RU2016136522A - Способы дегидратации-гидролиза и катализаторы для них - Google Patents

Способы дегидратации-гидролиза и катализаторы для них Download PDF

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RU2016136522A
RU2016136522A RU2016136522A RU2016136522A RU2016136522A RU 2016136522 A RU2016136522 A RU 2016136522A RU 2016136522 A RU2016136522 A RU 2016136522A RU 2016136522 A RU2016136522 A RU 2016136522A RU 2016136522 A RU2016136522 A RU 2016136522A
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zeolite
axis
equal
size along
fer type
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RU2016136522A
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RU2698458C2 (ru
RU2016136522A3 (ru
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Эверт Ян ДИТЦЕЛЬ
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Бп Кемикэлз Лимитед
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
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    • B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
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    • B01J35/633—Pore volume less than 0.5 ml/g
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/643—Pore diameter less than 2 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
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    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/44—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/44—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C01B39/445—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38 using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/09—Preparation of ethers by dehydration of compounds containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/16—Preparation of ethers by reaction of esters of mineral or organic acids with hydroxy or O-metal groups
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/50—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/08—Acetic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/183—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/77—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by unit-cell parameters, atom positions or structure diagrams

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Nanotechnology (AREA)
  • Dispersion Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Claims (11)

1. Способ совместного получения уксусной кислоты и диметилового эфира, включающий стадию введения во взаимодействие метилацетата с метанолом в присутствии катализатора, содержащего кристаллический цеолит, обладающий каркасной структурой типа FER, где кристаллиты цеолита обладают размером по оси с, равным примерно 500 нанометров (нм) или менее, и отношением размера по оси с к размеру по оси b, большим или равным 5:1.
2. Способ по п. 1, в котором кристаллиты цеолита обладают размером по оси с, равным примерно 500 нанометров (нм) или менее, и отношением размера по оси с к размеру по оси b, находящимся в диапазоне от 5:1 до 11:1.
3. Способ по п. 1 или 2, в котором цеолит обладает объемом мезопор, измеренным по адсорбции N2, равным не менее 0,1 см3/г.
4. Способ по п. 1 или 2, в котором цеолитом, обладающим каркасной структурой типа FER, является феррьерит.
5. Способ по п. 1 или 2, в котором цеолит, обладающий каркасной структурой типа FER, находится в водородной форме или в основном в водородной форме.
6. Способ по п. 1 или 2, в котором цеолит, обладающий каркасной структурой типа FER, находится в форме, содержащей щелочной металл.
7. Способ по п. 6, в котором щелочным металлом является цезий.
8. Способ по п. 1 или 2, в котором катализатор содержит связующий огнеупорный оксид.
9. Способ по п. 1 или 2, где способ проводят в паровой фазе.
10. Способ по п. 1 или 2, где способ проводят при температурах, равных от 170 до 300°С.
11. Способ по п. 1 или 2, где способ проводят при давлениях, находящихся в диапазоне от атмосферного до равного 30 бар избыточного давления.
RU2016136522A 2014-02-13 2015-02-13 Способы дегидратации-гидролиза и катализаторы для них RU2698458C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14155069 2014-02-13
EP14155069.9 2014-02-13
PCT/EP2015/053082 WO2015121411A1 (en) 2014-02-13 2015-02-13 Dehydration-hydrolysis processes and catalysts therefor

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RU2016136522A true RU2016136522A (ru) 2018-03-20
RU2016136522A3 RU2016136522A3 (ru) 2018-08-10
RU2698458C2 RU2698458C2 (ru) 2019-08-27

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US (1) US10207975B2 (ru)
JP (1) JP2017510556A (ru)
KR (1) KR20160123332A (ru)
CN (1) CN106794453B (ru)
RU (1) RU2698458C2 (ru)
TW (1) TW201538471A (ru)
WO (1) WO2015121411A1 (ru)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019037766A1 (en) * 2017-08-24 2019-02-28 Bp P.L.C. PROCESS
WO2019037764A1 (en) * 2017-08-24 2019-02-28 Bp P.L.C. PROCESS
US11066350B2 (en) 2017-08-24 2021-07-20 Bp P.L.C. Process for dehydrating methanol to dimethyl ether
WO2019037768A1 (en) * 2017-08-24 2019-02-28 Bp P.L.C. PROCESS
US11554964B2 (en) * 2018-07-27 2023-01-17 Basf Se Process for preparing a zeolitic material having a framework type FER
CN113753914B (zh) * 2021-10-08 2023-12-29 吉林化工学院 一种粉煤灰基fer结构沸石的制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4016245A (en) * 1973-09-04 1977-04-05 Mobil Oil Corporation Crystalline zeolite and method of preparing same
US3992466A (en) * 1975-08-13 1976-11-16 Mobil Oil Corporation Hydrocarbon conversion
NL7812162A (nl) * 1978-12-14 1980-06-17 Shell Int Research Werkwijze voor de bereiding van ferrieriet.
ES2012764B3 (es) * 1985-12-09 1990-04-16 Shell Int Research Procedimiento para la preparacion de ferrierita y su uso como catalizador (portador) de desparafinado.
ES2121074T3 (es) * 1992-10-16 1998-11-16 Mobil Oil Corp Procedimiento de isomerizacion esqueletica de la olefina utilizando el zsm-35.
US5288475A (en) * 1992-10-21 1994-02-22 Mobil Oil Corp. Synthesis of ZSM-35
GB0607395D0 (en) 2006-04-12 2006-05-24 Bp Chem Int Ltd Process
EP2292578A1 (en) * 2009-09-03 2011-03-09 BP Chemicals Limited Process for producing acetic acid and dimethyl ether using a zeolite catalyst
EP2817283A1 (en) * 2012-02-23 2014-12-31 BP Chemicals Limited Process for the production of acetic acid and diemthyl ether

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WO2015121411A1 (en) 2015-08-20
US20170183282A1 (en) 2017-06-29
TW201538471A (zh) 2015-10-16
KR20160123332A (ko) 2016-10-25
JP2017510556A (ja) 2017-04-13
RU2698458C2 (ru) 2019-08-27
RU2016136522A3 (ru) 2018-08-10
CN106794453A (zh) 2017-05-31
CN106794453B (zh) 2020-03-06
US10207975B2 (en) 2019-02-19

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