NO20003214L - FremgangsmÕte for fremstilling av elastomerer - Google Patents

FremgangsmÕte for fremstilling av elastomerer

Info

Publication number
NO20003214L
NO20003214L NO20003214A NO20003214A NO20003214L NO 20003214 L NO20003214 L NO 20003214L NO 20003214 A NO20003214 A NO 20003214A NO 20003214 A NO20003214 A NO 20003214A NO 20003214 L NO20003214 L NO 20003214L
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NO
Norway
Prior art keywords
charge
partial
acceptor
solution
donor
Prior art date
Application number
NO20003214A
Other languages
English (en)
Other versions
NO20003214D0 (no
Inventor
Karl-Heinz Aleksand Starzewski
Martin Hoch
Original Assignee
Bayer Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Ag filed Critical Bayer Ag
Publication of NO20003214L publication Critical patent/NO20003214L/no
Publication of NO20003214D0 publication Critical patent/NO20003214D0/no

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02Monomers containing only one unsaturated aliphatic radical
    • C08F12/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63908Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/06Cp analog where at least one of the carbon atoms of the non-coordinating part of the condensed ring is replaced by a heteroatom
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/07Heteroatom-substituted Cp, i.e. Cp or analog where at least one of the substituent of the Cp or analog ring is or contains a heteroatom
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Elastomerer med en krystallinitetstopp og smeltetemperatur over 40°C, i tillegg til å ha en amorf struktur og en lav glassomvandlmgstemperatur Tg målt ifølge DSC, kan fremstilles ved (ko)polymerisasjon av monomerer fra gruppen av C2-Cg-o: olefiner, C,t-Cij diolefiner og andre monomerer i en masse, løsning, høytemperaturløsning, slurry eller gassfase, hvorved metallocenforbindelser eller n-kompleksforbindelser med formel (I) eller (XHI) anvendes, hvori Cpl og CpII er karbanioner med en struktur som inneholder cyklopentadienyl, TI! og Ttll er ladede eller elektrisk nøytrale K-systemer, D er et donoratom og A er et akseptoratom, hvorved D og A er bundet ved en reversibel koordinert binding, donorgruppen far en positiv (delvis) ladning og akseptorgruppen far en negativ (delvis) ladning, M står for et overgangsmetall i det periodiske system av elementer (Mendeleev) som inkluderer latanoider og aktinoider, og X er en anionekvivalens som representerer tallet O, 1,2,3 eller 4, avhengig av ladningen til M.
NO20003214A 1997-12-22 2000-06-21 FremgangsmÕte for fremstilling av elastomerer NO20003214D0 (no)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19757218A DE19757218A1 (de) 1997-12-22 1997-12-22 Verfahren zur Herstellung von Elastomeren
PCT/EP1998/008012 WO1999032532A1 (de) 1997-12-22 1998-12-09 Verfahren zur herstellung von elastomeren

Publications (2)

Publication Number Publication Date
NO20003214L true NO20003214L (no) 2000-06-21
NO20003214D0 NO20003214D0 (no) 2000-06-21

Family

ID=7852982

Family Applications (1)

Application Number Title Priority Date Filing Date
NO20003214A NO20003214D0 (no) 1997-12-22 2000-06-21 FremgangsmÕte for fremstilling av elastomerer

Country Status (9)

Country Link
EP (1) EP1042378A1 (no)
JP (1) JP2001527099A (no)
KR (1) KR20010033431A (no)
CN (1) CN1282343A (no)
AU (1) AU1760299A (no)
CA (1) CA2315651A1 (no)
DE (1) DE19757218A1 (no)
NO (1) NO20003214D0 (no)
WO (1) WO1999032532A1 (no)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19915108A1 (de) * 1999-04-01 2000-10-05 Bayer Ag Geträgerte Katalysatoren mit einer Donor-Akzeptor-Wechselwirkung
DE10244214A1 (de) 2002-09-23 2004-04-01 Bayer Ag Übergangsmetallverbindungen mit Donor-Akzeptor-Wechselwirkung und speziellem Substitutionsmuster
CN101235106B (zh) * 2008-01-31 2010-09-08 河南省科学院化学研究所有限公司 茂金属催化剂的制备方法及其在乙丙橡胶生产中的应用
CN104448090B (zh) * 2014-12-19 2017-02-22 无锡市人民医院 一种侧链含二茂铁共聚物的制备方法
CN106008777B (zh) * 2016-06-20 2018-12-11 安徽欧凯密封件有限公司 一种稀土催化体系制备三元乙丙橡胶的方法
CN115501916B (zh) * 2022-09-22 2023-08-25 中化泉州石化有限公司 一种用于乙烯三聚的催化剂组合物及其应用

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0590486A3 (en) * 1992-09-24 1994-08-24 Idemitsu Kosan Co Polymerization catalysts and process for producing polymers
EP0638593A1 (en) * 1993-08-02 1995-02-15 Shell Internationale Researchmaatschappij B.V. Catalyst compositions
DE4420456A1 (de) * 1994-06-13 1995-12-14 Hoechst Ag Übergangsmetallverbindung
US5554775A (en) * 1995-01-17 1996-09-10 Occidental Chemical Corporation Borabenzene based olefin polymerization catalysts
US6174974B1 (en) * 1996-07-05 2001-01-16 Bayer Aktiengesellschaft Method for producing thermoplastic elastomers

Also Published As

Publication number Publication date
DE19757218A1 (de) 1999-06-24
EP1042378A1 (de) 2000-10-11
CN1282343A (zh) 2001-01-31
NO20003214D0 (no) 2000-06-21
WO1999032532A1 (de) 1999-07-01
JP2001527099A (ja) 2001-12-25
AU1760299A (en) 1999-07-12
CA2315651A1 (en) 1999-07-01
KR20010033431A (ko) 2001-04-25

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