RU2019106696A - Кислородобарьерный пластиковый материал - Google Patents
Кислородобарьерный пластиковый материал Download PDFInfo
- Publication number
- RU2019106696A RU2019106696A RU2019106696A RU2019106696A RU2019106696A RU 2019106696 A RU2019106696 A RU 2019106696A RU 2019106696 A RU2019106696 A RU 2019106696A RU 2019106696 A RU2019106696 A RU 2019106696A RU 2019106696 A RU2019106696 A RU 2019106696A
- Authority
- RU
- Russia
- Prior art keywords
- esters
- packaging film
- film according
- multilayer packaging
- beta
- Prior art date
Links
- 239000000463 material Substances 0.000 title claims 2
- 229920003023 plastic Polymers 0.000 title claims 2
- 239000004033 plastic Substances 0.000 title claims 2
- 239000010410 layer Substances 0.000 claims 21
- 229920006281 multilayer packaging film Polymers 0.000 claims 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 11
- 229910052760 oxygen Inorganic materials 0.000 claims 11
- 239000001301 oxygen Substances 0.000 claims 11
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 claims 8
- -1 fellandrene Chemical compound 0.000 claims 7
- 230000002000 scavenging effect Effects 0.000 claims 7
- WONIGEXYPVIKFS-UHFFFAOYSA-N Verbenol Chemical compound CC1=CC(O)C2C(C)(C)C1C2 WONIGEXYPVIKFS-UHFFFAOYSA-N 0.000 claims 6
- GRWFGVWFFZKLTI-UHFFFAOYSA-N α-pinene Chemical compound CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 claims 6
- FQTLCLSUCSAZDY-UHFFFAOYSA-N (+) E(S) nerolidol Natural products CC(C)=CCCC(C)=CCCC(C)(O)C=C FQTLCLSUCSAZDY-UHFFFAOYSA-N 0.000 claims 5
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 claims 5
- FQTLCLSUCSAZDY-ATGUSINASA-N Nerolidol Chemical compound CC(C)=CCC\C(C)=C\CC[C@](C)(O)C=C FQTLCLSUCSAZDY-ATGUSINASA-N 0.000 claims 5
- 239000000654 additive Substances 0.000 claims 5
- 230000004888 barrier function Effects 0.000 claims 5
- WASNIKZYIWZQIP-AWEZNQCLSA-N nerolidol Natural products CC(=CCCC(=CCC[C@@H](O)C=C)C)C WASNIKZYIWZQIP-AWEZNQCLSA-N 0.000 claims 5
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 claims 4
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 claims 4
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N Citronellol Natural products OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 claims 4
- 239000005792 Geraniol Substances 0.000 claims 4
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 claims 4
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 claims 4
- 125000003710 aryl alkyl group Chemical group 0.000 claims 4
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 claims 4
- 235000000484 citronellol Nutrition 0.000 claims 4
- 229940113087 geraniol Drugs 0.000 claims 4
- 229930007744 linalool Natural products 0.000 claims 4
- NDTYTMIUWGWIMO-UHFFFAOYSA-N perillyl alcohol Chemical compound CC(=C)C1CCC(CO)=CC1 NDTYTMIUWGWIMO-UHFFFAOYSA-N 0.000 claims 4
- WTARULDDTDQWMU-RKDXNWHRSA-N (+)-β-pinene Chemical compound C1[C@H]2C(C)(C)[C@@H]1CCC2=C WTARULDDTDQWMU-RKDXNWHRSA-N 0.000 claims 3
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-Nopinene Natural products C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 claims 3
- 229930007631 (-)-perillyl alcohol Natural products 0.000 claims 3
- GRWFGVWFFZKLTI-IUCAKERBSA-N 1S,5S-(-)-alpha-Pinene Natural products CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 claims 3
- IRZWAJHUWGZMMT-UHFFFAOYSA-N Chrysanthenol Natural products CC1=CCC2C(C)(C)C1C2O IRZWAJHUWGZMMT-UHFFFAOYSA-N 0.000 claims 3
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 claims 3
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 claims 3
- 229930006722 beta-pinene Natural products 0.000 claims 3
- 239000003054 catalyst Substances 0.000 claims 3
- 229920001577 copolymer Polymers 0.000 claims 3
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 claims 3
- 235000005693 perillyl alcohol Nutrition 0.000 claims 3
- 150000003097 polyterpenes Chemical class 0.000 claims 3
- 229920005989 resin Polymers 0.000 claims 3
- 239000011347 resin Substances 0.000 claims 3
- 229910052723 transition metal Inorganic materials 0.000 claims 3
- 150000003624 transition metals Chemical class 0.000 claims 3
- IBVJWOMJGCHRRW-UHFFFAOYSA-N 3,7,7-Trimethylbicyclo[4.1.0]hept-2-ene Chemical compound C1CC(C)=CC2C(C)(C)C12 IBVJWOMJGCHRRW-UHFFFAOYSA-N 0.000 claims 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- 229920001328 Polyvinylidene chloride Polymers 0.000 claims 2
- 125000002877 alkyl aryl group Chemical group 0.000 claims 2
- 150000007860 aryl ester derivatives Chemical class 0.000 claims 2
- UAHWPYUMFXYFJY-UHFFFAOYSA-N beta-myrcene Chemical compound CC(C)=CCCC(=C)C=C UAHWPYUMFXYFJY-UHFFFAOYSA-N 0.000 claims 2
- CRPUJAZIXJMDBK-UHFFFAOYSA-N camphene Chemical compound C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 claims 2
- BQOFWKZOCNGFEC-UHFFFAOYSA-N carene Chemical compound C1C(C)=CCC2C(C)(C)C12 BQOFWKZOCNGFEC-UHFFFAOYSA-N 0.000 claims 2
- ULDHMXUKGWMISQ-UHFFFAOYSA-N carvone Chemical compound CC(=C)C1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-UHFFFAOYSA-N 0.000 claims 2
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 claims 2
- GJWSUKYXUMVMGX-UHFFFAOYSA-N citronellic acid Chemical compound OC(=O)CC(C)CCC=C(C)C GJWSUKYXUMVMGX-UHFFFAOYSA-N 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 2
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 claims 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- CDSMSBUVCWHORP-UHFFFAOYSA-N perillic acid Chemical compound CC(=C)C1CCC(C(O)=O)=CC1 CDSMSBUVCWHORP-UHFFFAOYSA-N 0.000 claims 2
- RUMOYJJNUMEFDD-UHFFFAOYSA-N perillyl aldehyde Chemical compound CC(=C)C1CCC(C=O)=CC1 RUMOYJJNUMEFDD-UHFFFAOYSA-N 0.000 claims 2
- 229920000098 polyolefin Polymers 0.000 claims 2
- 239000004800 polyvinyl chloride Substances 0.000 claims 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims 2
- 229920001169 thermoplastic Polymers 0.000 claims 2
- YKFLAYDHMOASIY-UHFFFAOYSA-N γ-terpinene Chemical compound CC(C)C1=CCC(C)=CC1 YKFLAYDHMOASIY-UHFFFAOYSA-N 0.000 claims 2
- FUDNBFMOXDUIIE-SNVBAGLBSA-N (S)-3,7-Dimethyl-1,6-octadiene Chemical compound C=C[C@@H](C)CCC=C(C)C FUDNBFMOXDUIIE-SNVBAGLBSA-N 0.000 claims 1
- IBVJWOMJGCHRRW-DTWKUNHWSA-N 2-Carene Natural products C1CC(C)=C[C@H]2C(C)(C)[C@@H]12 IBVJWOMJGCHRRW-DTWKUNHWSA-N 0.000 claims 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims 1
- 239000005973 Carvone Substances 0.000 claims 1
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 claims 1
- 229930008398 Citronellate Natural products 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims 1
- 241000134874 Geraniales Species 0.000 claims 1
- 239000004594 Masterbatch (MB) Substances 0.000 claims 1
- 239000004952 Polyamide Substances 0.000 claims 1
- 239000004793 Polystyrene Substances 0.000 claims 1
- 239000004372 Polyvinyl alcohol Substances 0.000 claims 1
- PXRCIOIWVGAZEP-UHFFFAOYSA-N Primaeres Camphenhydrat Natural products C1CC2C(O)(C)C(C)(C)C1C2 PXRCIOIWVGAZEP-UHFFFAOYSA-N 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 239000012790 adhesive layer Substances 0.000 claims 1
- 125000005907 alkyl ester group Chemical group 0.000 claims 1
- UZFLPKAIBPNNCA-BQYQJAHWSA-N alpha-ionone Chemical compound CC(=O)\C=C\C1C(C)=CCCC1(C)C UZFLPKAIBPNNCA-BQYQJAHWSA-N 0.000 claims 1
- UZFLPKAIBPNNCA-UHFFFAOYSA-N alpha-ionone Natural products CC(=O)C=CC1C(C)=CCCC1(C)C UZFLPKAIBPNNCA-UHFFFAOYSA-N 0.000 claims 1
- VYBREYKSZAROCT-UHFFFAOYSA-N alpha-myrcene Natural products CC(=C)CCCC(=C)C=C VYBREYKSZAROCT-UHFFFAOYSA-N 0.000 claims 1
- 229930006739 camphene Natural products 0.000 claims 1
- ZYPYEBYNXWUCEA-UHFFFAOYSA-N camphenilone Natural products C1CC2C(=O)C(C)(C)C1C2 ZYPYEBYNXWUCEA-UHFFFAOYSA-N 0.000 claims 1
- 229930006737 car-3-ene Natural products 0.000 claims 1
- 229930003633 citronellal Natural products 0.000 claims 1
- 235000000983 citronellal Nutrition 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- 229920001519 homopolymer Polymers 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 235000001510 limonene Nutrition 0.000 claims 1
- 229940087305 limonene Drugs 0.000 claims 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 claims 1
- 238000004806 packaging method and process Methods 0.000 claims 1
- 229920002239 polyacrylonitrile Polymers 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 229920002223 polystyrene Polymers 0.000 claims 1
- 229920002451 polyvinyl alcohol Polymers 0.000 claims 1
- 230000003014 reinforcing effect Effects 0.000 claims 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
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- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
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- B32B27/283—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polysiloxanes
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
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- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
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- B32B9/02—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
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- B32B2439/00—Containers; Receptacles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
- B32B2439/40—Closed containers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
- B32B2439/70—Food packaging
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
- B32B2439/80—Medical packaging
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Wrappers (AREA)
- Laminated Bodies (AREA)
- Packages (AREA)
Claims (25)
1. Многослойная упаковочная пленка, содержащая, по меньшей мере, три различных типа слоев (А), (В) и (С):
(А) представляет собой, по меньшей мере, один внешний слой,
(В) представляет собой, по меньшей мере, один слой пассивного кислородного барьера,
(С) представляет собой, по меньшей мере, один слой для активного акцептирования кислорода,
характеризующаяся тем, что
по меньшей мере, один внешний слой (А) представляет собой термопластичный полимер;
по меньшей мере, один слой пассивного кислородного барьера (В), выбран из группы, состоящей из сополимеров этилена-винилового спирта, поливинилхлорида, сополимеров поливинилхлорида, поливинилового спирта, поливинилидендихлорида, сополимеров поливинилидендихлорида, полиакрилонитрилов, сополимеров полиакрилонитрилов, полиэтилентерефталата, полиэтиленнафталата, полиэтиленфураноата, полисилоксанов и полиамидов;
по меньшей мере, один слой для активного акцептирования кислорода (C) содержит
а) пластиковый материал, который представляет собой полиолефин, сополимер полиолефина или полистирол, и добавки (b) и (с); где
b) представляет собой политерпеновую смолу; и
с) представляет собой катализатор на основе переходного металла,
при этом добавку (b) используют в количестве в диапазоне от 0,05 до 10% (масс.) при расчете на совокупную массу соответствующего слоя для активного акцептирования кислорода (С).
2. Многослойная упаковочная пленка по п. 1, где добавки b) и с) объединяют в одном и том же слое для акцептирования кислорода.
3. Многослойная упаковочная пленка по п. 1 или 2, содержащая, кроме того, по меньшей мере, один внутренний слой (D), который представляет собой термопластичный полимер.
4. Многослойная упаковочная пленка по любому из предшествующих пунктов, где, по меньшей мере, один из слоев для активного акцептирования кислорода (С) заключен в сэндвичевую конструкцию между слоем пассивного кислородного барьера (В) и внутренним слоем (D) или, в случае отсутствия такового внутренней стороной самой упаковки.
5. Многослойная упаковочная пленка по любому из предшествующих пунктов, где один или несколько дополнительных слоев, выбранных из группы, состоящей из влагобарьерных слоев, упрочняющих слоев и клеящих слоев, располагают между, по меньшей мере, двумя из слоев (А), (В), (С) и (D).
6. Многослойная упаковочная пленка по любому из предшествующих пунктов, где политерпеновая смола (b) содержит мономеры, выбранные из альфа-пинена, бета-пинена, гамма-терпинена, лимонена, норборнена, мирцена, фелландрена, карвона, камфена, 2-карена, 3-карена, периллилового спирта, периллальдегида, перилловой кислоты, алкиловых сложных эфиров периллилового спирта, ариловых сложных эфиров периллилового спирта, арилалкиловых сложных эфиров периллилового спирта, алкилариловых сложных эфиров периллилового спирта, альфа-ионона, бета-ионона, бета-цитронеллола, бета-цитронеллена, цитронеллаля, цитронелловой кислоты, алкиловых сложных эфиров бета-цитронеллола, ариловых сложных эфиров бета-цитронеллола, арилалкиловых сложных эфиров бета-цитронеллола, алкилариловых сложных эфиров бета-цитронеллола, гераниола, гераниаля, алкиловых сложных эфиров гераниола, ариловых сложных эфиров гераниола, арилалкиловых сложных эфиров гераниола, алкилариловых сложных эфиров гераниола, линалоола, алкиловых сложных эфиров линалоола, ариловых сложных эфиров линалоола, арилалкиловых сложных эфиров линалоола, алкилариловых сложных эфиров линалоола, неролидола, алкиловых сложных эфиров неролидола, ариловых сложных эфиров неролидола, арилалкиловых сложных эфиров неролидола, алкилариловых сложных эфиров неролидола, вербенола, вербенона, алкиловых сложных эфиров вербенола, ариловых сложных эфиров вербенола, арилалкиловых сложных эфиров вербенола, алкилариловых сложных эфиров вербенола и их смесей.
7. Многослойная упаковочная пленка по любому из предшествующих пунктов, где политерпеновая смола (b) представляет собой гомополимер или сополимер альфа-пинена, бета-пинена или смесей из альфа/бета-пинена.
8. Многослойная упаковочная пленка по любому из предшествующих пунктов, где катализатор на основе переходного металла (с) содержит железо, никель, марганец, кобальт или медь.
9. Многослойная упаковочная пленка по любому из предшествующих пунктов, где катализатор на основе переходного металла (с) используют в количестве в диапазоне от 0,001 до 1% (масс.) при расчете на совокупную массу соответствующего слоя для активного акцептирования кислорода (С).
10. Многослойная упаковочная пленка по любому из предшествующих пунктов, где толщина слоев пассивного кислородного барьера в сопоставлении с совокупной толщиной многослойной пленки находится в диапазоне от 3 до 30%.
11. Многослойная упаковочная пленка по любому из предшествующих пунктов, где толщина слоев для активного акцептирования кислорода в сопоставлении с совокупной толщиной многослойной пленки находится в диапазоне от 9 до 43%.
12. Многослойная упаковочная пленка по любому из предшествующих пунктов, которая имеет форму контейнера.
13. Способ изготовления многослойной упаковочной пленки по любому из предшествующих пунктов, включающий стадию подачи полимеров, соответствующих слоям (А), (В) и (С) и необязательно (D), подачи добавок (b) и (с) и включающий стадию смешивания и технологический процесс профилирующего формования.
14. Способ по п. 13, где добавки (b) и (с) подают в форме маточной смеси.
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| EP16183923.8A EP3281788A1 (en) | 2016-08-12 | 2016-08-12 | Oxygen barrier plastic material |
| EP16183923.8 | 2016-08-12 | ||
| PCT/EP2017/068927 WO2018028996A1 (en) | 2016-08-12 | 2017-07-26 | Oxygen barrier plastic material |
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| RU2019106696A true RU2019106696A (ru) | 2020-09-14 |
| RU2019106696A3 RU2019106696A3 (ru) | 2020-11-23 |
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| JP7127257B2 (ja) * | 2017-09-08 | 2022-08-30 | 東洋製罐株式会社 | 酸素吸収性樹脂組成物及びその製造方法、並びに容器 |
| ES2923891T3 (es) | 2018-08-08 | 2022-10-03 | Danapak Flexibles As | Películas y láminas mejoradas para usarse en el envase de compuestos reactivos |
| WO2020041246A1 (en) * | 2018-08-20 | 2020-02-27 | Celanese EVA Performance Polymers Corporation | Polymer and metal foil laminates |
| US11518149B2 (en) | 2018-11-13 | 2022-12-06 | Campbell Soup Company | Multilayer packaging materials with release of migratory active substances |
| US20210101375A1 (en) * | 2019-10-08 | 2021-04-08 | Kuraray Co., Ltd. | Polyfluoroalkyl substances (pfas) diffusion preventing system |
| BR112022007816A2 (pt) * | 2019-11-01 | 2022-07-05 | Dow Global Technologies Llc | Estrutura sobremoldada por injeção transparente, processo de sobremoldagem por injeção, e, estrutura moldada por injeção |
| CN110746723A (zh) * | 2019-12-02 | 2020-02-04 | 苏州奥凯高分子材料股份有限公司 | 一种pvc高阻隔片材及其制备方法 |
| CN113124309B (zh) * | 2019-12-31 | 2023-03-17 | 中国科学院宁波材料技术与工程研究所 | 一种高压储氢瓶塑料内胆及其制备方法 |
| EP4135964A4 (en) * | 2020-04-16 | 2024-05-15 | MuCell Extrusion LLC | PLASTIC CONTAINER FOR PACKAGING OXYGEN-SENSITIVE PRODUCTS AND METHOD FOR MANUFACTURING SAME |
| CN111775518A (zh) * | 2020-07-01 | 2020-10-16 | 汕头万顺新材集团股份有限公司 | 一种耐候性高的阻隔膜结构 |
| CN112078210A (zh) * | 2020-08-27 | 2020-12-15 | 上海春宜药品包装材料有限公司 | 聚乙烯复合医用包装膜及生产工艺的制备方法 |
| CN114714728A (zh) * | 2022-03-17 | 2022-07-08 | 乐美包装（昆山）有限公司 | 纵封条及其制作方法 |
| WO2023196441A1 (en) * | 2022-04-05 | 2023-10-12 | Faulkner James D | Contaminant-resistant packaging |
| CN115195167A (zh) * | 2022-07-15 | 2022-10-18 | 浙江多凌药用包装材料有限公司 | 一种聚氯乙烯、聚偏二氯乙烯、聚氯乙烯新三层复合硬片工艺 |
| CN117551370B (zh) * | 2023-11-23 | 2024-07-23 | 东营博邦泰晟新材料科技有限公司 | 一种应用于膜基材料上的可降解复合阻隔涂料及其生产设备 |
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| US5776361A (en) * | 1995-02-15 | 1998-07-07 | Chevron Chemical Company | Multi-component oxygen scavenging composition |
| US5660761A (en) | 1995-02-15 | 1997-08-26 | Chevron Chemical Company | Multi-component oxygen scavenger system useful in film packaging |
| US6333087B1 (en) * | 1998-08-27 | 2001-12-25 | Chevron Chemical Company Llc | Oxygen scavenging packaging |
| AU2002213165A1 (en) | 2000-11-02 | 2002-05-15 | Chevron Phillips Chemical Company Lp | Active masterbatch using stearate and an oxidizable resin carrier |
| US7052628B2 (en) * | 2003-11-19 | 2006-05-30 | Chevron Phillips Chemical Company, Lp | Transition metal carboxylates as catalysts for oxygen scavenging |
| JP2007320576A (ja) | 2006-05-30 | 2007-12-13 | Toyo Seikan Kaisha Ltd | 酸素感受性の内容物を充填した製品 |
| US7521523B2 (en) * | 2006-12-28 | 2009-04-21 | Eastman Chemical Company | Oxygen-scavenging polyester compositions useful in packaging |
| US8815360B2 (en) * | 2007-08-28 | 2014-08-26 | Cryovac, Inc. | Multilayer film having passive and active oxygen barrier layers |
| EP2112201A1 (en) | 2008-04-25 | 2009-10-28 | INEOS Manufacturing Belgium NV | Oxygen Barrier Composition |
| CN102015860B (zh) | 2008-05-06 | 2013-04-24 | 巴斯夫欧洲公司 | 氧清除混合物 |
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| JP6124592B2 (ja) * | 2009-12-02 | 2017-05-10 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 酸素捕捉要素としての光感受性分子及び金属錯体の使用 |
| BR112012013206A2 (pt) * | 2009-12-02 | 2016-03-01 | Basf Se | composição de remoção de oxigênio para aplicação em acondicionamento de alimentos, artigo, e, uso da composição de remoção de oxigênio |
| WO2013028290A1 (en) * | 2011-08-24 | 2013-02-28 | Amyris, Inc. | Oxygen scavengers |
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- 2017-07-26 CN CN201780049421.5A patent/CN109562609A/zh active Pending
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- 2017-07-26 JP JP2019506502A patent/JP7050049B2/ja active Active
- 2017-07-26 KR KR1020197007152A patent/KR102417298B1/ko active IP Right Grant
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| EP3281788A1 (en) | 2018-02-14 |
| KR102417298B1 (ko) | 2022-07-08 |
| JP7050049B2 (ja) | 2022-04-07 |
| MX2019001566A (es) | 2019-07-01 |
| JP2019524502A (ja) | 2019-09-05 |
| TW201817598A (zh) | 2018-05-16 |
| US20190210337A1 (en) | 2019-07-11 |
| KR20190040244A (ko) | 2019-04-17 |
| CN109562609A (zh) | 2019-04-02 |
| TWI762499B (zh) | 2022-05-01 |
| RU2019106696A3 (ru) | 2020-11-23 |
| RU2768756C2 (ru) | 2022-03-24 |
| CA3032576A1 (en) | 2018-02-15 |
| BR112019002751A2 (pt) | 2019-05-14 |
| BR112019002751B1 (pt) | 2022-08-23 |
| EP4019248A1 (en) | 2022-06-29 |
| SG11201900507SA (en) | 2019-02-27 |
| WO2018028996A1 (en) | 2018-02-15 |
| EP3496946A1 (en) | 2019-06-19 |
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