RU2205869C2 - Многофазная детергентная таблетка, способ ее получения и способ мытья в моечной машине - Google Patents

Многофазная детергентная таблетка, способ ее получения и способ мытья в моечной машине Download PDF

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Publication number
RU2205869C2
RU2205869C2 RU2001104447/04A RU2001104447A RU2205869C2 RU 2205869 C2 RU2205869 C2 RU 2205869C2 RU 2001104447/04 A RU2001104447/04 A RU 2001104447/04A RU 2001104447 A RU2001104447 A RU 2001104447A RU 2205869 C2 RU2205869 C2 RU 2205869C2
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RU
Russia
Prior art keywords
phase
detergent
acid
preferred
surfactants
Prior art date
Application number
RU2001104447/04A
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English (en)
Russian (ru)
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RU2001104447A (ru
Inventor
Патрицио РИЧЧИ
Бренда Франсез БЕННИ
Кристофер Джеймс БАЙНДЕР
Original Assignee
Дзе Проктер Энд Гэмбл Компани
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26314049&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=RU2205869(C2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from GBGB9815525.2A external-priority patent/GB9815525D0/en
Application filed by Дзе Проктер Энд Гэмбл Компани filed Critical Дзе Проктер Энд Гэмбл Компани
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Publication of RU2205869C2 publication Critical patent/RU2205869C2/ru
Publication of RU2001104447A publication Critical patent/RU2001104447A/ru

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047Detergents in the form of bars or tablets
    • C11D17/0065Solid detergents containing builders
    • C11D17/0073Tablets
    • C11D17/0086Laundry tablets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047Detergents in the form of bars or tablets
    • C11D17/0065Solid detergents containing builders
    • C11D17/0073Tablets
    • C11D17/0078Multilayered tablets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246Silicates, e.g. diatomaceous earth
    • C11D3/1253Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/126Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246Silicates, e.g. diatomaceous earth
    • C11D3/1253Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/1273Crystalline layered silicates of type NaMeSixO2x+1YH2O
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/221Mono, di- or trisaccharides or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707Polyethers, e.g. polyalkyleneoxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776Heterocyclic compounds, e.g. lactam
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3792Amine oxide containing polymers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38609Protease or amylase in solid compositions only
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38645Preparations containing enzymes, e.g. protease or amylase containing cellulase
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40Dyes ; Pigments
    • C11D3/42Brightening agents ; Blueing agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Sealing With Elastic Sealing Lips (AREA)
RU2001104447/04A 1998-07-17 1999-07-09 Многофазная детергентная таблетка, способ ее получения и способ мытья в моечной машине RU2205869C2 (ru)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GBGB9815525.2A GB9815525D0 (en) 1998-07-17 1998-07-17 Detergent tablet
GB9815525.2 1998-07-17
GB9911217A GB2339790B (en) 1998-07-17 1999-05-17 Detergent tablet
GB9911217.9 1999-05-17

Publications (2)

Publication Number Publication Date
RU2205869C2 true RU2205869C2 (ru) 2003-06-10
RU2001104447A RU2001104447A (ru) 2003-08-27

Family

ID=26314049

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2001104447/04A RU2205869C2 (ru) 1998-07-17 1999-07-09 Многофазная детергентная таблетка, способ ее получения и способ мытья в моечной машине

Country Status (21)

Country Link
EP (2) EP0979864B1 (de)
JP (1) JP2002520478A (de)
CN (1) CN1309693A (de)
AT (2) ATE211503T1 (de)
AU (1) AU762815B2 (de)
BR (1) BR9912834A (de)
CA (1) CA2333388C (de)
DE (2) DE69908139T2 (de)
DK (1) DK0979864T3 (de)
ES (2) ES2168835T3 (de)
FI (1) FI4406U1 (de)
FR (1) FR2782089B1 (de)
IE (1) IES990569A2 (de)
IT (2) ITMI991509A1 (de)
NL (1) NL1012583C1 (de)
PL (1) PL189558B1 (de)
PT (1) PT979864E (de)
RU (1) RU2205869C2 (de)
SK (1) SK642001A3 (de)
TR (1) TR200100094T2 (de)
WO (1) WO2000004123A2 (de)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2511399C2 (ru) * 2008-07-23 2014-04-10 Рекитт Бенкизер Н.В. Контейнер
RU2533552C2 (ru) * 2009-04-16 2014-11-20 ПУРАК Биокем БВ Очистка с регулируемым высвобождением кислоты
RU2612142C2 (ru) * 2012-06-11 2017-03-02 Дзе Проктер Энд Гэмбл Компани Моющий состав

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE29911484U1 (de) * 1998-07-17 2000-02-24 Procter & Gamble Reinigungsmitteltablette
PT979865E (pt) * 1998-07-17 2002-09-30 Procter & Gamble Pastilhas detergentes
DK0976819T3 (da) * 1998-07-17 2002-05-13 Procter & Gamble Detergenttablet
DE19922578C2 (de) * 1999-05-17 2003-12-24 Benckiser Nv Verfahren zur Herstellung einer mehrschichtigen Tablette, insbesondere Reinigungsmitteltablette, sowie danach herstellbares Produkt
DE10007608A1 (de) * 2000-02-18 2001-08-30 Henkel Kgaa Protease und Percarbonat enthaltende Wasch- und Reinigungsmittel
DE10010760A1 (de) * 2000-03-04 2001-09-20 Henkel Kgaa Mehrphasige Wasch- und Reinigungsmittelformkörper mit nicht-gepreßten Anteilen
US6386462B1 (en) * 2000-07-31 2002-05-14 S. C. Johnson & Son, Inc. Method and apparatus for dispensing liquids in aerosolized form with minimum spillage
DE10243311A1 (de) * 2002-09-18 2004-04-01 Henkel Kgaa Befüllte Muldentabletten und Verfahren zu ihrer Herstellung
DE10253479A1 (de) * 2002-11-16 2004-06-03 Henkel Kgaa Befüllte Muldentabletten und Verfahren zu ihrer Herstellung II
DE102007059968A1 (de) * 2007-12-11 2009-06-18 Henkel Ag & Co. Kgaa Reinigungsmittel
CN107090014B (zh) 2008-03-26 2023-04-25 诺维信公司 稳定化的液体酶组合物
AU2010299953B2 (en) * 2009-09-25 2015-02-12 Novozymes A/S Detergent composition
PL414778A1 (pl) 2015-11-13 2017-05-22 Skorut Systemy Solarne Spółka Z Ograniczoną Odpowiedzialnością Sposób modyfikacji laminatów stosowanych do wytwarzania obwodów drukowanych
CN109971562A (zh) * 2019-04-23 2019-07-05 南京巨鲨显示科技有限公司 一种缓释型医用手工多酶清洗片及其制备方法
CN110373287B (zh) * 2019-08-15 2021-11-09 广州立白企业集团有限公司 一种具有多相结构的自动洗碗机清洁片
CN112646672A (zh) * 2019-10-10 2021-04-13 杨子凡 一种洗衣机槽用清洁块及其制备方法

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2035622A5 (de) * 1969-02-18 1970-12-18 Lion Fat Oil Co Ltd
CA1182371A (en) * 1980-12-18 1985-02-12 Jeyes Group Limited Lavatory cleansing blocks
DE3541146A1 (de) * 1985-11-21 1987-05-27 Henkel Kgaa Mehrschichtige reinigungsmitteltabletten fuer das maschinelle geschirrspuelen
GB9015503D0 (en) * 1990-07-13 1990-08-29 Unilever Plc Detergent composition
US5133892A (en) * 1990-10-17 1992-07-28 Lever Brothers Company, Division Of Conopco, Inc. Machine dishwashing detergent tablets
GB9022724D0 (en) * 1990-10-19 1990-12-05 Unilever Plc Detergent compositions
CA2226143C (en) * 1995-07-13 2007-11-20 Joh. A. Benckiser Gmbh Dish washer product in tablet form
US5837663A (en) * 1996-12-23 1998-11-17 Lever Brothers Company, Division Of Conopco, Inc. Machine dishwashing tablets containing a peracid
GB9711829D0 (en) * 1997-06-06 1997-08-06 Unilever Plc Detergent compositions
GB2327949A (en) * 1997-08-02 1999-02-10 Procter & Gamble Detergent tablet
ES2190120T3 (es) * 1997-11-10 2003-07-16 Procter & Gamble Procedimiento para la preparacion de una pastilla de detergente.
EP1032643B1 (de) * 1997-11-10 2003-05-21 The Procter & Gamble Company Mehrschichtige waschmitteltablette mit sowohl verpresstem als auch nicht-verpresstem anteil
ES2198768T3 (es) * 1997-11-10 2004-02-01 THE PROCTER & GAMBLE COMPANY Procedimiento para fabricar una pastilla detergente.
ES2227900T3 (es) * 1997-11-26 2005-04-01 THE PROCTER & GAMBLE COMPANY Procedimiento para fabricar una pastilla detergente.
DE69830334T2 (de) * 1997-11-26 2006-02-02 The Procter & Gamble Company, Cincinnati Waschmitteltablette
ATE287944T1 (de) * 1997-11-26 2005-02-15 Procter & Gamble Waschmitteltablette
DE69805758T2 (de) * 1997-11-26 2003-01-30 Procter & Gamble Geschirrspülverfahren
WO2000004117A2 (en) * 1998-07-17 2000-01-27 The Procter & Gamble Company Detergent tablet
PT979865E (pt) * 1998-07-17 2002-09-30 Procter & Gamble Pastilhas detergentes
DE69920517T2 (de) * 1998-07-17 2005-11-10 The Procter & Gamble Company, Cincinnati Waschmitteltablette
DE29911484U1 (de) * 1998-07-17 2000-02-24 Procter & Gamble Reinigungsmitteltablette
DK0976819T3 (da) * 1998-07-17 2002-05-13 Procter & Gamble Detergenttablet

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2511399C2 (ru) * 2008-07-23 2014-04-10 Рекитт Бенкизер Н.В. Контейнер
RU2533552C2 (ru) * 2009-04-16 2014-11-20 ПУРАК Биокем БВ Очистка с регулируемым высвобождением кислоты
RU2612142C2 (ru) * 2012-06-11 2017-03-02 Дзе Проктер Энд Гэмбл Компани Моющий состав

Also Published As

Publication number Publication date
JP2002520478A (ja) 2002-07-09
DE69908139D1 (de) 2003-06-26
ES2194802T3 (es) 2003-12-01
PT979864E (pt) 2002-06-28
BR9912834A (pt) 2001-05-02
NL1012583A1 (nl) 2000-01-19
CN1309693A (zh) 2001-08-22
EP0979864A1 (de) 2000-02-16
ATE241004T1 (de) 2003-06-15
DK0979864T3 (da) 2002-04-22
DE69900736T2 (de) 2002-08-29
TR200100094T2 (tr) 2001-05-21
SK642001A3 (en) 2001-06-11
ITMI991568A0 (it) 1999-07-15
ITMI991568A1 (it) 2001-01-15
CA2333388C (en) 2005-04-05
ITMI991509A1 (it) 1999-12-18
AU762815B2 (en) 2003-07-03
EP1097191A2 (de) 2001-05-09
FR2782089A1 (fr) 2000-02-11
WO2000004123A2 (en) 2000-01-27
FIU990320U0 (fi) 1999-07-16
FI4406U1 (fi) 2000-05-18
CA2333388A1 (en) 2000-01-27
DE69900736D1 (de) 2002-02-28
ITMI991509A0 (it) 1999-07-09
EP0979864B1 (de) 2002-01-02
ATE211503T1 (de) 2002-01-15
WO2000004123A3 (en) 2000-04-13
AU4964299A (en) 2000-02-07
PL189558B1 (pl) 2005-08-31
PL345972A1 (en) 2002-01-14
FR2782089B1 (fr) 2004-11-05
NL1012583C1 (nl) 2000-01-25
ES2168835T3 (es) 2002-06-16
DE69908139T2 (de) 2004-04-08
IES990569A2 (en) 2000-07-12

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Effective date: 20070710