RU2573412C2 - Способ получения гранулята, содержащего одну или несколько солей комплексообразователя - Google Patents
Способ получения гранулята, содержащего одну или несколько солей комплексообразователя Download PDFInfo
- Publication number
- RU2573412C2 RU2573412C2 RU2013119414/04A RU2013119414A RU2573412C2 RU 2573412 C2 RU2573412 C2 RU 2573412C2 RU 2013119414/04 A RU2013119414/04 A RU 2013119414/04A RU 2013119414 A RU2013119414 A RU 2013119414A RU 2573412 C2 RU2573412 C2 RU 2573412C2
- Authority
- RU
- Russia
- Prior art keywords
- vortex
- zone
- aqueous solution
- hydrogen atom
- vortex apparatus
- Prior art date
Links
- 150000003839 salts Chemical class 0.000 title claims abstract description 20
- 239000008139 complexing agent Substances 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title abstract description 9
- 239000008188 pellet Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 claims abstract description 23
- 239000002245 particle Substances 0.000 claims abstract description 20
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 8
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 8
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 4
- 125000001424 substituent group Chemical group 0.000 claims abstract description 4
- 239000007864 aqueous solution Substances 0.000 claims description 26
- 239000008187 granular material Substances 0.000 claims description 20
- 239000007789 gas Substances 0.000 claims description 9
- 239000000428 dust Substances 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 3
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 3
- 125000003342 alkenyl group Chemical group 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical group 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 238000010327 methods by industry Methods 0.000 abstract 1
- 238000005469 granulation Methods 0.000 description 5
- 230000003179 granulation Effects 0.000 description 5
- -1 methylglycine-N Chemical class 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- OHOTVSOGTVKXEL-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]propanoate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C(C)N(CC([O-])=O)CC([O-])=O OHOTVSOGTVKXEL-UHFFFAOYSA-K 0.000 description 5
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 4
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000001694 spray drying Methods 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- 101100345345 Arabidopsis thaliana MGD1 gene Proteins 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 239000000543 intermediate Substances 0.000 description 2
- 241000234282 Allium Species 0.000 description 1
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 1
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Natural products NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 108010077895 Sarcosine Proteins 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 238000005904 alkaline hydrolysis reaction Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- OUDSFQBUEBFSPS-UHFFFAOYSA-N ethylenediaminetriacetic acid Chemical compound OC(=O)CNCCN(CC(O)=O)CC(O)=O OUDSFQBUEBFSPS-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- BSRDNMMLQYNQQD-UHFFFAOYSA-N iminodiacetonitrile Chemical compound N#CCNCC#N BSRDNMMLQYNQQD-UHFFFAOYSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000723 toxicological property Toxicity 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C227/38—Separation; Purification; Stabilisation; Use of additives
- C07C227/40—Separation; Purification
- C07C227/42—Crystallisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
- B01J2/02—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops
- B01J2/06—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops in a liquid medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
- B01J2/16—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by suspending the powder material in a gas, e.g. in fluidised beds or as a falling curtain
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
- Medicinal Preparation (AREA)
- Glanulating (AREA)
- Seasonings (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10180031 | 2010-09-27 | ||
| EP10180031.6 | 2010-09-27 | ||
| PCT/EP2011/066376 WO2012041741A1 (de) | 2010-09-27 | 2011-09-21 | Verfahren zur herstellung eines granulates enthaltend eines oder mehrere komplexbildnersalze |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2013119414A RU2013119414A (ru) | 2014-11-10 |
| RU2573412C2 true RU2573412C2 (ru) | 2016-01-20 |
Family
ID=44654118
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2013119414/04A RU2573412C2 (ru) | 2010-09-27 | 2011-09-21 | Способ получения гранулята, содержащего одну или несколько солей комплексообразователя |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP2621892B1 (enExample) |
| JP (1) | JP5919278B2 (enExample) |
| KR (1) | KR101897991B1 (enExample) |
| CN (1) | CN103124720B (enExample) |
| BR (1) | BR112013006404A2 (enExample) |
| CA (1) | CA2809749A1 (enExample) |
| ES (1) | ES2547417T3 (enExample) |
| MX (1) | MX342570B (enExample) |
| MY (1) | MY160461A (enExample) |
| PL (1) | PL2621892T3 (enExample) |
| RU (1) | RU2573412C2 (enExample) |
| WO (1) | WO2012041741A1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112018011578A2 (pt) * | 2015-12-11 | 2018-11-27 | Basf Se | processo para fabricação de grânulos |
| BR112018075476B1 (pt) * | 2016-06-20 | 2022-10-04 | Basf Se | Processo para produção de um pó ou grânulo, pó ou grânulo, e, uso de grânulos e de pós |
| US12006487B2 (en) | 2018-09-27 | 2024-06-11 | Basf Se | Process for making a granule or powder |
| PL4073217T3 (pl) | 2019-12-11 | 2024-11-18 | Basf Se | Granulki mgda i homo- lub kopolimer kwasu (met)akrylowego; sposób ich wytwarzania |
| US12351776B2 (en) | 2020-03-17 | 2025-07-08 | Basf Se | Process for making a granule |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0845456A2 (de) * | 1996-11-29 | 1998-06-03 | Basf Aktiengesellschaft | Verfahren zur Herstellung eines kristallinen Feststoffes aus Glycin-N,N-diessigsäure-Derivaten mit hinreichend geringer Hygroskopizität |
| RU2399611C2 (ru) * | 2005-05-06 | 2010-09-20 | Басф Акциенгезельшафт | Способ получения трищелочных солей метилглицин-n,n-диуксусной кислоты с незначительным содержанием побочных продуктов |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL8502133A (nl) * | 1985-07-26 | 1987-02-16 | Unie Van Kunstmestfab Bv | Werkwijze voor het bereiden van granules en granules verkregen met deze werkwijze. |
| DE4319935A1 (de) | 1993-06-16 | 1994-12-22 | Basf Ag | Verwendung von Glycin-N,N-diessigsäure-Derivaten als Komplexbildner für Erdalkali- und Schwermetallionen |
| DE19518986A1 (de) | 1995-05-29 | 1996-12-05 | Basf Ag | Verfahren zur Herstellung von Glycin-N,N-diessigsäure-Derivaten durch Umsetzung von Glycinderivaten oder deren Vorstufen mit Formaldehyd und Cyanwasserstoff oder von Iminodiacetonitril oder Imindodiessigsäure mit entsprechenden Aldehyden und Cyanwasserstoff in wäßrig-saurem Medium |
| JP3008266B2 (ja) * | 1995-11-06 | 2000-02-14 | 花王株式会社 | 結晶性アルカリ金属ケイ酸塩顆粒の製造方法及び衣料用の高嵩密度粒状洗剤組成物 |
| DE10162781A1 (de) | 2001-12-20 | 2003-07-03 | Glatt Ingtech Gmbh | Strahlschichtapparat zur chargenweisen oder kontinuierlichen Prozessführung und Verfahren zum Betreiben eines Strahlschichtapparates |
| DE10322062A1 (de) * | 2003-05-15 | 2004-12-02 | Glatt Ingenieurtechnik Gmbh | Verfahren und Vorrichtung zum Aufbringen von Flüssigkeiten in eine Feststoffströmung eines Strahlschichtapparates |
| PL1638678T3 (pl) * | 2003-06-11 | 2012-02-29 | Glatt Ingtech Gmbh | Sposób wytwarzania granulatu enzymatycznego i otrzymywane granulaty enzymatyczne |
| DE102005037630A1 (de) | 2005-08-09 | 2007-02-15 | Glatt Gmbh | Verfahren zur Herstellung von Teilchen aus pharmazeutischen Substanzen, Teilchen aus pharmazeutischen Substanzen sowie deren Verwendung |
| DE102005037750A1 (de) * | 2005-08-10 | 2007-02-22 | Glatt Ingenieurtechnik Gmbh | Verfahren zur Herstellung von Harnstoffpellets |
| US8183410B2 (en) * | 2008-04-01 | 2012-05-22 | Conopco, Inc. | Preparation of free flowing granules of methylglycine diacetic acid |
| DE102009038951A1 (de) * | 2009-08-26 | 2011-03-03 | Inprotec Ag | Verfahren zur Herstellung eines kristallinen Feststoffes aus Glycin-N,N-diessigsäure-Derivaten mit hinreichend geringer Hygroskopizität |
-
2011
- 2011-09-21 CA CA2809749A patent/CA2809749A1/en not_active Abandoned
- 2011-09-21 PL PL11758206T patent/PL2621892T3/pl unknown
- 2011-09-21 MY MYPI2013001019A patent/MY160461A/en unknown
- 2011-09-21 MX MX2013003581A patent/MX342570B/es active IP Right Grant
- 2011-09-21 CN CN201180046439.2A patent/CN103124720B/zh not_active Expired - Fee Related
- 2011-09-21 KR KR1020137006511A patent/KR101897991B1/ko not_active Expired - Fee Related
- 2011-09-21 EP EP11758206.4A patent/EP2621892B1/de active Active
- 2011-09-21 BR BR112013006404A patent/BR112013006404A2/pt active Search and Examination
- 2011-09-21 WO PCT/EP2011/066376 patent/WO2012041741A1/de not_active Ceased
- 2011-09-21 RU RU2013119414/04A patent/RU2573412C2/ru active
- 2011-09-21 ES ES11758206.4T patent/ES2547417T3/es active Active
- 2011-09-21 JP JP2013529639A patent/JP5919278B2/ja not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0845456A2 (de) * | 1996-11-29 | 1998-06-03 | Basf Aktiengesellschaft | Verfahren zur Herstellung eines kristallinen Feststoffes aus Glycin-N,N-diessigsäure-Derivaten mit hinreichend geringer Hygroskopizität |
| RU2399611C2 (ru) * | 2005-05-06 | 2010-09-20 | Басф Акциенгезельшафт | Способ получения трищелочных солей метилглицин-n,n-диуксусной кислоты с незначительным содержанием побочных продуктов |
Non-Patent Citations (1)
| Title |
|---|
| D. GEHRMANN, Trockner, CHEMIE INGENIEUR TECHNIK, 2006, 78(12), 1778-1789. * |
Also Published As
| Publication number | Publication date |
|---|---|
| KR101897991B1 (ko) | 2018-09-12 |
| CN103124720B (zh) | 2014-12-10 |
| RU2013119414A (ru) | 2014-11-10 |
| MY160461A (en) | 2017-03-15 |
| KR20130106819A (ko) | 2013-09-30 |
| CA2809749A1 (en) | 2012-04-05 |
| JP2013544901A (ja) | 2013-12-19 |
| MX342570B (es) | 2016-10-05 |
| CN103124720A (zh) | 2013-05-29 |
| PL2621892T3 (pl) | 2015-12-31 |
| EP2621892B1 (de) | 2015-07-29 |
| BR112013006404A2 (pt) | 2016-07-05 |
| JP5919278B2 (ja) | 2016-05-18 |
| ES2547417T3 (es) | 2015-10-06 |
| EP2621892A1 (de) | 2013-08-07 |
| MX2013003581A (es) | 2013-05-31 |
| WO2012041741A1 (de) | 2012-04-05 |
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