RU2012145643A - METHOD FOR SELECTIVE PRODUCTION OF 1'-ALKYL-1'-S-PENTYL-CARBOTIOYL-CYCLOPROPA [2 ', 3': 1,9] (C60-Ih) [5,6] FULLERENES - Google Patents

METHOD FOR SELECTIVE PRODUCTION OF 1'-ALKYL-1'-S-PENTYL-CARBOTIOYL-CYCLOPROPA [2 ', 3': 1,9] (C60-Ih) [5,6] FULLERENES Download PDF

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RU2012145643A
RU2012145643A RU2012145643/04A RU2012145643A RU2012145643A RU 2012145643 A RU2012145643 A RU 2012145643A RU 2012145643/04 A RU2012145643/04 A RU 2012145643/04A RU 2012145643 A RU2012145643 A RU 2012145643A RU 2012145643 A RU2012145643 A RU 2012145643A
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fullerenes
alkyl
carbotioyl
cyclopropa
pentyl
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RU2012145643/04A
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Russian (ru)
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Усеин Меметович Джемилев
Айрат Рамилевич Туктаров
Артур Альбертович Хузин
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Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук
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Abstract

Способ селективного получения 1'-алкил-1'-S-пентилкарботиоилциклопропа[2',3':1,9](C-I)[5,6]фуллеренов (1),R=i-Bu; -(CH)SMe,характеризующийся тем, что C-фуллерен взаимодействует с диазотиоатами формулы NC(R)C(O)SCH(R=i-Bu,-(CH)2SMe) в одихлорбензоле (о-ДХБ) в присутствии трехкомпонентного катализатора {Pd(acac):2PPh:4EtAl}, взятыми в мольном соотношении C: диазосоединение: Pd(acac):PPh:EtAl=0.01:(0.03-0.07):(0.0015-0.0025):(0.003-0.005):(0.006-0.01), при температуре 40°С в течение 0.2-1.0 ч.Method for the selective preparation of 1'-alkyl-1'-S-pentylcarbothioylcycloprop [2 ', 3': 1.9] (C-I) [5.6] fullerenes (1), R = i-Bu; - (CH) SMe, characterized in that C-fullerene interacts with diazothioates of the formula NC (R) C (O) SCH (R = i-Bu, - (CH) 2SMe) in dichlorobenzene (o-DCB) in the presence of a three-component catalyst {Pd (acac): 2PPh: 4EtAl}, taken in the molar ratio C: diazocompound: Pd (acac): PPh: EtAl = 0.01: (0.03-0.07) :( 0.0015-0.0025) :( 0.003-0.005) :( 0.006-0.005) :( 0.006 -0.01), at a temperature of 40 ° C for 0.2-1.0 hours

Claims (1)

Способ селективного получения 1'-алкил-1'-S-пентилкарботиоилциклопропа[2',3':1,9](C60-Ih)[5,6]фуллеренов (1),A method for the selective preparation of 1'-alkyl-1'-S-pentylcarbothioylcycloprop [2 ', 3': 1.9] (C 60 -I h ) [5.6] fullerenes (1),
Figure 00000001
R=i-Bu; -(CH2)2SMe,
Figure 00000001
R is i-Bu; - (CH 2 ) 2 SMe, характеризующийся тем, что C60-фуллерен взаимодействует с диазотиоатами формулы N2C(R)C(O)SC5H11 (R=i-Bu,-(CH2)2SMe) в одихлорбензоле (о-ДХБ) в присутствии трехкомпонентного катализатора {Pd(acac)2:2PPh3:4Et3Al}, взятыми в мольном соотношении C60: диазосоединение: Pd(acac)2:PPh3:Et3Al=0.01:(0.03-0.07):(0.0015-0.0025):(0.003-0.005):(0.006-0.01), при температуре 40°С в течение 0.2-1.0 ч. characterized in that the C 60 fullerene interacts with diazothioates of the formula N 2 C (R) C (O) SC 5 H 11 (R = i-Bu, - (CH 2 ) 2SMe) in dichlorobenzene (o-DCB) in the presence of ternary catalyst {Pd (acac) 2 : 2PPh 3 : 4Et 3 Al}, taken in a molar ratio of C 60 : diazo compound: Pd (acac) 2 : PPh 3 : Et 3 Al = 0.01: (0.03-0.07) :( 0.0015-0.0025 ) :( 0.003-0.005) :( 0.006-0.01), at a temperature of 40 ° C for 0.2-1.0 hours.
RU2012145643/04A 2012-10-25 2012-10-25 METHOD FOR SELECTIVE PRODUCTION OF 1'-ALKYL-1'-S-PENTYL-CARBOTIOYL-CYCLOPROPA [2 ', 3': 1,9] (C60-Ih) [5,6] FULLERENES RU2012145643A (en)

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