RU2544242C2 - Улучшенные пористые материалы на основе ароматических аминов - Google Patents
Улучшенные пористые материалы на основе ароматических аминов Download PDFInfo
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- RU2544242C2 RU2544242C2 RU2012128928/04A RU2012128928A RU2544242C2 RU 2544242 C2 RU2544242 C2 RU 2544242C2 RU 2012128928/04 A RU2012128928/04 A RU 2012128928/04A RU 2012128928 A RU2012128928 A RU 2012128928A RU 2544242 C2 RU2544242 C2 RU 2544242C2
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- Prior art keywords
- multifunctional
- group
- porous material
- component
- gel
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- 239000011148 porous material Substances 0.000 title claims abstract description 125
- 150000004982 aromatic amines Chemical class 0.000 title claims abstract description 51
- 239000002904 solvent Substances 0.000 claims abstract description 55
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 38
- 150000001412 amines Chemical class 0.000 claims abstract description 38
- 239000012948 isocyanate Substances 0.000 claims abstract description 38
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 36
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract description 32
- 150000001875 compounds Chemical class 0.000 claims abstract description 29
- -1 aliphatic amines Chemical class 0.000 claims abstract description 27
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 21
- 238000001035 drying Methods 0.000 claims abstract description 21
- 125000000524 functional group Chemical group 0.000 claims abstract description 17
- 239000001257 hydrogen Substances 0.000 claims abstract description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 125000001424 substituent group Chemical group 0.000 claims abstract description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 125000003118 aryl group Chemical group 0.000 claims abstract description 7
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract description 5
- 239000011810 insulating material Substances 0.000 claims abstract description 5
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 37
- 238000000034 method Methods 0.000 claims description 30
- 239000007788 liquid Substances 0.000 claims description 17
- 239000000178 monomer Substances 0.000 claims description 12
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 claims description 9
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 claims description 8
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 8
- 229920000768 polyamine Polymers 0.000 claims description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- 229920001281 polyalkylene Polymers 0.000 claims description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 4
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 4
- OHKOAJUTRVTYSW-UHFFFAOYSA-N 2-[(2-aminophenyl)methyl]aniline Chemical compound NC1=CC=CC=C1CC1=CC=CC=C1N OHKOAJUTRVTYSW-UHFFFAOYSA-N 0.000 claims description 3
- UTNMPUFESIRPQP-UHFFFAOYSA-N 2-[(4-aminophenyl)methyl]aniline Chemical compound C1=CC(N)=CC=C1CC1=CC=CC=C1N UTNMPUFESIRPQP-UHFFFAOYSA-N 0.000 claims description 3
- JIABEENURMZTTI-UHFFFAOYSA-N 1-isocyanato-2-[(2-isocyanatophenyl)methyl]benzene Chemical compound O=C=NC1=CC=CC=C1CC1=CC=CC=C1N=C=O JIABEENURMZTTI-UHFFFAOYSA-N 0.000 claims description 2
- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 20
- 230000015572 biosynthetic process Effects 0.000 abstract description 6
- 238000002360 preparation method Methods 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
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- 239000000499 gel Substances 0.000 description 57
- 239000000203 mixture Substances 0.000 description 52
- 239000002243 precursor Substances 0.000 description 22
- 125000003277 amino group Chemical group 0.000 description 13
- 238000002156 mixing Methods 0.000 description 11
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- 229920002873 Polyethylenimine Polymers 0.000 description 10
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 9
- 239000000463 material Substances 0.000 description 9
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- 150000001299 aldehydes Chemical class 0.000 description 7
- 150000002576 ketones Chemical class 0.000 description 7
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 6
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- 229910052753 mercury Inorganic materials 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- 238000001879 gelation Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
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- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- JXCHMDATRWUOAP-UHFFFAOYSA-N diisocyanatomethylbenzene Chemical compound O=C=NC(N=C=O)C1=CC=CC=C1 JXCHMDATRWUOAP-UHFFFAOYSA-N 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
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- 150000004658 ketimines Chemical class 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
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- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- AMIMRNSIRUDHCM-UHFFFAOYSA-N Isopropylaldehyde Chemical compound CC(C)C=O AMIMRNSIRUDHCM-UHFFFAOYSA-N 0.000 description 2
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 150000001983 dialkylethers Chemical class 0.000 description 2
- 125000005442 diisocyanate group Chemical group 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
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- 239000003381 stabilizer Substances 0.000 description 2
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- 238000003786 synthesis reaction Methods 0.000 description 2
- NUMQCACRALPSHD-UHFFFAOYSA-N tert-butyl ethyl ether Chemical compound CCOC(C)(C)C NUMQCACRALPSHD-UHFFFAOYSA-N 0.000 description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 2
- 150000004998 toluenediamines Chemical class 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
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- XSCLFFBWRKTMTE-UHFFFAOYSA-N 1,3-bis(isocyanatomethyl)cyclohexane Chemical compound O=C=NCC1CCCC(CN=C=O)C1 XSCLFFBWRKTMTE-UHFFFAOYSA-N 0.000 description 1
- IKYNWXNXXHWHLL-UHFFFAOYSA-N 1,3-diisocyanatopropane Chemical compound O=C=NCCCN=C=O IKYNWXNXXHWHLL-UHFFFAOYSA-N 0.000 description 1
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- SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 description 1
- UTFSEWQOIIZLRH-UHFFFAOYSA-N 1,7-diisocyanatoheptane Chemical compound O=C=NCCCCCCCN=C=O UTFSEWQOIIZLRH-UHFFFAOYSA-N 0.000 description 1
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- RQUBQBFVDOLUKC-UHFFFAOYSA-N 1-ethoxy-2-methylpropane Chemical compound CCOCC(C)C RQUBQBFVDOLUKC-UHFFFAOYSA-N 0.000 description 1
- PZHIWRCQKBBTOW-UHFFFAOYSA-N 1-ethoxybutane Chemical compound CCCCOCC PZHIWRCQKBBTOW-UHFFFAOYSA-N 0.000 description 1
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- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 1
- PISLZQACAJMAIO-UHFFFAOYSA-N 2,4-diethyl-6-methylbenzene-1,3-diamine Chemical compound CCC1=CC(C)=C(N)C(CC)=C1N PISLZQACAJMAIO-UHFFFAOYSA-N 0.000 description 1
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- RLYCRLGLCUXUPO-UHFFFAOYSA-N 2,6-diaminotoluene Chemical compound CC1=C(N)C=CC=C1N RLYCRLGLCUXUPO-UHFFFAOYSA-N 0.000 description 1
- PBUMTLOEAITQSM-UHFFFAOYSA-N 2-(3-aminopentan-3-yl)aniline Chemical compound CCC(N)(CC)C1=CC=CC=C1N PBUMTLOEAITQSM-UHFFFAOYSA-N 0.000 description 1
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- 238000004364 calculation method Methods 0.000 description 1
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- KLKFAASOGCDTDT-UHFFFAOYSA-N ethoxymethoxyethane Chemical compound CCOCOCC KLKFAASOGCDTDT-UHFFFAOYSA-N 0.000 description 1
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- 239000012530 fluid Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- HLJDOURGTRAFHE-UHFFFAOYSA-N isocyanic acid;3,5,5-trimethylcyclohex-2-en-1-one Chemical compound N=C=O.N=C=O.CC1=CC(=O)CC(C)(C)C1 HLJDOURGTRAFHE-UHFFFAOYSA-N 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- VNKYTQGIUYNRMY-UHFFFAOYSA-N methoxypropane Chemical compound CCCOC VNKYTQGIUYNRMY-UHFFFAOYSA-N 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000002459 porosimetry Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001812 pycnometry Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 238000000352 supercritical drying Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000011426 transformation method Methods 0.000 description 1
- 238000005829 trimerization reaction Methods 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3237—Polyamines aromatic
- C08G18/3243—Polyamines aromatic containing two or more aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
- C08J9/286—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum the liquid phase being a solvent for the monomers but not for the resulting macromolecular composition, i.e. macroporous or macroreticular polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0091—Aerogels; Xerogels
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2330/00—Thermal insulation material
- C08G2330/50—Evacuated open-celled polymer material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/04—Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
- C08J2201/05—Elimination by evaporation or heat degradation of a liquid phase
- C08J2201/0502—Elimination by evaporation or heat degradation of a liquid phase the liquid phase being organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/02—Polyureas
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09178783 | 2009-12-11 | ||
| EP09178783.8 | 2009-12-11 | ||
| PCT/EP2010/068962 WO2011069959A2 (de) | 2009-12-11 | 2010-12-06 | Verbesserte poröse materialien auf basis von aromatischen aminen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2012128928A RU2012128928A (ru) | 2014-01-20 |
| RU2544242C2 true RU2544242C2 (ru) | 2015-03-20 |
Family
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| RU2012128928/04A RU2544242C2 (ru) | 2009-12-11 | 2010-12-06 | Улучшенные пористые материалы на основе ароматических аминов |
Country Status (14)
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| US (1) | US11078320B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP2510026B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP5770202B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR101818094B1 (cg-RX-API-DMAC7.html) |
| CN (1) | CN102652145B (cg-RX-API-DMAC7.html) |
| AU (1) | AU2010330056B2 (cg-RX-API-DMAC7.html) |
| CA (1) | CA2783139C (cg-RX-API-DMAC7.html) |
| DK (1) | DK2510026T3 (cg-RX-API-DMAC7.html) |
| ES (1) | ES2454615T3 (cg-RX-API-DMAC7.html) |
| MX (1) | MX2012006475A (cg-RX-API-DMAC7.html) |
| PL (1) | PL2510026T3 (cg-RX-API-DMAC7.html) |
| PT (1) | PT2510026E (cg-RX-API-DMAC7.html) |
| RU (1) | RU2544242C2 (cg-RX-API-DMAC7.html) |
| WO (1) | WO2011069959A2 (cg-RX-API-DMAC7.html) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2708692C2 (ru) * | 2015-08-06 | 2019-12-11 | ХАНТСМЭН ИНТЕРНЭШНЛ ЭлЭлСи | Органические ксерогели с пониженной плотностью на основе изоцианатов |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL2448986T3 (pl) * | 2009-06-29 | 2014-05-30 | Basf Se | Porowate żele na bazie aromatycznego polimocznika |
| US9260580B2 (en) | 2010-06-28 | 2016-02-16 | Basf Se | Process for producing porous materials based on polyurea |
| JP5937606B2 (ja) * | 2010-11-04 | 2016-06-22 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | エアロゲル又はキセロゲルの製造方法 |
| US8697766B2 (en) | 2011-02-24 | 2014-04-15 | Basf Se | Process for producing pulverulent porous materials |
| US20120235070A1 (en) | 2011-03-18 | 2012-09-20 | Basf Se | Process for producing flame-retardant porous materials based on polyurea |
| US9188384B2 (en) | 2011-03-31 | 2015-11-17 | Basf Se | Dynamically evacuable devices comprising organic aerogels or xerogels |
| KR102139671B1 (ko) | 2012-09-27 | 2020-07-30 | 바스프 에스이 | 이소시아네이트에 기초한 다공성 재료의 제조 방법 |
| US9321876B2 (en) | 2012-09-27 | 2016-04-26 | Basf Se | Process for producing porous materials based on isocyanate |
| JP6433989B2 (ja) * | 2013-05-24 | 2018-12-05 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 多孔性材料の製造方法 |
| EP3122808B1 (en) | 2014-03-24 | 2018-10-03 | Basf Se | Process for producing porous materials |
| US10273341B2 (en) | 2014-07-18 | 2019-04-30 | Basf Se | Process for producing porous materials |
| PL3197679T3 (pl) | 2014-09-25 | 2020-07-27 | Basf Se | Sposób wytwarzania elementu kompozytowego dla próżniowych elementów izolacyjnych |
| EP3274401A1 (en) | 2015-03-24 | 2018-01-31 | Basf Se | Process for producing porous materials comprising a catalyst system |
| MX2017013786A (es) | 2015-04-27 | 2018-03-27 | Huntsman Int Llc | Materiales porosos a base de isocianato funcionalizado. |
| KR20180069864A (ko) | 2015-10-16 | 2018-06-25 | 바스프 에스이 | 무기산을 사용한 이소시아네이트에 기초한 크세로겔 및 에어로겔의 제조 방법 |
| US20190023864A1 (en) | 2016-01-18 | 2019-01-24 | Basf Se | Process for producing porous materials |
| US11248101B2 (en) | 2016-01-18 | 2022-02-15 | Basf Se | Process for producing porous materials |
| EP3652231A1 (en) | 2017-07-13 | 2020-05-20 | Basf Se | Porous materials with superior reversible water uptake |
| CN110914326B (zh) | 2017-07-17 | 2023-06-13 | 埃力格-伊特有限责任公司 | 制备多孔材料的方法 |
| WO2020148393A1 (en) | 2019-01-17 | 2020-07-23 | Basf Se | Process for producing porous materials |
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| EP0288067A1 (en) * | 1987-04-24 | 1988-10-26 | Asahi Glass Company Ltd. | Process for producing polyurethane elastomer and compositon as starting material therefor |
| WO1995002009A1 (en) * | 1993-07-07 | 1995-01-19 | The Dow Chemical Company | Microporous isocyanate-based polymer compositions and method of preparation |
| RU2184126C2 (ru) * | 2000-08-15 | 2002-06-27 | Хозин Вадим Григорьевич | Связующее для теплоизоляционного материала и способ изготовления теплоизоляционного материала |
| RU2268270C2 (ru) * | 2000-08-01 | 2006-01-20 | Хантсмэн Интернэшнл Ллс | Способ получения полиуретанового материала |
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| JPH10195163A (ja) * | 1996-11-14 | 1998-07-28 | Asahi Glass Co Ltd | 二液型硬化性組成物 |
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| WO2010105985A1 (de) | 2009-03-16 | 2010-09-23 | Basf Se | Verfahren zur herstellung von xerogel-kompositen |
| PL2448986T3 (pl) | 2009-06-29 | 2014-05-30 | Basf Se | Porowate żele na bazie aromatycznego polimocznika |
-
2010
- 2010-12-06 US US13/515,139 patent/US11078320B2/en not_active Expired - Fee Related
- 2010-12-06 CA CA2783139A patent/CA2783139C/en not_active Expired - Fee Related
- 2010-12-06 JP JP2012542490A patent/JP5770202B2/ja not_active Expired - Fee Related
- 2010-12-06 AU AU2010330056A patent/AU2010330056B2/en not_active Ceased
- 2010-12-06 PT PT107907495T patent/PT2510026E/pt unknown
- 2010-12-06 WO PCT/EP2010/068962 patent/WO2011069959A2/de not_active Ceased
- 2010-12-06 MX MX2012006475A patent/MX2012006475A/es active IP Right Grant
- 2010-12-06 EP EP10790749.5A patent/EP2510026B1/de not_active Not-in-force
- 2010-12-06 RU RU2012128928/04A patent/RU2544242C2/ru not_active IP Right Cessation
- 2010-12-06 CN CN201080056024.9A patent/CN102652145B/zh not_active Expired - Fee Related
- 2010-12-06 DK DK10790749.5T patent/DK2510026T3/da active
- 2010-12-06 PL PL10790749T patent/PL2510026T3/pl unknown
- 2010-12-06 ES ES10790749.5T patent/ES2454615T3/es active Active
- 2010-12-06 KR KR1020127017952A patent/KR101818094B1/ko not_active Expired - Fee Related
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| EP0288067A1 (en) * | 1987-04-24 | 1988-10-26 | Asahi Glass Company Ltd. | Process for producing polyurethane elastomer and compositon as starting material therefor |
| WO1995002009A1 (en) * | 1993-07-07 | 1995-01-19 | The Dow Chemical Company | Microporous isocyanate-based polymer compositions and method of preparation |
| RU2268270C2 (ru) * | 2000-08-01 | 2006-01-20 | Хантсмэн Интернэшнл Ллс | Способ получения полиуретанового материала |
| RU2184126C2 (ru) * | 2000-08-15 | 2002-06-27 | Хозин Вадим Григорьевич | Связующее для теплоизоляционного материала и способ изготовления теплоизоляционного материала |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2708692C2 (ru) * | 2015-08-06 | 2019-12-11 | ХАНТСМЭН ИНТЕРНЭШНЛ ЭлЭлСи | Органические ксерогели с пониженной плотностью на основе изоцианатов |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2011069959A2 (de) | 2011-06-16 |
| KR20120103700A (ko) | 2012-09-19 |
| DK2510026T3 (da) | 2014-05-26 |
| EP2510026B1 (de) | 2014-02-26 |
| US11078320B2 (en) | 2021-08-03 |
| PL2510026T3 (pl) | 2014-07-31 |
| CA2783139A1 (en) | 2011-06-16 |
| JP5770202B2 (ja) | 2015-08-26 |
| WO2011069959A3 (de) | 2011-12-01 |
| CN102652145B (zh) | 2014-04-16 |
| PT2510026E (pt) | 2014-04-02 |
| JP2013513675A (ja) | 2013-04-22 |
| AU2010330056A1 (en) | 2012-07-05 |
| KR101818094B1 (ko) | 2018-01-12 |
| CA2783139C (en) | 2018-01-09 |
| MX2012006475A (es) | 2012-06-28 |
| US20120305827A1 (en) | 2012-12-06 |
| AU2010330056B2 (en) | 2015-03-26 |
| EP2510026A2 (de) | 2012-10-17 |
| CN102652145A (zh) | 2012-08-29 |
| RU2012128928A (ru) | 2014-01-20 |
| ES2454615T3 (es) | 2014-04-11 |
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