NL9201970A - Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen. - Google Patents

Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen. Download PDF

Info

Publication number
NL9201970A
NL9201970A NL9201970A NL9201970A NL9201970A NL 9201970 A NL9201970 A NL 9201970A NL 9201970 A NL9201970 A NL 9201970A NL 9201970 A NL9201970 A NL 9201970A NL 9201970 A NL9201970 A NL 9201970A
Authority
NL
Netherlands
Prior art keywords
group
indenyl
grams
polymerization
ethylene
Prior art date
Application number
NL9201970A
Other languages
English (en)
Dutch (nl)
Original Assignee
Dsm Nv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=19861509&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=NL9201970(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Dsm Nv filed Critical Dsm Nv
Priority to NL9201970A priority Critical patent/NL9201970A/nl
Priority to JP51194394A priority patent/JP3419456B2/ja
Priority to ES94901064T priority patent/ES2203621T3/es
Priority to BR9307420-4A priority patent/BR9307420A/pt
Priority to CA002149026A priority patent/CA2149026A1/en
Priority to DE69333114T priority patent/DE69333114T2/de
Priority to PCT/NL1993/000229 priority patent/WO1994011406A1/en
Priority to AU55774/94A priority patent/AU677026B2/en
Priority to EP94901064A priority patent/EP0668865B1/en
Priority to RU95112455A priority patent/RU2128183C1/ru
Priority to MYPI93002351A priority patent/MY130143A/en
Priority to CN93112942A priority patent/CN1088212A/zh
Publication of NL9201970A publication Critical patent/NL9201970A/nl
Priority to NO951848A priority patent/NO306782B1/no
Priority to FI952266A priority patent/FI114798B/fi
Priority to US08/439,449 priority patent/US5646322A/en
Priority to US08/812,675 priority patent/US5990253A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
NL9201970A 1992-11-11 1992-11-11 Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen. NL9201970A (nl)

Priority Applications (16)

Application Number Priority Date Filing Date Title
NL9201970A NL9201970A (nl) 1992-11-11 1992-11-11 Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
RU95112455A RU2128183C1 (ru) 1992-11-11 1993-11-03 Инденильные соединения, способ полимеризации олефина, полиолефин
PCT/NL1993/000229 WO1994011406A1 (en) 1992-11-11 1993-11-03 Indenyl compounds and catalyst components for the polymerization of olefins
EP94901064A EP0668865B1 (en) 1992-11-11 1993-11-03 Indenyl compounds and catalyst components for the polymerization of olefins
BR9307420-4A BR9307420A (pt) 1992-11-11 1993-11-03 Compostos idenila e componentes catalisadores para a polimerização de olefinas
CA002149026A CA2149026A1 (en) 1992-11-11 1993-11-03 Indenyl compounds and catalyst components for the polymerization of olefins
DE69333114T DE69333114T2 (de) 1992-11-11 1993-11-03 Indenylverbindungen und katalysatorbestandteile fur olefinpolymerisation
JP51194394A JP3419456B2 (ja) 1992-11-11 1993-11-03 インデニル化合物及びオレフィンの重合のための触媒成分
AU55774/94A AU677026B2 (en) 1992-11-11 1993-11-03 Indenyl compounds and catalyst components for the polymerization of olefins
ES94901064T ES2203621T3 (es) 1992-11-11 1993-11-03 Compuestos de indenilo y componentes cataliticos para la polimerizacion de olefinas.
CN93112942A CN1088212A (zh) 1992-11-11 1993-11-10 用于烯烃聚合的茚基化合物和催化剂组分
MYPI93002351A MY130143A (en) 1992-11-11 1993-11-10 Indenyl compounds and catalyst components for the polymerisation of olefins
NO951848A NO306782B1 (no) 1992-11-11 1995-05-10 Indenylforbindelser og katalysatorkomponenter for polymerisasjon av olefiner
FI952266A FI114798B (fi) 1992-11-11 1995-05-10 Indenyyliyhdisteitä ja katalyyttiainesosia olefiinien polymeroimiseksi
US08/439,449 US5646322A (en) 1992-11-11 1995-05-11 Indenyl compounds and catalyst components for the polymerization of olefins
US08/812,675 US5990253A (en) 1992-11-11 1997-03-10 Indenyl compounds and catalyst components for the polymerization of olefins

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL9201970A NL9201970A (nl) 1992-11-11 1992-11-11 Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
NL9201970 1992-11-11

Publications (1)

Publication Number Publication Date
NL9201970A true NL9201970A (nl) 1994-06-01

Family

ID=19861509

Family Applications (1)

Application Number Title Priority Date Filing Date
NL9201970A NL9201970A (nl) 1992-11-11 1992-11-11 Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.

Country Status (15)

Country Link
US (2) US5646322A (fi)
EP (1) EP0668865B1 (fi)
JP (1) JP3419456B2 (fi)
CN (1) CN1088212A (fi)
AU (1) AU677026B2 (fi)
BR (1) BR9307420A (fi)
CA (1) CA2149026A1 (fi)
DE (1) DE69333114T2 (fi)
ES (1) ES2203621T3 (fi)
FI (1) FI114798B (fi)
MY (1) MY130143A (fi)
NL (1) NL9201970A (fi)
NO (1) NO306782B1 (fi)
RU (1) RU2128183C1 (fi)
WO (1) WO1994011406A1 (fi)

Families Citing this family (68)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
NL9201970A (nl) * 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
US5491207A (en) * 1993-12-14 1996-02-13 Exxon Chemical Patents Inc. Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system
WO1995016716A1 (en) * 1993-12-14 1995-06-22 Exxon Chemical Patents Inc. Process for producing elastomers with an indenyl metallocene catalyst system
US5594080A (en) 1994-03-24 1997-01-14 Leland Stanford, Jr. University Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor
NL9400758A (nl) * 1994-05-06 1995-12-01 Dsm Nv Werkwijze voor de bereiding van een hoogmoleculair polymeer uit etheen, alfa-olefine en eventueel dieen.
US5541272A (en) * 1994-06-03 1996-07-30 Phillips Petroleum Company High activity ethylene selective metallocenes
IT1273662B (it) 1994-07-20 1997-07-09 Spherilene Srl Procedimento per la preparazione di polimeri amorfi del propiline'
DE69500979T2 (de) * 1994-07-22 1998-03-05 Mitsubishi Chem Corp Katalysatorbestandteil für alpha-Olefinpolymerisation und Verfahren zur Herstellung von alpha-Olefinpolymeren unter Anwendung desselben
ES2116188B1 (es) * 1994-12-30 1999-04-01 Repsol Quimica Sa Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales.
IT1275408B (it) 1995-05-30 1997-08-05 Spherilene Spa Composti metallocenici bis-indenilici pontanti procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
US5780659A (en) * 1996-03-29 1998-07-14 Phillips Petroleum Company Substituted indenyl unbridged metallocenes
US6329541B1 (en) * 1997-01-08 2001-12-11 Phillips Petroleum Company Organo omega-alkenyl cyclopentacarbyl silane-bridged metallocene compounds
FI971565A (fi) 1997-04-14 1998-10-15 Borealis As Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä
NL1006346C2 (nl) * 1997-06-18 1998-12-21 Dsm Nv Werkwijze voor de bereiding van polyolefines bij hoge temperatuur met behulp van Zr-metallocenen.
DE19809159A1 (de) * 1998-03-04 1999-09-09 Bayer Ag Metallorganische Verbindungen
DE19809160A1 (de) * 1998-03-04 1999-09-09 Bayer Ag Ataktische Propylen-(Co)Polymere
ES2188047T3 (es) 1998-03-09 2003-06-16 Basell Polyolefine Gmbh Compuestos de circonoceno puenteados, procedimiento para su preparacion y su empleo como componentes catalizadores en la polimerizacion de olefinas.
EP0941997B1 (en) * 1998-03-09 2002-12-18 Basell Polyolefine GmbH Bridged zirconocene compounds, process for their preparation, and their use as catalyst components in the polymerization of olefins
IL137036A0 (en) 1998-11-18 2001-06-14 Montell Technology Company Bv Bis(tetrahydro-indenyl) metallocenes as olefin-polymerisation-catalyst
ES2197714T3 (es) 1998-11-18 2004-01-01 Basell Polyolefine Gmbh Metalocenos de eslabon metileno como componentes cataliticos de la polimerizacion de olefinas.
ATE371636T1 (de) * 1999-01-21 2007-09-15 Boulder Scient Co Synthese und isomerisierung von 1,2-bis(indenyl)- ethanen
DE19908938A1 (de) 1999-03-02 2000-09-07 Targor Gmbh Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
EP1059300A1 (en) * 1999-06-11 2000-12-13 Dsm N.V. Indenyl compounds for the polymerisation of olefins
US6342622B1 (en) 1999-06-11 2002-01-29 Dsm B.V. Indenyl compounds for the polymerization of olefins
EP1059299B1 (en) * 1999-06-11 2003-12-17 SABIC Polypropylenes B.V. Process for the polymerisation of olefins in the presence of indenyl compounds
US6482905B1 (en) * 1999-08-16 2002-11-19 Phillips Petroleum Company Unsymmetric unbridged bis-indenyl metallocenes and their use
IT1314261B1 (it) * 1999-12-03 2002-12-06 Enichem Spa Composti metallocenici pontati, processo per la loro preparazione eloro uso come catalizzatori per la polimerizzazione di olefine.
DE10003581A1 (de) * 2000-01-28 2001-08-02 Bayer Ag Metallorganische Verbindungen mit anellierten Indenyl Liganden
DE10127926A1 (de) 2001-06-08 2002-12-12 Bayer Ag 1,3-disubstituierte Indenkomplexe
US6936675B2 (en) * 2001-07-19 2005-08-30 Univation Technologies, Llc High tear films from hafnocene catalyzed polyethylenes
BR0211288A (pt) 2001-07-19 2004-08-10 Univation Tech Llc Sistemas catalisadores de metaloceno mistos contendo um incorporador de comonÈmero fraco e um incorporador de comonÈmero bom
BR0211286B1 (pt) 2001-07-19 2012-10-02 filmes com propriedades fìsicas aperfeiçoadas.
WO2003008465A2 (en) * 2001-07-19 2003-01-30 Univation Technologies, Llc Low comonomer incorporating metallocene catalyst compounds
US6562921B1 (en) * 2001-10-12 2003-05-13 Univation Technologies, Llc Catalyst precursor compound and olefin polymerization process using same
EP1574525B1 (en) * 2004-03-12 2007-05-02 Saudi Basic Industries Corporation Catalyst composition for polymerization of olefins and polymerization process using the same
US7312283B2 (en) * 2005-08-22 2007-12-25 Chevron Phillips Chemical Company Lp Polymerization catalysts and process for producing bimodal polymers in a single reactor
US7226886B2 (en) * 2005-09-15 2007-06-05 Chevron Phillips Chemical Company, L.P. Polymerization catalysts and process for producing bimodal polymers in a single reactor
US7619047B2 (en) * 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
US9000200B2 (en) * 2011-12-19 2015-04-07 Saudi Basic Industries Corporation Process for the preparation of metallocene complexes
CN104093730A (zh) * 2011-12-19 2014-10-08 沙特基础工业公司 用于制备茂金属络合物的方法
EP2610269A1 (en) 2011-12-28 2013-07-03 Saudi Basic Industries Corporation Catalyst composition and method for preparing the same
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
WO2014168373A1 (en) * 2013-04-08 2014-10-16 Hanwha Chemical Corporation Metallocene catalyst system comprising antistatic agent and method for preparing polyolefin using the same
KR101584350B1 (ko) * 2013-04-08 2016-01-13 한화케미칼 주식회사 대전 방지제를 포함하는 메탈로센 촉매 시스템 및 이를 이용한 폴리올레핀의 제조 방법
EP2832739A1 (en) 2013-08-01 2015-02-04 Saudi Basic Industries Corporation Bridged metallocene complex for olefin polymerization
KR20160049541A (ko) 2013-08-30 2016-05-09 사우디 베이식 인더스트리즈 코포레이션 올레핀 중합용 가교된 메탈로센 착물
SG10201800002WA (en) 2014-02-11 2018-02-27 Univation Tech Llc Producing polyolefin products
EP3034546B1 (en) 2014-12-17 2019-10-16 SABIC Global Technologies B.V. A process for the preparation of a block copolymer comprising a first polyolefin block and a second polymer block
EP3034545B1 (en) 2014-12-17 2020-11-04 SABIC Global Technologies B.V. A process for the preparation of a graft copolymer comprising a polyolefin main chain and one or a multiple polymer side chains and the products obtained therefrom
EP3034547B1 (en) 2014-12-17 2019-10-09 SABIC Global Technologies B.V. A process for the preparation of a block copolymer comprising a first polyolefin block and a second polymer block
EP3034544B1 (en) 2014-12-17 2019-10-16 SABIC Global Technologies B.V. A process for the preparation of a graft copolymer comprising a polyolefin main chain and one or a multiple polymer side chains
EP3037437A1 (en) 2014-12-23 2016-06-29 SABIC Global Technologies B.V. Process for the preparation of a polyolefin having one or multiple end-functionalized branches.
EP3037438A1 (en) 2014-12-23 2016-06-29 SABIC Global Technologies B.V. Process for the preparation of a branched polyolefin
KR102064412B1 (ko) 2016-07-07 2020-01-09 주식회사 엘지화학 폴리올레핀 제조용 메탈로센 촉매의 제조방법
WO2018185176A1 (en) 2017-04-04 2018-10-11 Sabic Global Technologies B.V. Dihydrocarbyl-silyl-bridged-substituted cyclopentadienyl metallocene complexes for olefin polymerization
EP3606930B1 (en) * 2017-04-04 2021-03-31 SABIC Global Technologies B.V. Dihydrocarbyl-silyl-bridged-1.3 disubstituted-2-indenyl metallocene complexes for olefin polymerization
CN110650978B (zh) 2017-04-04 2022-09-23 Sabic环球技术有限责任公司 用于烯烃聚合的二甲基-甲硅烷基-桥连的-1-取代-2-茚基茂金属复合物
US11401360B2 (en) 2017-12-22 2022-08-02 Sabic Global Technologies B.V. Process for preparation of amorphous polyolefinic ionomers
WO2019122455A1 (en) 2017-12-22 2019-06-27 Sabic Global Technologies B.V. Process for preparation of amorphous functionalized olefin copolymer
EP3743431A1 (en) 2018-01-24 2020-12-02 SABIC Global Technologies B.V. 1,2-phenylene bridged 1-indenyl-2-indenyl metallocene complexes for olefin polymerisation
RU2666736C1 (ru) * 2018-05-30 2018-09-12 Публичное акционерное общество "Нефтяная компания "Роснефть" (ПАО "НК "Роснефть") Способ получения синтетических высоковязких полиальфаолефиновых базовых масел
EP4028437A1 (en) 2019-09-10 2022-07-20 SABIC Global Technologies, B.V. Compounds for use in catalyst compositions for the production of polyolefins
WO2021052797A1 (en) 2019-09-20 2021-03-25 Sabic Global Technologies B.V. Compounds for use in catalyst compositions for the production of polyolefins
EP4110834B1 (en) * 2020-02-24 2024-04-03 ExxonMobil Chemical Patents Inc. Ansa-bis(inden-2-yl) catalysts for producing vinylidene-terminated polyalphaolefins

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2322883A1 (fr) * 1975-09-02 1977-04-01 Michelin & Cie Elastomeres du type e p t, et articles comportant de tels elastomeres
CA1257863A (en) * 1985-10-17 1989-07-25 Vaclav G. Zboril SOLUTION PROCESS FOR THE PREPARATION OF POLYMERS OF .alpha.-OLEFINS
DE3752260T2 (de) * 1986-09-24 1999-09-02 Mitsui Chemicals Verfahren zur Olefinpolymerisation
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5017714A (en) * 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
IL89525A0 (en) * 1988-03-21 1989-09-10 Exxon Chemical Patents Inc Silicon-bridged transition metal compounds
US5120867A (en) * 1988-03-21 1992-06-09 Welborn Jr Howard C Silicon-bridged transition metal compounds
US4871705A (en) * 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
US5001205A (en) * 1988-06-16 1991-03-19 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst
KR930002411B1 (ko) * 1988-09-14 1993-03-30 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 벤젠불용성 유기알루미늄 옥시화합물 및 그 제조방법
DE3840772A1 (de) * 1988-12-03 1990-06-07 Hoechst Ag Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente
IL95278A0 (en) * 1989-08-03 1991-06-30 Exxon Chemical Patents Inc Very high molecular weight polyethylene
US5191042A (en) * 1989-09-06 1993-03-02 Exxon Chemical Patents Inc. Process for preparing alpha-olefin copolymers having a narrow MWD and broad compositional distribution
ES2087145T3 (es) * 1989-10-10 1996-07-16 Fina Technology Catalizadores metalocenos con acidos de lewis y alkilo-aluminios.
US5098635A (en) * 1989-11-09 1992-03-24 Copolymer Rubber & Chemical Corporation Process for manufacturing friable rubber bales
ES2072598T3 (es) * 1990-01-02 1995-07-16 Exxon Chemical Patents Inc Catalizadores ionicos de metaloceno soportados para la polimerizacion de olefinas.
JP3115595B2 (ja) * 1990-07-24 2000-12-11 三井化学株式会社 α―オレフィンの重合触媒及びそれを用いたポリ―α―オレフィンの製造方法
DE59107926D1 (de) * 1990-11-12 1996-07-18 Hoechst Ag Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
ES2071888T3 (es) * 1990-11-12 1995-07-01 Hoechst Ag Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas.
DE4039451A1 (de) * 1990-12-11 1992-06-17 Hoechst Ag Metallocene mit bicyclischen cyclopentadienderivaten als liganden, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren
ATE136040T1 (de) * 1991-05-27 1996-04-15 Hoechst Ag Verfahren zur herstellung von polyolefinen mit breiter molmassenverteilung
US5391789A (en) * 1991-08-08 1995-02-21 Hoechst Aktiengesellschaft Bridged, chiral metallocenes, processes for their preparation and their use as catalysts
DE4139261A1 (de) * 1991-11-29 1993-06-03 Basf Ag Ethylen-copolymerisate niederer dichte
DE59305691D1 (de) * 1992-05-26 1997-04-17 Hoechst Ag Verfahren zur Herstellung von Polyolefinwachsen
ATE165832T1 (de) * 1992-08-03 1998-05-15 Targor Gmbh Verfahren zur herstellung eines olefinpolymers unter verwendung von metallocenen mit speziell substituierten indenylliganden
NL9201970A (nl) * 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
US5372980A (en) * 1993-06-03 1994-12-13 Polysar Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
DE4344688A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung

Also Published As

Publication number Publication date
US5646322A (en) 1997-07-08
EP0668865B1 (en) 2003-07-23
NO951848D0 (no) 1995-05-10
DE69333114D1 (de) 2003-08-28
RU95112455A (ru) 1997-03-20
US5990253A (en) 1999-11-23
RU2128183C1 (ru) 1999-03-27
JPH08503457A (ja) 1996-04-16
AU5577494A (en) 1994-06-08
MY130143A (en) 2007-06-29
JP3419456B2 (ja) 2003-06-23
CA2149026A1 (en) 1994-05-26
BR9307420A (pt) 1999-08-31
FI952266A0 (fi) 1995-05-10
DE69333114T2 (de) 2004-06-24
WO1994011406A1 (en) 1994-05-26
CN1088212A (zh) 1994-06-22
FI114798B (fi) 2004-12-31
NO951848L (no) 1995-07-11
FI952266A (fi) 1995-05-10
AU677026B2 (en) 1997-04-10
ES2203621T3 (es) 2004-04-16
NO306782B1 (no) 1999-12-20
EP0668865A1 (en) 1995-08-30

Similar Documents

Publication Publication Date Title
NL9201970A (nl) Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
EP1412392B1 (en) Metallocene catalyst containing a cyclopentadienyl ligand substituted by a siloxy or germyloxy group containing an olefinic residue
US6268518B1 (en) Metallocene compounds and their use in catalysts for the polymerization of olefins
RU2078771C1 (ru) Способ получения полиолефинов
JP3371118B2 (ja) 配位子としてベンゼン融合したインデニル誘導体を持つメタロセン、その製造方法および触媒としてのその用途
US6342622B1 (en) Indenyl compounds for the polymerization of olefins
EP0991677B1 (en) Process for the preparation of copolymers of ethylene with alpha-olefins
EP1739103A1 (en) Catalyst
EP0693506B1 (en) Process for the preparation of amorphous polymers of propylene
EP0611773A2 (en) Catalyst component for use in the polymerization of alpha-olefins and process for producing alpha-olefin polymers using the same
ITMI940645A1 (it) Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
NL9400758A (nl) Werkwijze voor de bereiding van een hoogmoleculair polymeer uit etheen, alfa-olefine en eventueel dieen.
KR20010023862A (ko) 브리지 플루오레닐/인데닐 메탈로센 및 이의 용도
JP7278653B2 (ja) プロピレン－エチレンランダム共重合体
BE1007614A3 (nl) Werkwijze voor de polymerisatie van een olefine in aanwezigheid van een katalysator gevormd uit halogeenmetalloceen.
EP1059299B1 (en) Process for the polymerisation of olefins in the presence of indenyl compounds
EP1059300A1 (en) Indenyl compounds for the polymerisation of olefins
CA2120852C (en) 9-substituted fluorenyl compounds and the preparation and use of metallocenes thereof
KR20200141950A (ko) 프로필렌-에틸렌 랜덤 공중합체
KR20000016125A (ko) 메탈로센 및 올레핀 중합용 촉매_
MXPA98010099A (en) Metallocenes and catalysts for polymerization of olefins
MXPA98009115A (en) Procedure for the co-polymerization of an olefine and an aromat vinyl monomer

Legal Events

Date Code Title Description
A1B A search report has been drawn up
BV The patent application has lapsed
BV The patent application has lapsed