RU2013103708A - METHOD FOR PRODUCING 3-ARIL-1,5,3-DITIAZEPANES - Google Patents

METHOD FOR PRODUCING 3-ARIL-1,5,3-DITIAZEPANES Download PDF

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RU2013103708A
RU2013103708A RU2013103708/04A RU2013103708A RU2013103708A RU 2013103708 A RU2013103708 A RU 2013103708A RU 2013103708/04 A RU2013103708/04 A RU 2013103708/04A RU 2013103708 A RU2013103708 A RU 2013103708A RU 2013103708 A RU2013103708 A RU 2013103708A
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dithihexane
arylamine
fecl
tetramethyl
diamine
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RU2013103708/04A
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Russian (ru)
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RU2536149C2 (en
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Усеин Меметович Джемилев
Асхат Габдрахманович Ибрагимов
Леонард Мухибович Халилов
Наталья Наильевна Махмудиярова
Кирилл Игоревич Прокофьев
Лилия Вазилевна Мударисова
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Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук
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  • Nitrogen- Or Sulfur-Containing Heterocyclic Ring Compounds With Rings Of Six Or More Members (AREA)

Abstract

Способ получения 3-арил-1,5,3-дитиазепанов общей формулы (Ia-i):отличающийся тем, что N,N,N,N-тетраметил-2,5-дитиагексан-1,6-диамина подвергают взаимодействию с ариламином (арил = фенил, m- и p-метилфенил, o-, m- и р-метоксифенил, о-, m- и р-нитрофенил) в присутствии катализатора FeCl 6HO в мольном соотношении N,N,N,N-тетраметил-2,5-дитиагексан-1,6-диамин: ариламин: FeCl 6HO=10:10:(0,3-0,7) при температуре ~60°С и атмосферном давлении в хлороформе в качестве растворителя в течение 50-80 минут.The method of obtaining 3-aryl-1,5,3-dithiazepanes of the general formula (Ia-i): characterized in that N, N, N, N-tetramethyl-2,5-dithihexane-1,6-diamine are reacted with arylamine (aryl = phenyl, m- and p-methylphenyl, o-, m- and p-methoxyphenyl, o-, m- and p-nitrophenyl) in the presence of a FeCl 6HO catalyst in a molar ratio of N, N, N, N-tetramethyl- 2,5-dithihexane-1,6-diamine: arylamine: FeCl 6HO = 10: 10: (0.3-0.7) at a temperature of ~ 60 ° C and atmospheric pressure in chloroform as a solvent for 50-80 minutes .

Claims (1)

Способ получения 3-арил-1,5,3-дитиазепанов общей формулы (Ia-i):The method of obtaining 3-aryl-1,5,3-dithiazepanes of the general formula (Ia-i):
Figure 00000001
Figure 00000001
 отличающийся тем, что N1,N1,N6,N6-тетраметил-2,5-дитиагексан-1,6-диамина подвергают взаимодействию с ариламином (арил = фенил, m- и p-метилфенил, o-, m- и р-метоксифенил, о-, m- и р-нитрофенил) в присутствии катализатора FeCl3 ·6H2O в мольном соотношении N1,N1,N6,N6-тетраметил-2,5-дитиагексан-1,6-диамин: ариламин: FeCl3 ·6H2O=10:10:(0,3-0,7) при температуре ~60°С и атмосферном давлении в хлороформе в качестве растворителя в течение 50-80 минут. characterized in that N 1 , N 1 , N 6 , N 6 -tetramethyl-2,5-dithihexane-1,6-diamine are reacted with arylamine (aryl = phenyl, m- and p-methylphenyl, o-, m- and p-methoxyphenyl, o-, m- and p-nitrophenyl) in the presence of a FeCl 3 · 6H 2 O catalyst in a molar ratio of N 1 , N 1 , N 6 , N 6 -tetramethyl-2,5-dithihexane-1,6 -diamine: arylamine: FeCl 3 · 6H 2 O = 10: 10: (0.3-0.7) at a temperature of ~ 60 ° C and atmospheric pressure in chloroform as a solvent for 50-80 minutes.
RU2013103708/04A 2013-01-28 2013-01-28 Method of obtaining 3-aryl-1,5,3-dithiazepanes RU2536149C2 (en)

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