RU2017123618A - Поколинамиды с фунгицидной активностью - Google Patents

Поколинамиды с фунгицидной активностью Download PDF

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RU2017123618A
RU2017123618A RU2017123618A RU2017123618A RU2017123618A RU 2017123618 A RU2017123618 A RU 2017123618A RU 2017123618 A RU2017123618 A RU 2017123618A RU 2017123618 A RU2017123618 A RU 2017123618A RU 2017123618 A RU2017123618 A RU 2017123618A
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Чэнлинь Яо
Кевин Дж. МЕЙЕР
Юй ЛУ
Брайан ЛОЙ
Дэвид М. ДЖОУНС
Рональд Дж. ХЕМСТРА
Джеффри Б. ЭПП
Джонатан Е. ДИЛОРБ
Кайл А. ДЕКОРВЕР
СР. Джон Ф. ДЭУБЛ
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ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
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    • A61K31/435—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having six-membered rings with one nitrogen as the only ring hetero atom
    • A61K31/44—Non condensed pyridines; Hydrogenated derivatives thereof
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    • C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
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    • C07C229/06—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton
    • C07C229/08—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton the nitrogen atom of the amino group being further bound to hydrogen atoms
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C229/04—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C229/22—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated the carbon skeleton being further substituted by oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C229/34—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton containing six-membered aromatic rings
    • C07C229/36—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton containing six-membered aromatic rings with at least one amino group and one carboxyl group bound to the same carbon atom of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/81—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/02—Systems containing only non-condensed rings with a three-membered ring

Claims (36)

1. Композиция для борьбы с патогенными грибами, содержащая смеси по меньшей мере одного из соединений формулы I:
Figure 00000001
где
X представляет собой водород или C(O)R5;
Y представляет собой водород, C(O)R5 или Q;
Q представляет собой
Figure 00000002
;
R1 представляет собой CH2OCH3 или водород или алкил, где алкил необязательно замещен 0, 1 или несколькими R8;
R2 представляет собой метил;
R3 выбран из C(O)OCH3 или алкила, алкенила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8;
R4 выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8;
R5 представляет собой алкокси, необязательно замещенный 0, 1 или несколькими R8;
R6 выбран из водорода или алкокси, где алкокси необязательно замещен 0, 1 или несколькими R8;
R7 выбран из водорода, C(O)R9 или CH2OC(O)R9;
R8 выбран из водорода, алкила, арила, галогена, алкенила или фенокси, каждый из которых необязательно замещен 0, 1 или несколькими R10;
R9 выбран из алкила, алкокси или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8;
R10 выбран из алкила, арила, галогена, галогеналкила, галогенарила, алкенила или алкокси;
R11 выбран из водорода или метила.
2. Композиция по п.1, где X представляет собой водород, и Y представляет собой Q.
3. Композиция по п.2, где R7 представляет собой водород.
4. Композиция по п.3, где R6 представляет собой OCH3.
5. Композиция по п.4, где R1 и R11 независимо выбраны из водорода или метила.
6. Композиция по п.3, где R7 представляет собой C(O)R9 или CH2OC(O)R9.
7. Композиция по п.6, где R9 выбран из алкила, алкокси или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8.
8. Композиция по п.7, где R1 и R11 независимо выбраны из водорода или метила.
9. Композиция для борьбы с патогенными грибами, содержащая по меньшей мере одну из композиций по п.5 и ботанически приемлемый носитель.
10. Композиция для борьбы с патогенными грибами, содержащая по меньшей мере одну из композиций по п.8 и ботанически приемлемый носитель.
11. Композиция для борьбы с патогенными грибами, содержащая смеси по меньшей мере одной из композиций по п.5 и другого пестицида, включая фунгициды, инсектициды, нематоциды, майтициды, артроподициды, бактерициды и их комбинации.
12. Композиция для борьбы с патогенными грибами, содержащая смеси по меньшей мере одной из композиций по п.8 и другого пестицида, включая фунгициды, инсектициды, нематоциды, майтициды, артроподициды, бактерициды и их комбинации.
13. Композиции по п.1, где патогенный гриб представляет собой один из пятнистости листьев пшеницы (Zymoseptoria tritici), бурой ржавчины пшеницы (Puccinia triticina), желтой ржавчины (Puccinia striiformis), парши яблони (Venturia inaequalis), пузырчатой головни кукурузы (Ustilago maydis), мучнистой росы виноградной лозы (Uncinula necator), ожога ячменя (Rhynchosporium secalis), брунозе риса (Pyricularia oryzae), ржавчины сои (Phakopsora pachyrhizi), септориоза колосковой чешуи пшеницы (Leptosphaeria nodorum), мучнистой росы пшеницы (Blumeria graminis f. sp.tritici), мучнистой росы ячменя (Blumeria graminis f. sp. hordei), мучнистой росы тыквы (Erysiphe cichoracearum), антракноза тыквы (Colletotrichum lagenarium), пятнистости листьев свеклы (Cercospora beticola), бурой пятнистости томата (Alternaria solani) и сетчатой пятнистости ячменя (Pyrenophora teres).
14. Композиция по п.5 где патогенный гриб представляет собой один из пятнистости листьев пшеницы (Zymoseptoria tritici), бурой ржавчины пшеницы (Puccinia triticina) и ржавчины сои (Phakopsora pachyrhizi).
15. Композиция по п.8 где патогенный гриб представляет собой один из пятнистости листьев пшеницы (Zymoseptoria tritici), бурой ржавчины пшеницы (Puccinia triticina) и ржавчины сои (Phakopsora pachyrhizi).
16. Способ борьбы и предотвращения поражения грибами растения, включающий стадию: нанесения фунгицидно эффективного количества по меньшей мере одной из композиций по п.5 по меньшей мере на одно из следующего: на данное растение, площадь, прилегающую к данному растению, почву, адаптированную для поддержания роста данного растения, корень данного растения и листву данного растения.
17. Способ борьбы и предотвращения поражения грибами растения, включающий стадию: нанесения фунгицидно эффективного количества по меньшей мере одной из композиций по п.8 по меньшей мере на одно из следующего: на данное растение, площадь, прилегающую к данному растению, почву, адаптированную для поддержания роста данного растения, корень данного растения и листву данного растения.
18. Способ борьбы и предотвращения поражения грибами растения, включающий стадию: нанесения фунгицидно эффективного количества по меньшей мере одной из композиций по п.10 по меньшей мере на одно из следующего: на данное растение, площадь, прилегающую к данному растению, почву, адаптированную для поддержания роста данного растения, корень данного растения и листву данного растения.
19. Способ борьбы и предотвращения поражения грибами растения, включающий стадию: нанесения фунгицидно эффективного количества по меньшей мере одной из композиций по п.12 по меньшей мере на одно из следующего: на данное растение, площадь, прилегающую к данному растению, почву, адаптированную для поддержания роста данного растения, корень данного растения и листву данного растения.
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US201462098097P 2014-12-30 2014-12-30
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US201562255152P 2015-11-13 2015-11-13
US201562255144P 2015-11-13 2015-11-13
US62/255,152 2015-11-13
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PCT/US2015/067200 WO2016109301A1 (en) 2014-12-30 2015-12-21 Picolinamides with fungicidal activity

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