NO780528L - Fremgangsmaate ved klorering av etylenpolymere - Google Patents
Fremgangsmaate ved klorering av etylenpolymereInfo
- Publication number
- NO780528L NO780528L NO780528A NO780528A NO780528L NO 780528 L NO780528 L NO 780528L NO 780528 A NO780528 A NO 780528A NO 780528 A NO780528 A NO 780528A NO 780528 L NO780528 L NO 780528L
- Authority
- NO
- Norway
- Prior art keywords
- polyethylene
- chlorinated
- chlorination
- chlorine
- per
- Prior art date
Links
- 229920000573 polyethylene Polymers 0.000 title claims description 88
- 238000005660 chlorination reaction Methods 0.000 title claims description 68
- 238000000034 method Methods 0.000 title claims description 37
- 239000004698 Polyethylene Substances 0.000 claims description 69
- -1 polyethylene Polymers 0.000 claims description 66
- 238000002844 melting Methods 0.000 claims description 38
- 230000008018 melting Effects 0.000 claims description 38
- 239000000460 chlorine Substances 0.000 claims description 36
- 229910052801 chlorine Inorganic materials 0.000 claims description 36
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 35
- 239000004709 Chlorinated polyethylene Substances 0.000 claims description 23
- 238000009826 distribution Methods 0.000 claims description 18
- 239000002245 particle Substances 0.000 claims description 18
- 239000002904 solvent Substances 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 229910001868 water Inorganic materials 0.000 claims description 7
- 239000000155 melt Substances 0.000 claims description 5
- 239000000375 suspending agent Substances 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 4
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 239000000843 powder Substances 0.000 description 17
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 15
- 238000005245 sintering Methods 0.000 description 14
- 238000002845 discoloration Methods 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000004800 polyvinyl chloride Substances 0.000 description 7
- 229920000915 polyvinyl chloride Polymers 0.000 description 7
- 239000000725 suspension Substances 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000000605 extraction Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 5
- 239000005977 Ethylene Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 4
- 230000009477 glass transition Effects 0.000 description 4
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 4
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 4
- 238000013021 overheating Methods 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000000737 periodic effect Effects 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000012967 coordination catalyst Substances 0.000 description 2
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000000543 intermediate Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002902 organometallic compounds Chemical class 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZBBLRPRYYSJUCZ-GRHBHMESSA-L (z)-but-2-enedioate;dibutyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC ZBBLRPRYYSJUCZ-GRHBHMESSA-L 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 229910000809 Alumel Inorganic materials 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001804 chlorine Chemical class 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- SPTHWAJJMLCAQF-UHFFFAOYSA-M ctk4f8481 Chemical compound [O-]O.CC(C)C1=CC=CC=C1C(C)C SPTHWAJJMLCAQF-UHFFFAOYSA-M 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000006194 liquid suspension Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- 150000002835 noble gases Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 150000004978 peroxycarbonates Chemical class 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000005297 pyrex Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000005029 sieve analysis Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229920000638 styrene acrylonitrile Polymers 0.000 description 1
- 239000011145 styrene acrylonitrile resin Substances 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
- C08F8/22—Halogenation by reaction with free halogens
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL7701599A NL7701599A (nl) | 1977-02-16 | 1977-02-16 | Werkwijze voor het chloreren van etheen- polymeren. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO780528L true NO780528L (no) | 1978-08-17 |
Family
ID=19827982
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO780528A NO780528L (no) | 1977-02-16 | 1978-02-15 | Fremgangsmaate ved klorering av etylenpolymere |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US4197386A (fr) |
| JP (1) | JPS53101089A (fr) |
| AT (1) | AT363679B (fr) |
| BE (1) | BE863924A (fr) |
| BR (1) | BR7800912A (fr) |
| CA (1) | CA1098249A (fr) |
| DD (1) | DD134533A5 (fr) |
| DE (1) | DE2806653A1 (fr) |
| DK (1) | DK70478A (fr) |
| ES (1) | ES466900A1 (fr) |
| FR (1) | FR2381069A1 (fr) |
| GB (1) | GB1587801A (fr) |
| IL (1) | IL53969A (fr) |
| IN (1) | IN148047B (fr) |
| IT (1) | IT1102375B (fr) |
| NL (1) | NL7701599A (fr) |
| NO (1) | NO780528L (fr) |
| RO (1) | RO75138A (fr) |
| SE (1) | SE7801815L (fr) |
| SU (1) | SU786908A3 (fr) |
| ZA (1) | ZA78730B (fr) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0091973B1 (fr) * | 1982-04-15 | 1985-12-18 | Mitsui Petrochemical Industries, Ltd. | Caoutchoucs chlorés et compositions de polychlorure de vinyle renfermant ces caoutchoucs |
| JPS591512A (ja) * | 1982-06-25 | 1984-01-06 | Osaka Soda Co Ltd | 後塩素化エチレン共重合体の製法 |
| US4425206A (en) * | 1982-12-09 | 1984-01-10 | The Dow Chemical Company | Anhydrous process for preparing amorphous chlorinated polyethylene and product thereof |
| US4560731A (en) * | 1983-07-15 | 1985-12-24 | Union Carbide Corporation | Preparation of elastomeric, chlorosulfonated ethylene polymers |
| US4593075A (en) * | 1983-07-15 | 1986-06-03 | Union Carbide Corporation | Preparation of elastomeric, chlorinated ethylene polymers |
| JPS61113602A (ja) * | 1984-11-08 | 1986-05-31 | Mitsui Petrochem Ind Ltd | ハロゲン化変性エチレン系ランダム共重合体 |
| KR900001555B1 (ko) * | 1984-12-05 | 1990-03-15 | 더 다우 케미칼 캄파니 | 내응집성이 개선된 할로겐화 에틸렌 중합체 |
| JPS61209204A (ja) * | 1985-03-13 | 1986-09-17 | Nippon Oil Co Ltd | 塩素化された直鎖状超低密度ポリエチレンの製造方法 |
| CH663958A5 (de) | 1985-03-14 | 1988-01-29 | Dow Chemical Europ | Verfahren zum beschichten von kunststoffgegenstaenden. |
| US5068290A (en) * | 1989-05-06 | 1991-11-26 | Kang Hee Dong | Process for the chlorination of polyolefins |
| JPH0627131B2 (ja) * | 1989-12-27 | 1994-04-13 | 日本製紙株式会社 | 塩素化ポリオレフィンの製造方法 |
| US6124406A (en) | 1998-03-31 | 2000-09-26 | The B. F. Goodrich Company | Blocky chlorinated polyolefins, process for making and use as impact modifier compatibilizer for PVC or CPVC |
| US6277915B1 (en) | 1999-09-29 | 2001-08-21 | Pmd Holdings Corporation | Block chlorinated polyolefins for use as impact modifier enhancers for PVC or CPVC |
| US6630119B1 (en) | 2000-05-15 | 2003-10-07 | Yosohiro Sugie | Hydrogen gas generating method |
| KR101407776B1 (ko) | 2006-06-28 | 2014-06-17 | 다우 글로벌 테크놀로지스 엘엘씨 | 염소화 에틸렌-기재 중합체 및 그로부터 제조된 조성물 및 용품 |
| EP2816064B1 (fr) * | 2013-04-19 | 2018-12-26 | LG Chem, Ltd. | Polyéthylène à teneur en cire contrôlée, polyéthylène chloré correspondant, et produit moulé préparé à partir de celui-ci |
| KR101597421B1 (ko) | 2013-04-19 | 2016-02-24 | 주식회사 엘지화학 | 왁스 함량이 조절된 폴리에틸렌, 이의 염소화 폴리에틸렌 및 이로부터 제조된 성형품 |
| CN105294889B (zh) * | 2014-06-11 | 2017-12-19 | 中国石油化工股份有限公司 | 一种高刚性氯化聚乙烯树脂的制备方法 |
| JP2016061849A (ja) * | 2014-09-16 | 2016-04-25 | 住友ゴム工業株式会社 | 半導電性ローラ |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE552158A (fr) * | 1955-10-28 | |||
| DE1720295B2 (de) | 1967-08-29 | 1976-12-09 | Basf Ag, 6700 Ludwigshafen | Verfahren zum chlorieren von polyaethylen |
| DE1720293A1 (de) | 1967-08-29 | 1971-06-09 | Basf Ag | Verfahren zum Chlorieren von Polyaethylen |
| NL7504616A (nl) * | 1975-04-18 | 1976-10-20 | Stamicarbon | Nagechloreerde vinylchloridepolymeren. |
| US4029862A (en) * | 1975-06-25 | 1977-06-14 | The Dow Chemical Company | Olefin polymer chlorination products having improved handling properties and process for their preparation |
-
1977
- 1977-02-16 NL NL7701599A patent/NL7701599A/xx not_active Application Discontinuation
-
1978
- 1978-02-03 IL IL53969A patent/IL53969A/xx unknown
- 1978-02-03 GB GB4480/78A patent/GB1587801A/en not_active Expired
- 1978-02-07 ZA ZA00780730A patent/ZA78730B/xx unknown
- 1978-02-09 AT AT0090278A patent/AT363679B/de not_active IP Right Cessation
- 1978-02-11 ES ES466900A patent/ES466900A1/es not_active Expired
- 1978-02-14 DD DD203700A patent/DD134533A5/xx unknown
- 1978-02-14 FR FR7804087A patent/FR2381069A1/fr active Pending
- 1978-02-14 JP JP1585378A patent/JPS53101089A/ja active Pending
- 1978-02-14 BE BE185135A patent/BE863924A/xx not_active IP Right Cessation
- 1978-02-14 IT IT48043/78A patent/IT1102375B/it active
- 1978-02-15 SU SU782579204A patent/SU786908A3/ru active
- 1978-02-15 CA CA296,889A patent/CA1098249A/fr not_active Expired
- 1978-02-15 BR BR7800912A patent/BR7800912A/pt unknown
- 1978-02-15 NO NO780528A patent/NO780528L/no unknown
- 1978-02-15 RO RO7893214A patent/RO75138A/fr unknown
- 1978-02-16 DE DE19782806653 patent/DE2806653A1/de not_active Withdrawn
- 1978-02-16 DK DK70478A patent/DK70478A/da not_active Application Discontinuation
- 1978-02-16 SE SE7801815A patent/SE7801815L/xx unknown
- 1978-02-16 US US05/878,450 patent/US4197386A/en not_active Expired - Lifetime
- 1978-02-20 IN IN137/DEL/78A patent/IN148047B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GB1587801A (en) | 1981-04-08 |
| IN148047B (fr) | 1980-10-04 |
| SE7801815L (sv) | 1978-08-17 |
| US4197386A (en) | 1980-04-08 |
| ATA90278A (de) | 1981-01-15 |
| JPS53101089A (en) | 1978-09-04 |
| DD134533A5 (de) | 1979-03-07 |
| RO75138A (fr) | 1980-11-30 |
| DE2806653A1 (de) | 1978-08-17 |
| FR2381069A1 (fr) | 1978-09-15 |
| ZA78730B (en) | 1979-01-31 |
| ES466900A1 (es) | 1978-10-01 |
| NL7701599A (nl) | 1978-08-18 |
| BE863924A (nl) | 1978-08-14 |
| BR7800912A (pt) | 1978-10-10 |
| IL53969A (en) | 1981-10-30 |
| DK70478A (da) | 1978-08-17 |
| IT7848043A0 (it) | 1978-02-14 |
| CA1098249A (fr) | 1981-03-24 |
| SU786908A3 (ru) | 1980-12-07 |
| IT1102375B (it) | 1985-10-07 |
| AT363679B (de) | 1981-08-25 |
| IL53969A0 (en) | 1978-04-30 |
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