RU2012145844A - METHOD FOR PRODUCING 5-ALKYL-1,3,5-TRIAZINAN-2- (TI) ONES - Google Patents

METHOD FOR PRODUCING 5-ALKYL-1,3,5-TRIAZINAN-2- (TI) ONES Download PDF

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RU2012145844A
RU2012145844A RU2012145844/04A RU2012145844A RU2012145844A RU 2012145844 A RU2012145844 A RU 2012145844A RU 2012145844/04 A RU2012145844/04 A RU 2012145844/04A RU 2012145844 A RU2012145844 A RU 2012145844A RU 2012145844 A RU2012145844 A RU 2012145844A
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triazinan
ones
alkyl
thio
dimethylamino
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RU2012145844/04A
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RU2522446C2 (en
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Усеин Меметович Джемилев
Асхат Габдрахманович Ибрагимов
Регина Радиевна Хайруллина
Альфия Равзатовна Гениятова
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Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук
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Abstract

Способ получения 5-алкил-1,3,5-триазинан-2(ти)онов общей формулы (I):где Х=O, S; R=t-Bu, циклогексил; R'=Н, allylотличающийся тем, что первичные алифатические амины RNH(R = указанные выше) подвергаются взаимодействию с бис(N,N-диметиламино)метаном и (тио)мочевиной в присутствии катализатора кристаллогидрата хлорида меди CuCl·2HO при мольном соотношении (тио)мочевина: бис(N,N-диметиламино)метан: RNH:CuCl·2HO=10:20:10:(0.3-0.7) при температуре 80°С и атмосферном давлении в течение 6-10 ч.The method of obtaining 5-alkyl-1,3,5-triazinan-2 (ty) ones of the general formula (I): where X = O, S; R = t-Bu, cyclohexyl; R '= H, allyl characterized in that the primary aliphatic amines RNH (R = above) are reacted with bis (N, N-dimethylamino) methane and (thio) urea in the presence of a catalyst for crystalline copper chloride CuCl · 2HO molar ratio (thio ) urea: bis (N, N-dimethylamino) methane: RNH: CuCl · 2HO = 10: 20: 10: (0.3-0.7) at a temperature of 80 ° C and atmospheric pressure for 6-10 hours.

Claims (1)

Способ получения 5-алкил-1,3,5-триазинан-2(ти)онов общей формулы (I):The method of obtaining 5-alkyl-1,3,5-triazinan-2 (ty) ones of general formula (I):
Figure 00000001
где Х=O, S; R=t-Bu, циклогексил; R'=Н, allyl
Figure 00000001
where X = O, S; R = t-Bu, cyclohexyl; R '= H, allyl отличающийся тем, что первичные алифатические амины RNH2 (R = указанные выше) подвергаются взаимодействию с бис(N,N-диметиламино)метаном и (тио)мочевиной в присутствии катализатора кристаллогидрата хлорида меди CuCl2·2H2O при мольном соотношении (тио)мочевина: бис(N,N-диметиламино)метан: RNH2:CuCl2·2H2O=10:20:10:(0.3-0.7) при температуре 80°С и атмосферном давлении в течение 6-10 ч. characterized in that the primary aliphatic amines RNH 2 (R = above) are reacted with bis (N, N-dimethylamino) methane and (thio) urea in the presence of a catalyst of crystalline copper chloride CuCl 2 · 2H 2 O in a molar ratio (thio) urea: bis (N, N-dimethylamino) methane: RNH 2 : CuCl 2 · 2H 2 O = 10: 20: 10: (0.3-0.7) at a temperature of 80 ° C and atmospheric pressure for 6-10 hours
RU2012145844/04A 2012-10-26 2012-10-26 Method of producing 5-alkyl-1,3,5-triazinan-2-(thi)ones RU2522446C2 (en)

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