RU2011124568A - METHOD FOR PRODUCING α, ω-BIS- (1,5,3-DITIAZEPINAN-3-IL) ALKANOV - Google Patents

METHOD FOR PRODUCING α, ω-BIS- (1,5,3-DITIAZEPINAN-3-IL) ALKANOV Download PDF

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RU2011124568A
RU2011124568A RU2011124568/04A RU2011124568A RU2011124568A RU 2011124568 A RU2011124568 A RU 2011124568A RU 2011124568/04 A RU2011124568/04 A RU 2011124568/04A RU 2011124568 A RU2011124568 A RU 2011124568A RU 2011124568 A RU2011124568 A RU 2011124568A
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bis
producing
dithiazepinan
butyl
general formula
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RU2478634C2 (en
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Усеин Маметович Джемилев
Елена Борисовна Рахимова
Екатерина Александровна Ефремова
Шамиль Улфатович Сайфутдинов
Асхат Габдрахманович Ибрагимов
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Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран
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Abstract

Способ получения α,ω-бис-(1,5,3-дитиазепинан-3-ил)алканов общей формулы (1)отличающийся тем, что α,ω-алкандиамины общей формулы HN-CH-(CH)-NH, где n=1-8, подвергают взаимодействию с трет-N-бутил-1,5,3-дитиазепинаном в хлороформе в присутствии катализатора SmCl·6HO при мольном соотношении α,ω-алкандиамин:mpem-N-бутил-1,5,3-дитиазепинан: SmCl·6HO=10:20:(0.3-0.7) при комнатной (~20°С) температуре в течение 2,5-3,5 ч.The method of producing α, ω-bis- (1,5,3-dithiazepinan-3-yl) alkanes of the general formula (1) characterized in that α, ω-alkanediamines of the general formula HN-CH- (CH) -NH, where n = 1-8, is reacted with tert-N-butyl-1,5,3-dithiazepinane in chloroform in the presence of a SmCl 6HO catalyst with a molar ratio of α, ω-alkanediamine: mpem-N-butyl-1,5,3- dithiazepinan: SmCl6HO = 10: 20: (0.3-0.7) at room temperature (~ 20 ° C) for 2.5-3.5 hours.

Claims (1)

Способ получения α,ω-бис-(1,5,3-дитиазепинан-3-ил)алканов общей формулы (1)The method of obtaining α, ω-bis- (1,5,3-dithiazepinan-3-yl) alkanes of the general formula (1)
Figure 00000001
Figure 00000001
 отличающийся тем, что α,ω-алкандиамины общей формулы H2N-CH2-(CH2)n-NH2, где n=1-8, подвергают взаимодействию с трет-N-бутил-1,5,3-дитиазепинаном в хлороформе в присутствии катализатора SmCl3·6H2O при мольном соотношении α,ω-алкандиамин:mpem-N-бутил-1,5,3-дитиазепинан: SmCl3·6H2O=10:20:(0.3-0.7) при комнатной (~20°С) температуре в течение 2,5-3,5 ч. characterized in that the α, ω-alkanediamines of the general formula H 2 N-CH 2 - (CH 2 ) n -NH 2 , where n = 1-8, are reacted with tert-N-butyl-1,5,3-dithiazepinane in chloroform in the presence of a SmCl 3 · 6H 2 O catalyst at a molar ratio of α, ω-alkanediamine: mpem-N-butyl-1,5,3-dithiazepinan: SmCl 3 · 6H 2 O = 10: 20: (0.3-0.7) at room temperature (~ 20 ° С) for 2.5-3.5 hours
RU2011124568/04A 2011-06-16 2011-06-16 METHOD OF PRODUCING α,ω -BIS-(1,5,3-DITHIAZEPINAN-3-YL)ALKANES RU2478634C2 (en)

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RU2565790C1 (en) * 2014-11-13 2015-10-20 Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук Method of producing n-cyclopentyl-substituted 1,5,3-dithiazepanes
RU2591196C2 (en) * 2014-11-21 2016-07-10 Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук Method of producing n,n-bis-[(1,5,3-dithiazepan-3-yl)alkyl]amines

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RU2333910C1 (en) * 2006-11-23 2008-09-20 Институт нефтехимии и катализа РАН Method for obtaining 5-{2-[5-{2-[1,3,5-ditiazinan-5-il]ethyl}-4-methyl-1,3,5-tiadiazinan-3-il]ethyl}-1,3,5,-ditiazinan
RU2342370C1 (en) * 2007-07-16 2008-12-27 Институт нефтехимии и катализа РАН "method of obtaining n-[1',3',5'-dithiazinan-5'-yl-carbonyl]-1,3,5-dithiazinan-5-carboxamide"

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