RU2561606C2 - Полимеры или олигомерные активные агенты, обладающие биоцидным эффектом, способ их получения и композиция, содержащая полимерный или олигомерный активный агент - Google Patents
Полимеры или олигомерные активные агенты, обладающие биоцидным эффектом, способ их получения и композиция, содержащая полимерный или олигомерный активный агент Download PDFInfo
- Publication number
- RU2561606C2 RU2561606C2 RU2012119073/04A RU2012119073A RU2561606C2 RU 2561606 C2 RU2561606 C2 RU 2561606C2 RU 2012119073/04 A RU2012119073/04 A RU 2012119073/04A RU 2012119073 A RU2012119073 A RU 2012119073A RU 2561606 C2 RU2561606 C2 RU 2561606C2
- Authority
- RU
- Russia
- Prior art keywords
- active agent
- polymer
- oligomeric active
- oligomeric
- polymeric
- Prior art date
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- 239000013543 active substance Substances 0.000 title claims abstract description 115
- 239000000203 mixture Substances 0.000 title claims abstract description 75
- 229920000642 polymer Polymers 0.000 title claims abstract description 75
- 230000003115 biocidal effect Effects 0.000 title claims abstract description 38
- 238000000034 method Methods 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 22
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 65
- -1 triethylene glycol diamine Chemical class 0.000 claims abstract description 59
- 229920003023 plastic Polymers 0.000 claims abstract description 38
- 239000004033 plastic Substances 0.000 claims abstract description 38
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims abstract description 36
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims abstract description 31
- 150000001412 amines Chemical class 0.000 claims abstract description 31
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229920002635 polyurethane Polymers 0.000 claims abstract description 28
- 239000004814 polyurethane Substances 0.000 claims abstract description 28
- 229920001577 copolymer Polymers 0.000 claims abstract description 18
- 229960004198 guanidine Drugs 0.000 claims abstract description 16
- DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical group C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 claims abstract description 15
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims abstract description 15
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000008187 granular material Substances 0.000 claims abstract description 14
- 150000003839 salts Chemical class 0.000 claims abstract description 13
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 12
- 239000004417 polycarbonate Substances 0.000 claims abstract description 12
- 239000004952 Polyamide Substances 0.000 claims abstract description 11
- 239000002253 acid Substances 0.000 claims abstract description 11
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 11
- PJJJBBJSCAKJQF-UHFFFAOYSA-N guanidinium chloride Chemical compound [Cl-].NC(N)=[NH2+] PJJJBBJSCAKJQF-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920002647 polyamide Polymers 0.000 claims abstract description 11
- 239000004744 fabric Substances 0.000 claims abstract description 10
- 235000013305 food Nutrition 0.000 claims abstract description 10
- 229960000789 guanidine hydrochloride Drugs 0.000 claims abstract description 10
- 239000000155 melt Substances 0.000 claims abstract description 10
- 229920001519 homopolymer Polymers 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 238000006068 polycondensation reaction Methods 0.000 claims abstract description 9
- 239000004743 Polypropylene Substances 0.000 claims abstract description 8
- 239000004793 Polystyrene Substances 0.000 claims abstract description 8
- 239000002537 cosmetic Substances 0.000 claims abstract description 8
- 230000003203 everyday effect Effects 0.000 claims abstract description 8
- 239000005022 packaging material Substances 0.000 claims abstract description 8
- 229920000098 polyolefin Polymers 0.000 claims abstract description 8
- 229920001155 polypropylene Polymers 0.000 claims abstract description 8
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 8
- 229920002223 polystyrene Polymers 0.000 claims abstract description 8
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 8
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 8
- 239000004753 textile Substances 0.000 claims abstract description 8
- 229940127554 medical product Drugs 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 6
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 50
- 125000003118 aryl group Chemical group 0.000 claims description 21
- 239000004416 thermosoftening plastic Substances 0.000 claims description 17
- 239000007864 aqueous solution Substances 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 239000012634 fragment Substances 0.000 claims description 11
- 125000004122 cyclic group Chemical group 0.000 claims description 9
- 239000004695 Polyether sulfone Substances 0.000 claims description 7
- 229920006393 polyether sulfone Polymers 0.000 claims description 7
- 229920000426 Microplastic Polymers 0.000 claims description 6
- 239000004953 Aliphatic polyamide Substances 0.000 claims description 5
- 229920003231 aliphatic polyamide Polymers 0.000 claims description 5
- 239000004760 aramid Substances 0.000 claims description 5
- 229920003235 aromatic polyamide Polymers 0.000 claims description 5
- 229920002396 Polyurea Polymers 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 3
- 230000003993 interaction Effects 0.000 claims 1
- 230000002401 inhibitory effect Effects 0.000 abstract description 13
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract 1
- 238000005755 formation reaction Methods 0.000 abstract 1
- 150000004985 diamines Chemical class 0.000 description 23
- 239000000047 product Substances 0.000 description 19
- 239000000178 monomer Substances 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- JVZHVCMTUYEKCA-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine hexane-1,6-diamine Chemical compound NCCCCCCN.NC1CCC(CC2CCC(N)CC2)CC1 JVZHVCMTUYEKCA-UHFFFAOYSA-N 0.000 description 7
- 238000001125 extrusion Methods 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 150000002357 guanidines Chemical class 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 239000000654 additive Substances 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 6
- 238000001228 spectrum Methods 0.000 description 6
- 239000003139 biocide Substances 0.000 description 5
- 239000000284 extract Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 230000002349 favourable effect Effects 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 125000005263 alkylenediamine group Chemical group 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 239000006286 aqueous extract Substances 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 238000000065 atmospheric pressure chemical ionisation Methods 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 2
- 230000035622 drinking Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 238000004949 mass spectrometry Methods 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000000565 sealant Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- BYEAHWXPCBROCE-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropan-2-ol Chemical compound FC(F)(F)C(O)C(F)(F)F BYEAHWXPCBROCE-UHFFFAOYSA-N 0.000 description 1
- 238000005084 2D-nuclear magnetic resonance Methods 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 229920000305 Nylon 6,10 Polymers 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 210000001124 body fluid Anatomy 0.000 description 1
- 239000010839 body fluid Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000005100 correlation spectroscopy Methods 0.000 description 1
- 239000000551 dentifrice Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- PFRDRCIPKPEULG-UHFFFAOYSA-N imidazol-2-imine Chemical group N=C1N=CC=N1 PFRDRCIPKPEULG-UHFFFAOYSA-N 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 238000001819 mass spectrum Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/0605—Polycondensates containing five-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
- C08G73/0616—Polycondensates containing five-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with only two nitrogen atoms in the ring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/74—Synthetic polymeric materials
- A61K31/785—Polymers containing nitrogen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P31/00—Antiinfectives, i.e. antibiotics, antiseptics, chemotherapeutics
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0206—Polyalkylene(poly)amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0206—Polyalkylene(poly)amines
- C08G73/0213—Preparatory process
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0273—Polyamines containing heterocyclic moieties in the main chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/02—Polyamines
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Pharmacology & Pharmacy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- General Chemical & Material Sciences (AREA)
- Oncology (AREA)
- Communicable Diseases (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Medicinal Preparation (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009052667.6 | 2009-11-12 | ||
| DE102009052667A DE102009052667A1 (de) | 2009-11-12 | 2009-11-12 | Polymere oder oligomere Wirkstoffe mit biozider Wirkung, Verfahren zu deren Herstellung und Zusammensetzung umfassend einen polymeren oder oligomeren Wirkstoff |
| PCT/DE2010/001317 WO2011057611A1 (de) | 2009-11-12 | 2010-11-12 | Polymere oder oligomere wirkstoffe mit biozider wirkung, verfahren zu deren herstellung und zusammensetzung umfassend einen polymeren oder oligomeren wirkstoff |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2012119073A RU2012119073A (ru) | 2013-12-20 |
| RU2561606C2 true RU2561606C2 (ru) | 2015-08-27 |
Family
ID=43661973
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2012119073/04A RU2561606C2 (ru) | 2009-11-12 | 2010-11-12 | Полимеры или олигомерные активные агенты, обладающие биоцидным эффектом, способ их получения и композиция, содержащая полимерный или олигомерный активный агент |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20120259064A1 (https=) |
| EP (1) | EP2498766A1 (https=) |
| JP (1) | JP2013510909A (https=) |
| CN (1) | CN102753160B (https=) |
| AU (1) | AU2010317214A1 (https=) |
| BR (1) | BR112012011267A2 (https=) |
| DE (1) | DE102009052667A1 (https=) |
| RU (1) | RU2561606C2 (https=) |
| WO (1) | WO2011057611A1 (https=) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102009052721A1 (de) * | 2009-11-12 | 2011-05-26 | B. Braun Melsungen Ag | Verwendung polymerer oder oligomerer Wirkstoffe für medizinische Artikel |
| CN103214646A (zh) * | 2013-04-23 | 2013-07-24 | 四川大学 | 具有酶触释药性能的聚氨酯抗菌剂及其制备方法 |
| WO2017182536A1 (de) | 2016-04-20 | 2017-10-26 | Ineos Styrolution Group Gmbh | Antimikrobiell wirkende, nicht ausblutende thermoplastische formmassen |
| CA3051432A1 (en) * | 2017-01-30 | 2018-08-02 | Lubrizol Advanced Materials, Inc. | Antimicrobial, non-thrombogenic polymer compositions |
| IL268037B2 (en) * | 2017-01-30 | 2023-03-01 | Lubrizol Advanced Mat Inc | Antimicrobial thermoplastic polyurethanes |
| EP3381967A1 (de) | 2017-03-28 | 2018-10-03 | Thomas Flechsig | Homogene poly(alkylen)guanidine und verfahren zu deren herstellung |
| JP2021527708A (ja) * | 2018-04-19 | 2021-10-14 | ウジャル ヘルス ゲーエムベーハーＵｃａｒ Ｈｅａｌｔｈ Ｇｍｂｈ | 表面、空気、繊維、塗料、プラスチック、シリコーンおよび木材、ポリエチレン；金属および誘導体の抗菌性 |
| CN109535418B (zh) * | 2018-10-10 | 2019-08-30 | 桂林新先立抗菌材料有限公司 | 一种抗菌织物材料及其制备方法 |
| DE102022106745A1 (de) | 2022-03-23 | 2023-09-28 | Werner H. Salewski | Thermoplast-Blends mit inhärent bioziden Eigenschaften |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2264337C1 (ru) * | 2004-07-12 | 2005-11-20 | Общество с ограниченной ответственностью "Международный институт эколого-технологических проблем" | Антимикробный полимерный материал |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2325586A (en) | 1940-03-21 | 1943-08-03 | Du Pont | Polymeric guanidines and process for preparing the same |
| JPS616383A (ja) * | 1984-06-14 | 1986-01-13 | 三洋化成工業株式会社 | 湿潤堅牢度増進剤 |
| DE4002404A1 (de) | 1990-01-27 | 1991-08-01 | Degussa | Loesungen polymerer guanidinsalze mit erhoehter biozidwirksamkeit, verfahren zu ihrer herstellung und verwendung |
| AT406163B (de) * | 1998-04-22 | 2000-03-27 | P O C Oil Industry Technology | Verfahren zur gewinnung eines desinfektionsmittels |
| GB2349644A (en) * | 1999-05-01 | 2000-11-08 | Biointeractions Ltd | Infection resistant polymers, methods for their preparation, and their uses |
| KR100557559B1 (ko) * | 1999-12-20 | 2006-03-03 | 에스케이 주식회사 | 폴리헥사메틸렌구아니딘 인산염 분말, 이의 제조방법 및이를 함유한 항균수지 |
| UA55660C2 (en) * | 2002-04-05 | 2007-12-25 | Method for treatment of packaging or storage of foodstuffs, mainly, liquid, and packaging treated by this method | |
| US20030221330A1 (en) * | 2002-05-31 | 2003-12-04 | Bryan Arnold | Plastic granule dryer system |
| ITRM20020529A1 (it) * | 2002-10-18 | 2004-04-19 | Franco Staino | Polimeri sterilizzanti, processo di loro preparazione ed uso. |
| RU2239629C1 (ru) * | 2003-07-16 | 2004-11-10 | Общество с ограниченной ответственностью "Международный институт эколого-технологических проблем" | Полибигуаниды линейного и гребенчатого строения |
| CN100406496C (zh) * | 2003-07-23 | 2008-07-30 | 上海塑杰科技有限公司 | 一种多元胺与胍盐聚合物及其在抗菌聚酯和聚酰胺材料中的应用 |
| AT505102B1 (de) * | 2004-11-05 | 2010-05-15 | Schmidt Oskar | Biozid, insbesondere fungizid wirkendes mittel |
| AT502765B1 (de) * | 2005-10-17 | 2008-05-15 | Ke Kelit Kunststoffwerk Gesmbh | Biozide polymere |
| WO2009027186A2 (de) * | 2007-08-29 | 2009-03-05 | Basf Se | Hyperverzweigte polymere mit guanidineinheiten |
| CN101173041A (zh) * | 2007-10-19 | 2008-05-07 | 华南理工大学 | 高分子量胍盐和多元胺抗菌型聚合物及其制备方法与应用 |
| DE102009052721A1 (de) * | 2009-11-12 | 2011-05-26 | B. Braun Melsungen Ag | Verwendung polymerer oder oligomerer Wirkstoffe für medizinische Artikel |
| DE102009052725A1 (de) * | 2009-11-12 | 2011-05-19 | B. Braun Melsungen Ag | Verwendung von Polyoxyalkylendiamin-basierten Polyguanidinderivaten für medizinische Artikel |
-
2009
- 2009-11-12 DE DE102009052667A patent/DE102009052667A1/de not_active Ceased
-
2010
- 2010-11-12 JP JP2012538193A patent/JP2013510909A/ja active Pending
- 2010-11-12 BR BR112012011267A patent/BR112012011267A2/pt not_active IP Right Cessation
- 2010-11-12 WO PCT/DE2010/001317 patent/WO2011057611A1/de not_active Ceased
- 2010-11-12 CN CN201080051466.4A patent/CN102753160B/zh not_active Expired - Fee Related
- 2010-11-12 US US13/509,185 patent/US20120259064A1/en not_active Abandoned
- 2010-11-12 AU AU2010317214A patent/AU2010317214A1/en not_active Abandoned
- 2010-11-12 EP EP10805387A patent/EP2498766A1/de not_active Withdrawn
- 2010-11-12 RU RU2012119073/04A patent/RU2561606C2/ru not_active IP Right Cessation
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2264337C1 (ru) * | 2004-07-12 | 2005-11-20 | Общество с ограниченной ответственностью "Международный институт эколого-технологических проблем" | Антимикробный полимерный материал |
Non-Patent Citations (1)
| Title |
|---|
| He, B. et.al. Preparation of antimircobal-wet strength polymer and its polyelectrolyte complex as novel functional additives. 63rd Appita Annual Conference and exhibition, Melbourne, 19-22 aprel 2009 * |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2498766A1 (de) | 2012-09-19 |
| DE102009052667A1 (de) | 2011-05-19 |
| BR112012011267A2 (pt) | 2016-04-12 |
| RU2012119073A (ru) | 2013-12-20 |
| CN102753160B (zh) | 2015-12-16 |
| US20120259064A1 (en) | 2012-10-11 |
| WO2011057611A1 (de) | 2011-05-19 |
| AU2010317214A1 (en) | 2012-06-14 |
| JP2013510909A (ja) | 2013-03-28 |
| CN102753160A (zh) | 2012-10-24 |
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