RU2012155395A - METHOD FOR PRODUCING 3-ARYL-1,5,3-DITIAZOCANES - Google Patents

METHOD FOR PRODUCING 3-ARYL-1,5,3-DITIAZOCANES Download PDF

Info

Publication number
RU2012155395A
RU2012155395A RU2012155395/04A RU2012155395A RU2012155395A RU 2012155395 A RU2012155395 A RU 2012155395A RU 2012155395/04 A RU2012155395/04 A RU 2012155395/04A RU 2012155395 A RU2012155395 A RU 2012155395A RU 2012155395 A RU2012155395 A RU 2012155395A
Authority
RU
Russia
Prior art keywords
aryl
arylamine
tetramethyl
diamine
cucl
Prior art date
Application number
RU2012155395/04A
Other languages
Russian (ru)
Other versions
RU2538600C2 (en
Inventor
Усеин Меметович Джемилев
Асхат Габдрахманович Ибрагимов
Леонард Мухибович Халилов
Наталия Наильевна Махмудиярова
Кирилл Игоревич Прокофьев
Лилия Вазилевна Мударисова
Original Assignee
Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук filed Critical Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук
Priority to RU2012155395/04A priority Critical patent/RU2538600C2/en
Publication of RU2012155395A publication Critical patent/RU2012155395A/en
Application granted granted Critical
Publication of RU2538600C2 publication Critical patent/RU2538600C2/en

Links

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Thiazole And Isothizaole Compounds (AREA)

Abstract

Способ получения 3-арил-1,5,3-дитиазоканов общей формулы (1a-i)отличающийся тем, что N,N,N,N-тетраметил-2,6-дитиагептан-1,7-диамин подвергают взаимодействию с ариламином (арил - фенил, m- и p-метилфенил, o-, m- и p-метоксифенил, o-, m- и p-нитрофенил) в присутствии катализатора CuClв мольном соотношении N,N,N,N-тетраметил-2,6-дитиагептан-1,7-диамин:ариламин:CuCl=10:10:(0.3-0.7) при температуре ~60°С и атмосферном давлении в хлороформе в качестве растворителя в течение 60-90 мин.A method of obtaining 3-aryl-1,5,3-dithiazocanes of the general formula (1a-i) characterized in that N, N, N, N-tetramethyl-2,6-dithiaheptan-1,7-diamine is reacted with an arylamine ( aryl - phenyl, m- and p-methylphenyl, o-, m- and p-methoxyphenyl, o-, m- and p-nitrophenyl) in the presence of a CuCl catalyst in a molar ratio of N, N, N, N-tetramethyl-2.6 -dithiaheptane-1,7-diamine: arylamine: CuCl = 10: 10: (0.3-0.7) at a temperature of ~ 60 ° C and atmospheric pressure in chloroform as a solvent for 60-90 min.

Claims (1)

Способ получения 3-арил-1,5,3-дитиазоканов общей формулы (1a-i)The method of obtaining 3-aryl-1,5,3-dithiazocanes of the general formula (1a-i)
Figure 00000001
Figure 00000001
 отличающийся тем, что N1,N1,N7,N7-тетраметил-2,6-дитиагептан-1,7-диамин подвергают взаимодействию с ариламином (арил - фенил, m- и p-метилфенил, o-, m- и p-метоксифенил, o-, m- и p-нитрофенил) в присутствии катализатора CuCl2 в мольном соотношении N1,N1,N7,N7-тетраметил-2,6-дитиагептан-1,7-диамин:ариламин:CuCl2=10:10:(0.3-0.7) при температуре ~60°С и атмосферном давлении в хлороформе в качестве растворителя в течение 60-90 мин. characterized in that N 1 , N 1 , N 7 , N 7- tetramethyl-2,6-dithiaheptan-1,7-diamine are reacted with arylamine (aryl-phenyl, m- and p-methylphenyl, o-, m- and p-methoxyphenyl, o-, m- and p-nitrophenyl) in the presence of a CuCl 2 catalyst in a molar ratio of N 1 , N 1 , N 7 , N 7- tetramethyl-2,6-dithiaheptan-1,7-diamine: arylamine : CuCl 2 = 10: 10: (0.3-0.7) at a temperature of ~ 60 ° C and atmospheric pressure in chloroform as a solvent for 60-90 minutes.
RU2012155395/04A 2012-12-19 2012-12-19 Method of obtaining 3-aryl-1,5,3-dithiazocanes RU2538600C2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2012155395/04A RU2538600C2 (en) 2012-12-19 2012-12-19 Method of obtaining 3-aryl-1,5,3-dithiazocanes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2012155395/04A RU2538600C2 (en) 2012-12-19 2012-12-19 Method of obtaining 3-aryl-1,5,3-dithiazocanes

Publications (2)

Publication Number Publication Date
RU2012155395A true RU2012155395A (en) 2014-06-27
RU2538600C2 RU2538600C2 (en) 2015-01-10

Family

ID=51215897

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2012155395/04A RU2538600C2 (en) 2012-12-19 2012-12-19 Method of obtaining 3-aryl-1,5,3-dithiazocanes

Country Status (1)

Country Link
RU (1) RU2538600C2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2626006C1 (en) * 2016-02-02 2017-07-21 Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук Method of producing 4-(o,m,p-halogenphenyl)-2,6-dithia-4-azabicyclo [5,3,1]undeca-1(11),7,9-trienes

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2467002C1 (en) * 2011-05-30 2012-11-20 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран METHOD OF OBTAINING 3-(o-,m-,p-NITROPHENYL)-TETRAHYDRO-2H,6H-1,5,3-DITHIAZOCENES
RU2467001C1 (en) * 2011-05-30 2012-11-20 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран METHOD OF OBTAINING 3-(o-,m-,p-METHOXYPHENYL)-TETRAHYDRO-2H, 6H-1, 5, 3-DITHIAZOCENES
RU2467000C1 (en) * 2011-05-30 2012-11-20 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран Method of obtaining 3-aryl-tetrahydro-2h,6h-1,5,3-dithiazocines

Also Published As

Publication number Publication date
RU2538600C2 (en) 2015-01-10

Similar Documents

Publication Publication Date Title
EA201590583A1 (en) METHOD OF OBTAINING THERAPEUTIC NANOPARTICLES
MX346084B (en) Process for preparing polyether polyols.
RU2009101579A (en) MONOCER FOR POLYCONDENSATION
RU2012155395A (en) METHOD FOR PRODUCING 3-ARYL-1,5,3-DITIAZOCANES
EP3415505A3 (en) Methods of chemical synthesis of diaminophenothiazinium compounds including methylthioninium chloride (mtc)
RU2013103708A (en) METHOD FOR PRODUCING 3-ARIL-1,5,3-DITIAZEPANES
RU2012154466A (en) METHOD FOR PRODUCING 3-ARIL-1,5,3-DIOXAZEPANES
WO2012012689A3 (en) Circulating micrornas are biomarkers of various diseases
RU2012145642A (en) METHOD FOR PRODUCING 3-HETARIL-1,5,3-DITIAZOCINANES
RU2013103577A (en) METHOD FOR PRODUCING 3-ARYL-1,5,3-DITIAZOCANES
RU2013103706A (en) METHOD FOR PRODUCING 3-ARIL -1,5,3-DITIAZEPANES
RU2012100111A (en) METHOD FOR PRODUCING 2- AND 2,3-SUBSTITUTED QUINOLINS
RU2010119316A (en) POLY - N, N- DIALYLAMINETHANIC ACID
RU2011124568A (en) METHOD FOR PRODUCING α, ω-BIS- (1,5,3-DITIAZEPINAN-3-IL) ALKANOV
RU2012145843A (en) METHOD FOR PRODUCING 3-HETARIL-1,5,3-DITIAZEPINANES
RU2012145638A (en) METHOD FOR PRODUCING 3-Pyridinyl-1,5,3-Dithiazocinanes
RU2010122542A (en) METHOD FOR PRODUCING MONO- (DI-, TETRA-) METHYL-1,2-BIS- (1,3,5-DITIAZINAN-5-IL) ETHANES
RU2012145705A (en) METHOD FOR PRODUCING 3-Pyridinyl-1,5,3-Dithiazepinanes
RU2008132383A (en) METHOD FOR PRODUCING N1, N1, N4, N4-TETRAMETHYL-2-BUTIN-1,4-DIAMINE
RU2012101387A (en) METHOD FOR PRODUCING N- (1,5,3-DITIAZOCINAN-3-IL) AMIDES
RU2013152020A (en) METHOD FOR PRODUCING (1,5,3-DITIAZEPAN-3-IL) -ALKANDIOLS
RU2010104331A (en) METHOD FOR PRODUCING BENZYLBUTYL ETHER
RU2010126714A (en) METHOD FOR PRODUCING 1,4-DIAZABICYCLO [2.1.1] HEXAN
RU2010100494A (en) METHOD FOR PRODUCING SUBSTITUTED ETHILES (1,2,3-TRIAZOL-4-IL) OF DINITROACETATES HAVING FUNGICIDAL ACTIVITY
RU2012147376A (en) METHOD FOR PRODUCING 3,3-DI (METHOXICARBONIL) -1,5-DITIACYCLOalkanes

Legal Events

Date Code Title Description
MM4A The patent is invalid due to non-payment of fees

Effective date: 20150209