RU2012115956A - METHOD FOR PRODUCING N-ALKYL- AND N-ARILKARBOXAMIDIL-1aH, 2'H- [1,2] PYRAZOLINO [3 ', 4': 1.9] (C60-Ih) - [5,6] FULLERENES - Google Patents

METHOD FOR PRODUCING N-ALKYL- AND N-ARILKARBOXAMIDIL-1aH, 2'H- [1,2] PYRAZOLINO [3 ', 4': 1.9] (C60-Ih) - [5,6] FULLERENES Download PDF

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RU2012115956A
RU2012115956A RU2012115956/04A RU2012115956A RU2012115956A RU 2012115956 A RU2012115956 A RU 2012115956A RU 2012115956/04 A RU2012115956/04 A RU 2012115956/04A RU 2012115956 A RU2012115956 A RU 2012115956A RU 2012115956 A RU2012115956 A RU 2012115956A
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alkyl
pyrazolino
fullerenes
acac
arilkarboxamidil
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RU2517170C2 (en
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Усеин Меметович Джемилев
Айрат Рамилевич Туктаров
Лилия Линатовна Хузина
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Федеральное Государственное Бюджетное Учреждение Науки Институт Нефтехимии И Катализа Ран
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Abstract

Способ получения N-алкил- и N-арилкарбоксамидил-1aH,2'H-[1,2]пиразолино[3',4':1,9](C-I)-[5,6]фуллеренов общей формулы (I):;;характеризующийся тем, что C-фуллерен взаимодействует с алкил- и арилдиазоамидами формулы NCHC(O)NR в o-дихлорбензоле (o-ДХБ) в присутствии трехкомпонентной каталитической системы {Pd(acac): 2PPh: 4EtAl}, при мольном соотношении C:диазосоединение:Pd(acac):PPh:EtAl = 1:(3-7):(0,1-0,3):(0,2-0,6):(0,4-1,2), температуре 80°С в течение 0,5-1,5 ч.The method of obtaining N-alkyl- and N-arylcarboxamidyl-1aH, 2'H- [1,2] pyrazolino [3 ', 4': 1,9] (CI) - [5,6] fullerenes of the general formula (I): ; characterized by the fact that C-fullerene interacts with alkyl- and aryl diazoamides of the formula NCHC (O) NR in o-dichlorobenzene (o-DCB) in the presence of a three-component catalytic system {Pd (acac): 2PPh: 4EtAl}, at a molar ratio of C : diazo compound: Pd (acac): PPh: EtAl = 1: (3-7) :( 0.1-0.3) :( 0.2-0.6) :( 0.4-1.2), temperature of 80 ° C for 0.5-1.5 hours

Claims (1)

Способ получения N-алкил- и N-арилкарбоксамидил-1aH,2'H-[1,2]пиразолино[3',4':1,9](C60-Ih)-[5,6]фуллеренов общей формулы (I):The method of obtaining N-alkyl- and N-arylcarboxamidyl-1aH, 2'H- [1,2] pyrazolino [3 ', 4': 1,9] (C 60 -I h ) - [5,6] fullerenes of the General formula (I):
Figure 00000001
Figure 00000002
;
Figure 00000003
;
Figure 00000004
Figure 00000001
Figure 00000002
;
Figure 00000003
;
Figure 00000004
 характеризующийся тем, что C60-фуллерен взаимодействует с алкил- и арилдиазоамидами формулы N2CHC(O)NR в o-дихлорбензоле (o-ДХБ) в присутствии трехкомпонентной каталитической системы {Pd(acac)2 : 2PPh3 : 4Et3Al}, при мольном соотношении C60:диазосоединение:Pd(acac)2:PPh3:Et3Al = 1:(3-7):(0,1-0,3):(0,2-0,6):(0,4-1,2), температуре 80°С в течение 0,5-1,5 ч. characterized in that the C 60 fullerene interacts with alkyl and aryl diazoamides of the formula N 2 CHC (O) NR in o-dichlorobenzene (o-DCB) in the presence of a three-component catalytic system {Pd (acac) 2 : 2PPh 3 : 4Et 3 Al} , with a molar ratio of C 60 : diazo compound: Pd (acac) 2 : PPh 3 : Et 3 Al = 1: (3-7) :( 0.1-0.3) :( 0.2-0.6): (0.4-1.2), a temperature of 80 ° C for 0.5-1.5 hours
RU2012115956/04A 2012-04-19 2012-04-19 METHOD OF PRODUCING N-ALKYL AND N-ARYLCARBOXAMIDYL-1aH,2'H-[1,2]PYRAZOLINO[3',4':1,9](C60-Ih)-[5,6]FULLERENES RU2517170C2 (en)

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