RU2254348C2 - Резиновая композиция - Google Patents
Резиновая композиция Download PDFInfo
- Publication number
- RU2254348C2 RU2254348C2 RU2002105513/04A RU2002105513A RU2254348C2 RU 2254348 C2 RU2254348 C2 RU 2254348C2 RU 2002105513/04 A RU2002105513/04 A RU 2002105513/04A RU 2002105513 A RU2002105513 A RU 2002105513A RU 2254348 C2 RU2254348 C2 RU 2254348C2
- Authority
- RU
- Russia
- Prior art keywords
- rubber
- polymer
- mixing
- grafted
- conjugated diolefin
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 66
- 229920001971 elastomer Polymers 0.000 title claims abstract description 25
- 239000005060 rubber Substances 0.000 title claims abstract description 24
- 229920000642 polymer Polymers 0.000 claims abstract description 75
- 150000001993 dienes Chemical class 0.000 claims abstract description 49
- 239000000178 monomer Substances 0.000 claims abstract description 41
- 229920005557 bromobutyl Polymers 0.000 claims abstract description 34
- 229920001577 copolymer Polymers 0.000 claims abstract description 33
- 238000002156 mixing Methods 0.000 claims abstract description 29
- 238000000034 method Methods 0.000 claims abstract description 27
- 238000004073 vulcanization Methods 0.000 claims abstract description 14
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 239000007787 solid Substances 0.000 claims abstract description 6
- 230000000694 effects Effects 0.000 claims abstract description 3
- 229920002857 polybutadiene Polymers 0.000 claims description 18
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 17
- 239000005062 Polybutadiene Substances 0.000 claims description 12
- 229910052717 sulfur Inorganic materials 0.000 claims description 11
- 239000011593 sulfur Substances 0.000 claims description 11
- 229910044991 metal oxide Inorganic materials 0.000 claims description 7
- 150000004706 metal oxides Chemical class 0.000 claims description 7
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 7
- 239000002174 Styrene-butadiene Substances 0.000 claims description 4
- 229920001400 block copolymer Polymers 0.000 claims description 4
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 4
- 239000004071 soot Substances 0.000 claims description 4
- 229920006301 statistical copolymer Polymers 0.000 claims description 4
- 239000011115 styrene butadiene Substances 0.000 claims description 4
- 229920005683 SIBR Polymers 0.000 claims description 3
- 239000004636 vulcanized rubber Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 abstract description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 30
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 14
- 238000002255 vaccination Methods 0.000 description 13
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 11
- 229920002554 vinyl polymer Polymers 0.000 description 11
- 239000003153 chemical reaction reagent Substances 0.000 description 8
- -1 bromobutyl Chemical group 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 229920005555 halobutyl Polymers 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- 229920005549 butyl rubber Polymers 0.000 description 5
- 229920005556 chlorobutyl Polymers 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- FWMUJAIKEJWSSY-UHFFFAOYSA-N sulfur dichloride Chemical compound ClSCl FWMUJAIKEJWSSY-UHFFFAOYSA-N 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical group [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- 238000013329 compounding Methods 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
- 244000043261 Hevea brasiliensis Species 0.000 description 3
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
- 229910052794 bromium Inorganic materials 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 3
- 229920003052 natural elastomer Polymers 0.000 description 3
- 229920001194 natural rubber Polymers 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229920002959 polymer blend Polymers 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- UAJRSHJHFRVGMG-UHFFFAOYSA-N 1-ethenyl-4-methoxybenzene Chemical compound COC1=CC=C(C=C)C=C1 UAJRSHJHFRVGMG-UHFFFAOYSA-N 0.000 description 2
- RCJMVGJKROQDCB-UHFFFAOYSA-N 2-methylpenta-1,3-diene Chemical compound CC=CC(C)=C RCJMVGJKROQDCB-UHFFFAOYSA-N 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 229910052779 Neodymium Inorganic materials 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- XXWVVIRTHDRMEY-UHFFFAOYSA-N bromo thiohypobromite Chemical compound BrSBr XXWVVIRTHDRMEY-UHFFFAOYSA-N 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 229910052747 lanthanoid Inorganic materials 0.000 description 2
- 150000002602 lanthanoids Chemical class 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 description 2
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 2
- 229960002447 thiram Drugs 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- PCCCQOGUVCNYOI-FNORWQNLSA-N (3e)-2,3-dimethylpenta-1,3-diene Chemical compound C\C=C(/C)C(C)=C PCCCQOGUVCNYOI-FNORWQNLSA-N 0.000 description 1
- AHAREKHAZNPPMI-AATRIKPKSA-N (3e)-hexa-1,3-diene Chemical compound CC\C=C\C=C AHAREKHAZNPPMI-AATRIKPKSA-N 0.000 description 1
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- QTYUSOHYEPOHLV-FNORWQNLSA-N 1,3-Octadiene Chemical compound CCCC\C=C\C=C QTYUSOHYEPOHLV-FNORWQNLSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- LIRNFNXOTBZTPP-UHFFFAOYSA-N 1-[2-(2-hydroxyethoxy)ethoxy]-2-methylpropan-2-ol Chemical compound CC(C)(O)COCCOCCO LIRNFNXOTBZTPP-UHFFFAOYSA-N 0.000 description 1
- RRQYJINTUHWNHW-UHFFFAOYSA-N 1-ethoxy-2-(2-ethoxyethoxy)ethane Chemical compound CCOCCOCCOCC RRQYJINTUHWNHW-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- KXYAVSFOJVUIHT-UHFFFAOYSA-N 2-vinylnaphthalene Chemical compound C1=CC=CC2=CC(C=C)=CC=C21 KXYAVSFOJVUIHT-UHFFFAOYSA-N 0.000 description 1
- IGLWCQMNTGCUBB-UHFFFAOYSA-N 3-methylidenepent-1-ene Chemical compound CCC(=C)C=C IGLWCQMNTGCUBB-UHFFFAOYSA-N 0.000 description 1
- ZSNRMRKAYAJYRZ-UHFFFAOYSA-N 4-methylidenehex-2-ene Chemical compound CCC(=C)C=CC ZSNRMRKAYAJYRZ-UHFFFAOYSA-N 0.000 description 1
- YBPXZRWAVVJHBP-UHFFFAOYSA-N 4-methylocta-1,3-diene Chemical compound CCCCC(C)=CC=C YBPXZRWAVVJHBP-UHFFFAOYSA-N 0.000 description 1
- YGQQJSWILPTCPE-UHFFFAOYSA-N 5-ethylidene-6-methylidenedecane Chemical compound CCCCC(=C)C(=CC)CCCC YGQQJSWILPTCPE-UHFFFAOYSA-N 0.000 description 1
- LACOCUZUDZZTSJ-UHFFFAOYSA-N CC(CCSC(C)C(C)Cl)C(C)Cl Chemical compound CC(CCSC(C)C(C)Cl)C(C)Cl LACOCUZUDZZTSJ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 241001441571 Hiodontidae Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- IORUEKDKNHHQAL-UHFFFAOYSA-N [2-tert-butyl-6-[(3-tert-butyl-2-hydroxy-5-methylphenyl)methyl]-4-methylphenyl] prop-2-enoate Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)OC(=O)C=C)=C1O IORUEKDKNHHQAL-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000031709 bromination Effects 0.000 description 1
- 238000005893 bromination reaction Methods 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229940019778 diethylene glycol diethyl ether Drugs 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229920003049 isoprene rubber Polymers 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 238000012667 polymer degradation Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000010734 process oil Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000010092 rubber production Methods 0.000 description 1
- YWWOEPOBDHZQEJ-UHFFFAOYSA-N s-(4-cyclohexyl-1,3-benzothiazol-2-yl)thiohydroxylamine Chemical group C1=CC=C2SC(SN)=NC2=C1C1CCCCC1 YWWOEPOBDHZQEJ-UHFFFAOYSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229960005486 vaccine Drugs 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
- C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C08G81/021—Block or graft polymers containing only sequences of polymers of C08C or C08F
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/375—Plasticisers, homogenisers or feeders comprising two or more stages
- B29C48/39—Plasticisers, homogenisers or feeders comprising two or more stages a first extruder feeding the melt into an intermediate location of a second extruder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
- B29C48/405—Intermeshing co-rotating screws
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/505—Screws
- B29C48/625—Screws characterised by the ratio of the threaded length of the screw to its outside diameter [L/D ratio]
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
- C08L23/283—Iso-olefin halogenated homopolymers or copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Belt Conveyors (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Tires In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA002279085A CA2279085C (en) | 1999-07-29 | 1999-07-29 | Rubber composition |
| CA2,279,085 | 1999-07-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2002105513A RU2002105513A (ru) | 2003-09-27 |
| RU2254348C2 true RU2254348C2 (ru) | 2005-06-20 |
Family
ID=4163873
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2002105513/04A RU2254348C2 (ru) | 1999-07-29 | 2000-07-27 | Резиновая композиция |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6737476B1 (enExample) |
| EP (1) | EP1208136B1 (enExample) |
| JP (1) | JP4996800B2 (enExample) |
| CN (1) | CN1142966C (enExample) |
| AU (1) | AU6418300A (enExample) |
| CA (1) | CA2279085C (enExample) |
| DE (1) | DE60026035T2 (enExample) |
| HK (1) | HK1048825B (enExample) |
| RU (1) | RU2254348C2 (enExample) |
| WO (1) | WO2001009225A1 (enExample) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2315075C1 (ru) * | 2006-11-21 | 2008-01-20 | Общество с ограниченной ответственностью "Константа-2" (ООО "Константа-2") | Антикоррозионная композиция |
| RU2389741C2 (ru) * | 2007-06-27 | 2010-05-20 | Сумитомо Раббер Индастриз, Лтд. | Резиновая смесь для шины, элемент шины и шина |
| RU2415875C2 (ru) * | 2005-12-05 | 2011-04-10 | Джей Эс Эр КОРПОРЕЙШН | Способ получения конъюгированного диенового полимера, конъюгированный диеновый полимер и каучуковая композиция |
| RU2431644C2 (ru) * | 2006-01-20 | 2011-10-20 | Бриджстоун Корпорейшн | Каучуковая композиция, содержащая модифицированный полибутадиеновый каучук, и шина на ее основе |
| RU2460738C2 (ru) * | 2005-07-11 | 2012-09-10 | Ленксесс Инк. | Жидкий малеинированный бутилкаучук |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002088207A (ja) * | 2000-09-13 | 2002-03-27 | Polytec Design:Kk | ゴム組成物 |
| CA2339080C (en) | 2001-03-02 | 2009-11-17 | Bayer Inc. | Filled elastomeric butyl compounds |
| CA2446474C (en) * | 2003-10-24 | 2011-11-29 | Rui Resendes | Silica-filled elastomeric compounds |
| JP4583023B2 (ja) * | 2003-12-16 | 2010-11-17 | 住友ゴム工業株式会社 | タイヤサイドウォール用ゴム組成物 |
| DE102004024013A1 (de) | 2004-05-14 | 2005-12-01 | Bayer Chemicals Ag | Farbreine, gut dispergierbare Eisenoxidrotpigmente mit hoher Mahlstabilität |
| RU2418826C2 (ru) | 2004-12-16 | 2011-05-20 | Ленксесс Инк. | Наполненные диоксидом кремния эластомерные смеси |
| US8198379B2 (en) | 2005-08-05 | 2012-06-12 | Lanxess Inc. | Halobutyl elastomers |
| CA2551997C (en) | 2005-08-26 | 2014-05-27 | Lanxess Inc. | Novel methods for the preparation of butyl graft copolymers |
| KR100827335B1 (ko) * | 2005-10-06 | 2008-05-06 | 주식회사 엘지화학 | 그라프트 공중합체 및 이의 제조방법 |
| US20070100041A1 (en) * | 2005-11-03 | 2007-05-03 | Rui Resendes | Filled elastomeric compounds |
| KR20150043408A (ko) | 2012-08-14 | 2015-04-22 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 그래프팅된 아이소부틸렌 공중합체를 포함하는 접착제 |
| CN104311932A (zh) * | 2014-11-20 | 2015-01-28 | 三角轮胎股份有限公司 | 半钢子午线轮胎胎面橡胶组合物 |
| WO2016106062A1 (en) | 2014-12-23 | 2016-06-30 | Bridgestone Americas Tire Operations, Llc | Actinic radiation curable polymeric mixtures, cured polymeric mixtures and related processes |
| US11097531B2 (en) | 2015-12-17 | 2021-08-24 | Bridgestone Americas Tire Operations, Llc | Additive manufacturing cartridges and processes for producing cured polymeric products by additive manufacturing |
| CN108948273B (zh) * | 2018-05-29 | 2020-07-21 | 潍坊硕邑化学有限公司 | 一种丁二烯-氯化聚乙烯-苯乙烯接枝共聚橡胶及其制备方法 |
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| GB870947A (en) * | 1958-05-13 | 1961-06-21 | Firestone Tire & Rubber Co | Vulcanization rubbery composition |
| US4294732A (en) * | 1979-08-16 | 1981-10-13 | Bridgestone Tire Company Limited | Rubber mounting compositions |
| US4323485A (en) * | 1979-04-09 | 1982-04-06 | The Yokohama Rubber Co., Ltd. | Rubber compositions for tire treads having low rolling resistance |
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| US3928259A (en) * | 1972-11-24 | 1975-12-23 | Polysar Ltd | Halogenated butyl rubber of improved scorch characteristics |
| JPS6397645A (ja) | 1986-10-14 | 1988-04-28 | Yokohama Rubber Co Ltd:The | トレツド用ゴム組成物 |
| US5221716A (en) | 1990-03-26 | 1993-06-22 | The Goodyear Tire & Rubber Company | Comb polymers having a halobutyl rubber backbone |
| US5264494A (en) * | 1991-05-15 | 1993-11-23 | Polysar Rubber Corporation | Halogenated butyl rubber graft copolymers |
| DE59205083D1 (de) * | 1991-08-30 | 1996-02-29 | Huels Chemische Werke Ag | Verfahren zur Herstellung von Dienkautschuk-Vulkanisaten |
| EA199900535A1 (ru) * | 1996-12-18 | 2000-02-28 | Эксон Кемикэл Пейтентс Инк. | Смеси полимеров, которым придана совместимость, приготовленные с использованием полифункционального агента |
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- 1999-07-29 CA CA002279085A patent/CA2279085C/en not_active Expired - Fee Related
-
2000
- 2000-07-27 DE DE60026035T patent/DE60026035T2/de not_active Expired - Lifetime
- 2000-07-27 EP EP00951132A patent/EP1208136B1/en not_active Expired - Lifetime
- 2000-07-27 RU RU2002105513/04A patent/RU2254348C2/ru not_active IP Right Cessation
- 2000-07-27 US US10/048,281 patent/US6737476B1/en not_active Expired - Fee Related
- 2000-07-27 CN CNB008110484A patent/CN1142966C/zh not_active Expired - Fee Related
- 2000-07-27 HK HK03101087.9A patent/HK1048825B/zh not_active IP Right Cessation
- 2000-07-27 WO PCT/CA2000/000866 patent/WO2001009225A1/en not_active Ceased
- 2000-07-27 AU AU64183/00A patent/AU6418300A/en not_active Abandoned
- 2000-07-27 JP JP2001514029A patent/JP4996800B2/ja not_active Expired - Fee Related
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| GB870947A (en) * | 1958-05-13 | 1961-06-21 | Firestone Tire & Rubber Co | Vulcanization rubbery composition |
| US4323485A (en) * | 1979-04-09 | 1982-04-06 | The Yokohama Rubber Co., Ltd. | Rubber compositions for tire treads having low rolling resistance |
| US4294732A (en) * | 1979-08-16 | 1981-10-13 | Bridgestone Tire Company Limited | Rubber mounting compositions |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2460738C2 (ru) * | 2005-07-11 | 2012-09-10 | Ленксесс Инк. | Жидкий малеинированный бутилкаучук |
| RU2415875C2 (ru) * | 2005-12-05 | 2011-04-10 | Джей Эс Эр КОРПОРЕЙШН | Способ получения конъюгированного диенового полимера, конъюгированный диеновый полимер и каучуковая композиция |
| RU2431644C2 (ru) * | 2006-01-20 | 2011-10-20 | Бриджстоун Корпорейшн | Каучуковая композиция, содержащая модифицированный полибутадиеновый каучук, и шина на ее основе |
| RU2315075C1 (ru) * | 2006-11-21 | 2008-01-20 | Общество с ограниченной ответственностью "Константа-2" (ООО "Константа-2") | Антикоррозионная композиция |
| RU2389741C2 (ru) * | 2007-06-27 | 2010-05-20 | Сумитомо Раббер Индастриз, Лтд. | Резиновая смесь для шины, элемент шины и шина |
Also Published As
| Publication number | Publication date |
|---|---|
| HK1048825A1 (en) | 2003-04-17 |
| EP1208136A1 (en) | 2002-05-29 |
| AU6418300A (en) | 2001-02-19 |
| EP1208136B1 (en) | 2006-02-15 |
| WO2001009225A1 (en) | 2001-02-08 |
| DE60026035T2 (de) | 2006-08-24 |
| CA2279085A1 (en) | 2001-01-29 |
| JP4996800B2 (ja) | 2012-08-08 |
| DE60026035D1 (de) | 2006-04-20 |
| CN1365372A (zh) | 2002-08-21 |
| JP2003506510A (ja) | 2003-02-18 |
| CA2279085C (en) | 2008-10-07 |
| CN1142966C (zh) | 2004-03-24 |
| US6737476B1 (en) | 2004-05-18 |
| HK1048825B (zh) | 2005-01-21 |
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