RU2012145640A - METHOD FOR PRODUCING ARIL (C60-Ih) [5,6] FULLEREN- (9H) -IL KETONES - Google Patents

METHOD FOR PRODUCING ARIL (C60-Ih) [5,6] FULLEREN- (9H) -IL KETONES Download PDF

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RU2012145640A
RU2012145640A RU2012145640/04A RU2012145640A RU2012145640A RU 2012145640 A RU2012145640 A RU 2012145640A RU 2012145640/04 A RU2012145640/04 A RU 2012145640/04A RU 2012145640 A RU2012145640 A RU 2012145640A RU 2012145640 A RU2012145640 A RU 2012145640A
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ketones
etmgbr
oipr
fullerene
producing
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RU2012145640/04A
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RU2540082C2 (en
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Усеин Меметович Джемилев
Айрат Рамилевич Туктаров
Марина Альфисовна Фамутдинова
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Федеральное Государственное Бюджетное Учреждение Науки Институт Нефтехимии И Катализа Ран
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Abstract

Способ получения арил(C-I)[5,6]фуллерен-1(9H)-ил кетонов общей формулы (1);;характеризующийся тем, что C-фуллерен взаимодействует с эфирами ароматических карбоновых кислот формулы ArC(O)OMe (Ar=фенил, бифенил,) в толуоле под действием катализатора Ti(OiPr)в присутствии EtMgBr при мольном соотношении C: эфир: Ti(OiPr): EtMgBr=1:(5-15):(5-15):(30-50), при температуре 0°С в течение 5-30 мин.A method for producing aryl (CI) [5,6] fullerene-1 (9H) -yl ketones of the general formula (1); characterized in that C-fullerene interacts with aromatic carboxylic acid esters of the formula ArC (O) OMe (Ar = phenyl , biphenyl,) in toluene under the action of a Ti (OiPr) catalyst in the presence of EtMgBr at a molar ratio C: ether: Ti (OiPr): EtMgBr = 1: (5-15) :( 5-15) :( 30-50), at a temperature of 0 ° C for 5-30 minutes

Claims (1)

Способ получения арил(C60-Ih)[5,6]фуллерен-1(9H)-ил кетонов общей формулы (1)The method of obtaining aryl (C 60 -I h ) [5,6] fullerene-1 (9H) -yl ketones of the general formula (1)
Figure 00000001
;
Figure 00000002
;
Figure 00000003
Figure 00000001
;
Figure 00000002
;
Figure 00000003
 характеризующийся тем, что C60-фуллерен взаимодействует с эфирами ароматических карбоновых кислот формулы ArC(O)OMe (Ar=фенил, бифенил,
Figure 00000003
) в толуоле под действием катализатора Ti(OiPr)4 в присутствии EtMgBr при мольном соотношении C60: эфир: Ti(OiPr)4: EtMgBr=1:(5-15):(5-15):(30-50), при температуре 0°С в течение 5-30 мин. characterized in that the C 60 fullerene interacts with aromatic carboxylic acid esters of the formula ArC (O) OMe (Ar = phenyl, biphenyl,
Figure 00000003
) in toluene under the action of a Ti (OiPr) 4 catalyst in the presence of EtMgBr at a molar ratio of C 60 : ether: Ti (OiPr) 4 : EtMgBr = 1: (5-15) :( 5-15) :( 30-50), at a temperature of 0 ° C for 5-30 minutes
RU2012145640/04A 2012-10-25 2012-10-25 Method of obtaining aryl(c60-ih)[5,6]fullerene-(9h)-yl ketones RU2540082C2 (en)

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RU2610092C1 (en) * 2015-11-24 2017-02-07 Федеральное Государственное Бюджетное Учреждение Науки Институт Нефтехимии И Катализа Ран METHOD OF PRODUCING 1'-AMINO-1'-ETHYL (CYCLOALKYLIDENE) ACETYL- (C60-Ih) [5,6] FULLERO [2 ', 3': 1,9] CYCLOPROPANES
RU2714319C1 (en) * 2019-08-15 2020-02-14 Федеральное государственное бюджетное научное учреждение Уфимский федеральный исследовательский центр Российской академии наук Method for selective production of substituted 1-styryl-2-hydrofullerenes

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