RU2012145638A - METHOD FOR PRODUCING 3-Pyridinyl-1,5,3-Dithiazocinanes - Google Patents

METHOD FOR PRODUCING 3-Pyridinyl-1,5,3-Dithiazocinanes Download PDF

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RU2012145638A
RU2012145638A RU2012145638/04A RU2012145638A RU2012145638A RU 2012145638 A RU2012145638 A RU 2012145638A RU 2012145638/04 A RU2012145638/04 A RU 2012145638/04A RU 2012145638 A RU2012145638 A RU 2012145638A RU 2012145638 A RU2012145638 A RU 2012145638A
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pyridinyl
pyridinamine
propanedithiol
methoxymethyl
dithiazocinanes
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RU2012145638/04A
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Russian (ru)
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RU2536231C2 (en
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Усеин Меметович Джемилев
Асхат Габдрахманович Ибрагимов
Наталия Наильевна Махмудиярова
Кирилл Игоревич Прокофьев
Лилия Вазилевна Мударисова
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Федеральное Государственное Бюджетное Учреждение Науки Институт Нефтехимии И Катализа Ран
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  • Pyridine Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Способ получения 3-пиридинил-1,5,3-дитиазоцинанов общей формулы (1),,отличающийся тем, что N,N-бис(метоксиметил)-N-пиридинамин (где пиридинил - указанное выше) подвергают взаимодействию с 1,3-пропандитиолом в присутствии катализатора CuClв мольном соотношении N,N-бис(метоксиметил)-N-пиридинамин: 1,3-пропандитиол: CuCl=10:10:(0,3-0,7) при комнатной (~20°C) температуре и атмосферном давлении в хлороформе в качестве растворителя в течение 120-150 мин.A method for producing 3-pyridinyl-1,5,3-dithiazocinanes of the general formula (1), characterized in that N, N-bis (methoxymethyl) -N-pyridinamine (where pyridinyl is as defined above) is reacted with 1,3- propanedithiol in the presence of a CuCl catalyst in a molar ratio of N, N-bis (methoxymethyl) -N-pyridinamine: 1,3-propanedithiol: CuCl = 10: 10: (0.3-0.7) at room temperature (~ 20 ° C) and atmospheric pressure in chloroform as a solvent for 120-150 minutes.

Claims (1)

Способ получения 3-пиридинил-1,5,3-дитиазоцинанов общей формулы (1)The method of obtaining 3-pyridinyl-1,5,3-dithiazocinans of the general formula (1)
Figure 00000001
,
Figure 00000001
,
Figure 00000002
,
Figure 00000002
, отличающийся тем, что N,N-бис(метоксиметил)-N-пиридинамин (где пиридинил - указанное выше) подвергают взаимодействию с 1,3-пропандитиолом в присутствии катализатора CuCl2 в мольном соотношении N,N-бис(метоксиметил)-N-пиридинамин: 1,3-пропандитиол: CuCl2=10:10:(0,3-0,7) при комнатной (~20°C) температуре и атмосферном давлении в хлороформе в качестве растворителя в течение 120-150 мин. characterized in that N, N-bis (methoxymethyl) -N-pyridinamine (where pyridinyl is as defined above) is reacted with 1,3-propanedithiol in the presence of a CuCl 2 catalyst in a molar ratio of N, N-bis (methoxymethyl) -N- pyridinamine: 1,3-propanedithiol: CuCl 2 = 10: 10: (0.3-0.7) at room temperature (~ 20 ° C) and atmospheric pressure in chloroform as a solvent for 120-150 minutes.
RU2012145638/04A 2012-10-25 2012-10-25 Method of obtaining 3-pyridinyl-1,5,3-dithiazocinanes RU2536231C2 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2565785C1 (en) * 2014-05-20 2015-10-20 Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук Method of producing (1,5,3-dithiazepan-3-yl)-quinolines

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* Cited by examiner, † Cited by third party
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RU2447072C2 (en) * 2010-01-11 2012-04-10 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран Method of producing n-(1,3,5-dithiazinan-5-yl)-isonicotinamide and n-(2,4,6-trimethyl-1,3,5-dithiazinan-5-yl)-isonicotinamide
RU2467003C1 (en) * 2011-05-30 2012-11-20 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран METHOD OF OBTAINING 3-(m-,p-METHYLPHENYL)-TETRAHYDRO-2H,6H-1,5,3-DITHIAZOCENES

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2565785C1 (en) * 2014-05-20 2015-10-20 Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук Method of producing (1,5,3-dithiazepan-3-yl)-quinolines

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Effective date: 20141118