NL144919B - Werkwijze voor de bereiding van vinylacetaat uit etheen, azijnzuur en moleculaire zuurstof. - Google Patents
Werkwijze voor de bereiding van vinylacetaat uit etheen, azijnzuur en moleculaire zuurstof.Info
- Publication number
- NL144919B NL144919B NL666608847A NL6608847A NL144919B NL 144919 B NL144919 B NL 144919B NL 666608847 A NL666608847 A NL 666608847A NL 6608847 A NL6608847 A NL 6608847A NL 144919 B NL144919 B NL 144919B
- Authority
- NL
- Netherlands
- Prior art keywords
- ethene
- preparation
- acetic acid
- vinyl acetate
- molecular oxygen
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/58—Platinum group metals with alkali- or alkaline earth metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Chairs Characterized By Structure (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEK56472A DE1244766B (de) | 1965-06-25 | 1965-06-25 | Verfahren zur Herstellung von Vinylacetat |
DEK0056658 | 1965-07-20 | ||
DEK58898A DE1258863B (de) | 1965-06-25 | 1966-04-01 | Verfahren zur Herstellung von Vinylacetat |
Publications (2)
Publication Number | Publication Date |
---|---|
NL6608847A NL6608847A (ro) | 1966-12-27 |
NL144919B true NL144919B (nl) | 1975-02-17 |
Family
ID=27211286
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NL666608847A NL144919B (nl) | 1965-06-25 | 1966-06-24 | Werkwijze voor de bereiding van vinylacetaat uit etheen, azijnzuur en moleculaire zuurstof. |
Country Status (12)
Country | Link |
---|---|
US (2) | US3761513A (ro) |
AT (1) | AT266066B (ro) |
BE (1) | BE683079A (ro) |
CH (1) | CH467232A (ro) |
CS (1) | CS150182B2 (ro) |
DE (3) | DE1244766B (ro) |
ES (1) | ES328400A1 (ro) |
GB (1) | GB1103125A (ro) |
LU (1) | LU51388A1 (ro) |
NL (1) | NL144919B (ro) |
NO (1) | NO116246B (ro) |
SE (1) | SE321212B (ro) |
Families Citing this family (64)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3634496A (en) * | 1967-09-07 | 1972-01-11 | Naoya Kominami | Process for producing vinyl acetate |
DE2315037C3 (de) * | 1973-03-26 | 1978-03-09 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von ungesättigten Estern von Carbonsäuren |
US3879311A (en) * | 1973-04-26 | 1975-04-22 | Nat Distillers Chem Corp | Catalyst regeneration |
JPS514118A (en) * | 1974-06-27 | 1976-01-14 | Kuraray Co | Sakusanbiniruno seizohoho |
GB1571910A (en) * | 1975-12-18 | 1980-07-23 | Nat Distillers Chem Corp | Vinyl acetate process and catalyst therefor |
US4048096A (en) * | 1976-04-12 | 1977-09-13 | E. I. Du Pont De Nemours And Company | Surface impregnated catalyst |
US4158737A (en) * | 1976-12-14 | 1979-06-19 | National Distillers And Chemical Corp. | Vinyl acetate preparation |
US5179056A (en) * | 1991-05-06 | 1993-01-12 | Union Carbide Chemicals & Plastics Technology Corporation | Production of alkenyl alkanoate catalysts |
US5179057A (en) * | 1991-05-06 | 1993-01-12 | Union Carbide Chemicals & Plastics Technology Corporation | Catalysts for alkenyl alkanoate production |
US5274181A (en) * | 1991-05-06 | 1993-12-28 | Bp Chemicals Limited | Catalysts and processes for the manufacture of vinyl acetate |
US5342987A (en) * | 1991-05-06 | 1994-08-30 | Union Carbide Chemicals & Plastics Technology Corporation | Alkenyl alkanoate production |
US5185308A (en) * | 1991-05-06 | 1993-02-09 | Bp Chemicals Limited | Catalysts and processes for the manufacture of vinyl acetate |
AU643132B2 (en) * | 1991-11-18 | 1993-11-04 | Union Carbide Chemicals & Plastics Technology Corporation | Alkenyl alkanoate catalyst process |
US5189004A (en) * | 1991-11-18 | 1993-02-23 | Union Carbide Chemicals & Plastics Technology Corporation | Alkenyl alkanoate catalyst process |
US5194417A (en) * | 1991-12-05 | 1993-03-16 | Quantum Chemical Corporation | Pretreatment of palladium-gold catalysts useful in vinyl acetate synthesis |
DE69217648T2 (de) * | 1992-03-30 | 1997-06-12 | Union Carbide Chem Plastic | Verfahren für die Herstellung eines Katalysators für die Bereitung von Alkenylalkanoaten |
US5314858A (en) * | 1992-10-14 | 1994-05-24 | Hoechst Celanese Corporation | Vinyl acetate catalyst preparation method |
US5332710A (en) * | 1992-10-14 | 1994-07-26 | Hoechst Celanese Corporation | Vinyl acetate catalyst preparation method |
US5347046A (en) * | 1993-05-25 | 1994-09-13 | Engelhard Corporation | Catalyst and process for using same for the preparation of unsaturated carboxylic acid esters |
DE4323978C1 (de) * | 1993-07-16 | 1995-02-16 | Hoechst Ag | Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat |
CA2135021A1 (en) * | 1993-11-19 | 1995-05-20 | David J. Gulliver | Process for the preparation of catalysts for use in the production of vinyl acetate |
US6395676B2 (en) | 1994-02-22 | 2002-05-28 | The Standard Oil Company | Process for the preparation of fluid bed vinyl acetate catalyst |
US5466652A (en) * | 1994-02-22 | 1995-11-14 | The Standard Oil Co. | Process for the preparation of vinyl acetate catalyst |
US5536693A (en) * | 1994-06-02 | 1996-07-16 | The Standard Oil Company | Process for the preparation of vinyl acetate catalyst |
US5550281A (en) * | 1994-06-02 | 1996-08-27 | Cirjak; Larry M. | Fluid bed process for the acetoxylation of ethylene in the production of vinyl acetate |
DE69511464T2 (de) * | 1994-06-02 | 1999-12-16 | The Standard Oil Co., Cleveland | Fliessbett-Verfahren zur Acetoxylierung von Äthylen zur Herstellung von Vinylacetat |
US5665667A (en) * | 1994-06-02 | 1997-09-09 | The Standard Oil Company | Process for the preparation of vinyl acetate catalyst |
DE19501891C1 (de) * | 1995-01-23 | 1996-09-26 | Degussa | Verfahren zur Herstellung eines Trägerkatalysators und seine Verwendung für die Produktion von Vinylacetat |
US5576457A (en) * | 1995-05-23 | 1996-11-19 | Hoechst Celanese Corporation | Catalyst and procedure for preparation of vinyl acetate |
US5705679A (en) * | 1996-04-02 | 1998-01-06 | Nicolau; Ioan | Honeycomb catalyst for vinyl acetate synthesis |
DE19613791C2 (de) * | 1996-04-04 | 2002-01-31 | Celanese Chem Europe Gmbh | Katalysator, Verfahren zu seiner Herstellung und Verfahren zur Herstellung von Vinylacetat |
SA97180048B1 (ar) * | 1996-05-24 | 2005-12-21 | هوكست سيلانس كوربوريشن | محفز بلاديوم - ذهب palladium gold ثنائي المعدن متغاير الخواص heterogeneous bimetallic vinyl acetate لإنتاج أسيتات فينيل |
US5693586A (en) * | 1996-06-28 | 1997-12-02 | Hoechst Celanese Corporation | Palladium-gold catalyst for vinyl acetate production |
DE19721368A1 (de) * | 1997-05-22 | 1998-11-26 | Hoechst Ag | Verfahren zur Herstellung von Vinylacetat |
US6072078A (en) * | 1997-12-12 | 2000-06-06 | Celanese International Corporation | Vinyl acetate production using a catalyst comprising palladium, gold, copper and any of certain fourth metals |
GB9810928D0 (en) * | 1998-05-22 | 1998-07-22 | Bp Chem Int Ltd | Catalyst and process |
TW471982B (en) | 1998-06-02 | 2002-01-11 | Dairen Chemical Corp | Catalyst manufacture method and its use for preparing vinyl acetate |
DE19914066A1 (de) * | 1999-03-27 | 2000-10-05 | Celanese Chem Europe Gmbh | Katalysatoren für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat, Verfahren zu ihrer Herstellung und ihre Verwendung |
US6509293B1 (en) * | 2000-05-22 | 2003-01-21 | Eastman Chemical Company | Gold based heterogeneous carbonylation catalysts |
US6534438B1 (en) | 2000-07-26 | 2003-03-18 | Bp Chemicals Limited | Catalyst composition |
CA2448322A1 (en) * | 2001-03-30 | 2002-10-10 | Shell Internationale Research Maatschappij B.V. | Process for preparing a group viii-metal containing catalyst, use thereof for preparing an alkenyl carboxylate |
GB0201378D0 (en) * | 2002-01-22 | 2002-03-13 | Bp Chem Int Ltd | Process |
JP4421201B2 (ja) * | 2002-03-27 | 2010-02-24 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 触媒を調製する方法、触媒、および触媒の使用 |
US7468455B2 (en) | 2004-11-03 | 2008-12-23 | Velocys, Inc. | Process and apparatus for improved methods for making vinyl acetate monomer (VAM) |
US8168562B2 (en) | 2006-02-02 | 2012-05-01 | Lyondell Chemical Technology, L.P. | Preparation of palladium-gold catalysts |
US7811968B2 (en) * | 2007-05-11 | 2010-10-12 | Lyondell Chemical Technology, L.P. | Preparation of palladium-gold catalysts |
US20100121100A1 (en) * | 2008-11-12 | 2010-05-13 | Daniel Travis Shay | Supported palladium-gold catalysts and preparation of vinyl acetate therewith |
US20110087047A1 (en) | 2009-10-09 | 2011-04-14 | Noel Hallinan | Vinyl acetate production process |
US20110137075A1 (en) | 2009-12-09 | 2011-06-09 | Brtko Wayne J | Vinyl acetate production process |
US8329611B2 (en) * | 2009-12-16 | 2012-12-11 | Lyondell Chemical Technology, L,P. | Titania-containing extrudate |
US8507720B2 (en) * | 2010-01-29 | 2013-08-13 | Lyondell Chemical Technology, L.P. | Titania-alumina supported palladium catalyst |
US8273682B2 (en) * | 2009-12-16 | 2012-09-25 | Lyondell Chemical Technology, L.P. | Preparation of palladium-gold catalyst |
US8519182B2 (en) | 2010-10-18 | 2013-08-27 | Lyondell Chemical Technology, L.P. | Acetic acid production process |
US8822717B2 (en) | 2010-11-24 | 2014-09-02 | LyondellBassell Acetyls, LLC | Vinyl acetate production process |
US20120149939A1 (en) | 2010-12-10 | 2012-06-14 | Celanese International Corporation | Recovery of Acetic Acid from Heavy Ends in Vinyl Acetate Synthesis Process |
US8399700B2 (en) | 2011-04-15 | 2013-03-19 | Lyondell Chemical Technology, L.P. | Vinyl acetate production process |
GB201217541D0 (en) | 2012-10-01 | 2012-11-14 | Lucite Int Uk Ltd | A process for production of a silica-supported alkali metal catalyst |
CN106999899A (zh) | 2014-10-20 | 2017-08-01 | 维洛塞斯科技有限公司 | 去除热量的过程 |
DE102014223246A1 (de) * | 2014-11-14 | 2016-05-19 | Wacker Chemie Ag | Verfahren zur Herstellung von Vinylacetat |
US10780424B2 (en) | 2016-11-17 | 2020-09-22 | Lyondellbasell Acetyls, Llc | Crush strength and porosity of an alumina carrier for enhanced VAM catalysts |
CN109952150A (zh) | 2016-11-17 | 2019-06-28 | 利安德巴塞尔乙酰有限责任公司 | 用于乙酸乙烯酯单体(vam)工艺的高孔隙体积氧化铝负载催化剂 |
DE102017218375A1 (de) | 2017-10-13 | 2019-04-18 | Wacker Chemie Ag | Katalysator zur Herstellung von Vinylacetat |
TW202128605A (zh) | 2019-12-19 | 2021-08-01 | 美商瑟蘭斯國際股份有限公司 | 於乙酸乙烯酯製造期間監測各式流之可燃性之方法及系統 |
TW202204892A (zh) | 2020-06-29 | 2022-02-01 | 美商瑟蘭斯國際股份有限公司 | 於乙酸乙烯酯製造之金屬離子原位分析 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE618071A (ro) * | ||||
DE1185604B (de) * | 1962-02-03 | 1965-01-21 | Bayer Ag | Verfahren zur Herstellung von Vinylacetat |
US3190912A (en) * | 1962-05-02 | 1965-06-22 | Nat Distillers Chem Corp | Process for preparing esters |
BE638489A (ro) * | 1962-10-11 | |||
IT725140A (ro) * | 1963-06-04 | |||
FR1407526A (fr) * | 1963-09-12 | 1965-07-30 | Nat Distillers Chem Corp | Procédé amélioré de préparation d'esters organiques insaturés |
-
0
- DE DENDAT1252662D patent/DE1252662B/de active Pending
-
1965
- 1965-06-25 DE DEK56472A patent/DE1244766B/de active Pending
-
1966
- 1966-04-01 DE DEK58898A patent/DE1258863B/de active Pending
- 1966-05-25 NO NO66163167A patent/NO116246B/no unknown
- 1966-05-31 SE SE7419/66A patent/SE321212B/xx unknown
- 1966-06-02 GB GB24656/66A patent/GB1103125A/en not_active Expired
- 1966-06-13 CH CH848166A patent/CH467232A/de unknown
- 1966-06-22 LU LU51388A patent/LU51388A1/xx unknown
- 1966-06-24 NL NL666608847A patent/NL144919B/xx not_active IP Right Cessation
- 1966-06-24 AT AT602966A patent/AT266066B/de active
- 1966-06-24 BE BE683079D patent/BE683079A/xx not_active IP Right Cessation
- 1966-06-25 ES ES0328400A patent/ES328400A1/es not_active Expired
- 1966-12-01 CS CS7649A patent/CS150182B2/cs unknown
-
1969
- 1969-04-14 US US00816121A patent/US3761513A/en not_active Expired - Lifetime
-
1971
- 1971-05-21 US US00145979A patent/US3743607A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE1244766B (de) | 1967-07-20 |
CH467232A (de) | 1969-01-15 |
ES328400A1 (es) | 1967-04-01 |
AT266066B (de) | 1968-11-11 |
BE683079A (ro) | 1966-12-01 |
NO116246B (ro) | 1969-02-24 |
US3743607A (en) | 1973-07-03 |
US3761513A (en) | 1973-09-25 |
SE321212B (ro) | 1970-03-02 |
CS150182B2 (ro) | 1973-09-04 |
GB1103125A (en) | 1968-02-14 |
DE1252662B (ro) | |
DE1258863B (de) | 1968-01-18 |
NL6608847A (ro) | 1966-12-27 |
LU51388A1 (ro) | 1966-08-22 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
V1 | Lapsed because of non-payment of the annual fee | ||
NL80 | Abbreviated name of patent owner mentioned of already nullified patent |
Owner name: HOECHST |