MXPA05012264A - Composicion curable por radiacion. - Google Patents
Composicion curable por radiacion.Info
- Publication number
- MXPA05012264A MXPA05012264A MXPA05012264A MXPA05012264A MXPA05012264A MX PA05012264 A MXPA05012264 A MX PA05012264A MX PA05012264 A MXPA05012264 A MX PA05012264A MX PA05012264 A MXPA05012264 A MX PA05012264A MX PA05012264 A MXPA05012264 A MX PA05012264A
- Authority
- MX
- Mexico
- Prior art keywords
- compound
- ene
- group
- groups
- composition
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
- C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/02—Polythioethers
- C08G75/04—Polythioethers from mercapto compounds or metallic derivatives thereof
- C08G75/045—Polythioethers from mercapto compounds or metallic derivatives thereof from mercapto compounds and unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/08—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated side groups
- C08F290/14—Polymers provided for in subclass C08G
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
- C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/83—Chemically modified polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/12—Polythioether-ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/0275—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with dithiol or polysulfide compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G2650/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterized by the type of post-polymerisation functionalisation
- C08G2650/16—Photopolymerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Chemical & Material Sciences (AREA)
- General Physics & Mathematics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
La invencion se relaciona con un composicion curable de tiol-eno que comprende bien un compuesto A y un compuesto B, o un compuesto B que comprende ademas una funcionalidad politiol como se define bajo (A), donde (A) un politiol, (B) un compuesto que tiene una pluralidad de grupos eno ciclicos sobre si, donde dicho compuesto (B) comprende un grupo carbonilo directamente enlazado a al menos un grupo eno ciclico y comprende al menos un grupo donador de hidrogeno, donde la distancia entre el al menos uno de dichos grupos eno ciclicos y el al menos uno de dichos grupos donadores de hidrogeno es al menos dos enlaces del esqueleto, donde el compuesto B no contiene un grupo (met)acrilato, y (C) 0-10 % en peso de un fotoiniciador. La invencion se relaciona adicionalmente con el uso de tal composicion para recubrimiento de fibras opticas, como resina de estereolitografia, recubrimientos medicos y adhesivos.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP03076481A EP1477511A1 (en) | 2003-05-15 | 2003-05-15 | Radiation curable thiol-ene composition |
US51166403P | 2003-10-17 | 2003-10-17 | |
PCT/NL2004/000343 WO2004101649A2 (en) | 2003-05-15 | 2004-05-17 | Radiation curable thiol-ene composition |
Publications (1)
Publication Number | Publication Date |
---|---|
MXPA05012264A true MXPA05012264A (es) | 2006-02-10 |
Family
ID=33016941
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MXPA05012264A MXPA05012264A (es) | 2003-05-15 | 2004-05-17 | Composicion curable por radiacion. |
Country Status (9)
Country | Link |
---|---|
US (1) | US20070043205A1 (es) |
EP (2) | EP1477511A1 (es) |
JP (1) | JP2007505198A (es) |
KR (1) | KR20060012294A (es) |
CN (1) | CN1788037A (es) |
CA (1) | CA2525059A1 (es) |
MX (1) | MXPA05012264A (es) |
WO (1) | WO2004101649A2 (es) |
ZA (1) | ZA200509075B (es) |
Families Citing this family (48)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101474174B1 (ko) | 2004-03-22 | 2014-12-17 | 3디 시스템즈 인코오퍼레이티드 | 광경화성 조성물 |
US7521015B2 (en) * | 2005-07-22 | 2009-04-21 | 3M Innovative Properties Company | Curable thiol-ene compositions for optical articles |
US8044111B2 (en) | 2007-11-30 | 2011-10-25 | Novartis Ag | Actinically-crosslinkable silicone-containing block copolymers |
KR101587666B1 (ko) * | 2007-12-18 | 2016-01-21 | 다우 글로벌 테크놀로지스 엘엘씨 | 유리 결합용 접착제에 대한 접착성이 개선된 창 유리용 보호 코팅 |
US9243083B2 (en) * | 2008-04-03 | 2016-01-26 | Henkel IP & Holding GmbH | Thiol-ene cured oil-resistant polyacrylate sealants for in-place gasketing applications |
JP5677727B2 (ja) * | 2009-04-20 | 2015-02-25 | 株式会社ブリヂストン | チオール基含有接着性樹脂組成物 |
US20100311861A1 (en) * | 2009-06-03 | 2010-12-09 | 3M Innovative Properties Company | Thiol-yne shape memory polymer |
WO2011075553A1 (en) * | 2009-12-17 | 2011-06-23 | Dsm Ip Assets, B.V. | Liquid radiation curable resins for additive fabrication comprising a triaryl sulfonium borate cationic photoinitiator |
MY158037A (en) | 2010-07-30 | 2016-08-30 | Novartis Ag | Amphiphilic polysiloxane prepolymers and uses thereof |
HUE044765T2 (hu) | 2010-10-06 | 2019-11-28 | Novartis Ag | Polimerizálható hosszabbított láncú polisziloxánok hidrofil oldalcsoportokkal |
WO2012126695A1 (en) * | 2011-03-23 | 2012-09-27 | Huntsman Advanced Materials (Switzerland) Gmbh | Stable curable thiol-ene composition |
WO2013052328A1 (en) * | 2011-10-03 | 2013-04-11 | Synthes Usa, Llc | Thiol-ene polymerization with vinylesters and vinylcarbonate |
KR20140089549A (ko) * | 2011-11-17 | 2014-07-15 | 쓰리본드 화인 케미칼 가부시키가이샤 | 아크릴 수지 조성물 |
CN104039902B (zh) * | 2012-01-19 | 2016-10-26 | 阿克佐诺贝尔国际涂料股份有限公司 | 可固化涂料组合物 |
TWI572624B (zh) * | 2012-03-06 | 2017-03-01 | Arakawa Chemical Industries Ltd | A polyfunctional sulfur (meth) acrylate resin, an active energy ray-hardening hard coat resin composition containing the same, a hardened film obtained by hardening the plastic film, a plastic film having a hardened film, a plastic film And processed products |
US9441084B2 (en) | 2013-03-13 | 2016-09-13 | Poly6 Techniques | One-pot, high-performance recycling method for polymer waste achieved through renewable polymer synthesis |
US10144840B2 (en) | 2013-03-13 | 2018-12-04 | Poly6 Technologies | One-pot, high-performance recycling of polymer waste using renewable polymer synthesis |
WO2014203779A1 (ja) * | 2013-06-17 | 2014-12-24 | 昭和電工株式会社 | エンチオール系硬化性組成物およびその硬化物 |
CN105531333A (zh) * | 2013-09-13 | 2016-04-27 | 巴斯夫欧洲公司 | 耐刮擦的辐射固化涂料 |
JP5954296B2 (ja) * | 2013-11-07 | 2016-07-20 | 住友電気工業株式会社 | 光ファイバ心線 |
ES2597162T3 (es) | 2013-12-02 | 2017-01-16 | Allnex Belgium, S.A. | Estabilizante para composiciones de tiol-eno |
WO2015084753A1 (en) | 2013-12-03 | 2015-06-11 | Ocv Interllectual Capital, Llc | Uv-curable glass fiber sizing compositions |
WO2015153612A1 (en) * | 2014-03-31 | 2015-10-08 | Avery Dennison Corporation | Printable adhesive and label assembly |
TWI483073B (zh) * | 2014-04-02 | 2015-05-01 | Chi Mei Corp | 感光性樹脂組成物、彩色濾光片及其製造方法、液晶顯示裝置 |
JP6158742B2 (ja) * | 2014-04-17 | 2017-07-05 | 株式会社オートネットワーク技術研究所 | 光硬化性防水剤およびワイヤーハーネス |
EP3158578B1 (en) * | 2014-07-08 | 2024-01-10 | Canon Kabushiki Kaisha | Adhesion layer composition, method for forming film by nanoimprinting, methods for manufacturing optical component, circuit board and electronic apparatus |
FR3024733B1 (fr) | 2014-08-05 | 2018-01-12 | Coatex Sas | Agent epaississant pour systemes aqueux, formulations le contenant et utilisations. |
US9522975B2 (en) * | 2015-01-29 | 2016-12-20 | Chevron Phillips Chemical Company Lp | Mercaptanized vinylnorbornene compositions and methods of making same |
KR20180016505A (ko) * | 2015-06-08 | 2018-02-14 | 디에스엠 아이피 어셋츠 비.브이. | 부가적 제조용 액체 하이브리드 자외선/가시광선 복사선-경화성 수지 조성물 |
US11015115B2 (en) | 2015-12-31 | 2021-05-25 | 3M Innovative Properties Company | Curable quantum dot compositions and articles |
CN108431172B (zh) | 2015-12-31 | 2021-04-13 | 3M创新有限公司 | 包含具有量子点的颗粒的制品 |
KR102463384B1 (ko) | 2016-02-19 | 2022-11-04 | 애버리 데니슨 코포레이션 | 접착제를 제조하는 2단계 방법 및 관련 조성물 |
TW201800491A (zh) * | 2016-03-07 | 2018-01-01 | 道康寧公司 | 光可固化聚矽氧組成物及其經固化產物 |
CN107459871B (zh) * | 2016-07-11 | 2018-05-25 | 珠海赛纳打印科技股份有限公司 | 3d喷墨打印用光固化透明墨水及其制备方法 |
EP3532520A1 (en) | 2016-10-25 | 2019-09-04 | Avery Dennison Corporation | Block polymers with photoinitiator groups in backbone and their use in adhesive compositions |
DK3585748T3 (da) | 2017-02-27 | 2023-09-25 | Nufern | Optisk fiberbelægningssammensætning |
EP3441223B1 (en) | 2017-08-07 | 2024-02-21 | Eco3 Bv | A lithographic printing plate precursor |
EP3691901A1 (en) * | 2017-10-02 | 2020-08-12 | Basf Se | Uv curable compositions with controlled mechanical and chemical properties, methods, and articles therefrom |
EP3743452B1 (en) * | 2018-01-25 | 2023-06-07 | Momentive Performance Materials GmbH | Thiol-ene-curing compositions |
SI25663A (sl) | 2018-06-23 | 2019-12-31 | HELIOS Tovarna barv, lakov in umetnih smol KoliÄŤevo, d.o.o | Umetna smola za pripravo zaščitnega premaza in postopek priprave tovrstnega premaza |
WO2020016332A1 (en) * | 2018-07-18 | 2020-01-23 | Københavns Universitet | Methods for the treatment of thermoset polymers |
CN109337043B (zh) * | 2018-10-12 | 2021-03-26 | 泉州三欣新材料科技有限公司 | 一种无溶剂型自修复聚氨酯及其制备方法 |
EP3670627A1 (en) | 2018-12-18 | 2020-06-24 | Henkel AG & Co. KGaA | Method for the production of thioether-containing polyurethanes |
CN110218323A (zh) * | 2019-06-06 | 2019-09-10 | 南京恒桥化学技术材料有限公司 | 一种含降冰片烯结构单体光固化型组合物及光固化型封装材料 |
US11879023B2 (en) | 2020-08-21 | 2024-01-23 | United States Of America As Represented By The Secretary Of The Air Force | Articles comprising crosslinked polymer network comprising thioether crosslinks and process of making and using same |
CN114163598B (zh) * | 2021-12-24 | 2023-11-21 | 中国林业科学研究院林产化学工业研究所 | 一种生物基多元醇衍生的自修复聚氨酯及其制备方法 |
CN114345273B (zh) * | 2021-12-30 | 2024-03-08 | 南京恒桥化学技术材料有限公司 | 一种光固化组合物的制备方法 |
US20240059927A1 (en) * | 2022-08-15 | 2024-02-22 | Align Technology, Inc. | Vinyl ether-based inkjet ink photopolymerized by thiol-ene click chemistry used for toughening of photopolymers |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2087213A5 (es) * | 1970-05-11 | 1971-12-31 | Aquitaine Petrole | |
DE3785672T2 (de) * | 1986-10-14 | 1993-09-16 | Loctite Corp | Thiolenzusammensetzungen aus bizyklischen en-verbindungen. |
US5352712A (en) * | 1989-05-11 | 1994-10-04 | Borden, Inc. | Ultraviolet radiation-curable coatings for optical fibers |
US5167882A (en) * | 1990-12-21 | 1992-12-01 | Loctite Corporation | Stereolithography method |
US5208281A (en) * | 1991-02-05 | 1993-05-04 | Loctite Corporation | Stabilization of thiolene compositions |
US5459175A (en) * | 1990-11-28 | 1995-10-17 | Loctite Corporation | Optical fiber primary coatings and fibers coated therewith |
JPH0511449A (ja) * | 1990-12-21 | 1993-01-22 | Loctite Corp | 三次元品を堆積させる立体石版印刷法と硬化組成物 |
DE4440819A1 (de) * | 1993-11-19 | 1995-05-24 | Ciba Geigy Ag | Photoempfindliche Zusammensetzungen |
JP2003026805A (ja) * | 2001-07-16 | 2003-01-29 | Toagosei Co Ltd | 形状記憶性光学材料並びに光学部品及びその製造方法 |
JP2003055316A (ja) * | 2001-08-06 | 2003-02-26 | Toagosei Co Ltd | ノルボルネン構造を有する基を有する化合物及びその製造方法 |
-
2003
- 2003-05-15 EP EP03076481A patent/EP1477511A1/en not_active Withdrawn
-
2004
- 2004-05-17 CA CA002525059A patent/CA2525059A1/en not_active Abandoned
- 2004-05-17 KR KR1020057021810A patent/KR20060012294A/ko not_active Application Discontinuation
- 2004-05-17 EP EP04748586A patent/EP1622963A2/en not_active Withdrawn
- 2004-05-17 WO PCT/NL2004/000343 patent/WO2004101649A2/en active Application Filing
- 2004-05-17 US US10/556,303 patent/US20070043205A1/en not_active Abandoned
- 2004-05-17 CN CNA2004800129958A patent/CN1788037A/zh active Pending
- 2004-05-17 JP JP2006532124A patent/JP2007505198A/ja active Pending
- 2004-05-17 MX MXPA05012264A patent/MXPA05012264A/es unknown
-
2005
- 2005-11-09 ZA ZA200509075A patent/ZA200509075B/en unknown
Also Published As
Publication number | Publication date |
---|---|
CN1788037A (zh) | 2006-06-14 |
KR20060012294A (ko) | 2006-02-07 |
WO2004101649A2 (en) | 2004-11-25 |
JP2007505198A (ja) | 2007-03-08 |
CA2525059A1 (en) | 2004-11-25 |
US20070043205A1 (en) | 2007-02-22 |
WO2004101649A3 (en) | 2005-01-20 |
EP1622963A2 (en) | 2006-02-08 |
EP1477511A1 (en) | 2004-11-17 |
ZA200509075B (en) | 2007-12-27 |
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