NO322282B1 - Tokomponent polyuretan-beleggingsmiddel og anvendelse av dette som korrosjonsbeskyttelsesdekklakk - Google Patents
Tokomponent polyuretan-beleggingsmiddel og anvendelse av dette som korrosjonsbeskyttelsesdekklakk Download PDFInfo
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- NO322282B1 NO322282B1 NO19992459A NO992459A NO322282B1 NO 322282 B1 NO322282 B1 NO 322282B1 NO 19992459 A NO19992459 A NO 19992459A NO 992459 A NO992459 A NO 992459A NO 322282 B1 NO322282 B1 NO 322282B1
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- NO
- Norway
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- 239000011248 coating agent Substances 0.000 title claims abstract description 37
- 230000007797 corrosion Effects 0.000 title claims abstract description 16
- 238000005260 corrosion Methods 0.000 title claims abstract description 16
- 238000000576 coating method Methods 0.000 title abstract description 10
- 239000003795 chemical substances by application Substances 0.000 title description 11
- 239000011527 polyurethane coating Substances 0.000 title description 2
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 24
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 24
- 150000001875 compounds Chemical class 0.000 claims abstract description 22
- 229920000768 polyamine Polymers 0.000 claims abstract description 18
- 239000000654 additive Substances 0.000 claims abstract description 15
- 125000003277 amino group Chemical group 0.000 claims abstract description 15
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract description 11
- 239000002904 solvent Substances 0.000 claims abstract description 10
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- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000049 pigment Substances 0.000 claims abstract description 6
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- 239000001257 hydrogen Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
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- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 claims description 5
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- DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 claims description 2
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- 229920005789 ACRONAL® acrylic binder Polymers 0.000 description 3
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- RSOILICUEWXSLA-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 RSOILICUEWXSLA-UHFFFAOYSA-N 0.000 description 3
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- HXVNBWAKAOHACI-UHFFFAOYSA-N 2,4-dimethyl-3-pentanone Chemical compound CC(C)C(=O)C(C)C HXVNBWAKAOHACI-UHFFFAOYSA-N 0.000 description 2
- FTZILAQGHINQQR-UHFFFAOYSA-N 2-Methylpentanal Chemical compound CCCC(C)C=O FTZILAQGHINQQR-UHFFFAOYSA-N 0.000 description 2
- LGYNIFWIKSEESD-UHFFFAOYSA-N 2-ethylhexanal Chemical compound CCCCC(CC)C=O LGYNIFWIKSEESD-UHFFFAOYSA-N 0.000 description 2
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- POSWICCRDBKBMH-UHFFFAOYSA-N 3,3,5-trimethylcyclohexan-1-one Chemical compound CC1CC(=O)CC(C)(C)C1 POSWICCRDBKBMH-UHFFFAOYSA-N 0.000 description 2
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- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
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- 125000000468 ketone group Chemical group 0.000 description 1
- BGEHHAVMRVXCGR-UHFFFAOYSA-N methylundecylketone Natural products CCCCCCCCCCCCC=O BGEHHAVMRVXCGR-UHFFFAOYSA-N 0.000 description 1
- KPSSIOMAKSHJJG-UHFFFAOYSA-N neopentyl alcohol Chemical compound CC(C)(C)CO KPSSIOMAKSHJJG-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- YUPOCHDBBHTUBJ-UHFFFAOYSA-N nonadecan-10-one Chemical compound CCCCCCCCCC(=O)CCCCCCCCC YUPOCHDBBHTUBJ-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- FXLOVSHXALFLKQ-UHFFFAOYSA-N p-tolualdehyde Chemical compound CC1=CC=C(C=O)C=C1 FXLOVSHXALFLKQ-UHFFFAOYSA-N 0.000 description 1
- RZXMPPFPUUCRFN-UHFFFAOYSA-N p-toluidine Chemical compound CC1=CC=C(N)C=C1 RZXMPPFPUUCRFN-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N pentanal Chemical compound CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 1
- DTUQWGWMVIHBKE-UHFFFAOYSA-N phenylacetaldehyde Chemical compound O=CCC1=CC=CC=C1 DTUQWGWMVIHBKE-UHFFFAOYSA-N 0.000 description 1
- PJGSXYOJTGTZAV-UHFFFAOYSA-N pinacolone Chemical compound CC(=O)C(C)(C)C PJGSXYOJTGTZAV-UHFFFAOYSA-N 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002635 polyurethane Chemical group 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- IJNJLGFTSIAHEA-UHFFFAOYSA-N prop-2-ynal Chemical compound O=CC#C IJNJLGFTSIAHEA-UHFFFAOYSA-N 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000006462 rearrangement reaction Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- CYIFVRUOHKNECG-UHFFFAOYSA-N tridecan-2-one Chemical compound CCCCCCCCCCCC(C)=O CYIFVRUOHKNECG-UHFFFAOYSA-N 0.000 description 1
- GKASDNZWUGIAMG-UHFFFAOYSA-N triethyl orthoformate Chemical compound CCOC(OCC)OCC GKASDNZWUGIAMG-UHFFFAOYSA-N 0.000 description 1
- 238000005829 trimerization reaction Methods 0.000 description 1
- KYWIYKKSMDLRDC-UHFFFAOYSA-N undecan-2-one Chemical compound CCCCCCCCCC(C)=O KYWIYKKSMDLRDC-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
- C08G18/3821—Carboxylic acids; Esters thereof with monohydroxyl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3234—Polyamines cycloaliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3253—Polyamines being in latent form
- C08G18/3256—Reaction products of polyamines with aldehydes or ketones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2150/00—Compositions for coatings
- C08G2150/90—Compositions for anticorrosive coatings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19822842A DE19822842A1 (de) | 1998-05-22 | 1998-05-22 | 2K-PUR-Korrosionsschutz-Decklack |
Publications (3)
Publication Number | Publication Date |
---|---|
NO992459D0 NO992459D0 (no) | 1999-05-21 |
NO992459L NO992459L (no) | 1999-11-23 |
NO322282B1 true NO322282B1 (no) | 2006-09-04 |
Family
ID=7868537
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO19992459A NO322282B1 (no) | 1998-05-22 | 1999-05-21 | Tokomponent polyuretan-beleggingsmiddel og anvendelse av dette som korrosjonsbeskyttelsesdekklakk |
Country Status (9)
Country | Link |
---|---|
US (1) | US6169141B1 (fr) |
EP (1) | EP0959086B1 (fr) |
JP (1) | JP2000026799A (fr) |
AT (1) | ATE248197T1 (fr) |
CA (1) | CA2272340C (fr) |
DE (2) | DE19822842A1 (fr) |
ES (1) | ES2207060T3 (fr) |
NO (1) | NO322282B1 (fr) |
PT (1) | PT959086E (fr) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19924171A1 (de) * | 1999-05-25 | 2000-11-30 | Basf Coatings Ag | Beschichtungsstoff mit einer Mischung aus mindestens einem Netzmittel und Harnstoffen und/oder Harnstoffderivaten als Thixotropiermittel |
US6458293B1 (en) * | 1999-07-29 | 2002-10-01 | Bayer Corporation | Polyurea coatings from dimethyl-substituted polyaspartic ester mixtures |
US6482333B1 (en) * | 1999-12-30 | 2002-11-19 | Bayer Corporation | Polyurea coatings from dimethyl-substituted polyaspartic ester mixtures |
US7078475B2 (en) * | 2001-06-15 | 2006-07-18 | Huntsman Petrochemical Corporation | Synergistic amine chain-extenders in polyurea spray elastomers |
DE10152723A1 (de) | 2001-10-25 | 2003-05-15 | Degussa Construction Chem Gmbh | Wässriges hochvernetztes Zweikomponenten-Polyurethanbeschichtungssystem mit verringerter Hydrophilie und verbesserter Chemikalienbeständigkeit, Verfahren zu seiner Herstellung sowie dessen Verwendung |
US20050059790A1 (en) * | 2003-09-16 | 2005-03-17 | Roesler Richard R. | Process for preparing aspartates |
DE102005020269A1 (de) * | 2005-04-30 | 2006-11-09 | Bayer Materialscience Ag | Bindemittelgemische aus Polyasparaginsäureestern und sulfonatmodifizierten Polyisocyanaten |
DE102005047562A1 (de) * | 2005-10-04 | 2007-04-05 | Bayer Materialscience Ag | Zweitkomponenten-Systeme für die Herstellung flexibler Beschichtungen |
US20090176907A1 (en) * | 2008-01-08 | 2009-07-09 | Ramesh Subramanian | Direct-to-metal radiation curable compositions |
CA2840506C (fr) * | 2011-07-01 | 2016-02-09 | Ppg Industries Ohio, Inc. | Revetements a base de polyuree contenant du silane |
CN102229783B (zh) * | 2011-07-04 | 2012-10-17 | 广东花王涂料有限公司 | 一种低气味、不黄变的木器用聚氨酯类的哑光白面漆 |
CN105073815A (zh) * | 2013-03-15 | 2015-11-18 | 拜耳材料科学有限责任公司 | 多天冬氨酸涂料组合物 |
JP6075498B1 (ja) | 2015-08-07 | 2017-02-08 | ダイキン工業株式会社 | 組成物、塗膜、含フッ素塗膜及び積層体 |
JP6682037B2 (ja) * | 2017-03-07 | 2020-04-15 | 旭化成株式会社 | ポリアスパラティック塗料組成物、塗膜、及び塗装物品 |
CA3056946A1 (fr) * | 2017-04-04 | 2018-10-11 | Swimc Llc | Composition de revetement direct sur metal |
US20210163667A1 (en) | 2018-01-26 | 2021-06-03 | Sika Technology Ag | Curable composition comprising an acetal plasticizer |
US20190390064A1 (en) * | 2018-06-22 | 2019-12-26 | Covestro Llc | Solventborne compositions containing inorganic ion-exchangers to improve corrosion resistance |
CN110964422A (zh) * | 2018-09-28 | 2020-04-07 | 广州立邦涂料有限公司 | 复合材料表面的处理方法与涂层组合物,及涂层组合物的制备方法和应用 |
US11827788B2 (en) | 2019-10-07 | 2023-11-28 | Covestro Llc | Faster cure polyaspartic resins for faster physical property development in coatings |
WO2021175661A1 (fr) | 2020-03-04 | 2021-09-10 | Basf Coatings Gmbh | Kit de composants pour compositions de revêtement à base d'ester de poly(acide aspartique) durcissables |
CN112143360A (zh) * | 2020-10-10 | 2020-12-29 | 湘江涂料科技有限公司 | 一种石墨烯改性聚天门冬氨酸酯含锌涂料及其制备方法 |
US20220154037A1 (en) * | 2020-11-19 | 2022-05-19 | Covestro Llc | Polyaspartic coatings with recoat and stable initial gloss |
JP7324790B2 (ja) * | 2021-03-05 | 2023-08-10 | 日本ペイント・インダストリアルコーティングス株式会社 | 塗料組成物 |
EP4074745A1 (fr) | 2021-04-16 | 2022-10-19 | Sherwin-Williams Coatings Deutschland GmbH | Revêtement de protection contre la corrosion à base de polyuréthane |
JP7281591B1 (ja) | 2022-08-31 | 2023-05-25 | 日本ペイント・インダストリアルコーティングス株式会社 | 塗料組成物 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2236842C3 (de) * | 1972-07-27 | 1978-04-27 | Chemische Werke Huels Ag, 4370 Marl | Überzugsmittel |
CH659655A5 (de) * | 1984-06-29 | 1987-02-13 | Leuenberger Ingbuero | Rostumwandlungs- und rostschutzmittel. |
US5021535A (en) * | 1988-05-19 | 1991-06-04 | W. R. Grace & Co.-Conn. | Castor oil based polyurethane for underbody coatings and the like |
US5214086A (en) | 1991-09-04 | 1993-05-25 | Basf Corporation | Coating compositions which may be ambient cured |
US5391686A (en) * | 1992-12-17 | 1995-02-21 | W. R. Grace & Co.-Conn. | Polyurethane compositions having enhanced corrosion inhibiting properties |
DE4415778A1 (de) | 1994-05-05 | 1995-11-09 | Bayer Ag | Verfahren zur Herstellung von Überzügen |
US5661216A (en) * | 1994-06-06 | 1997-08-26 | Basf Corporation | Coating composition based on amines, aldimines and isocyanates |
US5516873A (en) * | 1994-07-11 | 1996-05-14 | Bayer Corporation | Polyisocyanate/polyamine mixtures and their use for the production of polyurea coatings |
US5489704A (en) | 1994-08-29 | 1996-02-06 | Bayer Corporation | Polyisocyanate/polyamine mixtures and their use for the production of polyurea coatings |
US5591807A (en) * | 1995-05-23 | 1997-01-07 | The Sherwin-Williams Company | Polyimine/polyisocyanate coating composition containing polymeric anhydride |
ES2148877T3 (es) | 1996-07-02 | 2000-10-16 | Bayer Ag | Procedimiento para la fabricacion de mono- y poliesteres del acido aspartico. |
-
1998
- 1998-05-22 DE DE19822842A patent/DE19822842A1/de not_active Withdrawn
-
1999
- 1999-05-08 PT PT99109122T patent/PT959086E/pt unknown
- 1999-05-08 EP EP99109122A patent/EP0959086B1/fr not_active Expired - Lifetime
- 1999-05-08 AT AT99109122T patent/ATE248197T1/de active
- 1999-05-08 DE DE59906731T patent/DE59906731D1/de not_active Expired - Lifetime
- 1999-05-08 ES ES99109122T patent/ES2207060T3/es not_active Expired - Lifetime
- 1999-05-13 US US09/311,681 patent/US6169141B1/en not_active Expired - Lifetime
- 1999-05-17 CA CA002272340A patent/CA2272340C/fr not_active Expired - Fee Related
- 1999-05-20 JP JP11140156A patent/JP2000026799A/ja active Pending
- 1999-05-21 NO NO19992459A patent/NO322282B1/no not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
PT959086E (pt) | 2004-01-30 |
DE59906731D1 (de) | 2003-10-02 |
NO992459D0 (no) | 1999-05-21 |
JP2000026799A (ja) | 2000-01-25 |
EP0959086B1 (fr) | 2003-08-27 |
ES2207060T3 (es) | 2004-05-16 |
CA2272340A1 (fr) | 1999-11-22 |
NO992459L (no) | 1999-11-23 |
ATE248197T1 (de) | 2003-09-15 |
CA2272340C (fr) | 2006-10-03 |
DE19822842A1 (de) | 1999-11-25 |
EP0959086A1 (fr) | 1999-11-24 |
US6169141B1 (en) | 2001-01-02 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM1K | Lapsed by not paying the annual fees |