RU2003137530A - Дружественный к окружающей среде способ гидрирования динитрилов - Google Patents
Дружественный к окружающей среде способ гидрирования динитрилов Download PDFInfo
- Publication number
- RU2003137530A RU2003137530A RU2003137530/04A RU2003137530A RU2003137530A RU 2003137530 A RU2003137530 A RU 2003137530A RU 2003137530/04 A RU2003137530/04 A RU 2003137530/04A RU 2003137530 A RU2003137530 A RU 2003137530A RU 2003137530 A RU2003137530 A RU 2003137530A
- Authority
- RU
- Russia
- Prior art keywords
- quaternary ammonium
- hydroxide
- modifier
- dinitrile
- catalyst
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 19
- 238000005984 hydrogenation reaction Methods 0.000 title claims 2
- 230000007613 environmental effect Effects 0.000 title 1
- 125000001453 quaternary ammonium group Chemical group 0.000 claims 14
- 239000003607 modifier Substances 0.000 claims 11
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical group [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 claims 8
- 239000003054 catalyst Substances 0.000 claims 6
- 235000011114 ammonium hydroxide Nutrition 0.000 claims 5
- 150000001875 compounds Chemical class 0.000 claims 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 4
- 125000005219 aminonitrile group Chemical group 0.000 claims 4
- 150000004985 diamines Chemical class 0.000 claims 4
- VDZOOKBUILJEDG-UHFFFAOYSA-M tetrabutylammonium hydroxide Chemical compound [OH-].CCCC[N+](CCCC)(CCCC)CCCC VDZOOKBUILJEDG-UHFFFAOYSA-M 0.000 claims 4
- DJFBJKSMACBYBD-UHFFFAOYSA-N phosphane;hydrate Chemical group O.P DJFBJKSMACBYBD-UHFFFAOYSA-N 0.000 claims 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- 239000000908 ammonium hydroxide Substances 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 229910052759 nickel Inorganic materials 0.000 claims 2
- 239000011541 reaction mixture Substances 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 2
- DFQPZDGUFQJANM-UHFFFAOYSA-M tetrabutylphosphanium;hydroxide Chemical compound [OH-].CCCC[P+](CCCC)(CCCC)CCCC DFQPZDGUFQJANM-UHFFFAOYSA-M 0.000 claims 2
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 claims 2
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 claims 2
- LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 claims 2
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 239000012429 reaction media Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
- C07C209/48—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of nitriles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/871,102 | 2001-05-31 | ||
| US09/871,102 US6376714B1 (en) | 2001-05-31 | 2001-05-31 | Environmentally friendly process for the hydrogenation of dinitriles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2003137530A true RU2003137530A (ru) | 2005-04-20 |
Family
ID=25356731
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2003137530/04A RU2003137530A (ru) | 2001-05-31 | 2002-05-24 | Дружественный к окружающей среде способ гидрирования динитрилов |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US6376714B1 (https=) |
| EP (1) | EP1392646A2 (https=) |
| JP (1) | JP2004534778A (https=) |
| KR (1) | KR20040004667A (https=) |
| CN (1) | CN1531523A (https=) |
| BR (1) | BR0210082A (https=) |
| CA (1) | CA2444442A1 (https=) |
| MX (1) | MXPA03010927A (https=) |
| MY (1) | MY134178A (https=) |
| PL (1) | PL364602A1 (https=) |
| RU (1) | RU2003137530A (https=) |
| SK (1) | SK14492003A3 (https=) |
| TW (1) | TW593235B (https=) |
| WO (1) | WO2002096862A2 (https=) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6569802B1 (en) * | 1999-11-30 | 2003-05-27 | E. I. Du Pont De Nemours And Company | Catalyst for selective hydrogenation of dinitriles |
| WO2006062496A1 (en) * | 2004-12-07 | 2006-06-15 | Invista Technologies S.A R.L. | Use of modifiers in a dinitrile hydrogenation process at high pressures |
| US7132562B2 (en) | 2003-11-12 | 2006-11-07 | Invista North America S.A R.L. | Use of modifiers in a dinitrile hydrogenation process |
| DE10361071A1 (de) * | 2003-12-22 | 2005-07-14 | Basf Ag | Nitrilhydrierung in Gegenwart Ionischer Flüssigkeiten |
| DE102006061533A1 (de) * | 2006-12-27 | 2008-07-03 | Saltigo Gmbh | Verfahren zur Herstellung von 2-Aminomethylpiperidin |
| KR20130047693A (ko) | 2010-05-19 | 2013-05-08 | 바이오엠버, 에스.아.에스. | 디아미노부탄(ｄａｂ), 석신산 디니트릴(ｓｄｎ) 및 석신아미드(ｄａｍ)의 제조방법 |
| WO2011146556A1 (en) | 2010-05-19 | 2011-11-24 | Bioamber S.A.S. | Processes for producing diaminobutane (dab), succinic dinitrile (sdn) and succinamide (dam) |
| WO2011159564A1 (en) | 2010-06-16 | 2011-12-22 | Bioamber S.A.S. | Processes for producing hexamethylenediamine (hmd), adiponitrile (adn), adipamide (adm) and derivatives thereof |
| CN103108858A (zh) | 2010-06-16 | 2013-05-15 | 生物琥珀酸有限公司 | 己二胺（hmd）、己二腈（adn）、己二酰胺（adm）及其衍生物的制备方法 |
| WO2012158182A1 (en) | 2011-05-17 | 2012-11-22 | Bioamber S.A.S. | Processes for producing butanediol and diaminobutane from fermentation broths containing ammonium succinates |
| US9464030B2 (en) | 2011-05-18 | 2016-10-11 | Bioamber Inc. | Processes for producing butanediol (BDO), diaminobutane (DAB), succinic dinitrile (SDN) and succinamide (DAM) |
| WO2012170060A1 (en) | 2011-06-10 | 2012-12-13 | Bioamber S.A.S. | Processes for producing hexanediol (hdo), hexamethylenediamine (hmd), and derivatives thereof |
| WO2013149373A1 (zh) * | 2012-04-01 | 2013-10-10 | 烟台万华聚氨酯股份有限公司 | 一种n-(2-氨乙基)-1,2-乙二胺的制备方法 |
| WO2015038676A1 (en) | 2013-09-13 | 2015-03-19 | Invista Technologies S.À R.L. | Hydrogenation process for the preparation of diamine from dinitriles |
| WO2015038679A1 (en) | 2013-09-13 | 2015-03-19 | Invista Technologies S.A R.L. | Catalyst preparation and hydrogenation process |
| WO2015038675A1 (en) | 2013-09-13 | 2015-03-19 | Invista Technologies S.À R.L. | Hydrogenation process for making diamine from dinitrile |
| WO2015038678A1 (en) | 2013-09-13 | 2015-03-19 | Invista Technologies S.À R.L. | Hydrogenation of dinitriles for the preparation of diamines |
| CN105555752A (zh) | 2013-09-13 | 2016-05-04 | 因温斯特技术公司 | 使二腈氢化以便制备二胺 |
| CN106536476B (zh) | 2014-04-25 | 2018-11-13 | 英威达纺织（英国）有限公司 | 通过使二腈氢化来制备二胺 |
| WO2015200630A1 (en) | 2014-06-27 | 2015-12-30 | Invista North America S.A R.L. | Integrated process for nitrile manufacture with enhanced liquid-liquid extraction |
| EP3416940B1 (en) | 2016-02-16 | 2019-10-30 | INVISTA Textiles (U.K.) Limited | Promoter for selective nitrile hydrogenation |
| BR112022019032A2 (pt) * | 2020-03-25 | 2022-11-01 | Basf Se | Processo para a preparação de hexametilenodiamina |
| CN116535321A (zh) * | 2022-01-29 | 2023-08-04 | 北京旭阳科技有限公司 | 壬二腈加氢制备壬二胺的方法 |
| CN117603161B (zh) * | 2023-11-28 | 2026-04-07 | 万华化学集团股份有限公司 | 一种环己亚胺季铵碱、己二腈加氢制备己二胺的方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE700877A (https=) * | 1966-07-04 | 1967-12-18 | ||
| US3773832A (en) * | 1970-01-16 | 1973-11-20 | Du Pont | Hydrogenation of adiponitrile over alkali-modified cobalt catalyst |
| US4721811A (en) | 1985-08-26 | 1988-01-26 | W. R. Grace & Co. | Synthesis of aliphatic polyamines |
| US5900511A (en) | 1997-03-28 | 1999-05-04 | E. I. De Pont De Nemours And Company | Process for continuous hydrogenation of adiponitrile |
| CA2371403A1 (en) * | 1999-04-28 | 2000-11-02 | E.I. Du Pont De Nemours And Company | Aminonitrile production |
| US6309758B1 (en) | 1999-05-06 | 2001-10-30 | W. R. Grace & Co.-Conn. | Promoted porous catalyst |
-
2001
- 2001-05-31 US US09/871,102 patent/US6376714B1/en not_active Expired - Lifetime
-
2002
- 2002-05-17 TW TW091110365A patent/TW593235B/zh not_active IP Right Cessation
- 2002-05-24 KR KR20037015547A patent/KR20040004667A/ko not_active Withdrawn
- 2002-05-24 CA CA002444442A patent/CA2444442A1/en not_active Abandoned
- 2002-05-24 SK SK1449-2003A patent/SK14492003A3/sk not_active Application Discontinuation
- 2002-05-24 JP JP2003500042A patent/JP2004534778A/ja not_active Withdrawn
- 2002-05-24 WO PCT/US2002/016374 patent/WO2002096862A2/en not_active Ceased
- 2002-05-24 PL PL02364602A patent/PL364602A1/xx unknown
- 2002-05-24 MX MXPA03010927A patent/MXPA03010927A/es unknown
- 2002-05-24 EP EP02739372A patent/EP1392646A2/en not_active Withdrawn
- 2002-05-24 BR BR0210082-7A patent/BR0210082A/pt not_active IP Right Cessation
- 2002-05-24 RU RU2003137530/04A patent/RU2003137530A/ru not_active Application Discontinuation
- 2002-05-24 CN CNA028109155A patent/CN1531523A/zh active Pending
- 2002-05-28 MY MYPI20021949A patent/MY134178A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP1392646A2 (en) | 2004-03-03 |
| BR0210082A (pt) | 2004-08-17 |
| MY134178A (en) | 2007-11-30 |
| US6376714B1 (en) | 2002-04-23 |
| TW593235B (en) | 2004-06-21 |
| WO2002096862A2 (en) | 2002-12-05 |
| CN1531523A (zh) | 2004-09-22 |
| CA2444442A1 (en) | 2002-12-05 |
| PL364602A1 (en) | 2004-12-13 |
| KR20040004667A (ko) | 2004-01-13 |
| SK14492003A3 (sk) | 2005-03-04 |
| MXPA03010927A (es) | 2004-02-17 |
| WO2002096862A3 (en) | 2003-07-31 |
| JP2004534778A (ja) | 2004-11-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA92 | Acknowledgement of application withdrawn (lack of supplementary materials submitted) |
Effective date: 20060207 |