RU2008143994A - Композитный материал - Google Patents
Композитный материал Download PDFInfo
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- RU2008143994A RU2008143994A RU2008143994/04A RU2008143994A RU2008143994A RU 2008143994 A RU2008143994 A RU 2008143994A RU 2008143994/04 A RU2008143994/04 A RU 2008143994/04A RU 2008143994 A RU2008143994 A RU 2008143994A RU 2008143994 A RU2008143994 A RU 2008143994A
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- 239000002131 composite material Substances 0.000 title claims abstract 34
- 239000000835 fiber Substances 0.000 claims abstract 25
- 239000011159 matrix material Substances 0.000 claims abstract 24
- 230000001747 exhibiting effect Effects 0.000 claims abstract 5
- 239000004753 textile Substances 0.000 claims abstract 2
- 239000004743 Polypropylene Substances 0.000 claims 6
- 239000000463 material Substances 0.000 claims 4
- -1 polypropylene Polymers 0.000 claims 4
- 229920001169 thermoplastic Polymers 0.000 claims 4
- 239000004593 Epoxy Substances 0.000 claims 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 3
- 125000003700 epoxy group Chemical group 0.000 claims 3
- 229920000647 polyepoxide Polymers 0.000 claims 3
- 229920001155 polypropylene Polymers 0.000 claims 3
- 229920001187 thermosetting polymer Polymers 0.000 claims 3
- 239000004677 Nylon Substances 0.000 claims 2
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 claims 2
- 229920001778 nylon Polymers 0.000 claims 2
- 229920000728 polyester Polymers 0.000 claims 2
- 239000004416 thermosoftening plastic Substances 0.000 claims 2
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 claims 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims 1
- 229910052797 bismuth Inorganic materials 0.000 claims 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 claims 1
- 239000001913 cellulose Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- 229910021419 crystalline silicon Inorganic materials 0.000 claims 1
- 239000003063 flame retardant Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 238000012986 modification Methods 0.000 claims 1
- 230000004048 modification Effects 0.000 claims 1
- 239000002052 molecular layer Substances 0.000 claims 1
- 229920005615 natural polymer Polymers 0.000 claims 1
- 239000000049 pigment Substances 0.000 claims 1
- 239000004014 plasticizer Substances 0.000 claims 1
- 239000004848 polyfunctional curative Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 229920002379 silicone rubber Polymers 0.000 claims 1
- 239000004945 silicone rubber Substances 0.000 claims 1
- 239000004634 thermosetting polymer Substances 0.000 claims 1
- 229910021493 α-cristobalite Inorganic materials 0.000 claims 1
- 229910021489 α-quartz Inorganic materials 0.000 claims 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/246—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using polymer based synthetic fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/247—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using fibres of at least two types
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/22—Thermoplastic resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/24—Thermosetting resins
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24132—Structurally defined web or sheet [e.g., overall dimension, etc.] including grain, strips, or filamentary elements in different layers or components parallel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
- Y10T428/24994—Fiber embedded in or on the surface of a polymeric matrix
- Y10T428/249942—Fibers are aligned substantially parallel
- Y10T428/249945—Carbon or carbonaceous fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
- Y10T442/102—Woven scrim
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
- Y10T442/184—Nonwoven scrim
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/40—Knit fabric [i.e., knit strand or strip material]
- Y10T442/406—Including parallel strips
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Laminated Bodies (AREA)
- Reinforced Plastic Materials (AREA)
- Moulding By Coating Moulds (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
- Glass Compositions (AREA)
Abstract
1. Композитный материал, включающий слой волокон, объединенных с матрицей, в котором одна из составных частей, включающих матрицу и волокна, включает первый компонент, проявляющий ауксетическое поведение для нагрузки вдоль первого направления, а другая из составных частей, включающих матрицу и волокна, включает второй компонент, проявляющий неауксетическое поведение для нагрузки вдоль первого направления. ! 2. Композитный материал по п.1, в котором слой волокон включает первый компонент, а матрица включает второй компонент. ! 3. Композитный материал по п.1, в котором слой волокон включает второй компонент, а матрица включает первый компонент. ! 4. Композитный материал по любому из предшествующих пунктов, в котором слой волокон встроен в матрицу, частично встроен в матрицу или формирует отдельный слой в контакте с матрицей. ! 5. Композитный материал по п.1, в котором слой волокон включает однонаправленные волокна или текстильную, вязаную или нетканую сеть. ! 6. Композитный материал по п.5, в котором слой волокон включает однонаправленные волокна, причем первое направление, вдоль которого прилагается нагрузка для оценки ауксетического поведения, является параллельным направлению волокон. ! 7. Композитный материал по п.1, в котором коэффициенты теплового расширения композитного материала, измеренные параллельно и перпендикулярно первому направлению, по существу равны. ! 8. Композитный материал по п.1, в котором объемная доля второго компонента составляет между 60 и 70%. ! 9. Композитный материал по п.1, в котором объемная доля первого компонента составляет менее, чем 40%. ! 10. Композитный материал по п.1, в котором композитный �
Claims (17)
1. Композитный материал, включающий слой волокон, объединенных с матрицей, в котором одна из составных частей, включающих матрицу и волокна, включает первый компонент, проявляющий ауксетическое поведение для нагрузки вдоль первого направления, а другая из составных частей, включающих матрицу и волокна, включает второй компонент, проявляющий неауксетическое поведение для нагрузки вдоль первого направления.
2. Композитный материал по п.1, в котором слой волокон включает первый компонент, а матрица включает второй компонент.
3. Композитный материал по п.1, в котором слой волокон включает второй компонент, а матрица включает первый компонент.
4. Композитный материал по любому из предшествующих пунктов, в котором слой волокон встроен в матрицу, частично встроен в матрицу или формирует отдельный слой в контакте с матрицей.
5. Композитный материал по п.1, в котором слой волокон включает однонаправленные волокна или текстильную, вязаную или нетканую сеть.
6. Композитный материал по п.5, в котором слой волокон включает однонаправленные волокна, причем первое направление, вдоль которого прилагается нагрузка для оценки ауксетического поведения, является параллельным направлению волокон.
7. Композитный материал по п.1, в котором коэффициенты теплового расширения композитного материала, измеренные параллельно и перпендикулярно первому направлению, по существу равны.
8. Композитный материал по п.1, в котором объемная доля второго компонента составляет между 60 и 70%.
9. Композитный материал по п.1, в котором объемная доля первого компонента составляет менее, чем 40%.
10. Композитный материал по п.1, в котором композитный материал дополнительно включает матричный материал, проявляющий неауксетическое поведение для нагрузки вдоль первого направления.
11. Композитный материал по п.10, в котором объемная доля неауксетического матричного материала составляет менее, чем 40%.
12. Композитный материал по п.1, в котором ауксетический материал выбирается из ауксетических термопластических (сложные полиэфируретаны), термореактивных (силиконовый каучук) и металлических (медь) вспененных материалов, ауксетических термопластических микропористых полимерных цилиндров (полиэтилен со сверхвысокой молекулярной массой (ПЭСММ, UHMWPE), полипропилен (РР) и найлон), моноволокон (полипропилен (РР), найлон и сложный полиэфир) и пленок (полипропилен (РР)), полимеров природного происхождения (кристаллическая целлюлоза), композитных многослойных материалов (армированные углеродными волокнами эпоксидные смолы, армированные стекловолокном эпоксидные смолы и армированные арамидными волокнами эпоксидные смолы), определенных поликристаллических сверхпроводящих соединений на основе купрата висмута, 69% элементарных металлов с кубической решеткой, и встречающихся в природе полиморфных модификаций кристаллического оксида кремния (α-кристобалит и α-кварц).
13. Композитный материал по п.1, в котором матричный материал включает один или более полимерных материалов, выбираемых из термореактивных полимеров, термопластических полимеров или как термореактивных, так и термопластических полимеров.
14. Композитный материал по п.1, в котором матричный материал также включает один или более дополнительных компонентов, включающих любой материал из нижеследующих по отдельности или в комбинации: отвердитель, ускоритель, пигмент, пластификатор, огнезащитный состав и средство для повышения ударной вязкости.
15. Композитный материал, включающий слой волокон и неотвержденную матрицу, в соответствии с чем отверждение матрицы создает композит по п.1.
16. Композитный материал по п.15, в котором матрица пропитывает слой волокон во время отверждения.
17. Способ получения композитного материала по п.1, включающий стадии объединения слоя волокон с матрицей.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0610272.7 | 2006-05-24 | ||
| GB0610272A GB0610272D0 (en) | 2006-05-24 | 2006-05-24 | A composite material |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2011125685/04A Division RU2011125685A (ru) | 2006-05-24 | 2011-06-22 | Композитный материал |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2008143994A true RU2008143994A (ru) | 2010-05-10 |
| RU2430119C2 RU2430119C2 (ru) | 2011-09-27 |
Family
ID=36687617
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2008143994A RU2430119C2 (ru) | 2006-05-24 | 2007-05-24 | Композитный материал |
| RU2011125685/04A RU2011125685A (ru) | 2006-05-24 | 2011-06-22 | Композитный материал |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2011125685/04A RU2011125685A (ru) | 2006-05-24 | 2011-06-22 | Композитный материал |
Country Status (19)
| Country | Link |
|---|---|
| US (2) | US7989057B2 (ru) |
| EP (2) | EP1989249B1 (ru) |
| JP (1) | JP5108006B2 (ru) |
| KR (1) | KR20090024128A (ru) |
| CN (2) | CN101448877A (ru) |
| AT (1) | ATE447595T1 (ru) |
| AU (2) | AU2007253060B2 (ru) |
| BR (1) | BRPI0711828A2 (ru) |
| CA (1) | CA2652996C (ru) |
| DE (1) | DE602007003077D1 (ru) |
| DK (1) | DK1989249T3 (ru) |
| ES (1) | ES2340629T3 (ru) |
| GB (1) | GB0610272D0 (ru) |
| PL (1) | PL1989249T3 (ru) |
| PT (1) | PT1989249E (ru) |
| RU (2) | RU2430119C2 (ru) |
| SI (1) | SI1989249T1 (ru) |
| WO (1) | WO2007135447A1 (ru) |
| ZA (1) | ZA200809544B (ru) |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0610272D0 (en) * | 2006-05-24 | 2006-07-05 | Auxetic Technologies Ltd | A composite material |
| GB2451357B (en) * | 2008-09-04 | 2009-10-14 | Global Composites Group Ltd | Ceramic Armour |
| GB0818523D0 (en) * | 2008-10-09 | 2008-11-19 | Univ Exeter | Fibrous assembly |
| JP2010285049A (ja) * | 2009-06-11 | 2010-12-24 | Nsk Ltd | ステアリング装置 |
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| CA2652996C (en) | 2010-04-27 |
| JP2009537359A (ja) | 2009-10-29 |
| US20110064909A1 (en) | 2011-03-17 |
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| EP1989249A1 (en) | 2008-11-12 |
| PL1989249T3 (pl) | 2010-06-30 |
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| AU2008101138A4 (en) | 2009-01-08 |
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| RU2430119C2 (ru) | 2011-09-27 |
| BRPI0711828A2 (pt) | 2012-01-17 |
| ATE447595T1 (de) | 2009-11-15 |
| EP1989249B1 (en) | 2009-11-04 |
| CA2652996A1 (en) | 2007-11-29 |
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