RU2018124933A - Блок-сополимеры, формирующие полиэлектролитный слой, композиции с ними и их применение - Google Patents

Блок-сополимеры, формирующие полиэлектролитный слой, композиции с ними и их применение Download PDF

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RU2018124933A
RU2018124933A RU2018124933A RU2018124933A RU2018124933A RU 2018124933 A RU2018124933 A RU 2018124933A RU 2018124933 A RU2018124933 A RU 2018124933A RU 2018124933 A RU2018124933 A RU 2018124933A RU 2018124933 A RU2018124933 A RU 2018124933A
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composition
block copolymer
fragment
stabilizing
anchor
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RU2018124933A
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RU2018124933A3 (ru
RU2769260C2 (ru
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Гилад СИЛБЕРТ
Михаель БЕРКОВИЧ
Дэвид Джеймс УИЛСОН
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Адама Махтешим Лтд.
Родиа Операсьон
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Claims (43)

1. Композиция с сельскохозяйственным веществом, содержащая:
(i) частицы по меньшей мере одного сельскохозяйственного вещества; и
(ii) диспергирующую систему, содержащую блок-сополимер, формирующий полиэлектролитный слой, где указанный блок-сополимер содержит (A) якорный фрагмент и (B) по меньшей мере один стабилизирующий фрагмент,
где указанный блок-сополимер адсорбирован на гидрофобных поверхностях частиц сельскохозяйственного вещества.
2. Композиция по п. 1, где сельскохозяйственное вещество представляет собой пестицид.
3. Композиция по пп. 1 или 2, где композиция представляет собой эмульсию типа масло-в-воде, предпочтительно содержащую по меньшей мере 60 мас.% масляной фазы.
4. Композиция по любому из пп. 1-3, где:
a) композиция гранулирована;
b) композиция является высококонцентрированной, и концентрация частиц сельскохозяйственного вещества в композиции составляет 900-1200 г/л,
c) плотность композиции составляет 1,4-1,6 кг/л, и/или
d) вязкость композиции меньше 750 сПз при определении со шпинделем 62 и 12 об/мин на вискозиметре Брукфилда.
5. Композиция по любому из пп. 1-4, где композиция является стабильной при высоком содержании соли.
6. Композиция по любому из пп. 2-5, где пестицид представляет собой флуенсульфон.
7. Композиция с несельскохозяйственным веществом, содержащая:
(i) красящий компонент;
(ii) несельскохозяйственное вещество и воду; или
(iii) твердые частицы,
и
блок-сополимер, формирующий полиэлектролитный слой, где указанный блок-сополимер содержит (A) якорный фрагмент и (B) по меньшей мере один стабилизирующий фрагмент.
8. Композиция по любому из пп. 1-7, где блок-сополимер, формирующий полиэлектролитный слой, представляет собой гребнеобразный блок-сополимер, или линейный блок-сополимер, предпочтительно ди-блок-сополимер или три-блок-сополимер.
9. Композиция по любому из пп. 1-8, где якорный фрагмент представляет собой гидрофобный блок-сополимер.
10. Композиция по п. 9, где по меньшей мере 90% якорного фрагмента представляет собой гидрофобные мономеры, предпочтительно выбранные из группы, состоящей из акрилатных производных, метакрилатных производных, стирольных производных, и любых их комбинаций.
11. Композиция по п. 9 или 10, где гидрофобный мономер представляет собой этилакрилат (ЭА).
12. Композиция по любому из пп. 1-11, где указанный по меньшей мере один стабилизирующий фрагмент представляет собой гидрофильный блок-сополимер.
13. Композиция по п. 12, где по меньшей мере 60 мас.% мономеров в стабилизирующем фрагменте представляют собой заряженные мономеры и/или где менее 40 мас.% мономеров в стабилизирующем фрагменте представляют собой нейтральные гидрофильные мономеры.
14. Композиция по п. 13, где
a) по меньшей мере один из заряженных мономеров представляет собой 2-акриламидо-2-метилпропан сульфонат (AMPS), и/или
b) нейтральный гидрофильный мономер выбран из группы, состоящей из N-винилпирролидона, этиленоксида, гликозид акрилата и акриламида.
15. Композиция по любому из пп. 1-14, где:
a) блок-сополимер содержит до 150 мономеров,
b) масса блок-сополимера составляет вплоть до 31000 г/моль,
c) масса стабилизирующего фрагмента составляет от 5000 до 100000 г/моль,
d) масса якорного фрагмента составляет от 500 до 5000 г/моль,
e) массовый процент стабилизирующего фрагмента составляет 65-90% от общей массы блок-сополимера,
f) мольное соотношение якорного фрагмента и стабилизирующего фрагмента составляет 1:2-4, и/или
g) концентрация блок-сополимера в композиция составляет 0,2-3% мас./мас.
16. Способ (i) борьбы с вредителями и предотвращения появления вредителей, и/или (ii) улучшения роста растений, включающий нанесение композиции по любому из пп. 1-6 или 8-15 на по меньшей мере одну область, в которой необходимо истребить или предотвратить появление вредителей, на растение, область рядом с растением, почву, подготовленную для поддержки роста растения, корень растения, листву растения и/или семена, подготовленные для производства растения, с тем чтобы истребить и предотвратить появление вредителей и/или улучшить рост растения.
17. Способ приготовления композиции с сельскохозяйственным веществом, включающий смешивание частиц по меньшей мере одного сельскохозяйственного вещества с определенным количеством блок-сополимера, формирующего полиэлектролитный слой, где указанный блок-сополимер содержит (A) якорный фрагмент и (B) по меньшей мере один стабилизирующий фрагмент.
18. Способ приготовления композиции с несельскохозяйственным веществом, включающий смешивание частиц по меньшей мере одного несельскохозяйственного вещества с определенным количеством блок-сополимера, формирующего полиэлектролитный слой, где указанный блок-сополимер содержит (A) якорный фрагмент и (B) по меньшей мере один стабилизирующий фрагмент.
19. Способ по п. 18, где композиция с несельскохозяйственным веществом представляет собой композицию покрытия, и способ включает введение в контакт пленкообразующего полимерного латекса с диспергирующей системой, содержащей блок-сополимер, формирующий полиэлектролитный слой, где указанный блок-сополимер содержит (A) якорный фрагмент и (B) по меньшей мере один стабилизирующий фрагмент.
20. Способ по п. 18, где композиция с несельскохозяйственным веществом представляет собой красящую композицию, и способ включает введение в контакт красящего компонента с диспергирующей системой, содержащей блок-сополимер, формирующий полиэлектролитный слой, где указанный блок-сополимер содержит (A) якорный фрагмент и (B) по меньшей мере один стабилизирующий фрагмент, и где получаемая красящая композиция представляет собой дисперсию.
21. Способ подкрашивания алкидного базового покрытия или латексного базового покрытия, включающий введение в контакт алкидного базового покрытия или латексного базового покрытия с композицией с несельскохозяйственным веществом, содержащей красящий компонент, по п. 7.
22. Применение блок-сополимера, формирующего полиэлектролитный слой, содержащего (A) якорный фрагмент и (B) по меньшей мере один стабилизирующий фрагмент, для удерживания твердых частиц в суспензии в масляной композиции цементного раствора.
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