PL2396356T3 - Wodne systemy powlekające na bazie fizycznie wysychających uretanoakrylanów - Google Patents

Wodne systemy powlekające na bazie fizycznie wysychających uretanoakrylanów

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Publication number
PL2396356T3
PL2396356T3 PL10702610T PL10702610T PL2396356T3 PL 2396356 T3 PL2396356 T3 PL 2396356T3 PL 10702610 T PL10702610 T PL 10702610T PL 10702610 T PL10702610 T PL 10702610T PL 2396356 T3 PL2396356 T3 PL 2396356T3
Authority
PL
Poland
Prior art keywords
basis
aqueous coating
coating systems
urethane acrylates
physically drying
Prior art date
Application number
PL10702610T
Other languages
English (en)
Inventor
Stefan Sommer
Harald Blum
Jürgen Lippemeier
Miguel Fernandez
Original Assignee
Bayer Ip Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=42046116&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=PL2396356(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Bayer Ip Gmbh filed Critical Bayer Ip Gmbh
Publication of PL2396356T3 publication Critical patent/PL2396356T3/pl

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C08G18/4213—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from terephthalic acid and dialcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C08G18/4219—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from aromatic dicarboxylic acids and dialcohols in combination with polycarboxylic acids and/or polyhydroxy compounds which are at least trifunctional
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633—Compounds of group C08G18/42
    • C08G18/6659—Compounds of group C08G18/42 with compounds of group C08G18/34
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/721—Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
    • C08G18/724—Combination of aromatic polyisocyanates with (cyclo)aliphatic polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/758—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing two or more cycloaliphatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C08L75/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2170/00—Compositions for adhesives
    • C08G2170/80—Compositions for aqueous adhesives
PL10702610T 2009-02-13 2010-01-30 Wodne systemy powlekające na bazie fizycznie wysychających uretanoakrylanów PL2396356T3 (pl)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102009008950A DE102009008950A1 (de) 2009-02-13 2009-02-13 Wässrige Beschichtungssysteme auf Basis physikalisch trocknender Urethanacrylate
PCT/EP2010/000567 WO2010091797A1 (de) 2009-02-13 2010-01-30 Wässrige beschichtungssysteme auf basis physikalisch trocknender urethanacrylate
EP10702610.6A EP2396356B1 (de) 2009-02-13 2010-01-30 Wässrige beschichtungssysteme auf basis physikalisch trocknender urethanacrylate

Publications (1)

Publication Number Publication Date
PL2396356T3 true PL2396356T3 (pl) 2014-03-31

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PL10702610T PL2396356T3 (pl) 2009-02-13 2010-01-30 Wodne systemy powlekające na bazie fizycznie wysychających uretanoakrylanów

Country Status (16)

Country Link
US (1) US9034985B2 (pl)
EP (1) EP2396356B1 (pl)
JP (1) JP2012518043A (pl)
KR (1) KR20110126621A (pl)
CN (1) CN102414233B (pl)
BR (1) BRPI1008554A2 (pl)
CA (1) CA2752101C (pl)
DE (1) DE102009008950A1 (pl)
DK (1) DK2396356T3 (pl)
ES (1) ES2435802T3 (pl)
HR (1) HRP20131212T1 (pl)
PL (1) PL2396356T3 (pl)
RU (1) RU2011137471A (pl)
SI (1) SI2396356T1 (pl)
TW (1) TW201041984A (pl)
WO (1) WO2010091797A1 (pl)

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WO2012115984A2 (en) 2011-02-21 2012-08-30 Felice Kristopher M Polyurethane dispersions and methods of making and using same
EP2718383A4 (en) 2011-06-10 2015-05-20 Kristopher M Felice CLEAR VARNISH, ACRYLIC COATINGS
CN102659995A (zh) * 2012-04-24 2012-09-12 南昌航空大学 一种低表面能紫外光固化水性含氟涂料的制备方法
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WO2014063920A1 (de) * 2012-10-24 2014-05-01 Basf Se Strahlungshärtbare wasserdispergierbare polyurethan(meth)acrylate
US9011984B2 (en) * 2012-10-30 2015-04-21 Bayer Materialscience Llc Processes for coating substrates and substrates formed therefrom
CN103881054B (zh) * 2012-12-20 2016-04-20 江南大学 一种防雾涂料用uv固化树脂的制备方法
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CN103819646A (zh) * 2013-06-09 2014-05-28 江阴摩尔化工新材料有限公司 可紫外光固化的水性聚氨酯及其制备方法
JP6377447B2 (ja) * 2014-07-11 2018-08-22 ジャパンコーティングレジン株式会社 ポリウレタン及びウレタン−（メタ）アクリル複合樹脂
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EP3071661A1 (en) 2013-11-22 2016-09-28 Arkema France Solvent-free aqueous curable polyurethane dispersions and methods of producing solvent-free aqueous polyurethane dispersions
CN103666237A (zh) * 2013-12-06 2014-03-26 上海富臣化工有限公司 一种适用于橱柜的水性uv清面漆产品
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US20170049683A1 (en) * 2014-04-30 2017-02-23 Arkema France Nail polish composition based on solvent-free aqueous polyurethane dispersions
EP2980110A1 (en) * 2014-07-31 2016-02-03 ALLNEX AUSTRIA GmbH Aqueous polyurethane-vinyl polymer hybrid dispersions
CN107250193B (zh) * 2015-01-30 2021-03-12 惠普发展公司，有限责任合伙企业 基于聚氨酯的粘结剂分散体
KR102557281B1 (ko) * 2015-08-12 2023-07-18 쓰리엠 이노베이티브 프로퍼티즈 캄파니 내화학성 미소구체 물품
CN107922762B (zh) * 2015-10-28 2021-02-05 惠普发展公司，有限责任合伙企业 基于可辐射固化聚氨酯的粘合剂分散体
JP6859911B2 (ja) * 2016-10-07 2021-04-14 三菱ケミカル株式会社 コーティング剤、アンダーコート層付き基材フィルムおよび金属薄膜層付き積層フィルム
CN110248979B (zh) * 2017-02-08 2022-07-22 科思创(荷兰)有限公司 水性涂料组合物
CN106866929A (zh) * 2017-02-24 2017-06-20 中国林业科学研究院林产化学工业研究所 一种多官能度蓖麻油基光固化树脂及其制备方法和应用
CN110520498B (zh) 2017-02-28 2022-03-18 3M创新有限公司 具有耐化学品性的聚氨酯粘合剂
WO2019183323A1 (en) * 2018-03-23 2019-09-26 Covestro Llc One component polyurethane/allophanate formulations with reactive reducer
DE102018124332A1 (de) * 2018-10-02 2020-04-02 Ceracon Gmbh Zusammensetzung zur Herstellung wärmeaushärtender Polyurethanmassen
EP3924185B1 (de) * 2019-02-15 2023-01-25 Covestro Intellectual Property GmbH & Co. KG Neue systeme für die grundierung und das kleben von bodenbelägen
GB2582919B (en) * 2019-04-05 2022-07-13 Henkel IP & Holding GmbH Anaerobically curable compositions
CN110256625B (zh) * 2019-06-13 2020-09-25 华南理工大学 高固体含量含氟羟基聚丙烯酸酯水分散体及其制备方法与应用
CN112778487A (zh) * 2019-11-05 2021-05-11 万华化学集团股份有限公司 一种聚氨酯或聚氨酯-脲的水分散体及其制备方法和应用
CN111138614A (zh) * 2019-12-19 2020-05-12 合肥科天水性科技有限责任公司 一种用于低模量高强度超薄聚氨酯安全套的水性聚氨酯乳液及其制备方法
CN114181608A (zh) * 2021-12-14 2022-03-15 朱柏林 一种用于处理富含油脂的木材的紫外光固化封油剂
CN115521694A (zh) * 2022-11-01 2022-12-27 江南大学 一种制备氟改性水性uv固化的聚脲-氨酯涂料的方法
CN115948055B (zh) * 2022-12-23 2024-01-30 郑州圣莱特空心微珠新材料有限公司 一种低密度硅橡胶及其制备方法
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US20120041145A1 (en) 2012-02-16
CA2752101A1 (en) 2010-08-19
CN102414233A (zh) 2012-04-11
DK2396356T3 (da) 2014-01-13
WO2010091797A1 (de) 2010-08-19
EP2396356B1 (de) 2013-10-16
SI2396356T1 (sl) 2014-02-28
KR20110126621A (ko) 2011-11-23
CN102414233B (zh) 2014-05-07
DE102009008950A1 (de) 2010-08-19
HRP20131212T1 (hr) 2014-01-31
ES2435802T3 (es) 2013-12-23
RU2011137471A (ru) 2013-03-20
US9034985B2 (en) 2015-05-19
EP2396356A1 (de) 2011-12-21
JP2012518043A (ja) 2012-08-09
BRPI1008554A2 (pt) 2016-03-15
CA2752101C (en) 2018-07-17

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