RU2622383C2 - Прозрачные изделия из привитых сополимеров pvc - Google Patents
Прозрачные изделия из привитых сополимеров pvc Download PDFInfo
- Publication number
- RU2622383C2 RU2622383C2 RU2015138701A RU2015138701A RU2622383C2 RU 2622383 C2 RU2622383 C2 RU 2622383C2 RU 2015138701 A RU2015138701 A RU 2015138701A RU 2015138701 A RU2015138701 A RU 2015138701A RU 2622383 C2 RU2622383 C2 RU 2622383C2
- Authority
- RU
- Russia
- Prior art keywords
- grafted
- vinyl chloride
- copolymer
- glass transition
- transition temperature
- Prior art date
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- 229920000578 graft copolymer Polymers 0.000 title claims abstract description 12
- 229920001577 copolymer Polymers 0.000 claims abstract description 122
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims abstract description 34
- 230000009477 glass transition Effects 0.000 claims abstract description 34
- 238000000034 method Methods 0.000 claims abstract description 30
- 239000002245 particle Substances 0.000 claims abstract description 29
- 239000007787 solid Substances 0.000 claims abstract description 21
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 15
- 239000000178 monomer Substances 0.000 claims abstract description 14
- 239000004816 latex Substances 0.000 claims abstract description 8
- 229920000126 latex Polymers 0.000 claims abstract description 8
- 238000002255 vaccination Methods 0.000 claims description 48
- 239000000203 mixture Substances 0.000 claims description 46
- 239000003995 emulsifying agent Substances 0.000 claims description 13
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 9
- -1 vinyl compound Chemical class 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 6
- 238000002834 transmittance Methods 0.000 claims description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 6
- 238000001125 extrusion Methods 0.000 claims description 5
- 238000007334 copolymerization reaction Methods 0.000 claims description 4
- 238000003490 calendering Methods 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 238000001746 injection moulding Methods 0.000 claims description 3
- 238000009757 thermoplastic moulding Methods 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 239000004014 plasticizer Substances 0.000 abstract description 9
- 230000015572 biosynthetic process Effects 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 2
- 239000000839 emulsion Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000000758 substrate Substances 0.000 abstract 2
- 239000011521 glass Substances 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 description 29
- XXQBEVHPUKOQEO-UHFFFAOYSA-N potassium superoxide Chemical compound [K+].[K+].[O-][O-] XXQBEVHPUKOQEO-UHFFFAOYSA-N 0.000 description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 229920000915 polyvinyl chloride Polymers 0.000 description 18
- 239000004800 polyvinyl chloride Substances 0.000 description 17
- PYJBVGYZXWPIKK-UHFFFAOYSA-M potassium;tetradecanoate Chemical compound [K+].CCCCCCCCCCCCCC([O-])=O PYJBVGYZXWPIKK-UHFFFAOYSA-M 0.000 description 17
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 15
- 239000000047 product Substances 0.000 description 15
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 13
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 13
- 239000000243 solution Substances 0.000 description 12
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 11
- 239000011541 reaction mixture Substances 0.000 description 11
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
- 239000001110 calcium chloride Substances 0.000 description 9
- 229910001628 calcium chloride Inorganic materials 0.000 description 9
- 239000012065 filter cake Substances 0.000 description 9
- 238000005259 measurement Methods 0.000 description 9
- 239000001301 oxygen Substances 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 9
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 8
- 239000004641 Diallyl-phthalate Substances 0.000 description 7
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- 235000019589 hardness Nutrition 0.000 description 6
- 239000003999 initiator Substances 0.000 description 6
- 239000004793 Polystyrene Substances 0.000 description 5
- 229920002223 polystyrene Polymers 0.000 description 5
- 229960005070 ascorbic acid Drugs 0.000 description 4
- 235000010323 ascorbic acid Nutrition 0.000 description 4
- 239000011668 ascorbic acid Substances 0.000 description 4
- 229920000058 polyacrylate Polymers 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 229920002725 thermoplastic elastomer Polymers 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 3
- 229920012485 Plasticized Polyvinyl chloride Polymers 0.000 description 3
- 238000011081 inoculation Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 239000002174 Styrene-butadiene Substances 0.000 description 2
- 206010047289 Ventricular extrasystoles Diseases 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- SRBSSROHORQGBO-UHFFFAOYSA-N 11-methyldodecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCC(C)C SRBSSROHORQGBO-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JJBFVQSGPLGDNX-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)COC(=O)C(C)=C JJBFVQSGPLGDNX-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- ZVYGIPWYVVJFRW-UHFFFAOYSA-N 3-methylbutyl prop-2-enoate Chemical compound CC(C)CCOC(=O)C=C ZVYGIPWYVVJFRW-UHFFFAOYSA-N 0.000 description 1
- GFLJTEHFZZNCTR-UHFFFAOYSA-N 3-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OCCCOC(=O)C=C GFLJTEHFZZNCTR-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- 229920002633 Kraton (polymer) Polymers 0.000 description 1
- 229920003346 Levapren® Polymers 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 150000001253 acrylic acids Chemical class 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 125000005228 aryl sulfonate group Chemical group 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 125000005670 ethenylalkyl group Chemical group 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- GYDSPAVLTMAXHT-UHFFFAOYSA-N pentyl 2-methylprop-2-enoate Chemical compound CCCCCOC(=O)C(C)=C GYDSPAVLTMAXHT-UHFFFAOYSA-N 0.000 description 1
- ULDDEWDFUNBUCM-UHFFFAOYSA-N pentyl prop-2-enoate Chemical compound CCCCCOC(=O)C=C ULDDEWDFUNBUCM-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000036316 preload Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 229960005486 vaccine Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2013/052656 WO2014121851A1 (de) | 2013-02-11 | 2013-02-11 | Transparente artikel aus pfropfcopolymeren des pvc's |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2015138701A RU2015138701A (ru) | 2017-03-16 |
| RU2622383C2 true RU2622383C2 (ru) | 2017-06-15 |
Family
ID=47739234
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2015138701A RU2622383C2 (ru) | 2013-02-11 | 2013-02-11 | Прозрачные изделия из привитых сополимеров pvc |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US20160075811A1 (enExample) |
| EP (1) | EP2953981B1 (enExample) |
| JP (1) | JP6259837B2 (enExample) |
| CN (1) | CN105246921B (enExample) |
| BR (1) | BR112015019105B1 (enExample) |
| CA (1) | CA2900843C (enExample) |
| MX (1) | MX382495B (enExample) |
| RU (1) | RU2622383C2 (enExample) |
| UA (1) | UA117237C2 (enExample) |
| WO (1) | WO2014121851A1 (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2900843C (en) | 2013-02-11 | 2019-09-03 | Vestolit Gmbh & Co. Kg | Transparent articles from graft copolymers of pvc |
| WO2014121850A1 (de) | 2013-02-11 | 2014-08-14 | Vestolit Gmbh & Co. Kg | Transparente artikel aus pfropfcopolymeren des pvc's |
| ES2616140T3 (es) | 2013-02-11 | 2017-06-09 | Vestolit Gmbh | Artículo exento de plastificante constituido por copolímeros de injerto de PVC |
| JP7181054B2 (ja) * | 2018-10-31 | 2022-11-30 | 株式会社カネカ | グラフト共重合体の製造方法、及び成形体の製造方法。 |
| EP4071213B1 (de) * | 2021-04-06 | 2025-12-17 | Westlake Vinnolit GmbH & Co. KG | Weichmacherfreie flexible formmassen auf basis von vinylchlorid-pfropfcopolymeren |
| CN114196136B (zh) * | 2021-12-27 | 2023-02-28 | 广东远华新材料股份有限公司 | 一种pvc瑜伽垫及其制备方法 |
Citations (6)
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| SU481160A3 (ru) * | 1972-06-08 | 1975-08-15 | Лонца Аг,Гампель Валлис (Фирма) | Способ получени прозрачных, ударопрочных и атмосферостойких полимеров винилхлорида |
| US4981907A (en) * | 1987-10-23 | 1991-01-01 | Hoechst Aktiengesellschaft | Process for the preparation of an acrylate-vinyl chloride graft polymer |
| RU2021292C1 (ru) * | 1990-08-31 | 1994-10-15 | Хюльс АГ | Способ получения привитого сополимера |
| US5614049A (en) * | 1993-11-10 | 1997-03-25 | Wacker Chemie Gmbh | Use of aqueous dispersions of two-phase emulsion graft copolymers as binders for stiffening materials in the textile and leather industry |
| JP2003253082A (ja) * | 2002-02-27 | 2003-09-10 | Sekisui Chem Co Ltd | ポリ塩化ビニル系樹脂組成物 |
| RU2274647C2 (ru) * | 1999-12-07 | 2006-04-20 | Вестолит Гмбх Унд Ко Кг | Способ получения термопластичных формовочных масс |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2123384A1 (en) | 1971-05-12 | 1972-11-23 | Deutsche Solvay-Werke Gmbh, 5650 Solingen-Ohligs | Non-tacky vinyl chloride (co) polymer for moulded sheet - film,articles prodn |
| CH586722A5 (enExample) * | 1973-12-07 | 1977-04-15 | Lonza Ag | |
| FR2350361A1 (fr) | 1976-05-03 | 1977-12-02 | Solvay | Procede pour la polymerisation en suspension aqueuse du chlorure de vinyle |
| JPS6213414A (ja) * | 1985-07-12 | 1987-01-22 | Tokuyama Soda Co Ltd | 塩化ビニル架橋共重合体の製造方法 |
| DE3544235C2 (de) | 1985-12-14 | 1993-10-07 | Hoechst Ag | Formmasse zur Verarbeitung als Plastisol |
| DE3803036A1 (de) | 1988-02-02 | 1989-08-10 | Wacker Chemie Gmbh | Verfahren zur herstellung eines elastomerhaltigen vinylchloridpfropfcopolymerisats |
| DE4233052A1 (de) | 1992-10-01 | 1994-04-07 | Wacker Chemie Gmbh | Verfahren zur Herstellung von Vinylchlorid-Polymerisatmassen mit stufenlos einstellbaren Stoffeigenschaften |
| DE4334727A1 (de) | 1993-10-12 | 1995-04-13 | Vinnolit Kunststoff Gmbh | Thermoplastische Elastomere auf der Basis von Vinylchlorid-Pfropfcopolymerisaten |
| CN1053202C (zh) * | 1997-01-06 | 2000-06-07 | 中国石油化工集团公司北京化工研究院 | 高透明耐冲击聚氯乙烯的制造方法 |
| JP2000119349A (ja) | 1998-10-19 | 2000-04-25 | Sekisui Chem Co Ltd | 塩化ビニル系樹脂、その製造方法及び成形体 |
| JP2002285105A (ja) | 2001-01-22 | 2002-10-03 | Sony Chem Corp | 粘着剤組成物及び粘着シート |
| DE10121580A1 (de) | 2001-05-03 | 2002-11-14 | Vinnolit Gmbh & Co Kg | Schlagzähmodifier, Verfahren zu dessen Herstellung und Verwendung |
| AU2003222274A1 (en) | 2002-03-12 | 2003-09-29 | Dow Global Technologies Inc. | Linear ethylene/vinyl alcohol and ethylene/vinyl acetate polymers and process for making same |
| US20070149713A1 (en) | 2004-12-14 | 2007-06-28 | Kanaeka Corporation | Soft vinyl chloride copolymer resin, resin composition and process for preparing the same |
| US20090143547A1 (en) * | 2007-11-29 | 2009-06-04 | Cheng-Jung Lin | Method for producing a functional vinyl halide polymer |
| EP2067795A1 (en) * | 2007-12-04 | 2009-06-10 | Formosa Plastics Corporation | A method for producing a functional vinyl halide polymer |
| CA2900843C (en) | 2013-02-11 | 2019-09-03 | Vestolit Gmbh & Co. Kg | Transparent articles from graft copolymers of pvc |
| ES2616140T3 (es) | 2013-02-11 | 2017-06-09 | Vestolit Gmbh | Artículo exento de plastificante constituido por copolímeros de injerto de PVC |
| WO2014121850A1 (de) | 2013-02-11 | 2014-08-14 | Vestolit Gmbh & Co. Kg | Transparente artikel aus pfropfcopolymeren des pvc's |
-
2013
- 2013-02-11 CA CA2900843A patent/CA2900843C/en active Active
- 2013-02-11 EP EP13704922.7A patent/EP2953981B1/de active Active
- 2013-02-11 UA UAA201508726A patent/UA117237C2/uk unknown
- 2013-02-11 US US14/767,257 patent/US20160075811A1/en not_active Abandoned
- 2013-02-11 MX MX2015010335A patent/MX382495B/es unknown
- 2013-02-11 JP JP2015556402A patent/JP6259837B2/ja active Active
- 2013-02-11 BR BR112015019105-3A patent/BR112015019105B1/pt not_active IP Right Cessation
- 2013-02-11 WO PCT/EP2013/052656 patent/WO2014121851A1/de not_active Ceased
- 2013-02-11 RU RU2015138701A patent/RU2622383C2/ru active
- 2013-02-11 CN CN201380074420.8A patent/CN105246921B/zh not_active Expired - Fee Related
-
2018
- 2018-05-30 US US15/993,309 patent/US10407529B2/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU481160A3 (ru) * | 1972-06-08 | 1975-08-15 | Лонца Аг,Гампель Валлис (Фирма) | Способ получени прозрачных, ударопрочных и атмосферостойких полимеров винилхлорида |
| US4981907A (en) * | 1987-10-23 | 1991-01-01 | Hoechst Aktiengesellschaft | Process for the preparation of an acrylate-vinyl chloride graft polymer |
| RU2021292C1 (ru) * | 1990-08-31 | 1994-10-15 | Хюльс АГ | Способ получения привитого сополимера |
| US5614049A (en) * | 1993-11-10 | 1997-03-25 | Wacker Chemie Gmbh | Use of aqueous dispersions of two-phase emulsion graft copolymers as binders for stiffening materials in the textile and leather industry |
| RU2274647C2 (ru) * | 1999-12-07 | 2006-04-20 | Вестолит Гмбх Унд Ко Кг | Способ получения термопластичных формовочных масс |
| JP2003253082A (ja) * | 2002-02-27 | 2003-09-10 | Sekisui Chem Co Ltd | ポリ塩化ビニル系樹脂組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2015138701A (ru) | 2017-03-16 |
| US20180273666A1 (en) | 2018-09-27 |
| EP2953981A1 (de) | 2015-12-16 |
| MX2015010335A (es) | 2016-09-19 |
| UA117237C2 (uk) | 2018-07-10 |
| US20160075811A1 (en) | 2016-03-17 |
| JP2016506984A (ja) | 2016-03-07 |
| CA2900843C (en) | 2019-09-03 |
| BR112015019105A2 (pt) | 2017-07-18 |
| US10407529B2 (en) | 2019-09-10 |
| WO2014121851A1 (de) | 2014-08-14 |
| BR112015019105B1 (pt) | 2021-05-11 |
| CN105246921A (zh) | 2016-01-13 |
| CN105246921B (zh) | 2020-01-31 |
| CA2900843A1 (en) | 2014-08-14 |
| JP6259837B2 (ja) | 2018-01-10 |
| MX382495B (es) | 2025-03-13 |
| EP2953981B1 (de) | 2023-06-14 |
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