RU2010137370A - METHOD FOR PRODUCING N, N-DIMETHYL-N - [(Alkylsulfanyl) methyl] amines - Google Patents

METHOD FOR PRODUCING N, N-DIMETHYL-N - [(Alkylsulfanyl) methyl] amines Download PDF

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RU2010137370A
RU2010137370A RU2010137370/04A RU2010137370A RU2010137370A RU 2010137370 A RU2010137370 A RU 2010137370A RU 2010137370/04 A RU2010137370/04 A RU 2010137370/04A RU 2010137370 A RU2010137370 A RU 2010137370A RU 2010137370 A RU2010137370 A RU 2010137370A
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Russia
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alkylsulfanyl
amines
dimethyl
methyl
tetramethylmethanediamine
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RU2010137370/04A
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Russian (ru)
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RU2466985C2 (en
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Усеин Меметович Джемилев (RU)
Усеин Меметович Джемилев
Регина Радиевна Хайруллина (RU)
Регина Радиевна Хайруллина
Байрас Фаритович Акманов (RU)
Байрас Фаритович Акманов
Асхат Габдрахманович Ибрагимов (RU)
Асхат Габдрахманович Ибрагимов
Внира Рахимовна Ахметова (RU)
Внира Рахимовна Ахметова
Райхана Валиулловна Кунакова (RU)
Райхана Валиулловна Кунакова
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Учреждение Российской академии наук ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА РАН (RU)
Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран
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Abstract

Способ получения N,N-диметил-N-[(алкилсульфанил)метил] аминов общей формулы (1): ! !отличающийся тем, что алкилтиолы общей формулы RSH, где R=н-С4Н9, н-С5Н11, н-С7Н15 подвергают взаимодействию с N,N,N,N-тетраметилметандиамином в присутствии катализатора кристаллогидрата хлорида самария (SmCl3·6H2O), взятыми в мольном соотношении алкилтиол: N,N,N,N-тетраметилметандиамин: SmCl3·6H2O=10:(10-14):10:12:0.5, температуре 20-40°C в течение 0.5-2 ч. The method of obtaining N, N-dimethyl-N - [(alkylsulfanyl) methyl] amines of the general formula (1):! ! characterized in that the alkylthiols of the general formula RSH, where R = n-C4H9, n-C5H11, n-C7H15 are reacted with N, N, N, N-tetramethylmethanediamine in the presence of a samarium chloride crystalline hydrate catalyst (SmCl3 · 6H2O), taken in the molar ratio of alkylthiol: N, N, N, N-tetramethylmethanediamine: SmCl3 · 6H2O = 10: (10-14): 10: 12: 0.5, at a temperature of 20-40 ° C for 0.5-2 hours.

Claims (1)

Способ получения N,N-диметил-N-[(алкилсульфанил)метил] аминов общей формулы (1):The method of obtaining N, N-dimethyl-N - [(alkylsulfanyl) methyl] amines of the general formula (1):
Figure 00000001
Figure 00000001
 отличающийся тем, что алкилтиолы общей формулы RSH, где R=н-С4Н9, н-С5Н11, н-С7Н15 подвергают взаимодействию с N,N,N,N-тетраметилметандиамином в присутствии катализатора кристаллогидрата хлорида самария (SmCl3·6H2O), взятыми в мольном соотношении алкилтиол: N,N,N,N-тетраметилметандиамин: SmCl3·6H2O=10:(10-14):10:12:0.5, температуре 20-40°C в течение 0.5-2 ч. characterized in that the alkylthiols of the general formula RSH, where R = n — C 4 H 9 , n — C 5 H 11 , n — C 7 H 15 are reacted with N, N, N, N-tetramethylmethanediamine in the presence of a samarium chloride crystalline catalyst (SmCl 3 · 6H 2 O) taken in the molar ratio of alkylthiol: N, N, N, N-tetramethylmethanediamine: SmCl 3 · 6H 2 O = 10: (10-14): 10: 12: 0.5, temperature 20-40 ° C for 0.5-2 hours
RU2010137370/04A 2010-09-07 2010-09-07 Method of obtaining n,n-dimethyl-n-[(alkylsulfanyl)methyl]amines RU2466985C2 (en)

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RU2551689C1 (en) * 2013-11-21 2015-05-27 Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук Method of obtaining n,n,n-tri[(phenyl(benzyl)sulphanyl)-methyl]amines
RU2735739C1 (en) * 2020-02-10 2020-11-06 Федеральное государственное бюджетное научное учреждение Уфимский федеральный исследовательский центр Российской академии наук Method of producing 4-thia-2,6-diazabicyclo[6_3_1]{[6_2_2]}-dodeca-1(12{10}),8,10{11}-trien-7-ones

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