RU2383557C2 - Плавкая полимерная композиция, содержащая фторполимер, имеющий длинные боковые цепочки - Google Patents
Плавкая полимерная композиция, содержащая фторполимер, имеющий длинные боковые цепочки Download PDFInfo
- Publication number
- RU2383557C2 RU2383557C2 RU2005138309/04A RU2005138309A RU2383557C2 RU 2383557 C2 RU2383557 C2 RU 2383557C2 RU 2005138309/04 A RU2005138309/04 A RU 2005138309/04A RU 2005138309 A RU2005138309 A RU 2005138309A RU 2383557 C2 RU2383557 C2 RU 2383557C2
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- RU
- Russia
- Prior art keywords
- polymer
- fluorine
- fluorinated
- fluoropolymer
- polymers
- Prior art date
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- 229920000642 polymer Polymers 0.000 title claims abstract description 245
- 239000000203 mixture Substances 0.000 title claims abstract description 100
- 229920002313 fluoropolymer Polymers 0.000 title claims abstract description 41
- 239000004811 fluoropolymer Substances 0.000 title claims abstract description 24
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 144
- 239000011737 fluorine Substances 0.000 claims abstract description 138
- 239000000178 monomer Substances 0.000 claims abstract description 52
- 238000001125 extrusion Methods 0.000 claims abstract description 50
- 239000000654 additive Substances 0.000 claims abstract description 43
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims abstract description 32
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 32
- 230000000996 additive effect Effects 0.000 claims abstract description 25
- 239000003607 modifier Substances 0.000 claims abstract description 22
- 150000001336 alkenes Chemical class 0.000 claims abstract description 21
- 125000001153 fluoro group Chemical group F* 0.000 claims abstract description 19
- 229920006120 non-fluorinated polymer Polymers 0.000 claims abstract description 17
- 229910052794 bromium Inorganic materials 0.000 claims abstract description 14
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 12
- 239000000126 substance Substances 0.000 claims abstract description 12
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims abstract description 11
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract description 11
- 239000000460 chlorine Substances 0.000 claims abstract description 10
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 10
- 239000001257 hydrogen Substances 0.000 claims abstract description 10
- 229910052740 iodine Chemical group 0.000 claims abstract description 9
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 5
- 125000006551 perfluoro alkylene group Chemical group 0.000 claims abstract description 5
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims abstract 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract 3
- -1 1-1-dibromethylene Chemical group 0.000 claims description 28
- 238000002844 melting Methods 0.000 claims description 24
- 230000008018 melting Effects 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 23
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- 230000008569 process Effects 0.000 claims description 10
- QZGNGBWAMYFUST-UHFFFAOYSA-N 2-bromo-1,1-difluoroethene Chemical group FC(F)=CBr QZGNGBWAMYFUST-UHFFFAOYSA-N 0.000 claims description 9
- 238000007334 copolymerization reaction Methods 0.000 claims description 7
- 239000010702 perfluoropolyether Substances 0.000 claims description 5
- INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical compound BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 claims description 2
- 238000001746 injection moulding Methods 0.000 claims description 2
- UWTUEMKLYAGTNQ-UHFFFAOYSA-N 1,2-dibromoethene Chemical group BrC=CBr UWTUEMKLYAGTNQ-UHFFFAOYSA-N 0.000 claims 1
- AYCANDRGVPTASA-UHFFFAOYSA-N 1-bromo-1,2,2-trifluoroethene Chemical group FC(F)=C(F)Br AYCANDRGVPTASA-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 132
- 238000006116 polymerization reaction Methods 0.000 description 38
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 32
- 238000006243 chemical reaction Methods 0.000 description 30
- 238000012545 processing Methods 0.000 description 29
- 125000005702 oxyalkylene group Chemical group 0.000 description 26
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 21
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- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
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- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 5
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- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical class [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
- 239000012935 ammoniumperoxodisulfate Substances 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
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- 150000003839 salts Chemical class 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
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- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 3
- 241000251730 Chondrichthyes Species 0.000 description 3
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- YOALFLHFSFEMLP-UHFFFAOYSA-N azane;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoic acid Chemical compound [NH4+].[O-]C(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YOALFLHFSFEMLP-UHFFFAOYSA-N 0.000 description 3
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- 238000013461 design Methods 0.000 description 3
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
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- HFNSTEOEZJBXIF-UHFFFAOYSA-N 2,2,4,5-tetrafluoro-1,3-dioxole Chemical class FC1=C(F)OC(F)(F)O1 HFNSTEOEZJBXIF-UHFFFAOYSA-N 0.000 description 2
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- 125000005409 triarylsulfonium group Chemical group 0.000 description 1
- KSMYREBPTSSZDR-UHFFFAOYSA-M tributyl(prop-2-enyl)phosphanium;chloride Chemical compound [Cl-].CCCC[P+](CCCC)(CCCC)CC=C KSMYREBPTSSZDR-UHFFFAOYSA-M 0.000 description 1
- JABYJIQOLGWMQW-UHFFFAOYSA-N undec-4-ene Chemical compound CCCCCCC=CCCC JABYJIQOLGWMQW-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/182—Monomers containing fluorine not covered by the groups C08F214/20 - C08F214/28
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/22—Vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/16—Homopolymers or copolymers or vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
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| US47708403P | 2003-06-09 | 2003-06-09 | |
| US60/477,084 | 2003-06-09 |
Publications (2)
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| RU2005138309A RU2005138309A (ru) | 2007-07-20 |
| RU2383557C2 true RU2383557C2 (ru) | 2010-03-10 |
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| EP (1) | EP1631602B1 (OSRAM) |
| JP (2) | JP4642768B2 (OSRAM) |
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| CA (1) | CA2528550C (OSRAM) |
| RU (1) | RU2383557C2 (OSRAM) |
| WO (1) | WO2004111124A2 (OSRAM) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US20060025504A1 (en) * | 2004-07-29 | 2006-02-02 | Oriani Steven R | Process aid for melt processable polymers that contain hindered amine light stabilizer |
| US8557938B2 (en) | 2005-11-10 | 2013-10-15 | Arkema Inc. | Branched fluoropolymers |
| US9029477B2 (en) * | 2006-03-03 | 2015-05-12 | 3M Innovative Properties Company | Compositions comprising melt-processable thermoplastic fluoropolymers and methods of making the same |
| WO2008000730A2 (fr) * | 2006-06-26 | 2008-01-03 | Solvay (Societe Anonyme) | Compositions polymeriques a proprietes adhesives |
| US20090280520A1 (en) * | 2006-09-15 | 2009-11-12 | Konica Minolta Medical & Graphic, Inc. | Fluorescent semiconductor particles, method of manufacturing the same, biosubstance fluorescent labeling agent employing the same, and bioimaging method thereof |
| GB0709033D0 (en) * | 2007-05-11 | 2007-06-20 | 3M Innovative Properties Co | Melt-Processible fluoropolymers having long-chain branches, Methods of preparing them and uses thereof |
| CN101688040B (zh) * | 2007-07-11 | 2013-01-02 | 3M创新有限公司 | 用于熔融加工热塑性含氟聚合物的方法 |
| GB0801194D0 (en) * | 2008-01-23 | 2008-02-27 | 3M Innovative Properties Co | Processing aid compositions comprising fluoropolymers having long-chain branches |
| WO2009096544A1 (ja) * | 2008-02-01 | 2009-08-06 | Asahi Glass Company, Limited | 熱可塑性フッ素樹脂及びその製造方法 |
| US10259899B2 (en) * | 2008-07-07 | 2019-04-16 | Arkema Inc. | Vinylidene fluoride / 2,3,3,3-tetrafluoropropene copolymers |
| ITMI20081900A1 (it) * | 2008-10-28 | 2010-04-29 | Solvay Solexis Spa | Uso di polimeri termoplastici fluorurati come additivi per polimeri idrogenati |
| US20110318589A1 (en) * | 2009-02-27 | 2011-12-29 | Massimo Pignatelli | Plasma Treated EVOH Multilayer Film |
| US8053526B2 (en) * | 2009-05-20 | 2011-11-08 | Dupont Performance Elastomers Llc | Fluoroelastomer process aid contains polyalkylene oxide and polycaprolactone |
| CN102482374B (zh) * | 2009-08-27 | 2014-08-27 | 大金工业株式会社 | 加工助剂、成型用组合物、加工助剂用母料和成型品 |
| US20110184061A1 (en) * | 2010-01-22 | 2011-07-28 | Nielsen Kurt R | Thiocolchicine and colchicine analogs, methods of making and methods of use thereof |
| EP2585521B1 (en) | 2010-06-24 | 2018-04-11 | 3M Innovative Properties Company | Polymerizable compositions free of organic emulsifier and polymers and methods of making thereof |
| US10093761B2 (en) | 2010-12-17 | 2018-10-09 | 3M Innovative Properties Company | Fluorine-containing polymer comprising a sulfinate-containing molecule |
| US9447214B2 (en) | 2011-03-16 | 2016-09-20 | Arkema Inc. | High melting fluoropolymers |
| US8809471B2 (en) | 2011-03-16 | 2014-08-19 | Arkema Inc. | Synthesis of making 2,3,3,3-tetrafluoropropene containing fluoropolymers |
| GB201108963D0 (en) * | 2011-05-27 | 2011-07-13 | 3M Innovative Properties Co | Composite materials comprising polyamides and fluoroelastomers |
| CN104080854B (zh) * | 2011-12-16 | 2016-12-07 | 3M创新有限公司 | 来源于含亚磺酸根的分子的加工助剂组合物 |
| CA2924818A1 (en) | 2013-09-20 | 2015-03-26 | 3M Innovative Properties Company | Polymer processing additive, compositions, and methods |
| EP3696224A1 (en) | 2014-03-06 | 2020-08-19 | 3M Innovative Properties Co. | Highly fluorinated elastomers |
| CN105085762B (zh) * | 2014-05-13 | 2017-08-08 | 浙江蓝天环保高科技股份有限公司 | 一种长支链高分子量聚偏氟乙烯及其制备方法 |
| EP3234004B1 (en) | 2014-12-19 | 2020-07-01 | 3M Innovative Properties Company | Poly(oxyalkylene) polymer processing additive, compositions, and methods |
| JP2018532019A (ja) | 2015-10-13 | 2018-11-01 | スリーエム イノベイティブ プロパティズ カンパニー | フルオロポリマー加工用添加剤、組成物、及び方法 |
| CN108350244B (zh) | 2015-10-23 | 2021-01-29 | 3M创新有限公司 | 包含无定形含氟聚合物和氟塑料粒子的组合物及其制备方法 |
| JP2018533662A (ja) | 2015-11-13 | 2018-11-15 | スリーエム イノベイティブ プロパティズ カンパニー | 非晶質フルオロポリマーのバイモーダルブレンドを含む組成物及びそれらの使用 |
| US11248071B2 (en) | 2016-04-01 | 2022-02-15 | Arkema Inc. | 3-D printed fluoropolymer structures |
| WO2017173258A1 (en) * | 2016-04-01 | 2017-10-05 | Arkema Inc. | 3-d printed fluoropolymer structures |
| TW201815845A (zh) | 2016-05-17 | 2018-05-01 | ３Ｍ新設資產公司 | 包括二氟亞乙烯與四氟乙烯的共聚物之組成物及其使用方法 |
| KR102695301B1 (ko) * | 2016-11-17 | 2024-08-16 | 현대자동차주식회사 | 폴리케톤 복합재 수지 조성물 |
| WO2018213671A1 (en) * | 2017-05-18 | 2018-11-22 | 3M Innovative Properties Company | Compositions including co-coagulated fluoropolymers and methods of using the same |
| FR3067032B1 (fr) * | 2017-06-06 | 2021-10-01 | Arkema France | Elastomere de fluoropolymere thermoplastique |
| US20210189031A1 (en) * | 2017-10-27 | 2021-06-24 | 3M Innovative Properties Company | Branched fluorothermoplasts and method of making the same |
| US10738182B2 (en) * | 2018-04-23 | 2020-08-11 | Dow Global Technologies Llc | Molded articles and methods thereof |
| RU2018141773A (ru) | 2018-11-27 | 2020-05-27 | 3М Инновейтив Пропертиз Компани | Композиции полимерных процессинговых добавок и изделия, полученные с использованием указанных композиций |
| US10711124B1 (en) * | 2019-12-30 | 2020-07-14 | Chang Chun Petrochemical Co., Ltd. | Ethylene vinyl alcohol pellets as well as films thereof |
| TWI741853B (zh) * | 2019-12-30 | 2021-10-01 | 長春石油化學股份有限公司 | 乙烯-乙烯醇共聚物樹脂組合物及其膜和多層結構 |
| US11512196B2 (en) | 2019-12-30 | 2022-11-29 | Chang Chun Petrochemical Co., Ltd. | Fluorine-containing ethylene-vinyl alcohol copolymer resin composition as well as mixture and blend thereof |
| US20230075186A1 (en) | 2020-02-21 | 2023-03-09 | Arkema Inc. | Pvdf extrusion agent containing interfacial agent |
| EP4370598A1 (en) | 2021-07-14 | 2024-05-22 | Nova Chemicals (International) S.A. | Fluoropolymer free polymer processing aids |
| WO2023017327A1 (en) | 2021-08-12 | 2023-02-16 | Nova Chemicals (International) S.A. | Block copolymer polymer processing aids |
| CN116200880A (zh) * | 2021-11-30 | 2023-06-02 | 浙江省化工研究院有限公司 | 一种高粘合力含氟熔喷布的制备方法 |
| CN116410557B (zh) * | 2021-12-31 | 2025-11-28 | 浙江省化工研究院有限公司 | 一种含氟树脂、其制备方法及应用 |
| CN121086112A (zh) * | 2021-12-31 | 2025-12-09 | 浙江蓝天环保高科技股份有限公司 | 一种超支化偏氟乙烯聚合物及其制备方法 |
| WO2023238032A1 (en) | 2022-06-10 | 2023-12-14 | Nova Chemicals (International) S.A. | Fluorine free polymer processing aids |
| US20250346745A1 (en) | 2022-06-15 | 2025-11-13 | Nova Chemicals (International) S.A. | Block copolymer polymer processing aids |
| WO2024079553A1 (en) | 2022-10-11 | 2024-04-18 | Nova Chemicals (International) S.A. | Metal salt as a polymer processing aid |
| WO2025003837A1 (en) | 2023-06-26 | 2025-01-02 | Nova Chemicals (International) S.A. | Polar polymers as processing aids in polyethylene |
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- 2004-06-09 KR KR1020057023548A patent/KR101068175B1/ko not_active Expired - Lifetime
- 2004-06-09 EP EP04754889A patent/EP1631602B1/en not_active Expired - Lifetime
- 2004-06-09 BR BRPI0411119-2A patent/BRPI0411119B1/pt not_active IP Right Cessation
- 2004-06-09 RU RU2005138309/04A patent/RU2383557C2/ru not_active IP Right Cessation
- 2004-06-09 WO PCT/US2004/018422 patent/WO2004111124A2/en not_active Ceased
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| US5064594A (en) * | 1989-10-06 | 1991-11-12 | E. I. Du Pont De Nemours And Company | Extrusion process for difficultly-melt-processible polymers |
| RU2128667C1 (ru) * | 1993-10-29 | 1999-04-10 | Аусимонт С.п.А. | Способ (со)полимеризации фторированных олефиновых мономеров |
| US6277919B1 (en) * | 1999-05-13 | 2001-08-21 | Dyneon Llc | Polymer processing additive containing a multimodal fluoropolymer and melt processable thermoplastic polymer composition employing the same |
| EP1462465A1 (en) * | 2003-03-25 | 2004-09-29 | 3M Innovative Properties Company | Melt-processible thermoplastic fluoropolymers having improved processing characteristics and method of producing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2005138309A (ru) | 2007-07-20 |
| CN100558769C (zh) | 2009-11-11 |
| BRPI0411119A (pt) | 2006-07-18 |
| EP1631602A2 (en) | 2006-03-08 |
| JP2007502359A (ja) | 2007-02-08 |
| JP4642768B2 (ja) | 2011-03-02 |
| KR101068175B1 (ko) | 2011-09-28 |
| ATE517932T1 (de) | 2011-08-15 |
| US7375157B2 (en) | 2008-05-20 |
| CA2528550C (en) | 2013-07-16 |
| KR20060028688A (ko) | 2006-03-31 |
| BRPI0411119B1 (pt) | 2014-12-02 |
| CN1802393A (zh) | 2006-07-12 |
| WO2004111124A2 (en) | 2004-12-23 |
| US20040260022A1 (en) | 2004-12-23 |
| CA2528550A1 (en) | 2004-12-23 |
| EP1631602B1 (en) | 2011-07-27 |
| JP2011006696A (ja) | 2011-01-13 |
| WO2004111124A3 (en) | 2005-02-03 |
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