NZ594955A - Enzyme-based self-polishing coating compositions - Google Patents

Info

Publication number

NZ594955A

NZ594955A NZ594955A NZ59495510A NZ594955A NZ 594955 A NZ594955 A NZ 594955A NZ 594955 A NZ594955 A NZ 594955A NZ 59495510 A NZ59495510 A NZ 59495510A NZ 594955 A NZ594955 A NZ 594955A

Authority

NZ

New Zealand

Prior art keywords

enzyme

polysaccharide

coating composition

acid

starch

Prior art date

2009-02-06

Links

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• Global Dossier
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• 102000004190 Enzymes Human genes 0.000 title claims abstract description 164
• 108090000790 Enzymes Proteins 0.000 title claims abstract description 164
• 239000008199 coating composition Substances 0.000 title claims abstract description 115
• 238000005498 polishing Methods 0.000 title claims abstract description 70
• 229920001282 polysaccharide Polymers 0.000 claims abstract description 113
• 239000005017 polysaccharide Substances 0.000 claims abstract description 113
• 239000011230 binding agent Substances 0.000 claims abstract description 107
• 239000000049 pigment Substances 0.000 claims abstract description 94
• 230000003301 hydrolyzing effect Effects 0.000 claims abstract description 12
• 150000004676 glycans Chemical class 0.000 claims abstract 20
• 229940088598 enzyme Drugs 0.000 claims description 161
• 229920002472 Starch Polymers 0.000 claims description 84
• 235000019698 starch Nutrition 0.000 claims description 83
• 239000008107 starch Substances 0.000 claims description 81
• 239000007787 solid Substances 0.000 claims description 75
• 108010073178 Glucan 1,4-alpha-Glucosidase Proteins 0.000 claims description 42
• 230000003373 anti-fouling effect Effects 0.000 claims description 42
• 102100022624 Glucoamylase Human genes 0.000 claims description 41
• 230000000694 effects Effects 0.000 claims description 29
• 238000000034 method Methods 0.000 claims description 26
• 239000002519 antifouling agent Substances 0.000 claims description 23
• 239000000470 constituent Substances 0.000 claims description 20
• 239000002904 solvent Substances 0.000 claims description 20
• 239000000945 filler Substances 0.000 claims description 18
• 239000000654 additive Substances 0.000 claims description 15
• 102000013142 Amylases Human genes 0.000 claims description 13
• 108010065511 Amylases Proteins 0.000 claims description 13
• 235000019418 amylase Nutrition 0.000 claims description 13
• 239000004382 Amylase Substances 0.000 claims description 12
• 239000003795 chemical substances by application Substances 0.000 claims description 11
• 229940025131 amylases Drugs 0.000 claims description 10
• 238000002360 preparation method Methods 0.000 claims description 8
• 239000000975 dye Substances 0.000 claims description 7
• 239000003973 paint Substances 0.000 description 126
• 150000004804 polysaccharides Chemical class 0.000 description 93
• -1 WO 97/00919) Chemical compound 0.000 description 86
• 239000000178 monomer Substances 0.000 description 62
• 238000000576 coating method Methods 0.000 description 56
• 239000011248 coating agent Substances 0.000 description 42
• 238000012360 testing method Methods 0.000 description 42
• NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 36
• 239000002253 acid Substances 0.000 description 34
• RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 32
• 229920001577 copolymer Polymers 0.000 description 29
• BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 27
• KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 26
• XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 26
• 229920005989 resin Polymers 0.000 description 26
• 239000011347 resin Substances 0.000 description 26
• KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 26
• 230000000052 comparative effect Effects 0.000 description 25
• 230000007062 hydrolysis Effects 0.000 description 23
• 238000006460 hydrolysis reaction Methods 0.000 description 23
• 239000000203 mixture Substances 0.000 description 23
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 23
• 239000000306 component Substances 0.000 description 22
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 19
• 229920002554 vinyl polymer Polymers 0.000 description 19
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 18
• WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 17
• 239000008103 glucose Substances 0.000 description 17
• 239000000463 material Substances 0.000 description 17
• 229910052751 metal Inorganic materials 0.000 description 17
• 239000002184 metal Substances 0.000 description 17
• 239000013535 sea water Substances 0.000 description 15
• 239000000758 substrate Substances 0.000 description 15
• 239000012876 carrier material Substances 0.000 description 14
• 150000001875 compounds Chemical class 0.000 description 14
• KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 14
• 229940112669 cuprous oxide Drugs 0.000 description 14
• 239000011787 zinc oxide Substances 0.000 description 13
• RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 12
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• 239000000843 powder Substances 0.000 description 11
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• 239000010949 copper Substances 0.000 description 10
• 229910052500 inorganic mineral Inorganic materials 0.000 description 10
• 239000011707 mineral Substances 0.000 description 10
• 125000004432 carbon atom Chemical group C* 0.000 description 9
• VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 9
• SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 8
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
• 240000008042 Zea mays Species 0.000 description 8
• 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 8
• 235000002017 Zea mays subsp mays Nutrition 0.000 description 8
• 235000005822 corn Nutrition 0.000 description 8
• 239000006185 dispersion Substances 0.000 description 8
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• 229910021485 fumed silica Inorganic materials 0.000 description 8
• 229920000642 polymer Polymers 0.000 description 8
• 150000003839 salts Chemical class 0.000 description 8
• 239000005995 Aluminium silicate Substances 0.000 description 7
• RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 7
• 244000024675 Eruca sativa Species 0.000 description 7
• 235000014755 Eruca sativa Nutrition 0.000 description 7
• VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical class OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 7
• NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
• 229920005822 acrylic binder Polymers 0.000 description 7
• 235000012211 aluminium silicate Nutrition 0.000 description 7
• 239000008358 core component Substances 0.000 description 7
• 150000002430 hydrocarbons Chemical class 0.000 description 7
• 238000007689 inspection Methods 0.000 description 7
• JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 7
• 239000002002 slurry Substances 0.000 description 7
• 239000004925 Acrylic resin Substances 0.000 description 6
• 229920000178 Acrylic resin Polymers 0.000 description 6
• 241001465754 Metazoa Species 0.000 description 6
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 6
• GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
• PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 6
• 229910000323 aluminium silicate Inorganic materials 0.000 description 6
• 239000003139 biocide Substances 0.000 description 6
• 238000001035 drying Methods 0.000 description 6
• 150000002148 esters Chemical class 0.000 description 6
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 6
• VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 6
• 150000002772 monosaccharides Chemical class 0.000 description 6
• 238000011020 pilot scale process Methods 0.000 description 6
• 239000003381 stabilizer Substances 0.000 description 6
• SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
• CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
• OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
• BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 5
• ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 description 5
• 239000001913 cellulose Substances 0.000 description 5
• 229920002678 cellulose Polymers 0.000 description 5
• 235000010980 cellulose Nutrition 0.000 description 5
• 229940047586 chemet Drugs 0.000 description 5
• QHNCWVQDOPICKC-UHFFFAOYSA-N copper;1-hydroxypyridine-2-thione Chemical compound [Cu].ON1C=CC=CC1=S.ON1C=CC=CC1=S QHNCWVQDOPICKC-UHFFFAOYSA-N 0.000 description 5
• XDUPUJNNHFTMQS-UHFFFAOYSA-N copper;1-oxidopyridine-2-thione Chemical compound [Cu+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S XDUPUJNNHFTMQS-UHFFFAOYSA-N 0.000 description 5
• 229910052739 hydrogen Inorganic materials 0.000 description 5
• 239000001257 hydrogen Substances 0.000 description 5
• 239000004615 ingredient Substances 0.000 description 5
• XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
• NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 5
• 229910052749 magnesium Inorganic materials 0.000 description 5
• 239000011777 magnesium Substances 0.000 description 5
• 239000011976 maleic acid Substances 0.000 description 5
• 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 5
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
• 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 5
• 239000000243 solution Substances 0.000 description 5
• 238000001694 spray drying Methods 0.000 description 5
• ACTRVOBWPAIOHC-XIXRPRMCSA-N succimer Chemical compound OC(=O)[C@@H](S)[C@@H](S)C(O)=O ACTRVOBWPAIOHC-XIXRPRMCSA-N 0.000 description 5
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• ZTOJFFHGPLIVKC-YAFCTCPESA-N (2e)-3-ethyl-2-[(z)-(3-ethyl-6-sulfo-1,3-benzothiazol-2-ylidene)hydrazinylidene]-1,3-benzothiazole-6-sulfonic acid Chemical compound S\1C2=CC(S(O)(=O)=O)=CC=C2N(CC)C/1=N/N=C1/SC2=CC(S(O)(=O)=O)=CC=C2N1CC ZTOJFFHGPLIVKC-YAFCTCPESA-N 0.000 description 4
• 229910002016 Aerosil® 200 Inorganic materials 0.000 description 4
• 239000004215 Carbon black (E152) Substances 0.000 description 4
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• LFQSCWFLJHTTHZ-UHFFFAOYSA-N EtOH Substances CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
• UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
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• 125000003118 aryl group Chemical group 0.000 description 4
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• GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 4
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• ZKIHLVYBGPFUAD-UHFFFAOYSA-N quinoline-2-sulfonic acid Chemical compound C1=CC=CC2=NC(S(=O)(=O)O)=CC=C21 ZKIHLVYBGPFUAD-UHFFFAOYSA-N 0.000 description 3
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