DE69333114D1 - Indenylverbindungen und katalysatorbestandteile fur olefinpolymerisation - Google Patents

Indenylverbindungen und katalysatorbestandteile fur olefinpolymerisation

Info

Publication number
DE69333114D1
DE69333114D1 DE69333114T DE69333114T DE69333114D1 DE 69333114 D1 DE69333114 D1 DE 69333114D1 DE 69333114 T DE69333114 T DE 69333114T DE 69333114 T DE69333114 T DE 69333114T DE 69333114 D1 DE69333114 D1 DE 69333114D1
Authority
DE
Germany
Prior art keywords
olefin polymerization
catalyst components
indenyl compounds
indenyl
compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69333114T
Other languages
English (en)
Other versions
DE69333114T2 (de
Inventor
Beek Antonius Van
Vries Gerardus De
Johannes Arts
Radjindrakumar Persad
Doremaele Henricus Van
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saudi Basic Industries Corp
Original Assignee
DSM NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=19861509&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE69333114(D1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by DSM NV filed Critical DSM NV
Publication of DE69333114D1 publication Critical patent/DE69333114D1/de
Application granted granted Critical
Publication of DE69333114T2 publication Critical patent/DE69333114T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
DE69333114T 1992-11-11 1993-11-03 Indenylverbindungen und katalysatorbestandteile fur olefinpolymerisation Expired - Lifetime DE69333114T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
NL9201970A NL9201970A (nl) 1992-11-11 1992-11-11 Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
NL9201970 1992-11-11
PCT/NL1993/000229 WO1994011406A1 (en) 1992-11-11 1993-11-03 Indenyl compounds and catalyst components for the polymerization of olefins

Publications (2)

Publication Number Publication Date
DE69333114D1 true DE69333114D1 (de) 2003-08-28
DE69333114T2 DE69333114T2 (de) 2004-06-24

Family

ID=19861509

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69333114T Expired - Lifetime DE69333114T2 (de) 1992-11-11 1993-11-03 Indenylverbindungen und katalysatorbestandteile fur olefinpolymerisation

Country Status (15)

Country Link
US (2) US5646322A (de)
EP (1) EP0668865B1 (de)
JP (1) JP3419456B2 (de)
CN (1) CN1088212A (de)
AU (1) AU677026B2 (de)
BR (1) BR9307420A (de)
CA (1) CA2149026A1 (de)
DE (1) DE69333114T2 (de)
ES (1) ES2203621T3 (de)
FI (1) FI114798B (de)
MY (1) MY130143A (de)
NL (1) NL9201970A (de)
NO (1) NO306782B1 (de)
RU (1) RU2128183C1 (de)
WO (1) WO1994011406A1 (de)

Families Citing this family (68)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
NL9201970A (nl) * 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
WO1995016716A1 (en) * 1993-12-14 1995-06-22 Exxon Chemical Patents Inc. Process for producing elastomers with an indenyl metallocene catalyst system
US5491207A (en) * 1993-12-14 1996-02-13 Exxon Chemical Patents Inc. Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system
US5594080A (en) * 1994-03-24 1997-01-14 Leland Stanford, Jr. University Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor
NL9400758A (nl) * 1994-05-06 1995-12-01 Dsm Nv Werkwijze voor de bereiding van een hoogmoleculair polymeer uit etheen, alfa-olefine en eventueel dieen.
US5541272A (en) * 1994-06-03 1996-07-30 Phillips Petroleum Company High activity ethylene selective metallocenes
IT1273662B (it) 1994-07-20 1997-07-09 Spherilene Srl Procedimento per la preparazione di polimeri amorfi del propiline'
EP0693502B1 (de) * 1994-07-22 1997-11-05 Mitsubishi Chemical Corporation Katalysatorbestandteil für alpha-Olefinpolymerisation und Verfahren zur Herstellung von alpha-Olefinpolymeren unter Anwendung desselben
ES2116188B1 (es) * 1994-12-30 1999-04-01 Repsol Quimica Sa Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales.
IT1275408B (it) 1995-05-30 1997-08-05 Spherilene Spa Composti metallocenici bis-indenilici pontanti procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
US5780659A (en) * 1996-03-29 1998-07-14 Phillips Petroleum Company Substituted indenyl unbridged metallocenes
US6329541B1 (en) * 1997-01-08 2001-12-11 Phillips Petroleum Company Organo omega-alkenyl cyclopentacarbyl silane-bridged metallocene compounds
FI971565A (fi) 1997-04-14 1998-10-15 Borealis As Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä
NL1006346C2 (nl) * 1997-06-18 1998-12-21 Dsm Nv Werkwijze voor de bereiding van polyolefines bij hoge temperatuur met behulp van Zr-metallocenen.
DE19809159A1 (de) 1998-03-04 1999-09-09 Bayer Ag Metallorganische Verbindungen
DE19809160A1 (de) * 1998-03-04 1999-09-09 Bayer Ag Ataktische Propylen-(Co)Polymere
DE69904521T2 (de) 1998-03-09 2003-10-02 Basell Polyolefine Gmbh Verbrückte Zirconocene, deren Herstellung und deren Verwendung als Katalysatorkomponente für die Polymerisation von Olefinen
EP0941997B1 (de) * 1998-03-09 2002-12-18 Basell Polyolefine GmbH Verbrückte Zirconocene, deren Herstellung und deren Verwendung als Katalysatorkomponente für die Polymerisation von Olefinen
IL137036A0 (en) 1998-11-18 2001-06-14 Montell Technology Company Bv Bis(tetrahydro-indenyl) metallocenes as olefin-polymerisation-catalyst
US6693156B1 (en) 1998-11-18 2004-02-17 Basell Polyolefine Gmbh Methylene bridged metallocenes as olefin-polymerization-catalyst components
ATE371636T1 (de) * 1999-01-21 2007-09-15 Boulder Scient Co Synthese und isomerisierung von 1,2-bis(indenyl)- ethanen
DE19908938A1 (de) * 1999-03-02 2000-09-07 Targor Gmbh Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
EP1059300A1 (de) * 1999-06-11 2000-12-13 Dsm N.V. Indenylverbindungen für die Polymerisation von Olefinen
US6342622B1 (en) 1999-06-11 2002-01-29 Dsm B.V. Indenyl compounds for the polymerization of olefins
EP1059299B1 (de) * 1999-06-11 2003-12-17 SABIC Polypropylenes B.V. Verfahren zur Polymerisation von Olefinen in Anwesenheit von Indenylverbindungen.
US6482905B1 (en) * 1999-08-16 2002-11-19 Phillips Petroleum Company Unsymmetric unbridged bis-indenyl metallocenes and their use
IT1314261B1 (it) * 1999-12-03 2002-12-06 Enichem Spa Composti metallocenici pontati, processo per la loro preparazione eloro uso come catalizzatori per la polimerizzazione di olefine.
DE10003581A1 (de) * 2000-01-28 2001-08-02 Bayer Ag Metallorganische Verbindungen mit anellierten Indenyl Liganden
DE10127926A1 (de) 2001-06-08 2002-12-12 Bayer Ag 1,3-disubstituierte Indenkomplexe
US6936675B2 (en) * 2001-07-19 2005-08-30 Univation Technologies, Llc High tear films from hafnocene catalyzed polyethylenes
US7060765B2 (en) 2001-07-19 2006-06-13 Univation Technologies, Llc Low comonomer incorporating metallocene catalyst compounds
US6956088B2 (en) 2001-07-19 2005-10-18 Univation Technologies, Llc Polyethylene films with improved physical properties
MXPA04000550A (es) 2001-07-19 2005-02-17 Univation Tech Llc Sistemas catalizadores de metaloceno mixtos, conteniendo un incorporador de co-monomero pobre y un buen incorporador de co-monomero.
US6562921B1 (en) * 2001-10-12 2003-05-13 Univation Technologies, Llc Catalyst precursor compound and olefin polymerization process using same
DE602004006223T2 (de) * 2004-03-12 2008-01-17 Saudi Basic Industries Corp. Katalysatorzusammensetzung für die Polymerisation von Olefinen und Polymerisationsverfahren unter dessen Verwendung
US7312283B2 (en) * 2005-08-22 2007-12-25 Chevron Phillips Chemical Company Lp Polymerization catalysts and process for producing bimodal polymers in a single reactor
US7226886B2 (en) * 2005-09-15 2007-06-05 Chevron Phillips Chemical Company, L.P. Polymerization catalysts and process for producing bimodal polymers in a single reactor
US7619047B2 (en) * 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
EP2800754B1 (de) * 2011-12-19 2017-06-28 Saudi Basic Industries Corporation (Sabic) Verfahren zur herstellung von metallocenkomplexen
WO2013091836A1 (en) * 2011-12-19 2013-06-27 Saudi Basic Industries Corporation (Sabic) Process for the preparation of metallocene complexes
EP2610269A1 (de) 2011-12-28 2013-07-03 Saudi Basic Industries Corporation Katalysatorzusammensetzung und Herstellungsverfahren dafür
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
WO2014168373A1 (en) * 2013-04-08 2014-10-16 Hanwha Chemical Corporation Metallocene catalyst system comprising antistatic agent and method for preparing polyolefin using the same
KR101584350B1 (ko) * 2013-04-08 2016-01-13 한화케미칼 주식회사 대전 방지제를 포함하는 메탈로센 촉매 시스템 및 이를 이용한 폴리올레핀의 제조 방법
EP2832739A1 (de) 2013-08-01 2015-02-04 Saudi Basic Industries Corporation Verbrückter Metallocenkomplex für Olefinpolymerisierung
CN105492451B (zh) 2013-08-30 2019-09-10 沙特基础工业公司 用于烯烃聚合的桥连茂金属配合物
MX2016010309A (es) * 2014-02-11 2016-12-20 Univation Tech Llc Produccion de productos de poliolefina.
EP3034544B1 (de) 2014-12-17 2019-10-16 SABIC Global Technologies B.V. Verfahren zur Herstellung eines Pfropfcopolymers mit einer Polyolefinhauptkette und einer oder mehreren Seitenketten von Polymeren
EP3034546B1 (de) 2014-12-17 2019-10-16 SABIC Global Technologies B.V. Verfahren zur Herstellung eines Blockcopolymers mit einem ersten Polyolefinblock und einem zweiten Polymerblock
EP3034545B1 (de) 2014-12-17 2020-11-04 SABIC Global Technologies B.V. Verfahren zur herstellung eines pfropfcopolymers mit einer polyolefinhauptkette und einer oder mehreren seitenketten von polymeren und damit erhaltene produkte
EP3034547B1 (de) 2014-12-17 2019-10-09 SABIC Global Technologies B.V. Verfahren zur Herstellung eines Blockcopolymers mit einem ersten Polyolefinblock und einem zweiten Polymerblock
EP3037437A1 (de) 2014-12-23 2016-06-29 SABIC Global Technologies B.V. Verfahren zur Herstellung eines Polyolefins mit einem oder mehreren endfunktionalisierten Zweigen
EP3037438A1 (de) 2014-12-23 2016-06-29 SABIC Global Technologies B.V. Verfahren zur Herstellung eines verzweigten Polyolefins
KR102064412B1 (ko) 2016-07-07 2020-01-09 주식회사 엘지화학 폴리올레핀 제조용 메탈로센 촉매의 제조방법
EP3606967B1 (de) 2017-04-04 2021-08-11 SABIC Global Technologies B.V. Dimethyl-silyl-verbrückte 1-phenyl-2-indenylmetallocenkomplexe zur olefinpolymerisierung
EP3606930B1 (de) 2017-04-04 2021-03-31 SABIC Global Technologies B.V. Dihydrocarbylsilyl-überbrückte-1,3-dimethyl-2-indenyl-metallocen-komplexe zur olefinpolymerisierung
CN110650964B (zh) 2017-04-04 2023-09-12 Sabic环球技术有限责任公司 用于烯烃聚合的二烃基-甲硅烷基-桥连的-取代环戊二烯基茂金属复合物
WO2019122455A1 (en) 2017-12-22 2019-06-27 Sabic Global Technologies B.V. Process for preparation of amorphous functionalized olefin copolymer
US11472900B2 (en) 2017-12-22 2022-10-18 Sabic Global Technologies B.V. Process for preparation of ethylene and propylene ionomer
WO2019145371A1 (en) 2018-01-24 2019-08-01 Sabic Global Technologies B.V. 1,2-phenylene bridged 1-indenyl-2-indenyl metallocene complexes for olefin polymerisation
RU2666736C1 (ru) * 2018-05-30 2018-09-12 Публичное акционерное общество "Нефтяная компания "Роснефть" (ПАО "НК "Роснефть") Способ получения синтетических высоковязких полиальфаолефиновых базовых масел
EP4028437A1 (de) 2019-09-10 2022-07-20 SABIC Global Technologies, B.V. Verbindungen zur verwendung in katalysatorzusammensetzungen zur herstellung von polyolefinen
CN114423769B (zh) 2019-09-20 2024-04-26 Sabic环球技术有限责任公司 用于生产聚烯烃的催化剂组合物中的化合物
US11613593B2 (en) 2020-02-24 2023-03-28 Exxonmobil Chemical Patents Inc. Ansa-bis(inden-2-yl) catalysts for producing vinylidene-terminated polyalphaolefins

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2322883A1 (fr) * 1975-09-02 1977-04-01 Michelin & Cie Elastomeres du type e p t, et articles comportant de tels elastomeres
CA1257863A (en) * 1985-10-17 1989-07-25 Vaclav G. Zboril SOLUTION PROCESS FOR THE PREPARATION OF POLYMERS OF .alpha.-OLEFINS
EP0594218B1 (de) * 1986-09-24 1999-03-17 Mitsui Chemicals, Inc. Verfahren zur Olefinpolymerisation
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
IL89525A0 (en) * 1988-03-21 1989-09-10 Exxon Chemical Patents Inc Silicon-bridged transition metal compounds
US5017714A (en) * 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
US5120867A (en) * 1988-03-21 1992-06-09 Welborn Jr Howard C Silicon-bridged transition metal compounds
US5001205A (en) * 1988-06-16 1991-03-19 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst
US4871705A (en) * 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
KR930002411B1 (ko) * 1988-09-14 1993-03-30 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 벤젠불용성 유기알루미늄 옥시화합물 및 그 제조방법
DE3840772A1 (de) * 1988-12-03 1990-06-07 Hoechst Ag Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente
IL95278A0 (en) * 1989-08-03 1991-06-30 Exxon Chemical Patents Inc Very high molecular weight polyethylene
US5191042A (en) * 1989-09-06 1993-03-02 Exxon Chemical Patents Inc. Process for preparing alpha-olefin copolymers having a narrow MWD and broad compositional distribution
ATE137770T1 (de) * 1989-10-10 1996-05-15 Fina Technology Metallocenkatalysator mit lewissäure und alkylaluminium
US5098635A (en) * 1989-11-09 1992-03-24 Copolymer Rubber & Chemical Corporation Process for manufacturing friable rubber bales
IL96810A0 (en) * 1990-01-02 1991-09-16 Exxon Chemical Patents Inc Supported ionic metallocene catalysts for olefin polymerization and methods for the preparation thereof
CA2066247C (en) * 1990-07-24 1998-09-15 Ryuichi Sugimoto Polymerization catalyst for .alpha.-olefin and method for preparing poly-.alpha.-olefin by using it
DE59107926D1 (de) * 1990-11-12 1996-07-18 Hoechst Ag Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
EP0485823B1 (de) * 1990-11-12 1995-03-08 Hoechst Aktiengesellschaft 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation
DE4039451A1 (de) * 1990-12-11 1992-06-17 Hoechst Ag Metallocene mit bicyclischen cyclopentadienderivaten als liganden, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren
DE59205811D1 (de) * 1991-05-27 1996-05-02 Hoechst Ag Verfahren zur Herstellung von Polyolefinen mit breiter Molmassenverteilung
US5391789A (en) * 1991-08-08 1995-02-21 Hoechst Aktiengesellschaft Bridged, chiral metallocenes, processes for their preparation and their use as catalysts
DE4139261A1 (de) * 1991-11-29 1993-06-03 Basf Ag Ethylen-copolymerisate niederer dichte
ATE150037T1 (de) * 1992-05-26 1997-03-15 Hoechst Ag Verfahren zur herstellung von polyolefinwachsen
DE59308494D1 (de) * 1992-08-03 1998-06-10 Targor Gmbh Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
NL9201970A (nl) * 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
US5372980A (en) * 1993-06-03 1994-12-13 Polysar Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
DE4344688A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung

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EP0668865B1 (de) 2003-07-23
ES2203621T3 (es) 2004-04-16
JP3419456B2 (ja) 2003-06-23
WO1994011406A1 (en) 1994-05-26
AU677026B2 (en) 1997-04-10
US5990253A (en) 1999-11-23
AU5577494A (en) 1994-06-08
CA2149026A1 (en) 1994-05-26
RU95112455A (ru) 1997-03-20
US5646322A (en) 1997-07-08
BR9307420A (pt) 1999-08-31
EP0668865A1 (de) 1995-08-30
NO306782B1 (no) 1999-12-20
MY130143A (en) 2007-06-29
FI114798B (fi) 2004-12-31
RU2128183C1 (ru) 1999-03-27
JPH08503457A (ja) 1996-04-16
FI952266A0 (fi) 1995-05-10
CN1088212A (zh) 1994-06-22
NL9201970A (nl) 1994-06-01
NO951848L (no) 1995-07-11
NO951848D0 (no) 1995-05-10
FI952266A (fi) 1995-05-10
DE69333114T2 (de) 2004-06-24

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