RU2004119410A - Катализатор, содержащий микропористый цеолит в мезопористом носителе, и способ его получения - Google Patents

Катализатор, содержащий микропористый цеолит в мезопористом носителе, и способ его получения Download PDF

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RU2004119410A
RU2004119410A RU2004119410/04A RU2004119410A RU2004119410A RU 2004119410 A RU2004119410 A RU 2004119410A RU 2004119410/04 A RU2004119410/04 A RU 2004119410/04A RU 2004119410 A RU2004119410 A RU 2004119410A RU 2004119410 A RU2004119410 A RU 2004119410A
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Russia
Prior art keywords
inorganic oxide
zeolite
mixture
temperature
material according
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RU2004119410/04A
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English (en)
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Чжипин ШАН (US)
Чжипин ШАН
Якобус Корнелис ЯНСЕН (NL)
Якобус Корнелис ЯНСЕН
Чуэнь И. ЙЕХ (US)
Чуэнь И. ЙЕХ
Йоханнес Хендрик КЕГЛЕР (DE)
Йоханнес Хендрик КЕГЛЕР
Томас МАШМЕЙЕР (NL)
Томас МАШМЕЙЕР
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Абб Ламмус Глобал Инк. (Us)
Абб Ламмус Глобал Инк.
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Publication of RU2004119410A publication Critical patent/RU2004119410A/ru

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Claims (31)

1. Материал, содержащий цеолит и пористый неорганический оксид, который включает, по меньшей мере, 97 об.% мезопор в расчете на микропоры и мезопоры неорганического оксида.
2. Материал по п.1, где цеолит представляет собой микропористый цеолит.
3. Материал по п.2, где микропористый цеолит выбран из группы, состоящей из бета-цеолита, цеолита Y и ZSM-5.
4. Материал по п.1, где пористый неорганический оксид содержит, по меньшей мере, 98 об.% мезопор.
5. Материал по п.1, где мезопоры имеют размер в диапазоне от около 2 нм до около 25 нм.
6. Материал по п.1, где пористый неорганический оксид представляет собой диоксид кремния.
7. Материал по п.1, где пористый неорганический оксид представляет собой оксид алюминия.
8. Материал по п.1, включающий атомы металла, выбранного из группы, состоящей из алюминия, титана, ванадия, циркония, галлия, марганца, цинка, хрома, молибдена, никеля, кобальта и железа.
9. Материал по п.1, где массовое процентное содержание цеолита в составе находится в диапазоне от около 5% до около 90%.
10. Материал по п.1, где массовое процентное содержание цеолита в составе находится в диапазоне от около 20% до около 80%.
11. Способ получения каталитического материала, включающий стадии:
a) объединения цеолита с водой, неорганическим оксидом или предшественником неорганического оксида и, по меньшей мере, одним образующим мезопоры органическим соединением, которое связывается с неорганическим оксидом или предшественником неорганического оксида за счет образования водородной связи с образованием смеси;
b) сушки смеси;
c) нагревания высушенной смеси до температуры и в течение периода времени, достаточных для образования мезопористой структуры оксида.
12. Способ по п.11, где образующее мезопоры органическое соединение выбрано из группы, состоящей из глицерина, диэтиленгликоля, триэтиленгликоля, тетраэтиленгликоля, пропиленгликоля, триэтаноламина, сульфолана, тетраэтиленпентамина и дибензоата диэтиленгликоля.
13. Способ по п.11, где образующее мезопоры органическое соединение имеет температуру кипения, по меньшей мере, около 150°С.
14. Способ по п.11, где неорганический оксид образован взаимодействием предшественника неорганического оксида с водой.
15. Способ по п.14, где предшественник неорганического оксида выбран из группы, состоящей из тетраэтилортосиликата и изопропоксида алюминия.
16. Способ по п.11, где смесь поддерживают при рН выше 7,0.
17. Способ по п.11, где соединение добавляют к смеси по каплям при перемешивании, и где смесь образует гель.
18. Способ по п.11, где смесь включает алканол.
19. Способ по п.11, где смесь сушат нагреванием в воздушной атмосфере при температуре и в течение периода времени, достаточных для отделения воды и летучих органических соединений.
20. Способ по п.11, где стадия нагревания (с) включает нагревание высушенной смеси до температуры от около 100°С до около 250°С.
21. Способ по п.11, где стадия нагревания (с) включает нагревание высушенного материала до температуры от около 150°С до около 200°С.
22. Способ по п.11, дополнительно включающий стадию прокаливания нагретой высушенной смеси при температуре от около 300°С до около 1000°С.
23. Способ по п.11, дополнительно включающий стадию прокаливания нагретой высушенной смеси при температуре от около 400°С до около 700°С в течение времени от около 2 ч до около 40 ч.
24. Способ по п.11, дополнительно включающий объединение ионов металла со смесью, при этом металл выбран из группы, состоящей из титана, ванадия, циркония, галлия, марганца, цинка, никеля, железа, кобальта, хрома и молибдена.
25. Способ по п.11, дополнительно включающий стадии смешивания связующего с каталитическим материалом и формования каталитического материала для придания заданной формы.
26. Способ обработки углеводородного сырья, включающий контактирование исходного сырья, содержащего, по меньшей мере, один углеводородный компонент, с каталитически эффективным количеством катализатора, который включает цеолит в пористом неорганическом оксиде, имеющем, по меньшей мере, 97 об.% мезопор в расчете на микропоры и мезопоры пористого неорганического оксида, при условиях реакции, достаточных для осуществления конверсии указанного углеводородного компонента.
27. Способ по п.26, где конверсию углеводородного компонента осуществляют посредством реакций гидрокрекинга, реакций гидроизомеризации, реакций депарафинизации или реакцией алкилирования.
28. Способ по п.26, где исходное сырье включает ароматическое соединение и олефин, и условия реакции являются достаточными для осуществления алкилирования ароматического соединения олефином.
29. Способ по п.28, где условия реакции включают температуру от около 90°С до около 250°С, давление от около 10 фунтов/дюйм2 до около 500 фунтов/дюйм2 и скорость подачи сырья от около 1 WHSV до около 20 WHSV.
30. Способ по п.26, где цеолит представляет собой микропористый цеолит.
31. Способ по п.30, где микропористый цеолит является бета-цеолитом.
RU2004119410/04A 2001-11-27 2002-11-18 Катализатор, содержащий микропористый цеолит в мезопористом носителе, и способ его получения RU2004119410A (ru)

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RU2490064C2 (ru) * 2009-04-22 2013-08-20 Басф Се Катализаторы и способ гидроаминирования олефинов
RU2499631C1 (ru) * 2010-03-31 2013-11-27 Юоп Ллк Алюмосиликатный цеолит uzm-37
RU2753868C2 (ru) * 2016-10-06 2021-08-24 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Алкилароматический катализатор конверсии

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