NO303062B1 - Zeolitt NU87, fremgangsmÕte for dens fremstilling, samt anvendelse derav - Google Patents
Zeolitt NU87, fremgangsmÕte for dens fremstilling, samt anvendelse derav Download PDFInfo
- Publication number
- NO303062B1 NO303062B1 NO895174A NO895174A NO303062B1 NO 303062 B1 NO303062 B1 NO 303062B1 NO 895174 A NO895174 A NO 895174A NO 895174 A NO895174 A NO 895174A NO 303062 B1 NO303062 B1 NO 303062B1
- Authority
- NO
- Norway
- Prior art keywords
- zeolite
- less
- cation
- range
- formula
- Prior art date
Links
- 239000010457 zeolite Substances 0.000 title claims abstract description 65
- 229910021536 Zeolite Inorganic materials 0.000 title claims abstract description 57
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims abstract description 57
- 238000002360 preparation method Methods 0.000 title description 12
- 239000011541 reaction mixture Substances 0.000 claims abstract description 22
- 150000001768 cations Chemical class 0.000 claims abstract description 20
- -1 polymethylene Polymers 0.000 claims abstract description 16
- 238000002441 X-ray diffraction Methods 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims description 86
- 229910001868 water Inorganic materials 0.000 claims description 57
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 52
- 239000000463 material Substances 0.000 claims description 32
- 229910052782 aluminium Inorganic materials 0.000 claims description 22
- 238000006243 chemical reaction Methods 0.000 claims description 20
- 229910052710 silicon Inorganic materials 0.000 claims description 18
- 238000005342 ion exchange Methods 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 16
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 14
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 10
- 229910052783 alkali metal Inorganic materials 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 239000002243 precursor Substances 0.000 claims description 8
- 239000004411 aluminium Substances 0.000 claims description 7
- 238000001354 calcination Methods 0.000 claims description 6
- 239000011368 organic material Substances 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- 150000001340 alkali metals Chemical class 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 4
- 229910052787 antimony Inorganic materials 0.000 claims description 4
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 4
- 229910052785 arsenic Inorganic materials 0.000 claims description 4
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 4
- 229910052796 boron Inorganic materials 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 239000011651 chromium Substances 0.000 claims description 4
- 229910052733 gallium Inorganic materials 0.000 claims description 4
- 229910052732 germanium Chemical group 0.000 claims description 4
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 239000011733 molybdenum Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052720 vanadium Inorganic materials 0.000 claims description 4
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052726 zirconium Inorganic materials 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 150000001450 anions Chemical class 0.000 claims description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 39
- 239000000377 silicon dioxide Substances 0.000 abstract description 17
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 7
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 48
- 239000000243 solution Substances 0.000 description 46
- 239000000047 product Substances 0.000 description 41
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 31
- 238000004458 analytical method Methods 0.000 description 24
- 229910052708 sodium Inorganic materials 0.000 description 22
- 239000011734 sodium Substances 0.000 description 22
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 20
- 238000000634 powder X-ray diffraction Methods 0.000 description 15
- 238000003756 stirring Methods 0.000 description 14
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- 239000008367 deionised water Substances 0.000 description 11
- 229910021641 deionized water Inorganic materials 0.000 description 11
- 235000012239 silicon dioxide Nutrition 0.000 description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 238000002425 crystallisation Methods 0.000 description 9
- 230000008025 crystallization Effects 0.000 description 9
- 239000012535 impurity Substances 0.000 description 9
- 229910001220 stainless steel Inorganic materials 0.000 description 9
- 239000010935 stainless steel Substances 0.000 description 9
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 239000013078 crystal Substances 0.000 description 7
- 239000012297 crystallization seed Substances 0.000 description 7
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 235000019270 ammonium chloride Nutrition 0.000 description 6
- 239000000499 gel Substances 0.000 description 5
- 238000001179 sorption measurement Methods 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- MTCUAOILFDZKCO-UHFFFAOYSA-N Decamethonium Chemical compound C[N+](C)(C)CCCCCCCCCC[N+](C)(C)C MTCUAOILFDZKCO-UHFFFAOYSA-N 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 3
- 239000008119 colloidal silica Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 229950000405 decamethonium Drugs 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 229910001388 sodium aluminate Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 229910052680 mordenite Inorganic materials 0.000 description 2
- CRSOQBOWXPBRES-UHFFFAOYSA-N neopentane Chemical compound CC(C)(C)C CRSOQBOWXPBRES-UHFFFAOYSA-N 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- 230000006911 nucleation Effects 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- XDZILQXNIZCEDV-UHFFFAOYSA-N trimethyl-[8-(trimethylazaniumyl)octyl]azanium Chemical compound C[N+](C)(C)CCCCCCCC[N+](C)(C)C XDZILQXNIZCEDV-UHFFFAOYSA-N 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 1
- PQVHMOLNSYFXIJ-UHFFFAOYSA-N 4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]pyrazole-3-carboxylic acid Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C=1C(=NN(C=1)CC(N1CC2=C(CC1)NN=N2)=O)C(=O)O PQVHMOLNSYFXIJ-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical class [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 229910052908 analcime Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 150000002892 organic cations Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- 150000004684 trihydrates Chemical class 0.000 description 1
- PUOAFIKQSLOKQZ-UHFFFAOYSA-N trimethyl-[12-(trimethylazaniumyl)dodecyl]azanium Chemical compound C[N+](C)(C)CCCCCCCCCCCC[N+](C)(C)C PUOAFIKQSLOKQZ-UHFFFAOYSA-N 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB888829924A GB8829924D0 (en) | 1988-12-22 | 1988-12-22 | Zeolites |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO895174D0 NO895174D0 (no) | 1989-12-21 |
| NO895174L NO895174L (no) | 1990-06-25 |
| NO303062B1 true NO303062B1 (no) | 1998-05-25 |
Family
ID=10648938
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO895174A NO303062B1 (no) | 1988-12-22 | 1989-12-21 | Zeolitt NU87, fremgangsmÕte for dens fremstilling, samt anvendelse derav |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US5102641A (ru) |
| EP (1) | EP0377291B1 (ru) |
| JP (1) | JP3090455B2 (ru) |
| KR (1) | KR0139289B1 (ru) |
| CN (1) | CN1023789C (ru) |
| AT (1) | ATE129486T1 (ru) |
| AU (1) | AU623464B2 (ru) |
| CA (1) | CA2006537C (ru) |
| DE (1) | DE68924640T2 (ru) |
| DK (1) | DK665389A (ru) |
| ES (1) | ES2078910T3 (ru) |
| GB (2) | GB8829924D0 (ru) |
| GR (1) | GR3017896T3 (ru) |
| IN (1) | IN178932B (ru) |
| NO (1) | NO303062B1 (ru) |
| RU (1) | RU2107659C1 (ru) |
| ZA (1) | ZA899698B (ru) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8829923D0 (en) * | 1988-12-22 | 1989-02-15 | Ici Plc | Zeolites |
| US5178748A (en) * | 1988-12-22 | 1993-01-12 | Imperial Chemical Industries | Catalytic reactions using zeolites |
| GB9013859D0 (en) * | 1990-06-21 | 1990-08-15 | Ici Plc | Zeolites |
| GB9013916D0 (en) * | 1990-06-22 | 1990-08-15 | Ici Plc | Zeolites |
| US5192521A (en) * | 1991-11-19 | 1993-03-09 | Mobil Oil Corp. | Synthesis of crystalline silicate ZSM-12 |
| US5641393A (en) * | 1992-06-30 | 1997-06-24 | Chevron U.S.A. Inc. | High-silica zeolite SSZ-37 and methods of making and using same |
| US5254787A (en) * | 1992-09-08 | 1993-10-19 | Mobil Oil Corp. | Dehydrogenation and dehydrocyclization using a non-acidic NU-87 catalyst |
| US5405596A (en) * | 1993-06-29 | 1995-04-11 | Mobil Oil Corp. | Synthesis of crystalline ZSM-23 |
| US5332566A (en) * | 1993-07-16 | 1994-07-26 | Mobil Oil Corp. | Synthesis of crystalline ZSM-23 |
| CN1044356C (zh) * | 1995-05-17 | 1999-07-28 | 北京大学 | 洗涤粉中改性沸石助剂的制备方法 |
| NL1001553C2 (nl) * | 1995-11-02 | 1997-05-13 | Akzo Nobel Nv | Werkwijze voor de synthese van poreuze keramische materialen. |
| IT1283284B1 (it) * | 1996-03-21 | 1998-04-16 | Eniricerche Spa | Zeolite ers-10 e procedimento per la sua preparazione |
| FR2752567B1 (fr) * | 1996-08-23 | 1998-10-16 | Inst Francais Du Petrole | Zeolithe nu-88, son procede de preparation et ses applications catalytiques |
| FR2752568B1 (fr) * | 1996-08-23 | 1998-09-25 | Inst Francais Du Petrole | Zeolithe desaluminee de type structural nes, et son utilisation en dismutation et/ou transalkylation d'hydrocarbures alkylaromatiques |
| FR2765237B1 (fr) * | 1997-06-25 | 1999-12-03 | Inst Francais Du Petrole | Catalyseur a base de zeolithe nu-87 modifiee et procede pour l'amelioration du point d'ecoulement de charges contenant des paraffines |
| FR2765236B1 (fr) * | 1997-06-25 | 1999-12-03 | Inst Francais Du Petrole | Procede pour l'amelioration du point d'ecoulement de charges contenant des paraffines avec un catalyseur a base de zeolithe nu-87 modifiee |
| DE69910278T8 (de) * | 1998-02-26 | 2004-11-11 | Institut Français du Pétrole, Rueil-Malmaison | Katalysator enthaltend einen Zeolith aus der Gruppe NU-85, NU-86 und NU-87 und seine Verwendung für die Hydrierumwandlung von Kohlenwasserstoffeinsätzen |
| FR2775293B1 (fr) * | 1998-02-26 | 2000-11-17 | Inst Francais Du Petrole | Procede d'hydrocraquage de charges petrolieres hydrocarbonees en presence d'un catalyseur comprenant au moins une zeolithe nu-86 ou nu-87 |
| FR2775202B1 (fr) * | 1998-02-26 | 2000-03-24 | Inst Francais Du Petrole | Catalyseur comprenant une zeolithe choisie dans le groupe forme par les zeolithes nu-86 et nu-87 et son utilisation en hydroconversion de charges petrolieres hydrocarbonees |
| ES2207916T3 (es) * | 1998-02-26 | 2004-06-01 | Institut Francais Du Petrole | Procedimiento de hidrocraqueo de cargas petroliferas hidrocarbonadas en presencia de un catalizador que comprende al menos una zeolita nu-8 nu-86 o nu-87. |
| US5976491A (en) * | 1998-10-09 | 1999-11-02 | Exxon Research And Engineering Co. | Synthesis of and composition of ECR-40, large pore aluminophosphate |
| US6111158A (en) * | 1999-03-04 | 2000-08-29 | Uop Llc | Process for producing arylalkanes at alkylation conditions using a zeolite having a NES zeolite structure type |
| CN100546911C (zh) * | 2000-12-08 | 2009-10-07 | 埃克森美孚化学专利公司 | 结晶状分子筛 |
| US6471941B1 (en) * | 2001-05-29 | 2002-10-29 | Exxonmobil Research And Engineering Company | Synthetic porous crystalline material ITQ-13, its synthesis and use |
| JP4533993B2 (ja) * | 2004-08-17 | 2010-09-01 | 独立行政法人産業技術総合研究所 | 含酸素有機化合物の吸着剤 |
| KR100634535B1 (ko) | 2005-01-24 | 2006-10-13 | 삼성에스디아이 주식회사 | 탈황용 제올라이트 흡착제 및 그것의 제조방법 |
| US7682599B2 (en) * | 2008-10-10 | 2010-03-23 | Chevron U.S.A. Inc. | Method for preparing NES-type zeolites using novel structure directing agents |
| CN102211780B (zh) * | 2010-04-02 | 2012-10-17 | 中国石油化工股份有限公司 | 一种nu-87分子筛及其制备方法 |
| US8763364B2 (en) | 2011-04-18 | 2014-07-01 | Chevron U.S.A. Inc. | Treatment of cold start engine exhaust |
| CN102862996B (zh) * | 2011-07-07 | 2014-07-23 | 中国石油化工股份有限公司 | 一种低成本nu-87分子筛的制备方法 |
| US9493363B2 (en) | 2014-09-26 | 2016-11-15 | Chevron U.S.A. Inc. | Method for making NES framework type zeolites |
| JP6375204B2 (ja) * | 2014-10-29 | 2018-08-15 | 国立大学法人 東京大学 | Ｎｅｓ型ゼオライトの製造方法 |
| JP7318193B2 (ja) * | 2017-11-20 | 2023-08-01 | 東ソー株式会社 | 炭化水素吸着剤及び炭化水素の吸着方法 |
| RU2735849C1 (ru) * | 2019-05-27 | 2020-11-09 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный университет имени М.В. Ломоносова" (МГУ) | Способ получения алюмосиликатного цеолита со структурой mtw (типа zsm-12) |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1064890A (en) * | 1975-06-10 | 1979-10-23 | Mae K. Rubin | Crystalline zeolite, synthesis and use thereof |
| EP0042226B1 (en) * | 1980-06-12 | 1984-08-08 | Imperial Chemical Industries Plc | Zeolite eu-1 |
| EP0063436B1 (en) * | 1981-04-14 | 1986-12-30 | Imperial Chemical Industries Plc | Zeolites |
| JPS5926924A (ja) * | 1982-07-30 | 1984-02-13 | Res Assoc Petroleum Alternat Dev<Rapad> | 結晶性シリケートの製造方法 |
| DE3375689D1 (en) * | 1982-10-05 | 1988-03-24 | Ici Plc | Preparation of zeolites |
| DK84884A (da) * | 1983-03-07 | 1984-09-08 | Res Ass Petroleum Alternat Dev | Krystallinsk aluminiumsilicat og fremgangsmaade til fremstilling deraf |
| US4490342A (en) * | 1983-04-29 | 1984-12-25 | Mobil Oil Corporation | Synthesis of ZSM-23 zeolite |
| US4531012A (en) * | 1983-04-29 | 1985-07-23 | Mobil Oil Corporation | Organic template for synthesis of ZSM-23 zeolite |
| NZ207864A (en) * | 1983-04-29 | 1987-01-23 | Mobil Oil Corp | Zsm-23 zeolite |
| US4619820A (en) * | 1984-10-17 | 1986-10-28 | Mobil Oil Corporation | Synthesis of ZSM-23 zeolite and the product produced |
| GB8617651D0 (en) * | 1986-07-18 | 1986-08-28 | Ici Plc | Zeolite synthesis |
-
1988
- 1988-12-22 GB GB888829924A patent/GB8829924D0/en active Pending
-
1989
- 1989-12-12 AT AT89312988T patent/ATE129486T1/de not_active IP Right Cessation
- 1989-12-12 ES ES89312988T patent/ES2078910T3/es not_active Expired - Lifetime
- 1989-12-12 EP EP89312988A patent/EP0377291B1/en not_active Expired - Lifetime
- 1989-12-12 DE DE68924640T patent/DE68924640T2/de not_active Expired - Fee Related
- 1989-12-13 GB GB898928164A patent/GB8928164D0/en active Pending
- 1989-12-18 IN IN1205DE1989 patent/IN178932B/en unknown
- 1989-12-18 ZA ZA899698A patent/ZA899698B/xx unknown
- 1989-12-21 RU SU4742705A patent/RU2107659C1/ru active
- 1989-12-21 NO NO895174A patent/NO303062B1/no not_active IP Right Cessation
- 1989-12-21 AU AU47155/89A patent/AU623464B2/en not_active Ceased
- 1989-12-22 CA CA002006537A patent/CA2006537C/en not_active Expired - Fee Related
- 1989-12-22 CN CN89109839A patent/CN1023789C/zh not_active Expired - Fee Related
- 1989-12-22 KR KR1019890019325A patent/KR0139289B1/ko not_active IP Right Cessation
- 1989-12-22 US US07/453,318 patent/US5102641A/en not_active Expired - Lifetime
- 1989-12-22 DK DK665389A patent/DK665389A/da not_active Application Discontinuation
- 1989-12-22 JP JP01334685A patent/JP3090455B2/ja not_active Expired - Lifetime
-
1995
- 1995-10-26 GR GR950402950T patent/GR3017896T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DK665389D0 (da) | 1989-12-22 |
| GB8928164D0 (en) | 1990-02-14 |
| IN178932B (ru) | 1997-07-19 |
| US5102641A (en) | 1992-04-07 |
| EP0377291A1 (en) | 1990-07-11 |
| CN1023789C (zh) | 1994-02-16 |
| CA2006537A1 (en) | 1990-06-22 |
| AU4715589A (en) | 1990-06-28 |
| JPH02221115A (ja) | 1990-09-04 |
| DE68924640D1 (de) | 1995-11-30 |
| GB8829924D0 (en) | 1989-02-15 |
| KR900009439A (ko) | 1990-07-04 |
| NO895174L (no) | 1990-06-25 |
| EP0377291B1 (en) | 1995-10-25 |
| RU2107659C1 (ru) | 1998-03-27 |
| GR3017896T3 (en) | 1996-01-31 |
| CA2006537C (en) | 2000-10-03 |
| JP3090455B2 (ja) | 2000-09-18 |
| NO895174D0 (no) | 1989-12-21 |
| DK665389A (da) | 1990-06-23 |
| ATE129486T1 (de) | 1995-11-15 |
| CN1044078A (zh) | 1990-07-25 |
| AU623464B2 (en) | 1992-05-14 |
| ES2078910T3 (es) | 1996-01-01 |
| KR0139289B1 (ko) | 1998-04-27 |
| ZA899698B (en) | 1991-03-27 |
| DE68924640T2 (de) | 1996-04-18 |
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