RU2011142180A - Композиция, пропитанная маслом и полярной добавкой, пригодная в каталитической гидропереработке углеводородов, способ изготовления такого катализатора и способ применения такого катализатора - Google Patents

Композиция, пропитанная маслом и полярной добавкой, пригодная в каталитической гидропереработке углеводородов, способ изготовления такого катализатора и способ применения такого катализатора Download PDF

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RU2011142180A
RU2011142180A RU2011142180/04A RU2011142180A RU2011142180A RU 2011142180 A RU2011142180 A RU 2011142180A RU 2011142180/04 A RU2011142180/04 A RU 2011142180/04A RU 2011142180 A RU2011142180 A RU 2011142180A RU 2011142180 A RU2011142180 A RU 2011142180A
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composition
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composition according
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Алексей Григорьевич ГАБРИЕЛОВ
Джон Энтони СМИГАЛ
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Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
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    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
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  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
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Abstract

1. Композиция, содержащая: материал носителя, который содержит предшественник активного металла, углеводородное масло и полярную добавку, имеющую дипольный момент, по меньшей мере, 0,45, где массовое отношение упомянутого углеводородного масла к полярной добавке находится в диапазоне вплоть до 10:1 (верхняя граница), и где упомянутый материал носителя затем обрабатывают газом, содержащим водород.2. Композиция, содержащая: материал носителя, содержащий металлический компонент из раствора соли металла, углеводородное масло и полярную добавку, имеющую дипольный момент, по меньшей мере, 0,45, где массовое отношение упомянутого углеводородного масла к полярной добавке находится в диапазоне вплоть до 10:1 (верхняя граница).3. Композиция по п.1 или 2, где упомянутая полярная добавка имеет точку кипения в интервале от 50°С до 275°С.4. Композиция по п.1 или 2, где упомянутую полярную добавку выбирают из группы гетеросоединений, состоящей из гетеросоединений.5. Композиция по п.4, где упомянутая группа гетеросоединений исключает серосодержащие соединения.6. Композиция по п.4, где упомянутая группа гетеросоединений исключает парафиновые и олефиновые углеводородные соединения.7. Композиция по 5, где упомянутая группа гетеросоединений исключает парафиновые и олефиновые углеводородные соединения.8. Композиция по п.1 или 2, где упомянутое углеводородное масло содержит углеводороды, имеющие температуру кипения в интервале от 100°С до 550°С, и может быть выбрано из углеводородных смесей из группы, состоящей из тяжелой нафты, керосина, дизельного топлива, газойля, олефинов, имеющих число атомов углерода в интервале от 12 до 40 атомов углерода, смес�

Claims (15)

1. Композиция, содержащая: материал носителя, который содержит предшественник активного металла, углеводородное масло и полярную добавку, имеющую дипольный момент, по меньшей мере, 0,45, где массовое отношение упомянутого углеводородного масла к полярной добавке находится в диапазоне вплоть до 10:1 (верхняя граница), и где упомянутый материал носителя затем обрабатывают газом, содержащим водород.
2. Композиция, содержащая: материал носителя, содержащий металлический компонент из раствора соли металла, углеводородное масло и полярную добавку, имеющую дипольный момент, по меньшей мере, 0,45, где массовое отношение упомянутого углеводородного масла к полярной добавке находится в диапазоне вплоть до 10:1 (верхняя граница).
3. Композиция по п.1 или 2, где упомянутая полярная добавка имеет точку кипения в интервале от 50°С до 275°С.
4. Композиция по п.1 или 2, где упомянутую полярную добавку выбирают из группы гетеросоединений, состоящей из гетеросоединений.
5. Композиция по п.4, где упомянутая группа гетеросоединений исключает серосодержащие соединения.
6. Композиция по п.4, где упомянутая группа гетеросоединений исключает парафиновые и олефиновые углеводородные соединения.
7. Композиция по 5, где упомянутая группа гетеросоединений исключает парафиновые и олефиновые углеводородные соединения.
8. Композиция по п.1 или 2, где упомянутое углеводородное масло содержит углеводороды, имеющие температуру кипения в интервале от 100°С до 550°С, и может быть выбрано из углеводородных смесей из группы, состоящей из тяжелой нафты, керосина, дизельного топлива, газойля, олефинов, имеющих число атомов углерода в интервале от 12 до 40 атомов углерода, смесей альфа-олефинов, имеющих число атомов углерода в интервале от 18 до 30.
9. Композиция по п.1, где упомянутый предшественник активного металла представляет собой соединение металла, которое включает в себя металлический компонент группы 9 и группы 10, выбранный из группы, состоящей из кобальта и никеля, и где упомянутый металлический компонент группы 9 и группы 10 присутствует в упомянутой композиции в количестве в интервале от 0,5% масс. до 20% масс.
10. Композиция по п.9, где упомянутое соединение металла дополнительно включает в себя металлический компонент группы 6, выбранный из группы, состоящей из молибдена и вольфрама, и где упомянутый металлический компонент группы 6 присутствует в упомянутой композиции в количестве в интервале от 5% масс. до 50% масс.
11. Композиция по п.1 или 2, где упомянутый материал носителя, обработанный водородом, затем обрабатывают сернистым соединением.
12. Способ изготовления композиции, где в упомянутом способе:
вводят металлсодержащий раствор в материал носителя, с получением материала носителя с введенным металлом; и
вводят углеводородное масло и полярную добавку, имеющую дипольный момент, по меньшей мере, 0,45, в упомянутый материал носителя с введенным металлом, с получением композиции, пропитанной маслом и добавкой, имеющей массовое отношение упомянутого углеводородного масла к полярной добавке в диапазоне вплоть до 10:1 (верхняя граница).
13. Способ по п.12, где дополнительно:
приводят упомянутую композицию, пропитанную маслом и добавкой, в контакт с водородом в подходящих условиях водородной обработки, с получением обработанной водородом композиции.
14. Способ по п.12 или 13, где до того, как вводят упомянутое углеводородное масло и упомянутую полярную добавку в упомянутый материал носителя с введенным металлом, упомянутый материал носителя с введенным металлом сушат так, чтобы получить содержание летучих веществ в интервале от 3 до 20% масс. LOI.
15. Способ, включающий:
приведение в контакт углеводородного сырья в условиях процесса гидрообессеривания с любой из композиций по пп.1-11.
RU2011142180/04A 2009-03-19 2010-03-17 Композиция, пропитанная маслом и полярной добавкой, пригодная в каталитической гидропереработке углеводородов, способ изготовления такого катализатора и способ применения такого катализатора RU2532160C2 (ru)

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US8262905B2 (en) 2012-09-11
CN102348503A (zh) 2012-02-08
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