NO334320B1 - Stivt skummateriale og fremgangsmåte for fremstilling av dette ved å anvende alkylalkanoat som esemiddel - Google Patents
Stivt skummateriale og fremgangsmåte for fremstilling av dette ved å anvende alkylalkanoat som esemiddel Download PDFInfo
- Publication number
- NO334320B1 NO334320B1 NO20043039A NO20043039A NO334320B1 NO 334320 B1 NO334320 B1 NO 334320B1 NO 20043039 A NO20043039 A NO 20043039A NO 20043039 A NO20043039 A NO 20043039A NO 334320 B1 NO334320 B1 NO 334320B1
- Authority
- NO
- Norway
- Prior art keywords
- weight
- polyols
- polyalkylated
- component
- approx
- Prior art date
Links
- 239000004604 Blowing Agent Substances 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title claims description 21
- 125000000217 alkyl group Chemical group 0.000 title abstract description 32
- 239000006261 foam material Substances 0.000 title 1
- 239000006260 foam Substances 0.000 claims abstract description 69
- 229920005862 polyol Polymers 0.000 claims abstract description 44
- 150000003077 polyols Chemical class 0.000 claims abstract description 42
- 239000012948 isocyanate Substances 0.000 claims abstract description 22
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 22
- 239000011541 reaction mixture Substances 0.000 claims abstract description 19
- 229920005906 polyester polyol Polymers 0.000 claims abstract description 16
- 150000002170 ethers Chemical class 0.000 claims abstract description 15
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 14
- 150000001412 amines Chemical class 0.000 claims abstract description 13
- 229920005830 Polyurethane Foam Polymers 0.000 claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 claims abstract description 12
- 239000011496 polyurethane foam Substances 0.000 claims abstract description 12
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 claims description 36
- 239000000203 mixture Substances 0.000 claims description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 239000004094 surface-active agent Substances 0.000 claims description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 3
- 239000001569 carbon dioxide Substances 0.000 claims description 2
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 239000007858 starting material Substances 0.000 description 20
- 239000004615 ingredient Substances 0.000 description 16
- 210000004027 cell Anatomy 0.000 description 14
- 229930195733 hydrocarbon Natural products 0.000 description 12
- 150000002430 hydrocarbons Chemical class 0.000 description 12
- 239000004088 foaming agent Substances 0.000 description 11
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 8
- 239000007789 gas Substances 0.000 description 7
- 238000012856 packing Methods 0.000 description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 150000002894 organic compounds Chemical class 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 235000019253 formic acid Nutrition 0.000 description 4
- -1 formic acid salt Chemical class 0.000 description 4
- 229920000582 polyisocyanurate Polymers 0.000 description 4
- 239000011495 polyisocyanurate Substances 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 229920005903 polyol mixture Polymers 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 210000002421 cell wall Anatomy 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000010561 standard procedure Methods 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- LOCPTSFJZDIICR-UHFFFAOYSA-N 1,3-bis(3-isocyanato-4-methylphenyl)-1,3-diazetidine-2,4-dione Chemical compound C1=C(N=C=O)C(C)=CC=C1N1C(=O)N(C=2C=C(C(C)=CC=2)N=C=O)C1=O LOCPTSFJZDIICR-UHFFFAOYSA-N 0.000 description 1
- VGHSXKTVMPXHNG-UHFFFAOYSA-N 1,3-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC(N=C=O)=C1 VGHSXKTVMPXHNG-UHFFFAOYSA-N 0.000 description 1
- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 230000001166 anti-perspirative effect Effects 0.000 description 1
- 239000003213 antiperspirant Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Polymers OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000008396 flotation agent Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 210000000497 foam cell Anatomy 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920013730 reactive polymer Polymers 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 150000003445 sucroses Polymers 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002937 thermal insulation foam Substances 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical class CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/482—Mixtures of polyethers containing at least one polyether containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/142—Compounds containing oxygen but no halogen atom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/149—Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/12—Organic compounds only containing carbon, hydrogen and oxygen atoms, e.g. ketone or alcohol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
- C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/04—Foams characterised by their properties characterised by the foam pores
- C08J2205/052—Closed cells, i.e. more than 50% of the pores are closed
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/10—Rigid foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/026,306 US6753357B2 (en) | 2001-12-18 | 2001-12-18 | Rigid foam compositions and method employing methyl formate as a blowing agent |
| PCT/US2002/040554 WO2003051097A2 (en) | 2001-12-18 | 2002-12-18 | Rigid foam compositions and methods employing alkyl alkanoates as a blowing agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NO20043039L NO20043039L (no) | 2004-07-16 |
| NO334320B1 true NO334320B1 (no) | 2014-02-03 |
Family
ID=21831053
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO20043039A NO334320B1 (no) | 2001-12-18 | 2004-07-16 | Stivt skummateriale og fremgangsmåte for fremstilling av dette ved å anvende alkylalkanoat som esemiddel |
Country Status (17)
| Country | Link |
|---|---|
| US (2) | US6753357B2 (de) |
| EP (1) | EP1458781B1 (de) |
| JP (1) | JP2005513179A (de) |
| KR (1) | KR100649377B1 (de) |
| CN (1) | CN100523037C (de) |
| AT (1) | ATE503786T1 (de) |
| AU (1) | AU2002357892B2 (de) |
| BR (1) | BRPI0215006B1 (de) |
| CA (1) | CA2468049C (de) |
| DE (1) | DE60239633D1 (de) |
| DK (1) | DK1458781T3 (de) |
| ES (1) | ES2359908T3 (de) |
| HK (1) | HK1072267A1 (de) |
| MX (1) | MXPA04005908A (de) |
| NO (1) | NO334320B1 (de) |
| SI (1) | SI1458781T1 (de) |
| WO (1) | WO2003051097A2 (de) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6753357B2 (en) * | 2001-12-18 | 2004-06-22 | Foam Supplies, Inc. | Rigid foam compositions and method employing methyl formate as a blowing agent |
| US20050277701A1 (en) * | 2004-06-15 | 2005-12-15 | Honeywell International Inc. | Process for making polyurethane and polyisocyanurate foams using mixtures of a hydrofluorocarbon and methyl formate as a blowing agent |
| JP2008509247A (ja) * | 2004-08-04 | 2008-03-27 | フォーム・サプライズ・インコーポレイテッド | ポリウレタンフォームにおける反応性ドリフトおよび触媒分解 |
| US20060052465A1 (en) * | 2004-09-03 | 2006-03-09 | Handa Yash P | Thermoplastic foams made with methyl formate-based blowing agents |
| US20060052466A1 (en) * | 2004-09-03 | 2006-03-09 | Handa Yash P | Expanded and extruded thermoplastic foams made with methyl formate-based blowing agents |
| US7307105B2 (en) * | 2004-09-03 | 2007-12-11 | Pactiv Corporation | Thermoplastic foams made with methyl formate-based blowing agents |
| US8309619B2 (en) | 2004-09-03 | 2012-11-13 | Pactiv LLC | Reduced-VOC and non-VOC blowing agents for making expanded and extruded thermoplastic foams |
| US7312253B2 (en) * | 2004-09-03 | 2007-12-25 | Pactiv Corporation | Insulating thermoplastic foams made with methyl formate-based blowing agents |
| CA2634484A1 (en) * | 2006-02-22 | 2007-09-07 | Pactiv Corporation | Expanded and extruded polyolefin foams made with methyl formate-based blowing agents |
| US7977397B2 (en) * | 2006-12-14 | 2011-07-12 | Pactiv Corporation | Polymer blends of biodegradable or bio-based and synthetic polymers and foams thereof |
| EP2089460B1 (de) * | 2006-12-14 | 2011-09-07 | Pactiv Corporation | Expandierte und extrudierte biologisch abbaubare schäume mit reduzierter emission hergestellt unter verwendung von blähmitteln auf basis von methylformiat |
| US9290604B2 (en) * | 2010-08-13 | 2016-03-22 | Air Products And Chemicals, Inc. | NPE-free emulsifiers for water-blown polyurethane spray foam |
| CA2829486C (en) * | 2011-03-11 | 2019-03-26 | Arkema Inc. | Improved stability of polyurethane polyol blends containing halogenated olefin blowing agent |
| US20120264842A1 (en) * | 2011-04-15 | 2012-10-18 | Basf Se | Process for producing rigid polyurethane foams |
| WO2012141822A1 (en) * | 2011-04-15 | 2012-10-18 | Arkema Inc. | Improved stability of polyurethane polyol blends containing halogenated olefin blowing agent |
| US9334383B2 (en) * | 2011-04-15 | 2016-05-10 | Basf Se | Process for producing rigid polyurethane foams |
| US9522973B2 (en) | 2012-10-02 | 2016-12-20 | Covestro Llc | Polyurethane and polyisocyanurate rigid foams for roofing insulation |
| US9481790B2 (en) * | 2012-10-08 | 2016-11-01 | Icp Adhesives And Sealants, Inc. | Marine foam |
| CN104341573A (zh) * | 2013-08-07 | 2015-02-11 | 上海抚佳精细化工有限公司 | 一种聚氨酯泡沫塑料及其制备方法 |
| WO2017189452A1 (en) | 2016-04-28 | 2017-11-02 | Natureworks Llc | Polymer foam insulation structures having a facing layer of a polylactide resin |
| WO2017189453A1 (en) | 2016-04-28 | 2017-11-02 | Natureworks Llc | Polymer foam insulation structure having a facing of a multi-layer sheet that contains a heat resistant polymer layer and a polylactide resin layer |
| CN106188485B (zh) * | 2016-08-01 | 2019-08-20 | 山东一诺威新材料有限公司 | 聚氨酯泡沫塑料发泡材料及其制备方法和应用 |
| WO2018071518A1 (en) * | 2016-10-11 | 2018-04-19 | Foam Supplies, Inc. | Reinforced composite structure and methods of making the same |
| CN108164672A (zh) * | 2017-12-28 | 2018-06-15 | 青岛海尔股份有限公司 | 聚氨酯硬质泡沫塑料及其制备方法 |
| CN109320677A (zh) * | 2018-09-29 | 2019-02-12 | 俞宝兴 | 绿色环保型聚氨酯硬泡组合聚醚、聚氨酯硬泡及制备方法 |
| EP3863849A4 (de) * | 2018-10-12 | 2022-06-15 | Firestone Building Products Company, LLC | Verkapselte zerbrechliche isoliermaterialien |
| CN110283352A (zh) * | 2019-05-29 | 2019-09-27 | 佳化化学科技发展（上海）有限公司 | 一种聚氨酯软泡海绵及其制备方法 |
| CA3158109A1 (en) | 2019-10-15 | 2021-04-22 | Icp Construction, Inc. | Sprayable marine foam |
Family Cites Families (76)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3072582A (en) * | 1955-10-20 | 1963-01-08 | Gen Tire & Rubber Co | Polyether-urethane foams and method of making same |
| US3745203A (en) * | 1971-08-19 | 1973-07-10 | Cincinnati Milling Machine Co | Process for molding polyurethane utilizing a mixture of two blowing agents |
| US3879315A (en) * | 1973-06-18 | 1975-04-22 | Union Carbide Corp | Process for the preparation of flexible polyurethane foams in the presence of alkyl alkanoate blowing agents |
| US4033910A (en) * | 1975-09-26 | 1977-07-05 | Union Carbide Corporation | Methyl formate as an adjuvant in phenolic foam formation |
| CA1189249A (en) * | 1981-07-09 | 1985-06-18 | Bernhard Liessem | Foam manufacture |
| US4448951A (en) * | 1983-01-17 | 1984-05-15 | Basf Wyandotte Corporation | Phenolic polyols and rigid cellular compositions derived therefrom |
| US4860804A (en) * | 1986-12-23 | 1989-08-29 | Mitsubishi Jukogyo Kabushiki Kaisha | Filled amount control system |
| BE1001853A7 (nl) | 1988-06-28 | 1990-03-20 | Recticel | Werkwijze voor het bereiden van soepel polyurethaanschuim. |
| BE1002108A7 (nl) | 1988-07-12 | 1990-07-03 | Recticel | Werkwijze voor het bereiden van een hoog veerkrachtig polyurethaanschuim. |
| US5118720A (en) * | 1989-01-13 | 1992-06-02 | Sealed Air Corporation | Method for producing polyurethane foam and apparatus therefor |
| US4960804A (en) | 1989-03-09 | 1990-10-02 | Mobay Corporation | Rigid foams using blends of chlorofluorocarbons and alkyl alkanoates as blowing agent |
| US4972003A (en) * | 1989-05-10 | 1990-11-20 | The Dow Chemical Company | Foaming system for rigid urethane and isocyanurate foams |
| US4945119A (en) * | 1989-05-10 | 1990-07-31 | The Dow Chemical Company | Foaming system for rigid urethane and isocyanurate foams |
| JPH02302448A (ja) | 1989-05-17 | 1990-12-14 | Mitsubishi Gas Chem Co Inc | ポリウレタンフォーム発泡剤組成物 |
| US5274007A (en) * | 1989-07-24 | 1993-12-28 | Foam Supplies, Inc. | Rigid foams using CHCLF2 as a blowing agent |
| US5032623A (en) * | 1989-07-24 | 1991-07-16 | Foam Supplies, Inc. | Rigid foams using CHClF2 as a blowing agent |
| US5194175A (en) * | 1989-07-24 | 1993-03-16 | Foam Supplies, Inc. | Rigid foams, methods for preparation thereof and compositions useful in methods and preparations thereof |
| EP0521877A1 (de) * | 1990-03-23 | 1993-01-13 | E.I. Du Pont De Nemours And Company | Eine polymergassperrschicht enthaltende polymerschäume |
| DE4014923A1 (de) * | 1990-05-10 | 1991-11-14 | Basf Ag | Verfahren zur herstellung von urethan- oder urethan- und isocyanuratgruppen enthaltenden hartschaumstoffen nach dem polyisocyanat-polyadditionsverfahren und die hierfuer geeigneten polyoxyalkylen-polyole |
| DE4034046A1 (de) * | 1990-10-26 | 1992-04-30 | Basf Ag | Verfahren zur herstellung von flammwidrigen polyurethan-weichschaumstoffen mit verminderter rauchgasdichte und melamin-blaehgraphit-polyether-polyol-dispersionen hierfuer |
| US5227408A (en) * | 1991-06-11 | 1993-07-13 | E. R. Carpenter Company, Inc. | Carbon dioxide blown polyurethane packaging foam with chemical nucleating agents |
| US5439948A (en) * | 1991-11-20 | 1995-08-08 | Imperial Chemical Industries Plc | Process for cellular polymeric products |
| US5166182A (en) * | 1992-03-23 | 1992-11-24 | Atlas Roofing Corporation | Thermosetting plastic foams and methods of production thereof using novel blowing agents |
| US5405885A (en) * | 1992-04-22 | 1995-04-11 | Basf Corporation | Rigid polyurethane/polyisocyanate foams containing paraffinic based oils |
| US5424338A (en) * | 1992-08-06 | 1995-06-13 | Basf Corporation | Rigid hydrophilic polyurethane foams |
| US5597885A (en) * | 1993-02-10 | 1997-01-28 | Basf Aktiengesellschaft | Preparation of chlorofluorocarbon-free flexible polyurethane foams using diphenylmethane diisocyanate-based polyisocyanate mixtures containing urethane groups, and modified polyisocyanate mixtures |
| US5283003A (en) * | 1993-03-04 | 1994-02-01 | Chen Wen Pin | Blowing agents for foaming polyurethane having no ozone depletion potential and uses and preparations thereof |
| JPH06306132A (ja) | 1993-04-23 | 1994-11-01 | Achilles Corp | ウレタン変性ポリイソシアヌレートフォームの製造方法 |
| US5652278A (en) * | 1993-06-22 | 1997-07-29 | Imperial Chemical Industries Plc | Microvoid polyurethane materials |
| US5478494A (en) * | 1993-09-22 | 1995-12-26 | Basf Corporation | Polyol composition having good flow and formic acid blown rigid polyurethane foams made thereby having good dimensional stability |
| CA2132595C (en) * | 1993-09-22 | 1999-03-16 | Thomas L. Fishback | Polyol composition having good flow and water blown rigid polyurethane foams made thereby having good dimensional stability |
| CZ287435B6 (en) * | 1993-11-04 | 2000-11-15 | Bayer Ag | Process for preparing foam polyurethane shaped parts without use of fluorochlorinated hydrocarbons |
| GB9324510D0 (en) | 1993-11-30 | 1994-01-19 | Ici Plc | Process for rigid polyurethane foams |
| US5336696A (en) * | 1993-12-10 | 1994-08-09 | Nisshinbo Industries, Inc. | Halogen-free blowing agents that include cycloaliphatic hydrocarbons and are suitable for isocyanate-based polymeric foams |
| US6013213A (en) * | 1994-01-14 | 2000-01-11 | Compsys, Inc. | Method for making deformable composite structures and assembling composite article |
| US5800749A (en) * | 1994-01-14 | 1998-09-01 | Compsys, Inc. | Method of making composite structures |
| US5664518A (en) * | 1994-01-14 | 1997-09-09 | Compsys, Inc. | Composite structures and method of making composite structures |
| US5429066A (en) * | 1994-01-14 | 1995-07-04 | Compsys, Inc. | Composite structures and method of making composite structures |
| US5908591A (en) * | 1994-01-14 | 1999-06-01 | Compsys, Inc. | Method for making composite structures |
| DE4411864A1 (de) * | 1994-04-08 | 1995-10-12 | Basf Schwarzheide Gmbh | Verfahren zur Herstellung von harten bis zähharten Polyurethanschaumstoffen mit erhöhtem Anteil an offenen Zellen und vermindertem Schrumpf |
| US5488072A (en) * | 1995-02-06 | 1996-01-30 | Basf Corporation | Rigid closed cell polyisocyanate based foams for use as positive flotation materials in watercraft |
| US5512319A (en) * | 1994-08-22 | 1996-04-30 | Basf Corporation | Polyurethane foam composite |
| KR0180613B1 (en) * | 1994-09-07 | 1999-05-15 | Matsushita Electric Ind Co Ltd | Thermal insulating foamed material and method for manufacturing the same |
| DE4434604B4 (de) * | 1994-09-28 | 2005-03-03 | Basf Ag | Verfahren zur Herstellung von fluorchlorkohlenwasserstofffreien, Urethangruppen enthaltenden Formkörpern mit einem zelligen Kern und einer verdichteten Randzone |
| DE4443432A1 (de) * | 1994-12-06 | 1996-06-13 | Elastogran Gmbh | Unter Druck stehende, Treibmittel enthaltende Isocyanat-Semirpräpolymermischungen auf Basis von Mischungen aus Polyhydroxylverbindungen und Monoalkoholen und/oder Hydroxyketonen, ihre Verwendung zur Herstellung von Polyurethanschaumstoffen und ein Verfahren hierfür |
| US5762822A (en) * | 1994-12-29 | 1998-06-09 | Basf Corporation | Dimensionally stable closed cell rigid polyisocyanate based foam prepared from a froth foaming mixture |
| US5605940A (en) * | 1995-02-13 | 1997-02-25 | The Celotex Corporation | High equivalent weight polyester polyols for closed cell, rigid foams |
| DE19506671C2 (de) * | 1995-02-25 | 1999-11-18 | Basf Ag | Verfahren zur Herstellung von Polyurethan-Schaumstoffen |
| US5604264A (en) * | 1995-04-03 | 1997-02-18 | Reilly Industries, Inc. | Polyvinylpyridinium anion-exchangers for recovery of technetium and plutonium anions |
| DE19519335A1 (de) * | 1995-05-26 | 1996-11-28 | Basf Ag | Verfahren zur Herstellung von Ester- und Urethangruppen enthaltenden Formkörpern, estergruppenhaltige Isocyanat-Semipräpolymere hierfür und ihre Verwendung |
| DE19533610A1 (de) * | 1995-09-11 | 1997-03-13 | Basf Ag | Verfahren zur Herstellung von Polyurethan-Hart- oder Halbhartschaumstoffen und derartige Polyurethan-Schaumstoffe enthaltende Verbundelemente |
| US6034148A (en) * | 1996-07-19 | 2000-03-07 | Foamex L.P. | Energy absorbing foams |
| SK58299A3 (en) * | 1996-11-04 | 2000-02-14 | Ici Plc | Isocyanate reactive composition, rigid polyurethane foams and process for their production |
| TR199900971T2 (en) * | 1996-11-04 | 1999-07-21 | Imperial Chemical Industries Plc | B�k�lmez poli�retan k�p�kleri |
| BR9807217A (pt) * | 1997-02-11 | 2000-05-23 | Huntsman Ici Chem Llc | Pré-polìmero terminado com isocianato, processo para sua preparação, e, espuma de poliuretano. |
| CA2280807A1 (en) * | 1997-03-20 | 1998-10-01 | Rik De Vos | Process for rigid polyurethane foams |
| DE19718018A1 (de) * | 1997-04-29 | 1998-11-05 | Basf Ag | Verfahren zur Herstellung von Polyurethan-Hartschaumstoffen |
| DE19728543A1 (de) * | 1997-07-04 | 1999-01-07 | Basf Ag | Verfahren zur Herstellung von Polyurethan-Hartschaumstoffen mit geringer Wärmeleitfähigkeit |
| DE19746807A1 (de) * | 1997-10-23 | 1999-04-29 | Basf Ag | Verfahren zur Herstellung von Polyurethanschaumstoffen |
| US5801210A (en) * | 1997-10-29 | 1998-09-01 | Bayer Corporation | Method and apparatus for the production of essentially void free foams |
| US5922348A (en) * | 1997-11-04 | 1999-07-13 | Intercool Energy Corp. | Integral skin foams |
| CA2329667A1 (en) * | 1998-05-21 | 1999-12-02 | Sachchida Nand Singh | Hydrocarbon blown rigid polyurethane foams having improved flammability performance |
| JP3322852B2 (ja) * | 1998-06-26 | 2002-09-09 | 日清紡績株式会社 | 連続気泡硬質ポリウレタンフォーム成形体およびその製造方法 |
| US6268402B1 (en) * | 1999-02-05 | 2001-07-31 | Basf Corporation | Process for making isocyanate-based rigid foam |
| DE19917787A1 (de) * | 1999-04-20 | 2000-11-02 | Bayer Ag | Komprimierte Polyurethanhartschaumstoffe |
| DE60004048T2 (de) * | 1999-05-31 | 2004-05-27 | Huntsman International Llc, Salt Lake City | Polymer-modifizierte polyole, ihre verwendung für die herstellung von polyurethanprodukten |
| US6420443B1 (en) * | 1999-09-09 | 2002-07-16 | Crompton Corporation | Additives for enhanced hydrocarbon compatibility in rigid polyurethane foam systems |
| KR100609851B1 (ko) * | 2000-02-09 | 2006-08-09 | 삼성전자주식회사 | 경질 폴리우레탄 발포체의 제조방법 |
| US6423755B1 (en) * | 2000-02-25 | 2002-07-23 | Essex Specialty Products, Inc | Rigid polyurethane foams |
| US6310111B1 (en) * | 2000-03-15 | 2001-10-30 | Atofina Chemicals, Inc. | Blowing agent blends |
| EP1167414A1 (de) | 2000-06-29 | 2002-01-02 | Huntsman International Llc | Verfahren zur Herstellung von Polyurethanhartschaumstoffen mit hoher Haftung |
| US6410609B1 (en) * | 2000-07-27 | 2002-06-25 | Fomo Products, Inc. | Low pressure generating polyurethane foams |
| JP2002155125A (ja) * | 2000-11-20 | 2002-05-28 | Sumika Bayer Urethane Kk | ポリウレタン変性ポリイソシアヌレートフォームの製造方法 |
| US6420448B1 (en) * | 2001-01-18 | 2002-07-16 | Foamex Lp | Energy absorbing foams |
| US6753357B2 (en) | 2001-12-18 | 2004-06-22 | Foam Supplies, Inc. | Rigid foam compositions and method employing methyl formate as a blowing agent |
| US20050277701A1 (en) * | 2004-06-15 | 2005-12-15 | Honeywell International Inc. | Process for making polyurethane and polyisocyanurate foams using mixtures of a hydrofluorocarbon and methyl formate as a blowing agent |
-
2001
- 2001-12-18 US US10/026,306 patent/US6753357B2/en not_active Expired - Lifetime
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2002
- 2002-12-18 MX MXPA04005908A patent/MXPA04005908A/es active IP Right Grant
- 2002-12-18 EP EP02792436A patent/EP1458781B1/de not_active Expired - Lifetime
- 2002-12-18 US US10/499,375 patent/US7635723B2/en not_active Expired - Lifetime
- 2002-12-18 CA CA2468049A patent/CA2468049C/en not_active Expired - Lifetime
- 2002-12-18 KR KR1020047009317A patent/KR100649377B1/ko active IP Right Grant
- 2002-12-18 AT AT02792436T patent/ATE503786T1/de active
- 2002-12-18 WO PCT/US2002/040554 patent/WO2003051097A2/en active Application Filing
- 2002-12-18 JP JP2003552036A patent/JP2005513179A/ja active Pending
- 2002-12-18 AU AU2002357892A patent/AU2002357892B2/en not_active Expired
- 2002-12-18 DK DK02792436.4T patent/DK1458781T3/da active
- 2002-12-18 ES ES02792436T patent/ES2359908T3/es not_active Expired - Lifetime
- 2002-12-18 CN CNB028251121A patent/CN100523037C/zh not_active Expired - Lifetime
- 2002-12-18 DE DE60239633T patent/DE60239633D1/de not_active Expired - Lifetime
- 2002-12-18 BR BRPI0215006-9A patent/BRPI0215006B1/pt active IP Right Grant
- 2002-12-18 SI SI200230941T patent/SI1458781T1/sl unknown
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- 2004-07-16 NO NO20043039A patent/NO334320B1/no not_active IP Right Cessation
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Also Published As
| Publication number | Publication date |
|---|---|
| US6753357B2 (en) | 2004-06-22 |
| CA2468049A1 (en) | 2003-06-26 |
| NO20043039L (no) | 2004-07-16 |
| BR0215006A (pt) | 2004-11-09 |
| JP2005513179A (ja) | 2005-05-12 |
| US7635723B2 (en) | 2009-12-22 |
| DK1458781T3 (da) | 2011-06-20 |
| US20030114549A1 (en) | 2003-06-19 |
| EP1458781B1 (de) | 2011-03-30 |
| ATE503786T1 (de) | 2011-04-15 |
| BRPI0215006B1 (pt) | 2020-04-14 |
| AU2002357892B2 (en) | 2006-05-04 |
| KR100649377B1 (ko) | 2006-11-27 |
| KR20040079907A (ko) | 2004-09-16 |
| CN1604925A (zh) | 2005-04-06 |
| EP1458781A2 (de) | 2004-09-22 |
| EP1458781A4 (de) | 2005-03-09 |
| HK1072267A1 (en) | 2005-08-19 |
| CN100523037C (zh) | 2009-08-05 |
| WO2003051097A3 (en) | 2003-10-30 |
| DE60239633D1 (de) | 2011-05-12 |
| AU2002357892A1 (en) | 2003-06-30 |
| ES2359908T3 (es) | 2011-05-30 |
| US20050131094A1 (en) | 2005-06-16 |
| MXPA04005908A (es) | 2005-03-31 |
| SI1458781T1 (sl) | 2011-06-30 |
| CA2468049C (en) | 2010-02-16 |
| WO2003051097A2 (en) | 2003-06-26 |
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