NO343675B1 - Fremgangsmåter for fremstilling av cesiumsalt - Google Patents
Fremgangsmåter for fremstilling av cesiumsalt Download PDFInfo
- Publication number
- NO343675B1 NO343675B1 NO20034392A NO20034392A NO343675B1 NO 343675 B1 NO343675 B1 NO 343675B1 NO 20034392 A NO20034392 A NO 20034392A NO 20034392 A NO20034392 A NO 20034392A NO 343675 B1 NO343675 B1 NO 343675B1
- Authority
- NO
- Norway
- Prior art keywords
- cesium
- solution
- acid
- hydroxide
- sulfate
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 52
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical class [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 title claims description 51
- 238000002360 preparation method Methods 0.000 title description 2
- FLJPGEWQYJVDPF-UHFFFAOYSA-L caesium sulfate Chemical compound [Cs+].[Cs+].[O-]S([O-])(=O)=O FLJPGEWQYJVDPF-UHFFFAOYSA-L 0.000 claims description 136
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 76
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Inorganic materials [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 claims description 58
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 43
- 238000006243 chemical reaction Methods 0.000 claims description 41
- MFGOFGRYDNHJTA-UHFFFAOYSA-N 2-amino-1-(2-fluorophenyl)ethanol Chemical compound NCC(O)C1=CC=CC=C1F MFGOFGRYDNHJTA-UHFFFAOYSA-N 0.000 claims description 40
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical group [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 39
- 239000000920 calcium hydroxide Substances 0.000 claims description 39
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 39
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 39
- 235000019253 formic acid Nutrition 0.000 claims description 39
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 37
- 239000012535 impurity Substances 0.000 claims description 29
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 27
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 27
- 239000004571 lime Substances 0.000 claims description 27
- 239000002253 acid Substances 0.000 claims description 20
- 229910052792 caesium Inorganic materials 0.000 claims description 19
- 159000000006 cesium salts Chemical class 0.000 claims description 14
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 8
- ATZQZZAXOPPAAQ-UHFFFAOYSA-M caesium formate Chemical compound [Cs+].[O-]C=O ATZQZZAXOPPAAQ-UHFFFAOYSA-M 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 5
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims description 4
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical group [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000292 calcium oxide Substances 0.000 claims description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 4
- 239000001569 carbon dioxide Substances 0.000 claims description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 3
- 239000000347 magnesium hydroxide Substances 0.000 claims description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- QFWPJPIVLCBXFJ-UHFFFAOYSA-N glymidine Chemical compound N1=CC(OCCOC)=CN=C1NS(=O)(=O)C1=CC=CC=C1 QFWPJPIVLCBXFJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 235000019260 propionic acid Nutrition 0.000 claims description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 2
- 229910052701 rubidium Inorganic materials 0.000 claims description 2
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 2
- 229960004889 salicylic acid Drugs 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 description 121
- 239000000706 filtrate Substances 0.000 description 49
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 48
- 238000006386 neutralization reaction Methods 0.000 description 33
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 28
- 239000002244 precipitate Substances 0.000 description 26
- 229910000019 calcium carbonate Inorganic materials 0.000 description 24
- 239000003513 alkali Substances 0.000 description 22
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 22
- 235000011132 calcium sulphate Nutrition 0.000 description 17
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 16
- 229940044170 formate Drugs 0.000 description 16
- 238000001914 filtration Methods 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 15
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 14
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 13
- 239000011575 calcium Substances 0.000 description 13
- 229910052791 calcium Inorganic materials 0.000 description 13
- 239000002002 slurry Substances 0.000 description 12
- 229910000027 potassium carbonate Inorganic materials 0.000 description 11
- 239000013078 crystal Substances 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 229910052925 anhydrite Inorganic materials 0.000 description 8
- 239000007787 solid Substances 0.000 description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 239000001175 calcium sulphate Substances 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 229910052716 thallium Inorganic materials 0.000 description 5
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229910052788 barium Inorganic materials 0.000 description 4
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 229910052796 boron Inorganic materials 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 4
- 229910021653 sulphate ion Inorganic materials 0.000 description 4
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 150000001553 barium compounds Chemical class 0.000 description 3
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 3
- 229910001863 barium hydroxide Inorganic materials 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- -1 cesium formate Chemical class 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 239000012066 reaction slurry Substances 0.000 description 3
- 229910052712 strontium Inorganic materials 0.000 description 3
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 3
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- VHUJINUACVEASK-UHFFFAOYSA-J aluminum;cesium;disulfate;dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Al+3].[Cs+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O VHUJINUACVEASK-UHFFFAOYSA-J 0.000 description 2
- ZOAIGCHJWKDIPJ-UHFFFAOYSA-M caesium acetate Chemical compound [Cs+].CC([O-])=O ZOAIGCHJWKDIPJ-UHFFFAOYSA-M 0.000 description 2
- NLSCHDZTHVNDCP-UHFFFAOYSA-N caesium nitrate Chemical compound [Cs+].[O-][N+]([O-])=O NLSCHDZTHVNDCP-UHFFFAOYSA-N 0.000 description 2
- 239000004281 calcium formate Substances 0.000 description 2
- 229940044172 calcium formate Drugs 0.000 description 2
- 235000019255 calcium formate Nutrition 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 235000012254 magnesium hydroxide Nutrition 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- YRAMACNQEYDINL-UHFFFAOYSA-J aluminum;cesium;disulfate Chemical compound [Al+3].[Cs+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O YRAMACNQEYDINL-UHFFFAOYSA-J 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 159000000009 barium salts Chemical class 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 description 1
- LYQFWZFBNBDLEO-UHFFFAOYSA-M caesium bromide Chemical compound [Br-].[Cs+] LYQFWZFBNBDLEO-UHFFFAOYSA-M 0.000 description 1
- FJDQFPXHSGXQBY-UHFFFAOYSA-L caesium carbonate Chemical compound [Cs+].[Cs+].[O-]C([O-])=O FJDQFPXHSGXQBY-UHFFFAOYSA-L 0.000 description 1
- 229910000024 caesium carbonate Inorganic materials 0.000 description 1
- AIYUHDOJVYHVIT-UHFFFAOYSA-M caesium chloride Chemical compound [Cl-].[Cs+] AIYUHDOJVYHVIT-UHFFFAOYSA-M 0.000 description 1
- XQPRBTXUXXVTKB-UHFFFAOYSA-M caesium iodide Chemical compound [I-].[Cs+] XQPRBTXUXXVTKB-UHFFFAOYSA-M 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- WBXAXPXIMFTJLQ-UHFFFAOYSA-M cesium;2-hydroxybenzoate Chemical compound [Cs+].OC1=CC=CC=C1C([O-])=O WBXAXPXIMFTJLQ-UHFFFAOYSA-M 0.000 description 1
- JARYTYXPZYEALC-UHFFFAOYSA-M cesium;butanoate Chemical class [Cs+].CCCC([O-])=O JARYTYXPZYEALC-UHFFFAOYSA-M 0.000 description 1
- YBZSHUAKOJGWRT-UHFFFAOYSA-M cesium;propanoate Chemical compound [Cs+].CCC([O-])=O YBZSHUAKOJGWRT-UHFFFAOYSA-M 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- HEQUOWMMDQTGCX-UHFFFAOYSA-L dicesium;oxalate Chemical compound [Cs+].[Cs+].[O-]C(=O)C([O-])=O HEQUOWMMDQTGCX-UHFFFAOYSA-L 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 150000004675 formic acid derivatives Chemical class 0.000 description 1
- 238000005816 glass manufacturing process Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- ZLDHYRXZZNDOKU-UHFFFAOYSA-N n,n-diethyl-3-trimethoxysilylpropan-1-amine Chemical compound CCN(CC)CCC[Si](OC)(OC)OC ZLDHYRXZZNDOKU-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229910001744 pollucite Inorganic materials 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- WDNRWJRRUZRRNB-UHFFFAOYSA-K tricesium;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Cs+].[Cs+].[Cs+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O WDNRWJRRUZRRNB-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D9/00—Nitrates of sodium, potassium or alkali metals in general
- C01D9/04—Preparation with liquid nitric acid
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D1/00—Oxides or hydroxides of sodium, potassium or alkali metals in general
- C01D1/04—Hydroxides
- C01D1/20—Preparation by reacting oxides or hydroxides with alkali metal salts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D17/00—Rubidium, caesium or francium compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D3/00—Halides of sodium, potassium or alkali metals in general
- C01D3/04—Chlorides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D3/00—Halides of sodium, potassium or alkali metals in general
- C01D3/10—Bromides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D3/00—Halides of sodium, potassium or alkali metals in general
- C01D3/12—Iodides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
- C01D5/16—Purification
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/46—Sulfates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Agronomy & Crop Science (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Treating Waste Gases (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/824,623 US6652820B2 (en) | 2001-04-02 | 2001-04-02 | Methods of making cesium salts and other alkali metal salts |
| PCT/US2002/010063 WO2002079089A1 (en) | 2001-04-02 | 2002-03-29 | Methods of making cesium salts and other alkali metal salts |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO20034392D0 NO20034392D0 (no) | 2003-10-01 |
| NO20034392L NO20034392L (no) | 2003-12-01 |
| NO343675B1 true NO343675B1 (no) | 2019-05-06 |
Family
ID=25241882
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO20034392A NO343675B1 (no) | 2001-04-02 | 2003-10-01 | Fremgangsmåter for fremstilling av cesiumsalt |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6652820B2 (enExample) |
| EP (1) | EP1373141B1 (enExample) |
| JP (1) | JP4541644B2 (enExample) |
| CN (1) | CN1512966B (enExample) |
| CA (1) | CA2443174C (enExample) |
| NO (1) | NO343675B1 (enExample) |
| WO (1) | WO2002079089A1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5424562B2 (ja) * | 2005-01-27 | 2014-02-26 | ヒェメタル ゲゼルシャフト ミット ベシュレンクテル ハフツング | 水酸化セシウム溶液の製造法 |
| US7759273B2 (en) * | 2005-04-20 | 2010-07-20 | Cabot Corporation | Methods of forming an alkali metal salt |
| US7198322B2 (en) * | 2005-04-20 | 2007-04-03 | Marco Savo | Spoiler and method of using the same |
| EP2075066B1 (en) | 2007-12-10 | 2016-08-17 | Honeywell International Inc. | Method for making catalyst compositions of alkali metal halide-doped bivalent metal fluorides and a process for making fluorinated olefins |
| US11473032B2 (en) | 2010-02-02 | 2022-10-18 | Fuchs Petrolub Se | Constant velocity joint having a boot |
| CN101774613B (zh) * | 2010-02-04 | 2011-11-30 | 江西东鹏新材料有限责任公司 | 以铯榴石生产碳酸铯的新工艺 |
| US9458524B2 (en) | 2013-03-05 | 2016-10-04 | Cabot Corporation | Methods to recover cesium or rubidium from secondary ore |
| CA3059637C (en) * | 2013-12-03 | 2020-07-07 | Cabot Corporation | Methods to recover cesium formate from a mixed alkali metal formate blend |
| US20160130682A1 (en) | 2014-11-12 | 2016-05-12 | Cabot Corporation | Methods For Recovering Cesium Or Rubidium Values From Ore Or Other Materials |
| AR107476A1 (es) | 2016-01-29 | 2018-05-02 | Cascadero Copper Corp | Proceso de recuperación de cesio de depósitos minerales epitérmicos |
| CN105540621B (zh) * | 2016-03-16 | 2017-05-03 | 江西东鹏新材料有限责任公司 | 一种生产氟化铯的方法 |
| CN112759512A (zh) * | 2020-12-31 | 2021-05-07 | 江西赣锋循环科技有限公司 | 一种生产高纯度甲酸铯的方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3207571A (en) * | 1962-04-09 | 1965-09-21 | San Antonio Chemicals Inc | Process for preparing cesium compounds from cesium alum |
| DE3801382A1 (de) * | 1988-01-19 | 1989-08-03 | Ebner Anlagen & Apparate | Verfahren und anlage zur umwandlung von natriumsulfat in natriumhydroxid |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2383247A (en) * | 1942-06-05 | 1945-08-21 | Gardner Daniel | Treatment of certain sodium-sulphur compounds to produce certain soluble nonsulphur compounds of sodium |
| US3489509A (en) | 1967-05-18 | 1970-01-13 | Kewanee Oil Co | Process for recovery of cesium compounds of high purity |
| JPS5333998A (en) * | 1976-08-18 | 1978-03-30 | Nippon Mining Co Ltd | Forming method for hydroxides of alkaline metals |
| US4597955A (en) | 1985-05-01 | 1986-07-01 | Carus Corporation | Process for recovering cesium from cesium ore |
| JPH0696330B2 (ja) * | 1986-05-20 | 1994-11-30 | 凸版印刷株式会社 | 表裏で光学特性が異なる透視材の製造方法 |
| US5034094A (en) * | 1987-11-06 | 1991-07-23 | Kurple Kenneth R | Method of converting inorganic materials from kraft pulping liquor into pulping chemicals without passing them through a recovery furnace |
| DE4313480C1 (de) | 1993-04-24 | 1994-04-14 | Metallgesellschaft Ag | Verfahren zur Herstellung von Cäsiumsalzen aus Cäsium-Aluminium-Alaun |
| US6015535A (en) | 1995-04-06 | 2000-01-18 | Cabot Corporation | Process for producing purified cesium compound from cesium alum |
| CN1295295C (zh) * | 1995-04-06 | 2007-01-17 | 卡伯特公司 | 钻井流体 |
| NO300038B1 (no) * | 1995-05-12 | 1997-03-24 | Norsk Hydro As | Fremgangsmåte for fremstilling av produkter inneholdende dobbelsalter av maursyre |
-
2001
- 2001-04-02 US US09/824,623 patent/US6652820B2/en not_active Expired - Lifetime
-
2002
- 2002-03-29 JP JP2002577725A patent/JP4541644B2/ja not_active Expired - Fee Related
- 2002-03-29 EP EP02719401.8A patent/EP1373141B1/en not_active Expired - Lifetime
- 2002-03-29 CN CN02811012.9A patent/CN1512966B/zh not_active Expired - Fee Related
- 2002-03-29 WO PCT/US2002/010063 patent/WO2002079089A1/en not_active Ceased
- 2002-03-29 CA CA2443174A patent/CA2443174C/en not_active Expired - Fee Related
-
2003
- 2003-10-01 NO NO20034392A patent/NO343675B1/no not_active IP Right Cessation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3207571A (en) * | 1962-04-09 | 1965-09-21 | San Antonio Chemicals Inc | Process for preparing cesium compounds from cesium alum |
| DE3801382A1 (de) * | 1988-01-19 | 1989-08-03 | Ebner Anlagen & Apparate | Verfahren und anlage zur umwandlung von natriumsulfat in natriumhydroxid |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2443174A1 (en) | 2002-10-10 |
| US20020143209A1 (en) | 2002-10-03 |
| JP2005504694A (ja) | 2005-02-17 |
| CN1512966B (zh) | 2012-08-22 |
| JP4541644B2 (ja) | 2010-09-08 |
| WO2002079089A1 (en) | 2002-10-10 |
| EP1373141B1 (en) | 2018-06-27 |
| NO20034392L (no) | 2003-12-01 |
| CN1512966A (zh) | 2004-07-14 |
| NO20034392D0 (no) | 2003-10-01 |
| EP1373141A1 (en) | 2004-01-02 |
| CA2443174C (en) | 2010-08-17 |
| US6652820B2 (en) | 2003-11-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| NO343675B1 (no) | Fremgangsmåter for fremstilling av cesiumsalt | |
| US20170233261A1 (en) | Production of lithium hydroxide | |
| JPH04295009A (ja) | 塩化ナトリウムの製造方法 | |
| NO178492B (no) | Fremgangsmåte ved fremstilling av et basisk polyaluminiumsulfat-lösningsprodukt | |
| FR2491451A1 (fr) | Procede de recuperation separee du molybdene et du vanadium | |
| NO343684B1 (no) | Fremgangsmåte for fremstilling av cesiumsalt | |
| KR101165453B1 (ko) | 염수로부터 고순도 탄산리튬을 제조하는 방법 | |
| RU2408534C2 (ru) | Способ получения растворов гидроксида цезия | |
| RU2543214C2 (ru) | Способ комплексной переработки природных рассолов хлоридного кальциево-магниевого типа | |
| JP3194176B2 (ja) | 硫酸根含有高塩基性塩化アルミニウム溶液の製造方法 | |
| JP2002047258A (ja) | Ｎ−イソプロピルグリシンの製造方法 | |
| US4277447A (en) | Process for reducing calcium ion concentrations in alkaline alkali metal chloride brines | |
| WO2001077019A2 (en) | A process for the production of potassium nitrate | |
| CN112299374A (zh) | 一种以氯化钠为原料制取盐酸和碳酸钠的方法 | |
| US4495160A (en) | Removal and recovery of magnesium, strontium and barium from brines | |
| CA2142663A1 (en) | Process for preparing calcium salts of low aluminum content | |
| RU2393117C1 (ru) | Способ получения нитрата калия и хлорида магния из хлорида калия и нитрата магния | |
| US4565612A (en) | Process for reducing sulphate ion concentration in aqueous sodium hydroxide solutions | |
| JPS59204149A (ja) | ヘキサフルオロアセトン水和物の精製方法 | |
| JP4566642B2 (ja) | スルホニウム化合物の製造方法 | |
| RU2192297C1 (ru) | Способ переработки реакционных масс, образующихся в процессе детоксикации люизита | |
| US5021231A (en) | Production of chlorine and sodium sulphate | |
| RU2393118C1 (ru) | Способ получения хлорида магния и нитрата кальция в замкнутом цикле | |
| JP4079439B2 (ja) | 低臭素無機塩類の製造方法 | |
| KR890003194B1 (ko) | 알루미늄 하이드록시 클로라이드의 제조방법 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM1K | Lapsed by not paying the annual fees |