 A KR20147015234 A KR 20147015234A KR 20140099475 A KR20140099475 A KR 20140099475A
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range
catalyst
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hydrotalcite
temperature
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엑크하르트 슈바브
안드리안 밀라노프
스테판 슝크
토마스 루시에레
귀도 바써샤프
안드레아스 스트라써
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바스프 에스이
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
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    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
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    • B01J27/20—Carbon compounds
    • B01J27/232—Carbonates
    • B01J27/236—Hydroxy carbonates
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    • B01J35/73—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline having a two-dimensional layered crystalline structure, e.g. layered double hydroxide [LDH]
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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    • C01B2203/1052—Nickel or cobalt catalysts
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    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
KR1020147015234A 2011-11-08 2012-11-05 개질 촉매의 제조 방법 및 메탄의 개질 Withdrawn KR20140099475A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11188237 2011-11-08
EP11188237.9 2011-11-08
PCT/IB2012/056158 WO2013068905A1 (en) 2011-11-08 2012-11-05 Process for producing reforming catalyst and reforming of methane

Publications (1)

Publication Number Publication Date
KR20140099475A true KR20140099475A (ko) 2014-08-12

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KR1020147015234A Withdrawn KR20140099475A (ko) 2011-11-08 2012-11-05 개질 촉매의 제조 방법 및 메탄의 개질

Country Status (9)

Country Link
EP (1) EP2776157B1 (enExample)
JP (1) JP6296990B2 (enExample)
KR (1) KR20140099475A (enExample)
CN (1) CN104039445B (enExample)
CA (1) CA2854863A1 (enExample)
DK (1) DK2776157T3 (enExample)
RU (1) RU2632197C2 (enExample)
WO (1) WO2013068905A1 (enExample)
ZA (1) ZA201404090B (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20230005097A (ko) * 2020-10-20 2023-01-09 한국화학연구원 메탄의 수증기 개질용 니켈계 촉매 및 이를 이용한 메탄의 수증기 개질 반응

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6305341B2 (ja) 2011-11-09 2018-04-04 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 燃料電池中でのメタン水蒸気改質用の触媒組成物
CN103611541B (zh) * 2013-12-06 2016-03-30 新奥科技发展有限公司 一种低温甲烷水蒸汽重整催化剂及其制备方法
EP2886514A1 (de) 2013-12-20 2015-06-24 Basf Se Verfahren zur Reformierung von Gemischen aus Kohlenwasserstoffen und Kohlendioxid
WO2015135968A1 (de) * 2014-03-14 2015-09-17 Basf Se Yttriumhaltiger katalysator zur hochtemperatur kohlendioxidhydrierung, kombinierten hochtemperatur kohlendioxidhydrierung und reformierung und/oder reformierung sowie ein verfahren zur hochtemperatur kohlendioxidhydrierung, kombinierten hochtemperatur kohlendioxidhydrierung und reformierung und/oder reformierung
FR3020356A1 (fr) 2014-04-29 2015-10-30 Univ Lille Sciences Tech Procede de reformage sec d'au moins un alcane.
CN103962145B (zh) * 2014-04-30 2016-08-24 上海倍能化工技术有限公司 一种高温型甲烷合成用催化剂、制备方法及甲烷合成方法
WO2016011240A1 (en) 2014-07-17 2016-01-21 Sabic Global Technologies B.V. Use of olivine catalysts for carbon dioxide reforming of methane
DE102014011213A1 (de) 2014-07-29 2016-02-04 Linde Aktiengesellschaft Verfahren zur Synthesegasherstellung
DK201400705A1 (en) * 2014-12-03 2016-04-18 Haldor Topsoe As A catalyst for prereforming and/or steam reforming
US11104575B2 (en) 2016-05-12 2021-08-31 Fujian Institute Of Research On The Structure Of Matter, Chinese Academy Of Science Nanocatalysts, preparation methods and applications for reforming carbon dioxide and methane to syngas
CN106622321B (zh) * 2016-09-06 2019-07-12 中国海洋石油集团有限公司 一种甲烷化催化剂及其制备方法与应用
EP3574994A1 (en) 2018-05-30 2019-12-04 Basf Se Method for producing catalyst monoliths for the reforming of hydrocarbons
FR3104462B1 (fr) * 2019-12-17 2022-06-10 Ifp Energies Now Catalyseur pour l’hydrogenation de composes aromatiques obtenu a partir de sels fondus et d’un additif organique
EP4096824A1 (en) 2020-01-31 2022-12-07 Basf Se A process for preparing a molding, a molding and use thereof as methane reforming catalyst
WO2022184892A1 (en) 2021-03-04 2022-09-09 Basf Se Process for the preparation of a mixed metal oxide
KR20240124964A (ko) 2021-12-15 2024-08-19 바스프 에스이 고압 nh3-개질, 및 탄화수소 및또는 co2-개질을 위한 공동-공급물로서의 nh3의 조합 개질
HUE072610T2 (hu) 2022-04-08 2025-11-28 Basf Se Zónás reaktor NH3 átalakítására
WO2023227605A1 (en) 2022-05-24 2023-11-30 Basf Se Method for the preparation of a supported mixed metal oxide
CN115282975B (zh) * 2022-07-29 2024-02-20 东南大学 适用于甲烷湿重整的催化剂、制备、还原及应用方法
KR20250071249A (ko) 2022-09-12 2025-05-21 바스프 에스이 Nh₃ 개질 방법
CN119894810A (zh) 2022-09-12 2025-04-25 巴斯夫欧洲公司 用于NH3重整应用的Ni基催化剂

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL302476A (enExample) * 1962-12-29
US3926583A (en) * 1967-06-12 1975-12-16 Haldor Topsoe As Process for the catalytic steam reforming of hydrocarbons
GB1182829A (en) * 1967-06-12 1970-03-04 Haldor Frederik Axel Topsoe Improvements in or relating to Nickel Catalysts.
US6242380B1 (en) * 1993-08-25 2001-06-05 Korea Research Institute Of Chemical Technology Process for preparing supported nickel catalyst for reforming hydrocarbons
EP1135327B1 (en) * 1999-10-01 2004-06-30 BP Corporation North America Inc. Preparing synthesis gas using hydrotalcite-derived nickel catalysts
KR100398058B1 (ko) * 2001-05-18 2003-09-19 주식회사 경동도시가스 수식된 θ-알루미나에 담지되어 이루어진 니켈계 개질촉매및 이를 이용한 천연가스로부터 합성가스의 제조방법
JP4013689B2 (ja) * 2002-07-30 2007-11-28 宇部興産株式会社 炭化水素改質用触媒、炭化水素分解装置、及び燃料電池用改質器
FR2879478B1 (fr) * 2004-12-17 2007-10-26 Inst Francais Du Petrole Catalyseur a base de cobalt pour la synthese fisher-tropsch
KR101300501B1 (ko) * 2005-10-20 2013-08-26 에스케이이노베이션 주식회사 유사 하이드로탈사이트 전구체를 이용한 니켈계 촉매와이를 이용한 액화석유가스의 수증기 개질반응
US20080260628A1 (en) * 2007-04-17 2008-10-23 Korea Institute Of Science And Technology Ni-based catalyst for tri-reforming of methane and its catalysis application for the production of syngas
KR100892033B1 (ko) * 2007-10-08 2009-04-07 한국에너지기술연구원 고표면적 스핀넬 구조의 나노크기 결정을 가지는ｙＭｇＯ(1-ｙ)Ａｌ₂Ｏ₃에 나노크기로 담지된 니켈계개질촉매 및 이를 이용한 수증기-이산화탄소 복합개질에의한 천연가스로부터 합성가스의 제조방법
KR100991263B1 (ko) * 2008-08-01 2010-11-01 현대중공업 주식회사 천연가스를 수증기와 이산화탄소로 동시에 개질하는 혼합개질 반응용 니켈계 촉매
CN101391218B (zh) * 2008-10-31 2010-08-11 西南化工研究设计院 一种焦炉气甲烷化催化剂的制备方法
ES2342814B1 (es) * 2009-01-13 2011-05-23 Hynergreen Technologies, S.A Catalizador para un proceso para la obtencion de hidrogeno mediante reformado de hidrocarburos con vapor de agua, proceso de preparacion del catalizador y uso del mismo en el proceso.
JP5477561B2 (ja) * 2009-09-09 2014-04-23 戸田工業株式会社 炭化水素を分解する多孔質触媒体及びその製造方法、炭化水素から水素を含む混合改質ガスを製造する方法、並びに燃料電池システム
AU2011329937B2 (en) * 2010-11-16 2017-02-02 Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno Catalyst for hydrogen production
JP6125518B2 (ja) * 2011-11-08 2017-05-10 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ メタン化触媒を製造するための方法および合成ガスのメタン化のための方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20230005097A (ko) * 2020-10-20 2023-01-09 한국화학연구원 메탄의 수증기 개질용 니켈계 촉매 및 이를 이용한 메탄의 수증기 개질 반응

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