NO303573B1 - FremgangsmÕte for fjerning av vesentlig kromfritt sulfat fra en kromat- og sulfatholdig vandig alkalimetallkloratoppl°sning, samt kontinuerlig fremgangsmÕte for fremstilling av alkalimetallklorat - Google Patents
FremgangsmÕte for fjerning av vesentlig kromfritt sulfat fra en kromat- og sulfatholdig vandig alkalimetallkloratoppl°sning, samt kontinuerlig fremgangsmÕte for fremstilling av alkalimetallklorat Download PDFInfo
- Publication number
- NO303573B1 NO303573B1 NO910888A NO910888A NO303573B1 NO 303573 B1 NO303573 B1 NO 303573B1 NO 910888 A NO910888 A NO 910888A NO 910888 A NO910888 A NO 910888A NO 303573 B1 NO303573 B1 NO 303573B1
- Authority
- NO
- Norway
- Prior art keywords
- chlorate
- alkali metal
- solution
- sulfate
- calcium
- Prior art date
Links
- XTEGARKTQYYJKE-UHFFFAOYSA-M chlorate Inorganic materials [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 title claims description 101
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 title claims description 62
- 238000000034 method Methods 0.000 title claims description 37
- 229910052783 alkali metal Inorganic materials 0.000 title claims description 27
- -1 alkali metal chlorate Chemical class 0.000 title claims description 25
- 238000010924 continuous production Methods 0.000 title claims description 9
- 239000000243 solution Substances 0.000 claims description 52
- 239000011575 calcium Substances 0.000 claims description 42
- 229910052791 calcium Inorganic materials 0.000 claims description 32
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 27
- 239000012452 mother liquor Substances 0.000 claims description 27
- 239000012266 salt solution Substances 0.000 claims description 21
- 238000005868 electrolysis reaction Methods 0.000 claims description 20
- 229910052602 gypsum Inorganic materials 0.000 claims description 20
- 239000010440 gypsum Substances 0.000 claims description 20
- 239000013078 crystal Substances 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 17
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 17
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 15
- 239000002244 precipitate Substances 0.000 claims description 15
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 14
- 229910001514 alkali metal chloride Inorganic materials 0.000 claims description 13
- 239000011344 liquid material Substances 0.000 claims description 12
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 238000001556 precipitation Methods 0.000 claims description 9
- 229910052749 magnesium Inorganic materials 0.000 claims description 8
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims description 7
- 239000003456 ion exchange resin Substances 0.000 claims description 7
- 229920003303 ion-exchange polymer Polymers 0.000 claims description 7
- 150000002500 ions Chemical class 0.000 claims description 7
- 238000004064 recycling Methods 0.000 claims description 7
- 239000000460 chlorine Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 239000003792 electrolyte Substances 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 4
- 238000002425 crystallisation Methods 0.000 claims description 4
- 230000008025 crystallization Effects 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 4
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 3
- 239000012267 brine Substances 0.000 claims description 3
- 239000003153 chemical reaction reagent Substances 0.000 claims description 3
- 150000003841 chloride salts Chemical class 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 15
- 239000011651 chromium Substances 0.000 description 11
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 9
- 229910052804 chromium Inorganic materials 0.000 description 9
- 239000011777 magnesium Substances 0.000 description 8
- 238000011282 treatment Methods 0.000 description 8
- 239000011780 sodium chloride Substances 0.000 description 7
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 6
- 238000005342 ion exchange Methods 0.000 description 6
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 5
- 239000001110 calcium chloride Substances 0.000 description 5
- 229910001628 calcium chloride Inorganic materials 0.000 description 5
- 235000011148 calcium chloride Nutrition 0.000 description 5
- 230000001105 regulatory effect Effects 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 229910052788 barium Inorganic materials 0.000 description 4
- 150000001553 barium compounds Chemical class 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 229910001424 calcium ion Inorganic materials 0.000 description 4
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 4
- 238000005265 energy consumption Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 235000011132 calcium sulphate Nutrition 0.000 description 3
- GYZGFUUDAQXRBT-UHFFFAOYSA-J calcium;disodium;disulfate Chemical compound [Na+].[Na+].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GYZGFUUDAQXRBT-UHFFFAOYSA-J 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- JHWIEAWILPSRMU-UHFFFAOYSA-N 2-methyl-3-pyrimidin-4-ylpropanoic acid Chemical compound OC(=O)C(C)CC1=CC=NC=N1 JHWIEAWILPSRMU-UHFFFAOYSA-N 0.000 description 2
- 239000004155 Chlorine dioxide Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
- QFFVPLLCYGOFPU-UHFFFAOYSA-N barium chromate Chemical compound [Ba+2].[O-][Cr]([O-])(=O)=O QFFVPLLCYGOFPU-UHFFFAOYSA-N 0.000 description 2
- 229940083898 barium chromate Drugs 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 229940043430 calcium compound Drugs 0.000 description 2
- 150000001674 calcium compounds Chemical class 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 235000011116 calcium hydroxide Nutrition 0.000 description 2
- 235000019398 chlorine dioxide Nutrition 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910006130 SO4 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
- 229910001626 barium chloride Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000011221 initial treatment Methods 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000004076 pulp bleaching Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000019635 sulfation Effects 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/12—Chloric acid
- C01B11/14—Chlorates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/12—Chloric acid
- C01B11/14—Chlorates
- C01B11/145—Separation; Crystallisation; Purification, After-treatment; Stabilisation by additives
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Removal Of Specific Substances (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9102502A FR2673423B1 (fr) | 1991-03-01 | 1991-03-01 | Procede d'elimination de sulfates contenus dans des solutions de chlorates alcalins et production desdits chlorates alcalins. |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO910888D0 NO910888D0 (no) | 1991-03-06 |
| NO910888L NO910888L (no) | 1992-09-02 |
| NO303573B1 true NO303573B1 (no) | 1998-08-03 |
Family
ID=9410262
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO910888A NO303573B1 (no) | 1991-03-01 | 1991-03-06 | FremgangsmÕte for fjerning av vesentlig kromfritt sulfat fra en kromat- og sulfatholdig vandig alkalimetallkloratoppl°sning, samt kontinuerlig fremgangsmÕte for fremstilling av alkalimetallklorat |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5176801A (fr) |
| CA (1) | CA2037718C (fr) |
| FI (1) | FI107810B (fr) |
| FR (1) | FR2673423B1 (fr) |
| NO (1) | NO303573B1 (fr) |
| SE (1) | SE504562C2 (fr) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE511987C2 (sv) * | 1993-03-09 | 2000-01-10 | Eka Chemicals Ab | Metod för avskiljning av sulfat från en vattenhaltig elektrolyt i en alkalimetallkloratprocess |
| SE512074C2 (sv) * | 1993-03-09 | 2000-01-24 | Eka Chemicals Ab | Metod att avlägsna kalciumjoner och kiselföreningar från vätska i en alkalimetallkloratprocess |
| FR2761357B1 (fr) * | 1997-03-28 | 1999-06-04 | Tredi | Production de gypse purifie a partir d'effluents industriels charges en sulfates |
| GB9815173D0 (en) * | 1998-07-13 | 1998-09-09 | Nat Power Plc | Process for the removal of sulphate ions |
| US7250144B2 (en) * | 2005-05-11 | 2007-07-31 | Tronox Llc | Perchlorate removal from sodium chlorate process |
| FR2951383B1 (fr) | 2009-10-20 | 2012-09-21 | Solvay | Procede pour la valorisation conjointe de sels solubles contenus dans un residu d'un procede industriel |
| WO2012129510A1 (fr) * | 2011-03-24 | 2012-09-27 | New Sky Energy, Inc. | Traitement d'électrolyse à base de sulfate avec commande de charge flexible et utilisation pour capturer du dioxyde de carbone |
| JP6236392B2 (ja) | 2012-10-01 | 2017-11-22 | 日本製紙株式会社 | 多硫化物製造用電解槽による連続電解方法及びそれを実施する電解装置 |
| CN113247921B (zh) * | 2021-05-20 | 2023-04-07 | 湖南恒光科技股份有限公司 | 一种氯碱与氯酸钠联合脱硝工艺 |
| CN114436311A (zh) * | 2022-02-24 | 2022-05-06 | 四川大学 | 一种钙芒硝石膏的深度提纯方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2450259B2 (de) * | 1974-10-23 | 1979-03-29 | Bayer Ag, 5090 Leverkusen | Verfahren zur Reinigung von Elektrolysesole |
| JPS5722117A (en) * | 1980-07-09 | 1982-02-05 | Toagosei Chem Ind Co Ltd | Purifying method of electrolytic brine |
| US4636376A (en) * | 1985-09-30 | 1987-01-13 | Ppg Industries, Inc. | Sulfate removal from alkali metal chlorate solutions |
| US4702805A (en) * | 1986-03-27 | 1987-10-27 | C-I-L Inc. | Production of sodium chlorate |
| US4747917A (en) * | 1987-03-02 | 1988-05-31 | Olin Corporation | Scale-free process for purifying concentrated alkali metal halide brines containing sulfate ions as an impurity |
-
1991
- 1991-03-01 FR FR9102502A patent/FR2673423B1/fr not_active Expired - Lifetime
- 1991-03-06 SE SE9100657A patent/SE504562C2/sv not_active IP Right Cessation
- 1991-03-06 NO NO910888A patent/NO303573B1/no not_active IP Right Cessation
- 1991-03-07 CA CA002037718A patent/CA2037718C/fr not_active Expired - Lifetime
- 1991-03-07 US US07/665,978 patent/US5176801A/en not_active Expired - Lifetime
- 1991-03-07 FI FI911137A patent/FI107810B/fi active
Also Published As
| Publication number | Publication date |
|---|---|
| FI107810B (fi) | 2001-10-15 |
| SE504562C2 (sv) | 1997-03-03 |
| SE9100657D0 (sv) | 1991-03-06 |
| NO910888D0 (no) | 1991-03-06 |
| FI911137A0 (fi) | 1991-03-07 |
| SE9100657L (sv) | 1992-09-02 |
| NO910888L (no) | 1992-09-02 |
| FI911137A (fi) | 1992-09-02 |
| CA2037718A1 (fr) | 1992-09-02 |
| CA2037718C (fr) | 1998-11-24 |
| FR2673423A1 (fr) | 1992-09-04 |
| FR2673423B1 (fr) | 1994-04-15 |
| US5176801A (en) | 1993-01-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0498484B1 (fr) | Procédé de production électrolytique de chlorate de métal alcalin et de produits chimiques auxiliaires | |
| AU600258B2 (en) | Production of sodium chlorate | |
| US4747917A (en) | Scale-free process for purifying concentrated alkali metal halide brines containing sulfate ions as an impurity | |
| CN108468065B (zh) | 一种氯酸钠和氯碱联合脱硝工艺 | |
| US4459188A (en) | Brine systems for chlor-alkali membrane cells | |
| US5126019A (en) | Purification of chlor-alkali membrane cell brine | |
| NO303573B1 (no) | FremgangsmÕte for fjerning av vesentlig kromfritt sulfat fra en kromat- og sulfatholdig vandig alkalimetallkloratoppl°sning, samt kontinuerlig fremgangsmÕte for fremstilling av alkalimetallklorat | |
| US4481088A (en) | Removal of chlorate from electrolyte cell brine | |
| CN108529562A (zh) | 一种氯酸钠母液膜法冷冻脱硝工艺 | |
| US5419818A (en) | Process for the production of alkali metal chlorate | |
| EP0427972B1 (fr) | Purification de saumure de cellule à membrane d'électrolyse de chlorure de métal alcalin | |
| FI101530B (fi) | Menetelmä sulfaatin erottamiseksi | |
| CA1325787C (fr) | Procede pour la production d'un chlorate de metal alcalin | |
| CA2181613C (fr) | Elimination des impuretes du chlorate de sodium | |
| US4159929A (en) | Chemical and electro-chemical process for production of alkali metal chlorates | |
| US7250144B2 (en) | Perchlorate removal from sodium chlorate process | |
| NO152645B (no) | Fremgangsmaate for fremstilling av klordioksyd | |
| US3690845A (en) | Crystallization of a metal chlorate from a chlorate-chloride containing solution | |
| Sedivy | Economy of salt in chloralkali manufacture | |
| CA2092651C (fr) | Methode de preparation d'hydroxydes de metaux alcalins | |
| US3407128A (en) | Process for the manufacture of chlorine, sodium hydroxide and hydrogen by the electrolysis of sodium chloride in mercury cells | |
| JPH0397880A (ja) | 水酸化ナトリウムの高濃度水溶液の製造方法 | |
| CA2226651C (fr) | Procede de production de dioxyde de chlore | |
| Kundu | Corrosion control of electrolyzer, anolyte tank and dechlorination tower tank of a chlor-alkali plant by an innovative method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MK1K | Patent expired |