RU2592537C2 - Эластомерные нанокомпозиты, нанокомпозитные композиции и способы их получения - Google Patents
Эластомерные нанокомпозиты, нанокомпозитные композиции и способы их получения Download PDFInfo
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- RU2592537C2 RU2592537C2 RU2013130296/05A RU2013130296A RU2592537C2 RU 2592537 C2 RU2592537 C2 RU 2592537C2 RU 2013130296/05 A RU2013130296/05 A RU 2013130296/05A RU 2013130296 A RU2013130296 A RU 2013130296A RU 2592537 C2 RU2592537 C2 RU 2592537C2
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- Russia
- Prior art keywords
- nanocomposite
- rubber
- elastomeric
- nanoclay
- polymer
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- 239000002114 nanocomposite Substances 0.000 title claims abstract description 141
- 238000000034 method Methods 0.000 title claims description 62
- 239000000203 mixture Substances 0.000 title description 112
- 238000004519 manufacturing process Methods 0.000 title description 5
- 229920001971 elastomer Polymers 0.000 claims abstract description 166
- 239000012802 nanoclay Substances 0.000 claims abstract description 106
- 239000005060 rubber Substances 0.000 claims abstract description 103
- 239000006229 carbon black Substances 0.000 claims abstract description 63
- 230000035699 permeability Effects 0.000 claims abstract description 50
- 239000002245 particle Substances 0.000 claims abstract description 37
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 18
- 230000004888 barrier function Effects 0.000 claims abstract description 17
- 229910021647 smectite Inorganic materials 0.000 claims abstract description 8
- 241000872198 Serjania polyphylla Species 0.000 claims abstract 2
- 229920000642 polymer Polymers 0.000 claims description 105
- 239000004927 clay Substances 0.000 claims description 75
- 239000007789 gas Substances 0.000 claims description 74
- -1 volconskite Chemical compound 0.000 claims description 59
- 238000002156 mixing Methods 0.000 claims description 45
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- 239000000839 emulsion Substances 0.000 claims description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 13
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 12
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- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 8
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 8
- 229910052794 bromium Inorganic materials 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 8
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical group O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 7
- 229910000271 hectorite Inorganic materials 0.000 claims description 7
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 claims description 7
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 7
- 229910000273 nontronite Inorganic materials 0.000 claims description 7
- 229910000275 saponite Inorganic materials 0.000 claims description 7
- 239000000440 bentonite Substances 0.000 claims description 6
- 229910000278 bentonite Inorganic materials 0.000 claims description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 6
- VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 claims description 6
- 239000000460 chlorine Substances 0.000 claims description 6
- 229940094522 laponite Drugs 0.000 claims description 6
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 claims description 6
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- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 5
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- 239000012298 atmosphere Substances 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 4
- 229910001701 hydrotalcite Inorganic materials 0.000 claims description 4
- 229960001545 hydrotalcite Drugs 0.000 claims description 4
- 239000000155 melt Substances 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 239000000806 elastomer Substances 0.000 abstract description 63
- 239000000126 substance Substances 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 2
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- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 12
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- 229920002857 polybutadiene Polymers 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 8
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- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber; Homopolymers or copolymers of other iso-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/008—Additives improving gas barrier properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (3)
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| US13/013,551 US9200152B2 (en) | 2011-01-25 | 2011-01-25 | Elastomeric nanocomposites, nanocomposite compositions, and methods of manufacture |
| US13/013,551 | 2011-01-25 | ||
| PCT/US2011/063551 WO2012102788A2 (en) | 2011-01-25 | 2011-12-06 | Elastomeric nanocomposites, nanocomposite compositions, and methods of manufacture |
Publications (2)
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|---|---|
| RU2013130296A RU2013130296A (ru) | 2015-01-10 |
| RU2592537C2 true RU2592537C2 (ru) | 2016-07-20 |
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| RU2013130296/05A RU2592537C2 (ru) | 2011-01-25 | 2011-12-06 | Эластомерные нанокомпозиты, нанокомпозитные композиции и способы их получения |
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| Country | Link |
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| US (1) | US9200152B2 (OSRAM) |
| EP (1) | EP2668227B1 (OSRAM) |
| JP (1) | JP5890845B2 (OSRAM) |
| CN (1) | CN103328554B (OSRAM) |
| CA (1) | CA2823023C (OSRAM) |
| RU (1) | RU2592537C2 (OSRAM) |
| SG (1) | SG191178A1 (OSRAM) |
| WO (1) | WO2012102788A2 (OSRAM) |
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| KR20140010298A (ko) * | 2012-07-16 | 2014-01-24 | 삼성전기주식회사 | 터치패널 |
| CN104619760B (zh) | 2012-08-02 | 2016-10-26 | 阿米利尔股份公司 | 含纳米碳的天然橡胶 |
| WO2014183024A1 (en) * | 2013-05-09 | 2014-11-13 | University Of Houston | Solution based polymer nanofiller-composites synthesis |
| US20170022658A1 (en) * | 2015-07-20 | 2017-01-26 | Goodrich Corporation | Gas barrier fabric |
| ITUB20153918A1 (it) * | 2015-09-25 | 2017-03-25 | Manuli Rubber Ind Spa | Tubo flessibile multistrato |
| CN105330920B (zh) * | 2015-11-20 | 2017-05-24 | 浙江世泰实业有限公司 | 一种丁基橡胶及其制备方法 |
| JP6817145B2 (ja) * | 2017-05-29 | 2021-01-20 | エルジー ディスプレイ カンパニー リミテッド | 有機電界発光装置および有機電界発光装置の製造方法 |
| JP6958838B2 (ja) * | 2017-12-08 | 2021-11-02 | 株式会社ブリヂストン | ゴム組成物、インナーライナーゴム、及びタイヤ |
| US11281257B2 (en) | 2017-12-14 | 2022-03-22 | Hewlett-Packard Development Company, L.P. | Housings with energy absorbing materials |
| CN110396252A (zh) * | 2018-04-24 | 2019-11-01 | 中国石油化工股份有限公司 | 纳米复合材料的制备方法与硫化橡胶的制备方法 |
| CN114921132B (zh) * | 2022-05-19 | 2024-03-01 | 山西长生伟业热能科技有限公司 | 一种温室大棚专用聚能纳米浆料 |
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| WO2010044776A1 (en) * | 2008-10-14 | 2010-04-22 | Exxonmobil Chemical Patents Inc. | Polymer-clay nanocomposite and process for preparing same |
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- 2011-12-06 WO PCT/US2011/063551 patent/WO2012102788A2/en not_active Ceased
- 2011-12-06 SG SG2013046149A patent/SG191178A1/en unknown
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- 2011-12-06 CA CA2823023A patent/CA2823023C/en not_active Expired - Fee Related
- 2011-12-06 EP EP11807803.9A patent/EP2668227B1/en not_active Not-in-force
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| WO2010044776A1 (en) * | 2008-10-14 | 2010-04-22 | Exxonmobil Chemical Patents Inc. | Polymer-clay nanocomposite and process for preparing same |
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| SG191178A1 (en) | 2013-07-31 |
| CN103328554B (zh) | 2016-03-16 |
| WO2012102788A8 (en) | 2012-12-06 |
| EP2668227B1 (en) | 2017-04-12 |
| RU2013130296A (ru) | 2015-01-10 |
| CA2823023C (en) | 2017-07-18 |
| US9200152B2 (en) | 2015-12-01 |
| CN103328554A (zh) | 2013-09-25 |
| EP2668227A2 (en) | 2013-12-04 |
| JP2014503028A (ja) | 2014-02-06 |
| WO2012102788A3 (en) | 2013-02-14 |
| CA2823023A1 (en) | 2012-08-02 |
| US20120190772A1 (en) | 2012-07-26 |
| JP5890845B2 (ja) | 2016-03-22 |
| WO2012102788A2 (en) | 2012-08-02 |
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