NO773639L - Fremgangsmaate ved elektrolyse av opploesninger av alkali-metallhalogenider - Google Patents
Fremgangsmaate ved elektrolyse av opploesninger av alkali-metallhalogeniderInfo
- Publication number
- NO773639L NO773639L NO773639A NO773639A NO773639L NO 773639 L NO773639 L NO 773639L NO 773639 A NO773639 A NO 773639A NO 773639 A NO773639 A NO 773639A NO 773639 L NO773639 L NO 773639L
- Authority
- NO
- Norway
- Prior art keywords
- nickel
- cell
- salt solution
- diaphragm
- added
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 27
- 229910052783 alkali metal Inorganic materials 0.000 title description 2
- 150000001340 alkali metals Chemical class 0.000 title 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 83
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 71
- 229910052759 nickel Inorganic materials 0.000 claims description 38
- 239000012266 salt solution Substances 0.000 claims description 38
- 150000002816 nickel compounds Chemical class 0.000 claims description 30
- 238000005868 electrolysis reaction Methods 0.000 claims description 19
- -1 hydroxyl ions Chemical class 0.000 claims description 18
- 230000015572 biosynthetic process Effects 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 15
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 10
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 claims description 9
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 8
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims description 6
- 229910001508 alkali metal halide Inorganic materials 0.000 claims description 6
- 150000008045 alkali metal halides Chemical class 0.000 claims description 6
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 6
- 239000011780 sodium chloride Substances 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 4
- 238000011109 contamination Methods 0.000 claims description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical class Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 19
- 238000011282 treatment Methods 0.000 description 18
- 239000000460 chlorine Substances 0.000 description 16
- 229910052801 chlorine Inorganic materials 0.000 description 16
- 238000007792 addition Methods 0.000 description 14
- 239000003518 caustics Substances 0.000 description 14
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 11
- 239000003513 alkali Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 235000002639 sodium chloride Nutrition 0.000 description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 239000010425 asbestos Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052895 riebeckite Inorganic materials 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 150000002815 nickel Chemical class 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 description 1
- YZCKVEUIGOORGS-UHFFFAOYSA-N Hydrogen atom Chemical compound [H] YZCKVEUIGOORGS-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229910021543 Nickel dioxide Inorganic materials 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910001514 alkali metal chloride Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 150000001804 chlorine Chemical class 0.000 description 1
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- ZLCCLBKPLLUIJC-UHFFFAOYSA-L disodium tetrasulfane-1,4-diide Chemical compound [Na+].[Na+].[S-]SS[S-] ZLCCLBKPLLUIJC-UHFFFAOYSA-L 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Inorganic materials [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
- C25B1/46—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in diaphragm cells
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/760,910 US4055476A (en) | 1977-01-21 | 1977-01-21 | Method for lowering chlorate content of alkali metal hydroxides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO773639L true NO773639L (no) | 1978-07-24 |
Family
ID=25060543
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO773639A NO773639L (no) | 1977-01-21 | 1977-10-27 | Fremgangsmaate ved elektrolyse av opploesninger av alkali-metallhalogenider |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US4055476A (it) |
| JP (1) | JPS5391098A (it) |
| AR (1) | AR216491A1 (it) |
| AU (1) | AU510228B2 (it) |
| BE (1) | BE863105A (it) |
| BR (1) | BR7800048A (it) |
| CA (1) | CA1092545A (it) |
| DD (1) | DD134784A5 (it) |
| DE (1) | DE2802264C3 (it) |
| FR (1) | FR2378105A1 (it) |
| GB (1) | GB1541336A (it) |
| IL (1) | IL53121A0 (it) |
| IT (1) | IT1091111B (it) |
| NL (1) | NL7711553A (it) |
| NO (1) | NO773639L (it) |
| PH (1) | PH15426A (it) |
| PL (1) | PL108934B1 (it) |
| SE (1) | SE7800711L (it) |
| SU (1) | SU660597A3 (it) |
| ZA (1) | ZA776326B (it) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4481088A (en) * | 1982-07-06 | 1984-11-06 | Olin Corporation | Removal of chlorate from electrolyte cell brine |
| JPS6077982A (ja) * | 1983-10-04 | 1985-05-02 | Kanegafuchi Chem Ind Co Ltd | 塩素酸塩抑制法 |
| US4595468A (en) * | 1984-07-19 | 1986-06-17 | Eltech Systems Corporation | Cathode for electrolysis cell |
| JPS6286187A (ja) * | 1985-10-09 | 1987-04-20 | Asahi Chem Ind Co Ltd | 水素発生用の電極 |
| DE3707713A1 (de) * | 1987-03-11 | 1988-09-22 | Basf Ag | Verfahren zur entfernung von chlorat aus natronlauge |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2823177A (en) * | 1954-01-13 | 1958-02-11 | Hooker Electrochemical Co | Method and apparatus for lowering the chlorate content of alkali metal hydroxides |
| BE795460A (fr) * | 1972-02-16 | 1973-08-16 | Diamond Shamrock Corp | Perfectionnements relatifs a des cuves electrolytiques |
| DE2624202A1 (de) * | 1975-06-02 | 1976-12-23 | Goodrich Co B F | Elektrolyseverfahren zur herstellung von chlor an der anode und von aetzalkali an der kathode |
-
1977
- 1977-01-21 US US05/760,910 patent/US4055476A/en not_active Expired - Lifetime
- 1977-10-13 IL IL53121A patent/IL53121A0/xx unknown
- 1977-10-20 CA CA289,161A patent/CA1092545A/en not_active Expired
- 1977-10-20 NL NL7711553A patent/NL7711553A/xx not_active Application Discontinuation
- 1977-10-21 IT IT51522/77A patent/IT1091111B/it active
- 1977-10-24 ZA ZA00776326A patent/ZA776326B/xx unknown
- 1977-10-27 NO NO773639A patent/NO773639L/no unknown
- 1977-10-28 AR AR269766A patent/AR216491A1/es active
- 1977-12-12 JP JP14916677A patent/JPS5391098A/ja active Granted
- 1977-12-15 SU SU772555249A patent/SU660597A3/ru active
- 1977-12-28 GB GB54038/77A patent/GB1541336A/en not_active Expired
-
1978
- 1978-01-04 BR BR7800048A patent/BR7800048A/pt unknown
- 1978-01-11 PH PH20645A patent/PH15426A/en unknown
- 1978-01-12 PL PL1978203948A patent/PL108934B1/pl unknown
- 1978-01-19 DE DE2802264A patent/DE2802264C3/de not_active Expired
- 1978-01-20 FR FR7801715A patent/FR2378105A1/fr active Granted
- 1978-01-20 DD DD78203330A patent/DD134784A5/xx unknown
- 1978-01-20 SE SE7800711A patent/SE7800711L/xx unknown
- 1978-01-20 BE BE184467A patent/BE863105A/xx unknown
- 1978-01-23 AU AU32627/78A patent/AU510228B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| ZA776326B (en) | 1978-11-29 |
| DE2802264A1 (de) | 1978-07-27 |
| BR7800048A (pt) | 1978-10-03 |
| DE2802264B2 (de) | 1979-07-19 |
| GB1541336A (en) | 1979-02-28 |
| BE863105A (fr) | 1978-07-20 |
| DD134784A5 (de) | 1979-03-21 |
| PH15426A (en) | 1983-01-18 |
| AU3262778A (en) | 1979-08-09 |
| SU660597A3 (ru) | 1979-04-30 |
| DE2802264C3 (de) | 1982-01-21 |
| FR2378105B1 (it) | 1980-08-22 |
| CA1092545A (en) | 1980-12-30 |
| PL203948A1 (pl) | 1978-07-31 |
| AU510228B2 (en) | 1980-06-12 |
| IT1091111B (it) | 1985-06-26 |
| US4055476A (en) | 1977-10-25 |
| JPS5391098A (en) | 1978-08-10 |
| JPS5511750B2 (it) | 1980-03-27 |
| AR216491A1 (es) | 1979-12-28 |
| IL53121A0 (en) | 1977-12-30 |
| FR2378105A1 (fr) | 1978-08-18 |
| PL108934B1 (en) | 1980-05-31 |
| NL7711553A (nl) | 1978-07-25 |
| SE7800711L (sv) | 1978-07-22 |
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