RU2107698C1 - Фторэластомерный сополимер - Google Patents
Фторэластомерный сополимер Download PDFInfo
- Publication number
- RU2107698C1 RU2107698C1 RU93005161A RU93005161A RU2107698C1 RU 2107698 C1 RU2107698 C1 RU 2107698C1 RU 93005161 A RU93005161 A RU 93005161A RU 93005161 A RU93005161 A RU 93005161A RU 2107698 C1 RU2107698 C1 RU 2107698C1
- Authority
- RU
- Russia
- Prior art keywords
- mol
- ethylene
- copolymers
- copolymer
- monomeric units
- Prior art date
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- 229920001973 fluoroelastomer Polymers 0.000 title abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000005977 Ethylene Substances 0.000 claims abstract description 17
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims abstract description 14
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920001577 copolymer Polymers 0.000 claims description 29
- 239000000178 monomer Substances 0.000 claims description 17
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 3
- 229920001971 elastomer Polymers 0.000 abstract 1
- 239000000806 elastomer Substances 0.000 abstract 1
- 229920002313 fluoropolymer Polymers 0.000 abstract 1
- 239000004811 fluoropolymer Substances 0.000 abstract 1
- 239000003566 sealing material Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 18
- 229920000642 polymer Polymers 0.000 description 12
- 239000003921 oil Substances 0.000 description 9
- 238000006116 polymerization reaction Methods 0.000 description 9
- 239000002585 base Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000004530 micro-emulsion Substances 0.000 description 4
- JMGNVALALWCTLC-UHFFFAOYSA-N 1-fluoro-2-(2-fluoroethenoxy)ethene Chemical compound FC=COC=CF JMGNVALALWCTLC-UHFFFAOYSA-N 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 3
- 150000003839 salts Chemical group 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical class [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical class [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical class BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Chemical class 0.000 description 2
- 150000001649 bromium compounds Chemical class 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 150000004694 iodide salts Chemical class 0.000 description 2
- -1 peroxide compounds Chemical class 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- VERMEZLHWFHDLK-UHFFFAOYSA-N tetrahydroxybenzene Natural products OC1=CC=C(O)C(O)=C1O VERMEZLHWFHDLK-UHFFFAOYSA-N 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- SSJKDUAYUOEFSU-UHFFFAOYSA-N 2-chloro-1,1,3,3,4,4,5,6,6,6-decafluorohex-1-ene Chemical compound FC(C(F)(F)F)C(C(C(=C(F)F)Cl)(F)F)(F)F SSJKDUAYUOEFSU-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical class [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical class [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical class [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- XQJHRCVXRAJIDY-UHFFFAOYSA-N aminophosphine Chemical compound PN XQJHRCVXRAJIDY-UHFFFAOYSA-N 0.000 description 1
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- YOALFLHFSFEMLP-UHFFFAOYSA-N azane;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoic acid Chemical compound [NH4+].[O-]C(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YOALFLHFSFEMLP-UHFFFAOYSA-N 0.000 description 1
- ZFVMWEVVKGLCIJ-UHFFFAOYSA-N bisphenol AF Chemical compound C1=CC(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C=C1 ZFVMWEVVKGLCIJ-UHFFFAOYSA-N 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Chemical class 0.000 description 1
- GRWZHXKQBITJKP-UHFFFAOYSA-N dithionous acid Chemical class OS(=O)S(O)=O GRWZHXKQBITJKP-UHFFFAOYSA-N 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 125000005342 perphosphate group Chemical group 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical class O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000004714 phosphonium salts Chemical class 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- WQGWDDDVZFFDIG-UHFFFAOYSA-N trihydroxybenzene Natural products OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/18—Monomers containing fluorine
- C08F14/22—Vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/22—Vinylidene fluoride
- C08F214/225—Vinylidene fluoride with non-fluorinated comonomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Sealing Material Composition (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI92A001244 | 1992-05-22 | ||
| ITMI921244A IT1255633B (it) | 1992-05-22 | 1992-05-22 | Copolimeri fluoroelastomerici e fluoroplastomerici dotati di elevata resistenza alle basi |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU93005161A RU93005161A (ru) | 1996-08-10 |
| RU2107698C1 true RU2107698C1 (ru) | 1998-03-27 |
Family
ID=11363360
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU93005161A RU2107698C1 (ru) | 1992-05-22 | 1993-05-21 | Фторэластомерный сополимер |
Country Status (12)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2432366C1 (ru) * | 2010-04-09 | 2011-10-27 | Федеральное государственное унитарное предприятие "Ордена Ленина и ордена Трудового Красного Знамени научно-исследовательский институт синтетического каучука имени академика С.В. Лебедева" | Низкомолекулярные тройные сополимеры винилиденфторида и мономера, содержащего фторсульфатную группу |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3178312B2 (ja) * | 1995-10-13 | 2001-06-18 | 日本メクトロン株式会社 | フルオロエラストマーおよびその架橋性組成物 |
| IT1286042B1 (it) * | 1996-10-25 | 1998-07-07 | Ausimont Spa | O-rings da fluoroelastomeri vulcanizzabili per via ionica |
| EP1209175A4 (en) * | 1999-06-29 | 2004-10-06 | Daikin Ind Ltd | Fluoroelastomer and vulcanized molding |
| US6803435B2 (en) | 2002-07-18 | 2004-10-12 | 3M Innovative Properties Company | Curable fluoropolymers containing bromine groups having improved compression set |
| US6734254B1 (en) | 2003-01-13 | 2004-05-11 | 3M Innovative Properties Company | Co-curable blends featuring bromine-and iodine-containing fluoroplastic polymers |
| JP5327215B2 (ja) * | 2008-03-27 | 2013-10-30 | ダイキン工業株式会社 | 含フッ素エラストマー組成物 |
| CN116157430A (zh) * | 2020-07-28 | 2023-05-23 | 大金工业株式会社 | 含氟弹性体水性分散液的制造方法和含氟弹性体水性分散液 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4368308A (en) * | 1980-07-08 | 1983-01-11 | Asahi Glass Company, Ltd. | Fluorine-containing elastomer having excellent low temperature resistance and oil resistance |
| US4694045A (en) * | 1985-12-11 | 1987-09-15 | E. I. Du Pont De Nemours And Company | Base resistant fluoroelastomers |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3194796A (en) * | 1962-03-22 | 1965-07-13 | Du Pont | Elastomeric fluorocarbon terpolymers of vinylidene fluoride, hexafluoropropylene and a halogen free polar monomer |
| US3655727A (en) * | 1970-01-16 | 1972-04-11 | Minnesota Mining & Mfg | Curing systems for vinylidine fluoride elastomers |
| DE2037028C2 (de) * | 1970-07-25 | 1982-07-08 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung fluorhaltiger Copolymerisate |
| US3876654A (en) * | 1970-12-23 | 1975-04-08 | Du Pont | Fluoroelastomer composition |
| US3686143A (en) * | 1971-03-22 | 1972-08-22 | Du Pont | Guanidine and amidine accelerators for vulcanization of fluoroelastomers |
| US3712877A (en) * | 1971-07-06 | 1973-01-23 | Minnesota Mining & Mfg | Curable vinylidene fluoride elastomers containing phosphonium curing agents |
| US3857807A (en) * | 1971-11-11 | 1974-12-31 | Daikin Ind Ltd | Fluoroelastomer composition |
| US3933732A (en) * | 1972-09-28 | 1976-01-20 | E. I. Du Pont De Nemours And Company | Fluoroelastomer composition and curing process |
| NL189567C (nl) * | 1977-12-14 | 1993-05-17 | Montedison Spa | Vulcaniseerbare mengsels op basis van elastomere copolymeren van vinylideenfluoride, werkwijze om deze te vulcaniseren en voorwerpen geheel of gedeeltelijk bestaande uit de zo verkregen gevulcaniseerde mengsels. |
| US4233421A (en) * | 1979-02-26 | 1980-11-11 | Minnesota Mining And Manufacturing Company | Fluoroelastomer composition containing sulfonium curing agents |
| IT1163158B (it) * | 1983-03-22 | 1987-04-08 | Montedison Spa | Acceleranti per la vulcanizzazione di copolimeri elastomerici |
| CA1265288A (en) * | 1984-11-22 | 1990-01-30 | E. I. Du Pont De Nemours And Company | Curable fluoroelastomer composition |
| IL82308A (en) * | 1986-06-26 | 1990-11-29 | Ausimont Spa | Microemulsions containing perfluoropolyethers |
| IT1204903B (it) * | 1986-06-26 | 1989-03-10 | Ausimont Spa | Processo di polimerizzazione in dispersione acquosa di monomeri florati |
| IT1203514B (it) * | 1987-02-26 | 1989-02-15 | Ausimont Spa | Microemulsioni a base di tre liquidi immiscibili,comprendenti un perfluoropolietere |
| IT1223324B (it) * | 1987-10-28 | 1990-09-19 | Ausimont Spa | Microemulsioni acquose comprendenti perfluoropolieteri funzionali |
| US4882390A (en) * | 1988-04-01 | 1989-11-21 | Minnesota Mining And Manufacturing Company | Fluoroelastomer composition with organo-onium compounds |
| IT1235545B (it) * | 1989-07-10 | 1992-09-09 | Ausimont Srl | Fluoroelastomeri dotati di migliore processabilita' e procedimento di preparazione |
| IT1247934B (it) * | 1991-05-15 | 1995-01-05 | Ausimont Spa | Fluoroelastomeri a base di vinilidenfluoruro, dotati di superiore resistenza alle basi |
-
1992
- 1992-05-22 IT ITMI921244A patent/IT1255633B/it active IP Right Grant
-
1993
- 1993-05-05 EP EP93107256A patent/EP0570762B1/en not_active Expired - Lifetime
- 1993-05-05 AT AT93107256T patent/ATE162534T1/de not_active IP Right Cessation
- 1993-05-05 DE DE69316437T patent/DE69316437T2/de not_active Expired - Lifetime
- 1993-05-20 US US08/064,276 patent/US5354824A/en not_active Expired - Lifetime
- 1993-05-20 CA CA002096673A patent/CA2096673C/en not_active Expired - Lifetime
- 1993-05-21 MX MX9302984A patent/MX9302984A/es not_active IP Right Cessation
- 1993-05-21 RU RU93005161A patent/RU2107698C1/ru active
- 1993-05-22 KR KR1019930008908A patent/KR100267450B1/ko not_active Expired - Lifetime
- 1993-05-22 CN CN93107600A patent/CN1081685A/zh active Pending
- 1993-05-24 JP JP14424093A patent/JP3436774B2/ja not_active Expired - Lifetime
- 1993-06-01 TW TW082104338A patent/TW249807B/zh active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4368308A (en) * | 1980-07-08 | 1983-01-11 | Asahi Glass Company, Ltd. | Fluorine-containing elastomer having excellent low temperature resistance and oil resistance |
| US4694045A (en) * | 1985-12-11 | 1987-09-15 | E. I. Du Pont De Nemours And Company | Base resistant fluoroelastomers |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2432366C1 (ru) * | 2010-04-09 | 2011-10-27 | Федеральное государственное унитарное предприятие "Ордена Ленина и ордена Трудового Красного Знамени научно-исследовательский институт синтетического каучука имени академика С.В. Лебедева" | Низкомолекулярные тройные сополимеры винилиденфторида и мономера, содержащего фторсульфатную группу |
Also Published As
| Publication number | Publication date |
|---|---|
| IT1255633B (it) | 1995-11-09 |
| JPH06248027A (ja) | 1994-09-06 |
| EP0570762A1 (en) | 1993-11-24 |
| ITMI921244A1 (it) | 1993-11-22 |
| TW249807B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1995-06-21 |
| CA2096673C (en) | 2007-10-16 |
| MX9302984A (es) | 1994-02-28 |
| DE69316437D1 (de) | 1998-02-26 |
| CN1081685A (zh) | 1994-02-09 |
| EP0570762B1 (en) | 1998-01-21 |
| JP3436774B2 (ja) | 2003-08-18 |
| KR100267450B1 (ko) | 2000-10-16 |
| CA2096673A1 (en) | 1993-11-23 |
| DE69316437T2 (de) | 1998-05-07 |
| US5354824A (en) | 1994-10-11 |
| KR930023382A (ko) | 1993-12-18 |
| ATE162534T1 (de) | 1998-02-15 |
| ITMI921244A0 (it) | 1992-05-22 |
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