NO301332B1 - Katalysatorsammensetning, fremgangsmåte for fremstilling derav og polymerisering av olefiner - Google Patents
Katalysatorsammensetning, fremgangsmåte for fremstilling derav og polymerisering av olefiner Download PDFInfo
- Publication number
- NO301332B1 NO301332B1 NO933078A NO933078A NO301332B1 NO 301332 B1 NO301332 B1 NO 301332B1 NO 933078 A NO933078 A NO 933078A NO 933078 A NO933078 A NO 933078A NO 301332 B1 NO301332 B1 NO 301332B1
- Authority
- NO
- Norway
- Prior art keywords
- catalyst composition
- group
- composition according
- polymerization
- metallocene
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 26
- 239000003054 catalyst Substances 0.000 title claims description 47
- 239000000203 mixture Substances 0.000 title claims description 43
- 238000000034 method Methods 0.000 title claims description 35
- 238000006116 polymerization reaction Methods 0.000 title claims description 23
- 238000002360 preparation method Methods 0.000 title description 15
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 28
- 239000005977 Ethylene Substances 0.000 claims description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- 125000004432 carbon atom Chemical group C* 0.000 claims description 17
- 229910052751 metal Inorganic materials 0.000 claims description 16
- 239000002184 metal Substances 0.000 claims description 16
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 13
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical class N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 150000004820 halides Chemical class 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 9
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 8
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 8
- 229910052726 zirconium Inorganic materials 0.000 claims description 8
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 7
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 claims description 6
- 239000012442 inert solvent Substances 0.000 claims description 6
- 239000003446 ligand Substances 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 239000003426 co-catalyst Substances 0.000 claims description 5
- 239000010703 silicon Chemical class 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical class [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical class [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 125000000129 anionic group Chemical group 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical class [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052732 germanium Inorganic materials 0.000 claims description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Chemical class 0.000 claims description 2
- 150000002899 organoaluminium compounds Chemical group 0.000 claims 1
- 150000002926 oxygen Chemical class 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract description 4
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 abstract description 3
- 239000012190 activator Substances 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 75
- 229920000642 polymer Polymers 0.000 description 41
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 37
- -1 IVA metals Chemical class 0.000 description 25
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 22
- 229920001577 copolymer Polymers 0.000 description 17
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 16
- 239000000243 solution Substances 0.000 description 16
- 239000002904 solvent Substances 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 11
- 239000000843 powder Substances 0.000 description 11
- 239000000155 melt Substances 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 9
- 239000004711 α-olefin Substances 0.000 description 9
- 239000004698 Polyethylene Substances 0.000 description 8
- 238000009826 distribution Methods 0.000 description 8
- 229920000573 polyethylene Polymers 0.000 description 8
- 239000011780 sodium chloride Substances 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 229920000098 polyolefin Polymers 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 229910052744 lithium Inorganic materials 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 5
- 239000012632 extractable Substances 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- SJXKHNOPPRPSLP-UHFFFAOYSA-L [Cl-].[Cl-].C(=CCC)C1=CC(C=C1)[Zr+2]C1C=C(C=C1)C=CCC Chemical compound [Cl-].[Cl-].C(=CCC)C1=CC(C=C1)[Zr+2]C1C=C(C=C1)C=CCC SJXKHNOPPRPSLP-UHFFFAOYSA-L 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 150000004703 alkoxides Chemical class 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 125000005842 heteroatom Chemical group 0.000 description 3
- 229910052809 inorganic oxide Inorganic materials 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910001507 metal halide Inorganic materials 0.000 description 3
- 150000005309 metal halides Chemical class 0.000 description 3
- MZRVEZGGRBJDDB-UHFFFAOYSA-N n-Butyllithium Substances [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 3
- 239000002685 polymerization catalyst Substances 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000002841 Lewis acid Substances 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- ADWDUVJLCGJBED-UHFFFAOYSA-L [Cl-].C(=CC)C1(C=CC=C1)[Zr+2]C1(C=CC=C1)C=CC.[Cl-] Chemical compound [Cl-].C(=CC)C1(C=CC=C1)[Zr+2]C1(C=CC=C1)C=CC.[Cl-] ADWDUVJLCGJBED-UHFFFAOYSA-L 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 150000001805 chlorine compounds Chemical group 0.000 description 2
- 239000012230 colorless oil Substances 0.000 description 2
- 239000012043 crude product Substances 0.000 description 2
- NUUNDIOOYFEMQN-UHFFFAOYSA-N cyclopenta-1,3-diene;sodium Chemical compound [Na].C1C=CC=C1 NUUNDIOOYFEMQN-UHFFFAOYSA-N 0.000 description 2
- 238000003795 desorption Methods 0.000 description 2
- LDYLHMQUPCBROZ-UHFFFAOYSA-N diethyl(methoxy)alumane Chemical compound [O-]C.CC[Al+]CC LDYLHMQUPCBROZ-UHFFFAOYSA-N 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000012685 gas phase polymerization Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 229910001502 inorganic halide Inorganic materials 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 150000007517 lewis acids Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000012968 metallocene catalyst Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 150000002902 organometallic compounds Chemical class 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 239000013557 residual solvent Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000003039 volatile agent Substances 0.000 description 2
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 2
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical class ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
- HMDSXECDIINLQM-UHFFFAOYSA-N 1-prop-1-enylcyclopenta-1,3-diene Chemical compound CC=CC1=CC=CC1 HMDSXECDIINLQM-UHFFFAOYSA-N 0.000 description 1
- MNVYDZWLJAOSSQ-UHFFFAOYSA-N 2-prop-1-enylcyclopenta-1,3-diene Chemical compound CC=CC1=CCC=C1 MNVYDZWLJAOSSQ-UHFFFAOYSA-N 0.000 description 1
- ZSPTYLOMNJNZNG-UHFFFAOYSA-N 3-Buten-1-ol Chemical compound OCCC=C ZSPTYLOMNJNZNG-UHFFFAOYSA-N 0.000 description 1
- 125000004975 3-butenyl group Chemical group C(CC=C)* 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- 241000349731 Afzelia bipindensis Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 125000005024 alkenyl aryl group Chemical group 0.000 description 1
- 125000004946 alkenylalkyl group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- BHELZAPQIKSEDF-UHFFFAOYSA-N allyl bromide Chemical compound BrCC=C BHELZAPQIKSEDF-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000005228 aryl sulfonate group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- UWAMTZZJXXCIOH-UHFFFAOYSA-M diethyl(phenoxy)alumane Chemical compound CC[Al+]CC.[O-]C1=CC=CC=C1 UWAMTZZJXXCIOH-UHFFFAOYSA-M 0.000 description 1
- HJXBDPDUCXORKZ-UHFFFAOYSA-N diethylalumane Chemical compound CC[AlH]CC HJXBDPDUCXORKZ-UHFFFAOYSA-N 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- AASUFOVSZUIILF-UHFFFAOYSA-N diphenylmethanone;sodium Chemical compound [Na].C=1C=CC=CC=1C(=O)C1=CC=CC=C1 AASUFOVSZUIILF-UHFFFAOYSA-N 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 150000002362 hafnium Chemical class 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- DLEDOFVPSDKWEF-UHFFFAOYSA-N lithium butane Chemical compound [Li+].CCC[CH2-] DLEDOFVPSDKWEF-UHFFFAOYSA-N 0.000 description 1
- IHLVCKWPAMTVTG-UHFFFAOYSA-N lithium;carbanide Chemical compound [Li+].[CH3-] IHLVCKWPAMTVTG-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000006263 metalation reaction Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- DVSDBMFJEQPWNO-UHFFFAOYSA-N methyllithium Chemical compound C[Li] DVSDBMFJEQPWNO-UHFFFAOYSA-N 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000012038 nucleophile Substances 0.000 description 1
- 230000000269 nucleophilic effect Effects 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000447 polyanionic polymer Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 150000003112 potassium compounds Chemical class 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000001226 reprecipitation Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- KSMWLICLECSXMI-UHFFFAOYSA-N sodium;benzene Chemical compound [Na+].C1=CC=[C-]C=C1 KSMWLICLECSXMI-UHFFFAOYSA-N 0.000 description 1
- OHUVHDUNQKJDKW-UHFFFAOYSA-N sodium;cyclopenta-1,3-diene Chemical compound [Na+].C=1C=C[CH-]C=1 OHUVHDUNQKJDKW-UHFFFAOYSA-N 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
- 229910003452 thorium oxide Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- YGRHYJIWZFEDBT-UHFFFAOYSA-N tridecylaluminum Chemical compound CCCCCCCCCCCCC[Al] YGRHYJIWZFEDBT-UHFFFAOYSA-N 0.000 description 1
- XBEXIHMRFRFRAM-UHFFFAOYSA-N tridodecylalumane Chemical compound CCCCCCCCCCCC[Al](CCCCCCCCCCCC)CCCCCCCCCCCC XBEXIHMRFRFRAM-UHFFFAOYSA-N 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/68—Vanadium, niobium, tantalum or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB929218805A GB9218805D0 (en) | 1992-09-04 | 1992-09-04 | Novel metallocene complexes |
| GB939305963A GB9305963D0 (en) | 1993-03-23 | 1993-03-23 | Novel metallocene complexes |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO933078D0 NO933078D0 (no) | 1993-08-30 |
| NO933078L NO933078L (no) | 1994-03-07 |
| NO301332B1 true NO301332B1 (no) | 1997-10-13 |
Family
ID=26301555
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO933078A NO301332B1 (no) | 1992-09-04 | 1993-08-30 | Katalysatorsammensetning, fremgangsmåte for fremstilling derav og polymerisering av olefiner |
| NO972953A NO972953D0 (no) | 1992-09-04 | 1997-06-24 | Kopolymer omfattende etylen og et C3-C8 <alfa>-olefin |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO972953A NO972953D0 (no) | 1992-09-04 | 1997-06-24 | Kopolymer omfattende etylen og et C3-C8 <alfa>-olefin |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US5714555A (fr) |
| EP (2) | EP0586167B1 (fr) |
| JP (1) | JP3397846B2 (fr) |
| KR (2) | KR100322932B1 (fr) |
| CN (1) | CN1087096A (fr) |
| AT (1) | ATE194630T1 (fr) |
| CA (1) | CA2105015C (fr) |
| DE (1) | DE69328996T2 (fr) |
| ES (1) | ES2148204T3 (fr) |
| FI (1) | FI112234B (fr) |
| GR (1) | GR3034346T3 (fr) |
| MY (1) | MY109833A (fr) |
| NO (2) | NO301332B1 (fr) |
| PT (1) | PT586167E (fr) |
Families Citing this family (71)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5498581A (en) * | 1994-06-01 | 1996-03-12 | Phillips Petroleum Company | Method for making and using a supported metallocene catalyst system |
| US6153716A (en) * | 1994-06-01 | 2000-11-28 | Phillips Petroleum Company | Polyethylenes containing a unique distribution of short chain branching |
| US5770755A (en) * | 1994-11-15 | 1998-06-23 | Phillips Petroleum Company | Process to prepare polymeric metallocenes |
| US5939347A (en) * | 1995-01-25 | 1999-08-17 | W.R. Grace & Co. -Conn. | Supported catalytic activator |
| US5670589A (en) * | 1995-02-08 | 1997-09-23 | Phillips Petroleum Company | Organoaluminoxy product, catalyst systems, preparation, and use |
| US5705578A (en) * | 1995-05-04 | 1998-01-06 | Phillips Petroleum Company | Method for making and using a supported metallocene catalyst system |
| US5631203A (en) * | 1995-05-04 | 1997-05-20 | Phillips Petroleum Company | Metallocene compounds and preparation thereof containing terminal alkynes |
| ES2157445T3 (es) * | 1995-05-09 | 2001-08-16 | Fina Research | Procedimiento para la preparacion y empleo de un catalizador de metaloceno-alumoxano soportado. |
| US5700748A (en) * | 1995-09-29 | 1997-12-23 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers comprising a bridging allyl-cyclodienyl ligand on a metal atom |
| FI104825B (fi) | 1996-01-26 | 2000-04-14 | Borealis As | Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö |
| US6114456A (en) * | 1996-11-25 | 2000-09-05 | Fina Research, S.A. | Medium density polyethylene compositions for film applications |
| US5854363A (en) * | 1997-01-08 | 1998-12-29 | Phillips Petroleum Company | (Omega-alkenyl) (cyclopentacarbyl) metallocene compounds |
| US5856547A (en) * | 1997-01-08 | 1999-01-05 | Phillips Petroleum Company | Organo omega-alkenyl cyclopentacarbyl silane compounds |
| US6329541B1 (en) | 1997-01-08 | 2001-12-11 | Phillips Petroleum Company | Organo omega-alkenyl cyclopentacarbyl silane-bridged metallocene compounds |
| JP2001525458A (ja) | 1997-12-08 | 2001-12-11 | アルベマール・コーポレーシヨン | 生産性を向上させた触媒組成物 |
| US6677265B1 (en) | 1997-12-08 | 2004-01-13 | Albemarle Corporation | Process of producing self-supported catalysts |
| US6551955B1 (en) | 1997-12-08 | 2003-04-22 | Albemarle Corporation | Particulate group 4 metallocene-aluminoxane catalyst compositions devoid of preformed support, and their preparation and their use |
| US6245868B1 (en) | 1998-05-29 | 2001-06-12 | Univation Technologies | Catalyst delivery method, a catalyst feeder and their use in a polymerization process |
| US6340651B1 (en) * | 1999-04-26 | 2002-01-22 | Phillips Petroleum Company | Multicyclic metallocycle metallocenes and their use |
| US6291382B1 (en) | 1999-05-24 | 2001-09-18 | Phillips Petroleum Company | Metallocenes, polymerization catalyst systems, their preparation, and use |
| DE19927766A1 (de) * | 1999-06-17 | 2000-12-21 | Basf Ag | Trägerkatalysator zur Olefinpolymerisation |
| US6420580B1 (en) | 1999-11-05 | 2002-07-16 | Univation Technologies, Llc | Catalyst compositions and method of polymerization therewith |
| CA2480006A1 (fr) * | 2002-04-12 | 2003-10-23 | Hong Yang | Complexes metalliques du groupe 4 azaborolyl, catalyseurs, et processus de polymerisation d'olefine |
| US7176158B2 (en) * | 2002-10-25 | 2007-02-13 | Exxonmobil Chemical Patents Inc. | Polymerization catalyst composition |
| US7119155B2 (en) | 2002-10-25 | 2006-10-10 | Exxonmobil Chemical Patents Inc. | Polymerized catalyst composition II |
| US7319083B2 (en) * | 2002-10-25 | 2008-01-15 | Exxonmobil Chemical Patents Inc. | Polymerized catalyst composition |
| US20040152591A1 (en) * | 2002-10-25 | 2004-08-05 | Guo-Xin Jin | Polymerized metallocene catalyst composition |
| WO2004094487A1 (fr) | 2003-03-21 | 2004-11-04 | Dow Global Technologies, Inc. | Procede de polymerisation d'olefines avec controle de la morphologie |
| US7148298B2 (en) * | 2004-06-25 | 2006-12-12 | Chevron Phillips Chemical Company, L.P. | Polymerization catalysts for producing polymers with low levels of long chain branching |
| US20050288461A1 (en) * | 2004-06-25 | 2005-12-29 | Jensen Michael D | Polymerization catalysts for producing polymers with low levels of long chain branching |
| DE602005020688D1 (de) | 2004-12-17 | 2010-05-27 | Dow Global Technologies Inc | Rheologiemodifizierte polyethylenzusammensetzungen |
| US7226886B2 (en) | 2005-09-15 | 2007-06-05 | Chevron Phillips Chemical Company, L.P. | Polymerization catalysts and process for producing bimodal polymers in a single reactor |
| EP1803747A1 (fr) | 2005-12-30 | 2007-07-04 | Borealis Technology Oy | Catalyseur de polymérisation à surface modifiée pour réduire la formation de gels dans des films |
| US7517939B2 (en) | 2006-02-02 | 2009-04-14 | Chevron Phillips Chemical Company, Lp | Polymerization catalysts for producing high molecular weight polymers with low levels of long chain branching |
| US7619047B2 (en) * | 2006-02-22 | 2009-11-17 | Chevron Phillips Chemical Company, Lp | Dual metallocene catalysts for polymerization of bimodal polymers |
| US7576163B2 (en) * | 2006-03-31 | 2009-08-18 | Chevron Phillips Chemical Company, Lp | Polymerization catalysts for producing polymers with low levels of long chain branching |
| CN101356226B (zh) | 2006-05-02 | 2012-09-05 | 陶氏环球技术有限责任公司 | 高密度聚乙烯组合物、其制备方法、由其制得的制品以及该制品的制备方法 |
| US7456244B2 (en) * | 2006-05-23 | 2008-11-25 | Dow Global Technologies | High-density polyethylene compositions and method of making the same |
| AU2007352541B2 (en) * | 2007-05-02 | 2013-03-28 | Dow Global Technologies Llc | High-density polyethylene compositions, method of making the same, injection molded articles made therefrom, and method of making such articles |
| US7981517B2 (en) * | 2007-08-28 | 2011-07-19 | Dow Global Technologies Inc. | Bituminous compositions and methods of making and using same |
| KR101077071B1 (ko) * | 2008-11-03 | 2011-10-26 | 에스케이이노베이션 주식회사 | 내충격성이 우수한 에틸렌 공중합체 |
| WO2010071798A1 (fr) | 2008-12-18 | 2010-06-24 | Univation Technologies, Llc | Procédé de traitement d'un lit d'ensemencement pour une réaction de polymérisation |
| CN102361925B (zh) | 2009-01-30 | 2013-08-14 | 陶氏环球技术有限责任公司 | 高密度聚乙烯组合物、其制备方法、由其制备的封闭器件、和制备所述封闭器件的方法 |
| MX2012000254A (es) | 2009-06-29 | 2012-01-25 | Chevron Philips Chemical Company Lp | El uso de catalizadores de depuracion de hidrogeno para controlar niveles de hidrogeno y peso molecular de polimero en un reactor de polimerizacion. |
| BRPI1014662B1 (pt) * | 2009-06-29 | 2021-06-29 | Chevron Phillips Chemical Company Lp | Processo de polimerização de olefina |
| US8937139B2 (en) | 2012-10-25 | 2015-01-20 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| US8895679B2 (en) | 2012-10-25 | 2014-11-25 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| WO2014105614A1 (fr) | 2012-12-28 | 2014-07-03 | Univation Technologies, Llc | Procédés consistant à intégrer la production d'aluminoxane dans la production de catalyseur |
| CN105121015A (zh) | 2013-01-14 | 2015-12-02 | 尤尼威蒂恩技术有限责任公司 | 制备高产率催化剂系统的方法 |
| US9034991B2 (en) | 2013-01-29 | 2015-05-19 | Chevron Phillips Chemical Company Lp | Polymer compositions and methods of making and using same |
| US8877672B2 (en) | 2013-01-29 | 2014-11-04 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| US9079993B1 (en) | 2014-05-22 | 2015-07-14 | Chevron Phillips Chemical Company Lp | High clarity low haze compositions |
| CN107660216B (zh) | 2015-05-08 | 2021-05-14 | 埃克森美孚化学专利公司 | 聚合方法 |
| KR102002983B1 (ko) | 2016-02-24 | 2019-07-23 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매 및 이를 이용한 폴리올레핀의 제조 방법 |
| WO2018063767A1 (fr) | 2016-09-27 | 2018-04-05 | Exxonmobil Chemical Patents Inc. | Processus de polymérisation |
| WO2018063764A1 (fr) | 2016-09-27 | 2018-04-05 | Exxonmobil Chemical Patents Inc. | Procédé de polymérisation |
| WO2018063765A1 (fr) | 2016-09-27 | 2018-04-05 | Exxonmobil Chemical Patents Inc. | Procédé de polymérisation |
| WO2018118155A1 (fr) | 2016-12-20 | 2018-06-28 | Exxonmobil Chemical Patents Inc. | Procédé de polymérisation |
| WO2019118073A1 (fr) | 2017-12-13 | 2019-06-20 | Exxonmobil Chemical Patents Inc. | Procédés de désactivation pour composants actifs à partir d'un procédé de polymérisation de polyoléfine en phase gazeuse |
| WO2019173030A1 (fr) | 2018-03-08 | 2019-09-12 | Exxonmobil Chemical Patents Inc. | Procédés de préparation et de surveillance d'un lit de germination pour le démarrage d'un réacteur de polymérisation |
| WO2019213227A1 (fr) | 2018-05-02 | 2019-11-07 | Exxonmobil Chemical Patents Inc. | Procédés de mise à l'échelle superieure d'une installation pilote à une installation de production de plus grande taille |
| US11459408B2 (en) | 2018-05-02 | 2022-10-04 | Exxonmobil Chemical Patents Inc. | Methods for scale-up from a pilot plant to a larger production facility |
| WO2020014138A1 (fr) | 2018-07-09 | 2020-01-16 | Exxonmobil Chemical Patents Inc. | Films coulés de polyéthylène et procédés de fabrication de tels films coulés de polyéthylène |
| CN112469556B (zh) | 2018-07-26 | 2023-05-02 | 埃克森美孚化学专利公司 | 多层泡沫膜及其制造方法 |
| US11649331B2 (en) | 2018-11-13 | 2023-05-16 | Exxonmobil Chemical Patents Inc. | Polyethylene blends and films |
| US20220025135A1 (en) | 2018-11-13 | 2022-01-27 | Exxonmobil Chemical Patents Inc. | Polyethylene Films |
| WO2020163079A1 (fr) | 2019-02-06 | 2020-08-13 | Exxonmobil Chemical Patents Inc. | Films et enveloppes de couche pour articles d'hygiène |
| KR102564398B1 (ko) * | 2019-11-20 | 2023-08-07 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매 및 이를 이용한 폴리에틸렌 공중합체의 제조 방법 |
| WO2021126458A1 (fr) | 2019-12-17 | 2021-06-24 | Exxonmobil Chemical Patents Inc. | Films constitués de mélanges de polyéthylène, destinés à améliorer les performances d'étanchéité et les propriétés mécaniques |
| WO2021183337A1 (fr) | 2020-03-12 | 2021-09-16 | Exxonmobil Chemical Patents Inc. | Films constitués de mélanges de polyéthylène pour une rigidité à la flexion améliorée et une résistance à la déchirure en md élevée |
| EP4330294A1 (fr) | 2021-04-30 | 2024-03-06 | ExxonMobil Chemical Patents Inc. | Procédés pour la transition entre différents catalyseurs de polymérisation dans un réacteur de polymérisation |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4363904A (en) * | 1979-06-18 | 1982-12-14 | Union Carbide Corporation | High tear strength polymers |
| US4701432A (en) * | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| JPH0777754B2 (ja) * | 1987-07-07 | 1995-08-23 | 三井石油化学工業株式会社 | ストレッチ包装用フィルム |
| DE3840772A1 (de) * | 1988-12-03 | 1990-06-07 | Hoechst Ag | Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente |
| US5126391A (en) * | 1990-04-27 | 1992-06-30 | Mitsubishi Petrochemical Co., Ltd. | Filler-containing stretched film |
| DE59104869D1 (de) * | 1990-11-12 | 1995-04-13 | Hoechst Ag | 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation. |
| ATE166077T1 (de) * | 1991-01-12 | 1998-05-15 | Targor Gmbh | Metallocen(co)polymere, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren; metallocene hierfür. |
| FR2680794A1 (fr) * | 1991-08-30 | 1993-03-05 | Bp Chemicals Snc | Procede de copolymerisation en phase gazeuse de l'ethylene avec l'octene-1. |
| TW318184B (fr) * | 1991-11-30 | 1997-10-21 | Hoechst Ag | |
| US5308817A (en) * | 1992-05-18 | 1994-05-03 | Fina Technology, Inc. | Metallocene catalyst component with good catalyst efficiency after aging |
| ATE165832T1 (de) * | 1992-08-03 | 1998-05-15 | Targor Gmbh | Verfahren zur herstellung eines olefinpolymers unter verwendung von metallocenen mit speziell substituierten indenylliganden |
-
1993
- 1993-08-23 DE DE69328996T patent/DE69328996T2/de not_active Expired - Fee Related
- 1993-08-23 PT PT93306665T patent/PT586167E/pt unknown
- 1993-08-23 AT AT93306665T patent/ATE194630T1/de not_active IP Right Cessation
- 1993-08-23 EP EP93306665A patent/EP0586167B1/fr not_active Expired - Lifetime
- 1993-08-23 ES ES93306665T patent/ES2148204T3/es not_active Expired - Lifetime
- 1993-08-23 EP EP99203278A patent/EP0969020A3/fr not_active Withdrawn
- 1993-08-27 CA CA002105015A patent/CA2105015C/fr not_active Expired - Fee Related
- 1993-08-27 MY MYPI93001745A patent/MY109833A/en unknown
- 1993-08-30 NO NO933078A patent/NO301332B1/no not_active IP Right Cessation
- 1993-08-31 FI FI933805A patent/FI112234B/fi active
- 1993-08-31 CN CN93118835A patent/CN1087096A/zh active Pending
- 1993-08-31 JP JP21656393A patent/JP3397846B2/ja not_active Expired - Fee Related
- 1993-08-31 KR KR1019930017236A patent/KR100322932B1/ko not_active IP Right Cessation
-
1995
- 1995-06-06 US US08/467,079 patent/US5714555A/en not_active Expired - Lifetime
- 1995-08-10 US US08/513,663 patent/US5714425A/en not_active Expired - Lifetime
-
1997
- 1997-06-24 NO NO972953A patent/NO972953D0/no not_active Application Discontinuation
-
2000
- 2000-09-06 GR GR20000402034T patent/GR3034346T3/el not_active IP Right Cessation
- 2000-11-28 KR KR1020000071247A patent/KR100295941B1/ko not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EP0969020A3 (fr) | 2000-01-19 |
| EP0586167B1 (fr) | 2000-07-12 |
| CA2105015A1 (fr) | 1994-03-05 |
| PT586167E (pt) | 2000-12-29 |
| FI933805A0 (fi) | 1993-08-31 |
| ES2148204T3 (es) | 2000-10-16 |
| KR940007063A (ko) | 1994-04-26 |
| EP0969020A2 (fr) | 2000-01-05 |
| NO933078D0 (no) | 1993-08-30 |
| US5714555A (en) | 1998-02-03 |
| KR100322932B1 (ko) | 2002-05-13 |
| FI112234B (fi) | 2003-11-14 |
| ATE194630T1 (de) | 2000-07-15 |
| DE69328996T2 (de) | 2000-11-16 |
| NO972953L (no) | 1994-03-07 |
| DE69328996D1 (de) | 2000-08-17 |
| CN1087096A (zh) | 1994-05-25 |
| KR100295941B1 (ko) | 2001-07-03 |
| GR3034346T3 (en) | 2000-12-29 |
| CA2105015C (fr) | 2007-04-03 |
| US5714425A (en) | 1998-02-03 |
| FI933805A (fi) | 1994-03-05 |
| EP0586167A1 (fr) | 1994-03-09 |
| NO933078L (no) | 1994-03-07 |
| MY109833A (en) | 1997-08-30 |
| JP3397846B2 (ja) | 2003-04-21 |
| NO972953D0 (no) | 1997-06-24 |
| JPH06172415A (ja) | 1994-06-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| NO301332B1 (no) | Katalysatorsammensetning, fremgangsmåte for fremstilling derav og polymerisering av olefiner | |
| US5747405A (en) | Catalyst compositions and process for preparing polyolefins | |
| US4701432A (en) | Supported polymerization catalyst | |
| US5077255A (en) | New supported polymerization catalyst | |
| US8569194B2 (en) | Catalyst composition for polymerization of olefins, polymerization process using the same, and method for its preparation | |
| US6034027A (en) | Borabenzene based olefin polymerization catalysts containing a group 3-10 metal | |
| JP2001524162A (ja) | オレフィンポリマー製造用触媒 | |
| NO174106B (no) | Katalysatorer for polymerisering av olefiner | |
| NO176764B (no) | Fast katalysator, prepolymerpartikler, fremgangsmåter for fremstilling av katalysatoren og prepolymerpartiklene samt fremgangsmåte for polymerisasjon av olefiner | |
| JP2004526818A (ja) | デュアルサイトのオレフィン重合触媒組成物 | |
| CN106795229B (zh) | 金属茂-负载型催化剂以及使用该催化剂制备聚烯烃的方法 | |
| NO318716B1 (no) | Katalysatorsystem for polymerisering | |
| US6500906B1 (en) | Olefin polymerization chelate catalyst and olefin polymerization method using the same | |
| US6992034B2 (en) | Catalyst component for olefin polymerization | |
| EP0722955B1 (fr) | Procédé de polymérisation d'oléfines | |
| RU2126424C1 (ru) | Каталитическая композиция для использования при полимеризации олефинов | |
| EP0641809A1 (fr) | Copolymères d'éthylène | |
| US6872683B2 (en) | Method for preparing chelated catalyst for olefin polymerization | |
| CA2219816C (fr) | Complexes metalliques d'azaborolinyle utilises comme catalyseurs de polymerisation d'olefines | |
| NO169015B (no) | Understoettet olefinpolymerisasjonskatalysator, fremgangsmaate for fremstilling derav og fremgangsmaate for fremstilling av polymerer av etylen og kopolymerer av etylen og alfa-olefiner eller di-olefiner | |
| EP1502924A1 (fr) | Catalyseurs pour la préparation de polyéthylène ayant une activité élevée préparés avec des composés phosphates et/ou phosphites |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM1K | Lapsed by not paying the annual fees |
Free format text: LAPSED IN FEBRUARY 2003 |