JP5017102B2 - エラストマー組成物、空気バリア、及びこれらの製造方法 - Google Patents
エラストマー組成物、空気バリア、及びこれらの製造方法 Download PDFInfo
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- JP5017102B2 JP5017102B2 JP2007516621A JP2007516621A JP5017102B2 JP 5017102 B2 JP5017102 B2 JP 5017102B2 JP 2007516621 A JP2007516621 A JP 2007516621A JP 2007516621 A JP2007516621 A JP 2007516621A JP 5017102 B2 JP5017102 B2 JP 5017102B2
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- JP
- Japan
- Prior art keywords
- copolymer
- rubber
- elastomer composition
- isobutylene
- cured elastomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000009826 distribution Methods 0.000 claims abstract description 54
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- 239000005060 rubber Substances 0.000 claims description 112
- 239000003085 diluting agent Substances 0.000 claims description 108
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 82
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- 150000007517 lewis acids Chemical class 0.000 claims description 30
- 239000003795 chemical substances by application Substances 0.000 claims description 28
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- 125000000217 alkyl group Chemical group 0.000 description 12
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 12
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- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- UMNKXPULIDJLSU-UHFFFAOYSA-N dichlorofluoromethane Chemical compound FC(Cl)Cl UMNKXPULIDJLSU-UHFFFAOYSA-N 0.000 description 1
- 229940099364 dichlorofluoromethane Drugs 0.000 description 1
- 125000004772 dichloromethyl group Chemical group [H]C(Cl)(Cl)* 0.000 description 1
- 229940087091 dichlorotetrafluoroethane Drugs 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- 125000001028 difluoromethyl group Chemical group [H]C(F)(F)* 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical compound C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- GCSJLQSCSDMKTP-UHFFFAOYSA-N ethenyl(trimethyl)silane Chemical compound C[Si](C)(C)C=C GCSJLQSCSDMKTP-UHFFFAOYSA-N 0.000 description 1
- WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 description 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 210000003746 feather Anatomy 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- SKRPCQXQBBHPKO-UHFFFAOYSA-N fluorocyclobutane Chemical compound FC1CCC1 SKRPCQXQBBHPKO-UHFFFAOYSA-N 0.000 description 1
- UHCBBWUQDAVSMS-UHFFFAOYSA-N fluoroethane Chemical compound CCF UHCBBWUQDAVSMS-UHFFFAOYSA-N 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 229940083123 ganglion-blocking adreneregic sulfonium derivative Drugs 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000002357 guanidines Chemical class 0.000 description 1
- 125000004968 halobutyl group Chemical group 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- UKACHOXRXFQJFN-UHFFFAOYSA-N heptafluoropropane Chemical compound FC(F)C(F)(F)C(F)(F)F UKACHOXRXFQJFN-UHFFFAOYSA-N 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229910052743 krypton Inorganic materials 0.000 description 1
- DNNSSWSSYDEUBZ-UHFFFAOYSA-N krypton atom Chemical compound [Kr] DNNSSWSSYDEUBZ-UHFFFAOYSA-N 0.000 description 1
- 229940094522 laponite Drugs 0.000 description 1
- 239000011968 lewis acid catalyst Substances 0.000 description 1
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- NRQNMMBQPIGPTB-UHFFFAOYSA-N methylaluminum Chemical compound [CH3].[Al] NRQNMMBQPIGPTB-UHFFFAOYSA-N 0.000 description 1
- YSTQWZZQKCCBAY-UHFFFAOYSA-L methylaluminum(2+);dichloride Chemical compound C[Al](Cl)Cl YSTQWZZQKCCBAY-UHFFFAOYSA-L 0.000 description 1
- NFWSQSCIDYBUOU-UHFFFAOYSA-N methylcyclopentadiene Chemical compound CC1=CC=CC1 NFWSQSCIDYBUOU-UHFFFAOYSA-N 0.000 description 1
- 229940073584 methylene chloride Drugs 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
- SNMVRZFUUCLYTO-UHFFFAOYSA-N n-propyl chloride Chemical compound CCCCl SNMVRZFUUCLYTO-UHFFFAOYSA-N 0.000 description 1
- 229910052754 neon Inorganic materials 0.000 description 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- VOHXSQNVXBUESN-UHFFFAOYSA-N nitrocyclodecane Chemical compound [O-][N+](=O)C1CCCCCCCCC1 VOHXSQNVXBUESN-UHFFFAOYSA-N 0.000 description 1
- WGQSPSMCVCWUDO-UHFFFAOYSA-N nitrocyclododecane Chemical compound [O-][N+](=O)C1CCCCCCCCCCC1 WGQSPSMCVCWUDO-UHFFFAOYSA-N 0.000 description 1
- LACLQAUWSKAKQJ-UHFFFAOYSA-N nitrocycloheptane Chemical compound [O-][N+](=O)C1CCCCCC1 LACLQAUWSKAKQJ-UHFFFAOYSA-N 0.000 description 1
- NJNQUTDUIPVROZ-UHFFFAOYSA-N nitrocyclohexane Chemical compound [O-][N+](=O)C1CCCCC1 NJNQUTDUIPVROZ-UHFFFAOYSA-N 0.000 description 1
- COJLRPBUSNPNMK-UHFFFAOYSA-N nitrocyclononane Chemical compound [O-][N+](=O)C1CCCCCCCC1 COJLRPBUSNPNMK-UHFFFAOYSA-N 0.000 description 1
- SKGLKPZSDNHVMF-UHFFFAOYSA-N nitrocyclooctane Chemical compound [O-][N+](=O)C1CCCCCCC1 SKGLKPZSDNHVMF-UHFFFAOYSA-N 0.000 description 1
- SYSLARHICMEYEQ-UHFFFAOYSA-N nitrocyclopropane Chemical compound [O-][N+](=O)C1CC1 SYSLARHICMEYEQ-UHFFFAOYSA-N 0.000 description 1
- BZYMCQZQEWLJHB-UHFFFAOYSA-N nitrocycloundecane Chemical compound [O-][N+](=O)C1CCCCCCCCCC1 BZYMCQZQEWLJHB-UHFFFAOYSA-N 0.000 description 1
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- ZCYXXKJEDCHMGH-UHFFFAOYSA-N nonane Chemical compound CCCC[CH]CCCC ZCYXXKJEDCHMGH-UHFFFAOYSA-N 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- BKIMMITUMNQMOS-UHFFFAOYSA-N normal nonane Natural products CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- QRMPKOFEUHIBNM-UHFFFAOYSA-N p-dimethylcyclohexane Natural products CC1CCC(C)CC1 QRMPKOFEUHIBNM-UHFFFAOYSA-N 0.000 description 1
- 239000010690 paraffinic oil Substances 0.000 description 1
- GTLACDSXYULKMZ-UHFFFAOYSA-N pentafluoroethane Chemical compound FC(F)C(F)(F)F GTLACDSXYULKMZ-UHFFFAOYSA-N 0.000 description 1
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 229910052615 phyllosilicate Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000012088 reference solution Substances 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 238000013040 rubber vulcanization Methods 0.000 description 1
- 229910000275 saponite Inorganic materials 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910000276 sauconite Inorganic materials 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 229920006132 styrene block copolymer Polymers 0.000 description 1
- NVBFHJWHLNUMCV-UHFFFAOYSA-N sulfamide Chemical compound NS(N)(=O)=O NVBFHJWHLNUMCV-UHFFFAOYSA-N 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000010059 sulfur vulcanization Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 150000005377 tertiary alkyl halides Chemical class 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 238000002076 thermal analysis method Methods 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
- C08L23/283—Halogenated homo- or copolymers of iso-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S152/00—Resilient tires and wheels
- Y10S152/16—Air impermeable liner
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Laminated Bodies (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Description
それゆえ、粒子の凝集を低減し、及び/又はメチルクロライドのような塩化炭化水素の量を減らす新しい重合システムを作り出すための、希釈剤又は希釈剤の混合物を見つけ出すことが望まれている。更に、このような方法を用いた新しいポリマーを見つけることはエラストマーに対する世界的需要を増加させ、及び/又は新しい最終製品を提供することにもなる。
式
F=mA/(1+mA)2
(式中、mはコポリマー配列分布パラメーターであり、Aはコポリマー中のイソオレフィン対マルチオレフィンのモル比であり、Fはコポリマー中のイソオレフィン−マルチオレフィン−マルチオレフィントライアド分画であり、mは1.5より大きい)、で定義されるコポリマー配列分布を有する。
式
F=mA/(1+mA)2
(式中、mはコポリマー配列分布パラメーターであり、Aはコポリマー中のイソオレフィンに対するマルチオレフィンのモル比であり、Fはコポリマー中のイソオレフィン−マルチオレフィン−マルチオレフィントライアド分画であり、mは1.10乃至1.25である)
で定義される配列分布を有する。
式
F=mA/(1+mA)2
(式中、mはコポリマー配列分布パラメーターであり、Aはコポリマー中のマルチオレフィンに対するイソオレフィンのモル比であり、Fはコポリマー中のイソオレフィン−マルチオレフィン−マルチオレフィントライアド分画であり、mは1.5以上か又は1.10乃至1.25である、
で定義される配列分布を有する。
式
F=1−{m−A/(1+mA)}
(式中mはコポリマー配列分布パラメーターであり、Aはコポリマー中のイソオレフィンに対するアルキルスチレンのモル比であり、Fはコポリマー中のアルキルスチレン−イソオレフィン−アルキルスチレントライアド分画であり、mは38未満である)
で定義されるコポリマー配列分布を有する。
式
F=1−{m−A/(1+mA)}
(式中、mはコポリマー配列分布パラメーターであり、Aはコポリマー中のイソオレフィンに対するアルキルスチレンのモル比であり、Fはコポリマー中のアルキルスチレン−イソオレフィン−アルキルスチレントライアド分画であり、mは38未満である)
で、定義されるコポリマー配列分布を有する。
本発明の様々な特定の態様、バージョン、および具体例を、請求する発明の理解のためにここで採用される好ましい態様および定義を含めて以下に記載する。侵害の判断にあっては、本発明の範囲は、いずれか任意の1以上のクレームその均等物、および記載された要件または制限を参照して決定される。
パラメーターK及びαはMwに対する固有粘度の両対数プロットにより得られる。αは傾きで、Kは切片である。確定された直鎖スタンダードに対する相関の有意偏差は長鎖分岐の存在を示している。一般的に、直鎖関係に対して有意な偏差を示すポリマーはより多くの長鎖分岐を含んでいる。スケーリングファクターg’もまた確立された直鎖関係に対する偏差を示している。
g’の値は、1以下、0以上と定義される。g’が1に等しいかこれに近いとき、サンプルは長鎖分岐を実質的に有しない。例えば、E.F. Casassa and G.C. Berry in Comprehensive Polymer Science, Vol. 2, (71−120) G. Allen and J.C. Bevington, Ed., Pergamon Press, New York, 1988参照のこと。三重検出SECにおいて、g’はクロマトグラフのカーブの一部のデータより計算される。粘性の平均g’vis.ave.は全体の分子重量分布から計算される。
特定の態様において、実質的に長鎖分岐を有しないポリマーは上で定義された三重検出SECにより決定されるg’vis.ave.が、0.978以上、あるいは0.980以上、あるいは0.985以上、あるいは0.990以上、あるいは0.995以上、あるいは、0.998以上、あるいは0.999以上であるポリマーであると定義される。国際公報US03/40341号に詳細が記されている。
式中、mはコポリマー配列分布パラメーター
Aはコポリマー、[IP]/[IB]中のイソブチレンに対するイソプレンのモル比である、
Fはコポリマー中のBIIトライアド分画である。
式中、A=2.8ppm共鳴のインテグラル値
B=2.6乃至2.2ppmの共鳴のインテグラル値。
式中、mはコポリマー配列分布パラメーター、
Aはコポリマー中のイソブチレンに対するイソプレンのモル比、[PMS]/[IB]、
FBSBは、コポリマー中のBSBトライアド分画。
本発明のシステムにより重合されるモノマーは、本発明を用いて重合することができるあらゆる炭化水素モノマーを含む。好ましいモノマーはオレフィンの1以上、置換オレフィン類、イソオレフィン、共役ジエン、非共役ジエン、スチレン及び/又は置換スチレン及びビニルエーテルを含む、前記スチレンはアルキル、アリル、ハライド、アルコキシ基により環上で置換されている。好ましくは、モノマーは、2乃至20炭素原子、より好ましくは2乃至9、より好ましくは3乃至9の炭素原子を含む。好ましいオレフィンの例はスチレン、パラ−アルキルスチレン、パラ−メチルスチレン、アルファ−メチルスチレン、ジビニルベンゼン、ジイソプロピルベンゼン、イソブチレン、2−メチル−1−ブテン、3−メチル−1−ブテン、2−メチル−2−ペンテン、イソプレン、ブタジエン、2,3−ジメチル−1,3−ブタジエン、β−ピネン、ミルセン、6,6−ジメチル−フルベン、ヘキサジエン、シクロペンタジエン、ピペリルネン、メチルビニルエーテル、エチルビニルエーテル、及びイソブチルビニルエーテル並びに同種のものを含む。モノマーは2以上のモノマーの組み合わせでもよい。スチレンブロックコポリマーもモノマーに用いることができる。好ましいブロックコポリマーはスチレン、パラ−メチルスチレン、アルファ−メチルスチレン等のスチレンのコポリマー、及びイソプレン、ブタジエン等のC4乃至C30ジオレフィン及び同種のものを含む。特に好ましいモノマーの組み合わせは、1)イソブチレン及びパラメチルスチレン、2)イソブチレン及びイソプレン、イソブチレンのホモポリマーも含む。
F=mA/(1+mA)2
式中、mはコポリマー配列分布パラメーター、
Aはコポリマー中のイソオレフィンに対するマルチオレフィンのモル比
Bはコポリマー中のイソオレフィン−マルチオレフィン−マルチオレフィントライアド分画。
F=1−{mA/(1+mA)}
式中、mはコポリマー配列分布パラメーター
Aはコポリマー中のイソオレフィンに対するp−アルキルスチレンのモル比、及び
Fはコポリマー中のp−アルキルスチレン−イソオレフィン−p−アルキルスチレントライアド分画。
臭素、アルミニウム、ガリウム、インジウム、チタニウム、ジルコニウム、スズ、バナジウム、ヒ素、アンチモン、及びビスマスを含む元素周期表の4、5、13、14及び15族の金属に基づくあらゆるルイス酸(共開始剤又は触媒とも言う)を用いることができる。当業者は本発明の実施に有用なルイス酸がわかる。1つの態様において、前記金属は、アルミニウム、臭素、及びチタニウムであり、アルミニウムが好ましい、代表的な例は、AlCl3、(アルキル)AlCl2、(C2H5)AlCl、及び(C2H5)3Al2Cl 3 、SnCl4、TiCl4を含む。
本発明に有用な開始剤は、選ばれたルイス酸と好適な希釈剤中で、オレフィンと素早く複合体を生成することができる開始剤であり。このような開始剤により成長反応するポリマー鎖が形成される。代表的な例は、H2O、HCl、RCOOH(Rはアルキル基)等のブロンステッド酸(Bronsted acid)及び(CH3)3CCl、C6H5C(CH3)2Cl及び(2−クロロ−2,4,4−トリメチルペンタン)等のアルキルハライドを含む。活性化された弱配位ルイス酸又はルイス酸塩がイソブチレン重合の開始剤に用いられてきた時のように、一部触媒システムとして作用することができるメタロセン及び他のそのような遷移金属がイソブチレン重合を開始するために用いられる。
ハイドロフルオロカーボンは、好ましくは、本発明において単独並びに他のハイドロフルオロカーボン又は他の希釈剤と共に、希釈剤として用いられる。本発明又は特許請求の範囲の目的のために、ハイドロフルオロカーボン(「HFC」又は「HFC」)は、少なくとも1つの炭素、少なくとも1つの水素、および少なくとも1つのフッ素が存在することを条件として、主要には水素、炭素およびフッ素から構成される飽和または不飽和の化合物と定義される。
本発明は連続及びバッチ工程において行われる。更に、本発明は栓流反応槽及び/又は撹拌タンク反応槽において行われる。特に、本発明は「ブチル反応槽」において行われる。代表的な例は、定流撹拌タンク反応槽、栓流反応槽、流動床ベルト又はドラム反応槽、ジェット又はノズル反応槽、管型反応装置、及び自動冷凍煮沸プール反応槽から選択される。
上で説明する本発明にしたがって製造されたポリマーは、最終製品へ製造されるエラストマー組成物を製造するために当該分野において既知の他の成分と混合される。例えば、エラストマー組成物は少なくとも1つのプラストマーを含む。
硬化性は、表示温度及び3弧度(degree arc)においてODR2000を用いて測定した。試験試料は、T90+適切な成形ラグ(mold lag)に対応する時間の間、表示温度(典型的には、150℃乃至160℃)において硬化させた。可能である場合には、標準ASTM試験を用いて、硬化化合物の物理的性質を評価した。応力/歪関係(引張り強度、破断点伸び、モジュラス値、破断エネルギー)は、インストロン4202を用いて、室温で測定した。ショアーA硬度は、Zwick Duromaticを用いて、室温で測定した。100%モジュラスの測定における誤差(2σ)は、±0.11MPa単位であり、伸びの測定における誤差(2σ)は、±13%単位である。
本発明はゴム組成物における本明細書で開示される新規な合成法に従って作られたブチルゴムの適用である。前記組成物は自転車、旅客自動車、トラック、バス、及び多の乗り物におけるインナーチューブとしての使用に適している。以下の例示された組成物及び表を参照することにより本発明をよりよく理解することができるが、本発明をこれらに限定することを意図していない。用いられる成分及びその市販元の概要を表5に示す。実施例において提案された組成物は表6に、百分率で示す。近年の商用方法により作られたブチルゴムに対するこれらの予測される試験性質を表7にまとめた(これらの予測される試験性質は表16および18に示されるように実証された)。市販のブチルゴムを用いた化合物に対する結果は100で示し、改良された点は増加分の値で示される。
本発明はゴム組成物における本明細書で開示される新規な合成法に従って作られた臭化ブチルゴムの適用である。前記組成物は自転車、旅客自動車、トラック、バス、及び多の乗り物におけるインナーチューブとしての使用に適している。
本発明はゴム組成物における本明細書で開示される新規な合成法に従って作られた臭化ブチルゴムの適用である。前記組成物は自転車、旅客自動車、トラック、バス、及び多の乗り物におけるインナーチューブとしての使用に適している。
本発明はゴム組成物における本明細書で開示される新規な合成法に従って作られた臭化イソブチレン−co−パラ−メチルスチレンゴムの適用である。前記組成物は自転車、旅客自動車、トラック、バス、及び多の乗り物におけるインナーチューブとしての使用に適している。
本発明はゴム組成物における本明細書で開示される新規な合成法に従って作られたブチルゴムの適用である。前記組成物は自転車、旅客自動車、トラック、バス、及び多の乗り物におけるインナーチューブとしての使用に適しており、エクソンモービル ケミカル カンパニー(ヒューストン、テキサス)から入手可能である。以下の実施例及び表を参照することにより本明細書をよりよく理解することができるが、本発明をこれらに限定することは意図しない。
本発明はゴム組成物における本明細書で開示される新規な合成法に従って作られたブチルゴムの適用である。前記組成物は自転車、旅客自動車、トラック、バス、及び多の乗り物におけるインナーチューブとしての使用に適しており、エクソンモービル ケミカル カンパニー(ヒューストン、テキサス)から入手可能である。
本発明はゴム組成物における本明細書で開示される新規な合成法に従って作られた臭化ブチルゴムの適用である。前記組成物は自転車、旅客自動車、トラック、バス、及び多の乗り物におけるインナーチューブとしての使用に適しており、エクソンモービル ケミカル カンパニー (ヒューストン、テキサス)から入手可能である。
本発明はゴム組成物における本明細書で開示される新規な合成法に従って作られた臭化ブチルゴムの適用である。前記組成物は自転車、旅客自動車、トラック、バス、及び多の乗り物におけるインナーチューブとしての使用に適しており、エクソンモービル ケミカル カンパニー (ヒューストン、テキサス)から入手可能である。
本発明はゴム組成物における本明細書で開示される新規な合成法に従って作られた臭化ブチルゴムの適用である。前記組成物は自転車、旅客自動車、トラック、バス、及び多の乗り物におけるインナーチューブとしての使用に適しており、エクソンモービル ケミカル カンパニー (ヒューストン、テキサス)から入手可能である。
Claims (21)
- イソブチレン、マルチオレフィン、1以上のルイス酸(三フッ化ホウ素を除く)、1以上の開始剤及び1以上のハイドロフルオロカーボンを含む希釈剤を接触させる工程を含む方法により製造されたコポリマーであって、三重検出サイズ排除クロマトグラフィーにより測定して、0.978以上のg’vis.avg.を有するコポリマーを含む硬化エラストマー組成物。
- 前記マルチオレフィンが共役ジエンであることを特徴とする、請求項1に記載の硬化エラストマー組成物。
- マルチオレフィン含量が前記コポリマー中のイソブチレン及びマルチオレフィンの総モル数に基づいて0.5モル%より大きいことを特徴とする請求項1又は2に記載の硬化エラストマー組成物。
- 前記コポリマーが2より大きい分子量分布を有することを特徴とする請求項1乃至3のいずれか1項に記載の硬化エラストマー組成物。
- 前記マルチオレフィンがメチルスチレンであることを特徴とする請求項1乃至4のいずれか1項に記載の硬化エラストマー組成物。
- 前記メチルスチレン含量が前記コポリマー中のイソブチレン及びメチルスチレンの総モル数をもとにして0.5モル%より大きいことを特徴とする請求項5に記載の硬化エラストマー組成物。
- 前記コポリマーがハロゲン化コポリマーを形成するためにハロゲン化されることを特徴とする請求項1乃至6のいずれか1項に記載の硬化エラストマー組成物。
- 前記ハロゲン化コポリマーが塩素又は臭素によりハロゲン化されることを特徴とする請求項7に記載の硬化エラストマー組成物。
- ハロゲン含量が前記ハロゲン化されたコポリマーに重量に基づいて0.5重量%より大きいことを特徴とする請求項7又は8に記載の硬化エラストマー組成物。
- 前記コポリマーが50,000より大きい重量平均分子量を有することを特徴とする請求項1乃至9のいずれか1請求項に記載の硬化エラストマー組成物。
- 前記コポリマーが少なくとも20±5(125℃においてML1+8、ASTM D1646)のムーニー粘度を有することを特徴とする請求項1乃至10のいずれか1請求項に記載の硬化エラストマー組成物。
- 少なくとも1の天然ゴム、ポリイソプレンゴム、ポリ(スチレン−co−ブタジエン)ゴム(SBR)、ポリブタジエンゴム(BR)、ポリ(イソプレン−co−ブタジエン)ゴム(IBR)、スチレン−イソプレン−ブタジエンゴム(SIBR)、エチレン−プロピレンゴム(EPR)、エチレン−プロピレン−ジエンゴム(EPDM)、ポリスチレン、イソブチレン/メチルシクロペンタジエンコポリマーゴム、イソブチレン/メチルシクロペンタジエンコポリマーゴム、二トリルゴム、プロピレンオキサイドポリマー、星状分岐ブチルゴム及びハロゲン化星状分岐ブチルゴム、臭素化ブチルゴム、塩素化ブチルゴム、星状分岐ポリイソブチレンゴム、星状分岐臭素化ブチル(ポリイソブチレン/イソプレンコポリマー)ゴム、ポリ(イソブチレン−co−p−メチルスチレン)及びハロゲン化ポリ(イソブチレン−co−p−メチルスチレン)、ハロゲン化ポリ(イソブチレン−co−イソプレン−co−p−メチルスチレン)、ポリ((イソブチレン−co−イソプレン−co−スチレン)、ハロゲン化ポリ(イソブチレン−co−イソプレン−co−スチレン)、ポリ(イソブチレン−co−イソプレン−co−α−メチルスチレン)ハロゲン化ポリ(イソブチレン−co−イソプレン−co−α−メチルスチレン)又はこれらの混合物を含む、ブレンドを更に含む、請求項1乃至11のいずれか1請求項に記載の硬化エラストマー組成物。
- 前記硬化エラストマー組成物が充填剤を含み、前記充填剤がカーボンブラック、修飾カーボンブラック、シリケート、カーボネート、クレイ、剥離クレイ、有機分子で処理したクレイ、又はこれらの混合物を含むことを特徴とする請求項1乃至12のいずれか1請求項に記載の硬化エラストマー組成物。
- 前記硬化エラストマー組成物が加工助剤を含むことを特徴とする請求項1乃至13のいずれか1請求項に記載の硬化エラストマー組成物。
- 前記加工助剤がミネラルオイル、ポリブテン加工助剤、プラストマー、パラフィンオイル、及びこれらの混合物からなる群より選択され、前記プラストマーがエチレン誘導単位及び前記プラストマーの重量に基づいて10wt%乃至30wt%のC3乃至C10α−オレフィン誘導単位を含むことを特徴とする請求項14に記載の硬化エラストマー組成物。
- 前記プラストマーが0.1乃至10dg/分のメルトインデックスを有することを特徴とする請求項15に記載の硬化エラストマー組成物。
- 前記プラストマーが前記硬化エラストマー組成物中に2乃至20phrの幅で存在することを特徴とする請求項15に記載の硬化エラストマー組成物。
- 前記硬化エラストマー組成物が、硫黄、硫黄ベース化合物、金属酸化物、金属酸化物複合体、脂肪酸、ペルオキサイド、ジアミン、又はこれらの混合物から選択される硬化剤で未硬化エラストマー組成物を硬化することにより得られたものであることを特徴とする請求項1乃至17のいずれか1請求項に記載の硬化エラストマー組成物。
- 空気膜において請求項1乃至18のいずれか1請求項に記載の硬化エラストマー組成物を使用する方法。
- 請求項1乃至19のいずれか1請求項に記載の硬化エラストマー組成物を含む製品。
- 前記製品が空気膜である請求項20に記載の製品。
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US20110060086A1 (en) * | 2009-09-10 | 2011-03-10 | Michael Brendan Rodgers | Elastomeric Copolymers, Copolymer Compositions, and Their Use in Articles |
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US7659355B2 (en) | 2010-02-09 |
WO2006002033A1 (en) | 2006-01-05 |
EP1765930B1 (en) | 2009-04-08 |
CA2755329C (en) | 2014-03-25 |
DE602005013782D1 (de) | 2009-05-20 |
CN101010377A (zh) | 2007-08-01 |
EP1765930A1 (en) | 2007-03-28 |
CA2581050C (en) | 2012-01-10 |
CA2581050A1 (en) | 2006-01-05 |
JP2008502778A (ja) | 2008-01-31 |
CN101010377B (zh) | 2010-11-24 |
CA2755329A1 (en) | 2006-01-05 |
ATE427980T1 (de) | 2009-04-15 |
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