RU2006106217A - Способ получения водорода из газа, содержащего метан, в частности, природного газа и установка для осуществления способа - Google Patents
Способ получения водорода из газа, содержащего метан, в частности, природного газа и установка для осуществления способа Download PDFInfo
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- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
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Claims (6)
1. Способ получения водорода из газа, содержащего метан, в частности, природного газа, при котором содержащиеся в газе углеводороды разлагаются в риформинг-печи (4) посредством водяного пара каталитическим путем на водород, оксид углерода и диоксид углерода, а на последующей конверсионной ступени с помощью водяного пара осуществляют каталитическую конверсию образовавшегося оксида углерода в диоксид углерода и водород, диоксид углерода удаляют посредством скруббера (7) из подвергнутого конверсии газового потока (8), и промытый, богатый водородом газовый поток (10) затем разделяют в адсорбционной установке (11) на состоящий из водорода поток (12) газового продукта и поток (13) отходящего газа, после чего поток (13) отходящего газа вместе с водородом (14), отводимым от газового потока (10) за скруббером (7), подают в качестве в значительной степени свободного от углерода горючего газа к риформинг-печи (4) и сжигают там.
2. Способ по п.1, отличающийся тем, что для конверсионной ступени используют работающий при средней температуре конверсионный реактор (5) или высокотемпературный конверсионный реактор (5') с подключенным к нему низкотемпературным конверсионным реактором (5").
3. Способ по п.1 или 2, отличающийся тем, что в скруббере (7) отделяют технически чистый диоксид углерода (18), который используют для технических целей или перерабатывают дальше в продукт (21) применяемого в пищевой промышленности качества.
4. Установка для осуществления способа получения водорода, содержащая, по меньшей мере, одну оборудованную камерой (3) сгорания риформинг-печь (4) для каталитического разложения газообразных углеводородов водяным паром, конверсионную ступень, по меньшей мере, с одним конверсионным реактором (5) для каталитической конверсии оксида углерода посредством водяного, пара в диоксид углерода и водород, скруббер (7) для отделения диоксида углерода от покидающего конверсионную ступень газового потока (8) и подключенную к нему адсорбционную установку (11) для извлечения водорода (12), к которой присоединен ведущий обратно к камере (3) сгорания газопровод (17) для обогревания риформера выходящим из адсорбционной установки газовым потоком, причем предусмотрено дополнительное устройство (19) для возврата части (14) покидающего скруббер (7) газового потока (10) в камеру (3) сгорания риформинг-печи (4).
5. Установка по п.4, отличающаяся тем, что конверсионная ступень включает в себя работающий при средней температуре конверсионный реактор (5) или высокотемпературный конверсионный реактор (5') с подключенным к нему низкотемпературным конверсионным реактором (5'').
6. Установка по п.4 или 5, отличающаяся тем, что к выходу скруббера (7) для диоксида углерода примыкает ступень (9) очистки для концентрации отделенного диоксида углерода (18).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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DE10334590.6 | 2003-07-28 | ||
DE10334590A DE10334590B4 (de) | 2003-07-28 | 2003-07-28 | Verfahren zur Gewinnung von Wasserstoff aus einem methanhaltigen Gas, insbesondere Erdgas und Anlage zur Durchführung des Verfahrens |
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RU2006106217A true RU2006106217A (ru) | 2006-07-10 |
RU2344069C2 RU2344069C2 (ru) | 2009-01-20 |
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RU2006106217/15A RU2344069C2 (ru) | 2003-07-28 | 2004-07-24 | Способ получения водорода из газа, содержащего метан, в частности природного газа, и установка для осуществления способа |
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US (2) | US7682597B2 (ru) |
EP (1) | EP1648817B1 (ru) |
JP (1) | JP4707665B2 (ru) |
CN (1) | CN100347077C (ru) |
AT (1) | ATE343545T1 (ru) |
CA (1) | CA2534210C (ru) |
DE (2) | DE10334590B4 (ru) |
DK (1) | DK1648817T3 (ru) |
ES (1) | ES2275235T3 (ru) |
HK (1) | HK1093335A1 (ru) |
NO (1) | NO337257B1 (ru) |
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WO (1) | WO2005012166A1 (ru) |
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EP2086875A2 (en) * | 2006-11-30 | 2009-08-12 | Shell Internationale Research Maatschappij B.V. | Systems and processes for producing hydrogen and carbon dioxide |
US20080181837A1 (en) * | 2007-01-29 | 2008-07-31 | Grover Bhadra S | Hydrogen, Carbon Monoxide, and N2 Recovery From Low BTU Gases |
CA2934541C (en) | 2008-03-28 | 2018-11-06 | Exxonmobil Upstream Research Company | Low emission power generation and hydrocarbon recovery systems and methods |
CA2718803C (en) | 2008-03-28 | 2016-07-12 | Exxonmobil Upstream Research Company | Low emission power generation and hydrocarbon recovery systems and methods |
US20100037521A1 (en) * | 2008-08-13 | 2010-02-18 | L'Air Liquide Societe Anonyme Pour L'Etude et l'Exploitatation Des Procedes Georges Claude | Novel Steam Reformer Based Hydrogen Plant Scheme for Enhanced Carbon Dioxide Recovery |
FR2936507B1 (fr) * | 2008-09-29 | 2011-04-08 | Inst Francais Du Petrole | Procede de production d'hydrogene avec captation totale du co2 et recyclage du methane non converti |
EP2172417A1 (en) * | 2008-10-02 | 2010-04-07 | Ammonia Casale S.A. | Process for the production of ammonia synthesis gas |
US9222671B2 (en) | 2008-10-14 | 2015-12-29 | Exxonmobil Upstream Research Company | Methods and systems for controlling the products of combustion |
AT507917B1 (de) * | 2009-03-02 | 2014-02-15 | Univ Wien Tech | Verfahren zur herstellung von kohlendioxid und wasserstoff |
US8137422B2 (en) * | 2009-06-03 | 2012-03-20 | Air Products And Chemicals, Inc. | Steam-hydrocarbon reforming with reduced carbon dioxide emissions |
TWI386365B (zh) * | 2009-07-24 | 2013-02-21 | Wei Hsin Chen | 富氫與純氫氣體製造之整合裝置與方法 |
EP2499332B1 (en) | 2009-11-12 | 2017-05-24 | Exxonmobil Upstream Research Company | Integrated system for power generation and method for low emission hydrocarbon recovery with power generation |
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CA2534210C (en) | 2012-09-11 |
RU2344069C2 (ru) | 2009-01-20 |
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ATE343545T1 (de) | 2006-11-15 |
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EP1648817A1 (de) | 2006-04-26 |
DE10334590A1 (de) | 2005-03-03 |
JP4707665B2 (ja) | 2011-06-22 |
CN1829656A (zh) | 2006-09-06 |
NO20060457L (no) | 2006-02-28 |
ES2275235T3 (es) | 2007-06-01 |
HK1093335A1 (en) | 2007-03-02 |
DE10334590B4 (de) | 2006-10-26 |
DE502004001866D1 (de) | 2006-12-07 |
US20100098601A1 (en) | 2010-04-22 |
CA2534210A1 (en) | 2005-02-10 |
NO337257B1 (no) | 2016-02-29 |
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