RU2013104851A - METHOD FOR SELECTIVE PRODUCTION OF 1'-ALKYL-1'-N-CYCLOGEXYL-CARBOXAAMIDYL-CYCLOPROPA [2 ', 3': 1,9] (C60-Ih) [5,6] FULLERENES - Google Patents

METHOD FOR SELECTIVE PRODUCTION OF 1'-ALKYL-1'-N-CYCLOGEXYL-CARBOXAAMIDYL-CYCLOPROPA [2 ', 3': 1,9] (C60-Ih) [5,6] FULLERENES Download PDF

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RU2013104851A
RU2013104851A RU2013104851/04A RU2013104851A RU2013104851A RU 2013104851 A RU2013104851 A RU 2013104851A RU 2013104851/04 A RU2013104851/04 A RU 2013104851/04A RU 2013104851 A RU2013104851 A RU 2013104851A RU 2013104851 A RU2013104851 A RU 2013104851A
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fullerenes
alkyl
cyclogexyl
carboxaamidyl
cyclopropa
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RU2540080C2 (en
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Усеин Меметович Джемилев
Айрат Рамилевич Туктаров
Лилия Линатовна Хузина
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Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук
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Abstract

Способ селективного получения 1′-алкил-1′-N-циклогексилкарбоксаамидилциклопропа[2′,3′:1,9](C-I)[5,6]фуллеренов (1),характеризующийся тем, что C-фуллерен взаимодействует с α-замещенными диазоамидами формулы NC(R)C(O)NHCy (R=Me, i-Bu, -(CH)SMe) в o-дихлорбензоле в присутствии трехкомпонентного катализатора {Pd(acac):2PPh:4EtAl}, взятыми в мольном соотношении C:диазосоединение:Pd(acac):PPh:EtAl=0.01:(0.03-0.07):(0.0015-0.0025):(0.003-0.005):(0.006-0.01) при температуре 80°C в течение 0,2-1,0 ч.Method for the selective preparation of 1′-alkyl-1′-N-cyclohexylcarboxaamidylcycloprop [2 ′, 3 ′: 1.9] (CI) [5.6] fullerenes (1), characterized in that C-fullerene interacts with α-substituted diazoamides of the formula NC (R) C (O) NHCy (R = Me, i-Bu, - (CH) SMe) in o-dichlorobenzene in the presence of a three-component catalyst {Pd (acac): 2PPh: 4EtAl}, taken in molar ratio C : diazo compound: Pd (acac): PPh: EtAl = 0.01: (0.03-0.07) :( 0.0015-0.0025) :( 0.003-0.005) :( 0.006-0.015) at a temperature of 80 ° C for 0.2-1, 0 h

Claims (1)

Способ селективного получения 1′-алкил-1′-N-циклогексилкарбоксаамидилциклопропа[2′,3′:1,9](C60-Ih)[5,6]фуллеренов (1)Method for the selective preparation of 1′-alkyl-1′-N-cyclohexylcarboxamidylcycloprop [2 ′, 3 ′: 1.9] (C 60 -I h ) [5,6] fullerenes (1)
Figure 00000001
,
Figure 00000001
, характеризующийся тем, что C60-фуллерен взаимодействует с α-замещенными диазоамидами формулы N2C(R)C(O)NHCy (R=Me, i-Bu, -(CH2)2SMe) в o-дихлорбензоле в присутствии трехкомпонентного катализатора {Pd(acac)2:2PPh3:4Et3Al}, взятыми в мольном соотношении C60:диазосоединение:Pd(acac)2:PPh3:Et3Al=0.01:(0.03-0.07):(0.0015-0.0025):(0.003-0.005):(0.006-0.01) при температуре 80°C в течение 0,2-1,0 ч. characterized in that the C 60 fullerene interacts with α-substituted diazoamides of the formula N 2 C (R) C (O) NHCy (R = Me, i-Bu, - (CH 2 ) 2 SMe) in o-dichlorobenzene in the presence of ternary catalyst {Pd (acac) 2 : 2PPh 3 : 4Et 3 Al}, taken in a molar ratio of C 60 : diazo compound: Pd (acac) 2 : PPh 3 : Et 3 Al = 0.01: (0.03-0.07) :( 0.0015-0.0025 ) :( 0.003-0.005) :( 0.006-0.01) at a temperature of 80 ° C for 0.2-1.0 hours.
RU2013104851/04A 2013-02-05 2013-02-05 Method of selective obtaining of 1'-alkyl-1'-n-cyclohexylcarboxaamidylcyclopropa[2',3':1,9](c60-ih)[5,6]fullerenes RU2540080C2 (en)

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