MXPA05008953A - Sistema de enfriamiento de reformado y metodo para uso en un subsistema de procesamiento de combustible. - Google Patents
Sistema de enfriamiento de reformado y metodo para uso en un subsistema de procesamiento de combustible.Info
- Publication number
- MXPA05008953A MXPA05008953A MXPA05008953A MXPA05008953A MXPA05008953A MX PA05008953 A MXPA05008953 A MX PA05008953A MX PA05008953 A MXPA05008953 A MX PA05008953A MX PA05008953 A MXPA05008953 A MX PA05008953A MX PA05008953 A MXPA05008953 A MX PA05008953A
- Authority
- MX
- Mexico
- Prior art keywords
- flow path
- reformate
- core portions
- cooling system
- processing subsystem
- Prior art date
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
- F28D7/16—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation
- F28D7/1615—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation the conduits being inside a casing and extending at an angle to the longitudinal axis of the casing; the conduits crossing the conduit for the other heat exchange medium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/248—Reactors comprising multiple separated flow channels
- B01J19/249—Plate-type reactors
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
- C01B3/58—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
- C01B3/58—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
- C01B3/583—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction the reaction being the selective oxidation of carbon monoxide
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
- F28D7/16—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2451—Geometry of the reactor
- B01J2219/2453—Plates arranged in parallel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2451—Geometry of the reactor
- B01J2219/2456—Geometry of the plates
- B01J2219/2459—Corrugated plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2461—Heat exchange aspects
- B01J2219/2462—Heat exchange aspects the reactants being in indirect heat exchange with a non reacting heat exchange medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2491—Other constructional details
- B01J2219/2492—Assembling means
- B01J2219/2493—Means for assembling plates together, e.g. sealing means, screws, bolts
- B01J2219/2495—Means for assembling plates together, e.g. sealing means, screws, bolts the plates being assembled interchangeably or in a disposable way
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0435—Catalytic purification
- C01B2203/044—Selective oxidation of carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/047—Composition of the impurity the impurity being carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/066—Integration with other chemical processes with fuel cells
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/146—At least two purification steps in series
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
- F28D2021/0019—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
- F28D2021/0043—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for fuel cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
- H01M8/0668—Removal of carbon monoxide or carbon dioxide
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1007—Fuel cells with solid electrolytes with both reactants being gaseous or vaporised
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Thermal Sciences (AREA)
- Fuel Cell (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
Se proporciona un sistema de enfriamiento de reformado (10) para su uso con un subsistema de procesamiento de combustible (12) para reducir el nivel de monoxido de carbono en un flujo de reformado (14) para un sistema de celda de combustible de membrana de intercambio de protones (16). El subsistema de procesamiento de combustible (12) incluye un primer oxidador preferencial (18) y un segundo oxidador preferencial (20) para oxidar el monoxido de carbono transportado en el flujo de reformado. El sistema de enfriamiento de reformado (10) incluye una trayectoria de flujo de refrigerante (30), una trayectoria de flujo de reformado (32), y una primera, segunda, tercera y cuarta porciones centrales (34, 36, 38, 40) de intercambiador de calor. Las porciones centrales (36-40) estan colocadas en una secuencia numerada a lo largo de la trayectoria de flujo de reformado (32) con la primera porcion central (34) y la segunda porcion central (36) localizadas corriente arriba del primer oxidador preferencial (18), y la tercera porcion central (38) y la cuarta porcion central (40) localizadas corriente abajo del primer oxidador preferencial (18), y corriente arriba de segundo oxidador preferencial (20). La primera porcion central (34) y la segunda porcion central (36) estan colocadas en una secuencia numerada lo largo de la trayectoria de flujo de refrigerante (30), una de la tercera porcion central (38) y cuarta porcion central (40) esta colocada corriente arriba de la primera porcion central (34) a lo largo de la trayectoria de flujo refrigerante (30), y la otra de la tercera porcion central (38) y cuarta porcion central (40) esta colocada corriente abajo de la segunda porcion central a lo largo de la trayectoria de flujo de refrigerante (30).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/376,367 US7192460B2 (en) | 2003-02-28 | 2003-02-28 | Reformate cooling system and method for use in a fuel processing subsystem |
PCT/US2003/040474 WO2004079777A2 (en) | 2003-02-28 | 2003-12-18 | Reformate cooling system and method for use in a fuel processing subsystem |
Publications (1)
Publication Number | Publication Date |
---|---|
MXPA05008953A true MXPA05008953A (es) | 2005-11-04 |
Family
ID=32907928
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MXPA05008953A MXPA05008953A (es) | 2003-02-28 | 2003-12-18 | Sistema de enfriamiento de reformado y metodo para uso en un subsistema de procesamiento de combustible. |
Country Status (12)
Country | Link |
---|---|
US (2) | US7192460B2 (es) |
EP (1) | EP1597788B1 (es) |
JP (1) | JP4738816B2 (es) |
KR (1) | KR20050102149A (es) |
CN (1) | CN100356622C (es) |
AU (1) | AU2003303985A1 (es) |
BR (1) | BR0318143A (es) |
CA (1) | CA2516891A1 (es) |
DE (1) | DE60308734T2 (es) |
MX (1) | MXPA05008953A (es) |
RU (1) | RU2005127055A (es) |
WO (1) | WO2004079777A2 (es) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7192460B2 (en) * | 2003-02-28 | 2007-03-20 | Modine Manufacturing Company | Reformate cooling system and method for use in a fuel processing subsystem |
US20040197619A1 (en) * | 2003-04-04 | 2004-10-07 | Deshpande Vijay A. | Coolant system for fuel processor |
US20080184892A1 (en) * | 2007-02-06 | 2008-08-07 | Ctp Hydrogen Corporation | Architectures for electrochemical systems |
JP5234401B2 (ja) * | 2007-12-06 | 2013-07-10 | 日産自動車株式会社 | 固体電解質型燃料電池システム |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3796547A (en) * | 1969-11-26 | 1974-03-12 | Texaco Inc | Heat exchange apparatus for catalytic system |
JPS5143525B2 (es) * | 1973-02-12 | 1976-11-22 | ||
US4098330A (en) * | 1976-07-23 | 1978-07-04 | General Motors Corporation | Annular metal recuperator |
JPS5936196B2 (ja) | 1978-02-28 | 1984-09-01 | 株式会社荏原製作所 | 熱交換・接触反応装置 |
JPS60153936A (ja) | 1984-01-25 | 1985-08-13 | Babcock Hitachi Kk | ヒ−トパイプ付反応器 |
US5271916A (en) * | 1991-07-08 | 1993-12-21 | General Motors Corporation | Device for staged carbon monoxide oxidation |
WO1994009903A1 (en) | 1992-10-28 | 1994-05-11 | Allied-Signal Inc. | Catalytic converter with metal monolith having an integral catalyst |
EP0611594A1 (de) * | 1993-02-17 | 1994-08-24 | Siemens Aktiengesellschaft | Katalysator zur Umsetzung von Reaktanten eines Gasgemisches |
US5338622A (en) * | 1993-04-12 | 1994-08-16 | Ztek Corporation | Thermal control apparatus |
US5360679A (en) * | 1993-08-20 | 1994-11-01 | Ballard Power Systems Inc. | Hydrocarbon fueled solid polymer fuel cell electric power generation system |
JPH09165202A (ja) | 1995-12-15 | 1997-06-24 | Ishikawajima Harima Heavy Ind Co Ltd | 水蒸気改質器 |
DE19716470C1 (de) | 1997-04-19 | 1998-10-01 | Mtu Friedrichshafen Gmbh | Integriertes Brennstoffaufbereitungsmodul für eine Brennstoffzellenanlage |
US6156084A (en) * | 1998-06-24 | 2000-12-05 | International Fuel Cells, Llc | System for desulfurizing a fuel for use in a fuel cell power plant |
CZ302007B6 (cs) * | 1998-07-08 | 2010-09-01 | Toyota Jidosha Kabushiki Kaisha | Zarízení pro reformování paliva a zpusob výroby vodíkem obohaceného plynného paliva provádený v tomto zarízení |
US6190624B1 (en) * | 1998-09-08 | 2001-02-20 | Uop Llc | Simplified plate channel reactor arrangement |
US6245214B1 (en) * | 1998-09-18 | 2001-06-12 | Alliedsignal Inc. | Electro-catalytic oxidation (ECO) device to remove CO from reformate for fuel cell application |
KR100297189B1 (ko) * | 1998-11-20 | 2001-11-26 | 황해웅 | 열전달촉진효과를갖는고효율모듈형오엘에프열교환기 |
JP4261679B2 (ja) * | 1999-04-30 | 2009-04-30 | 本田技研工業株式会社 | 燃料電池システムにおける燃料ガスの温調装置 |
DE19958404C2 (de) * | 1999-12-03 | 2002-04-04 | Xcellsis Gmbh | Vorrichtung zur selektiven katalytischen Oxidation von Kohlenmonoxid |
KR100427165B1 (ko) * | 1999-12-28 | 2004-04-14 | 마쯔시다덴기산교 가부시키가이샤 | 수소생성기 |
DE10028865C2 (de) * | 2000-06-10 | 2002-09-26 | Xcellsis Gmbh | Vorrichtung zur katalytischen Wasserstofferzeugung aus Kohlenwasserstoffen |
JP3903710B2 (ja) * | 2000-07-25 | 2007-04-11 | 富士電機ホールディングス株式会社 | 燃料改質器およびそれを用いた固体高分子型燃料電池発電装置 |
DE10038523C1 (de) * | 2000-08-08 | 2002-06-27 | Xcellsis Gmbh | Kombiniertes Bauteil aus Wärmeübertrager und Reaktor |
JP3739044B2 (ja) | 2002-07-04 | 2006-01-25 | 本田技研工業株式会社 | 熱交換器及びそれを利用した熱交換式反応器 |
US7069981B2 (en) * | 2002-11-08 | 2006-07-04 | Modine Manufacturing Company | Heat exchanger |
US7192460B2 (en) * | 2003-02-28 | 2007-03-20 | Modine Manufacturing Company | Reformate cooling system and method for use in a fuel processing subsystem |
-
2003
- 2003-02-28 US US10/376,367 patent/US7192460B2/en not_active Expired - Fee Related
- 2003-12-18 CA CA002516891A patent/CA2516891A1/en not_active Abandoned
- 2003-12-18 CN CNB2003801099955A patent/CN100356622C/zh not_active Expired - Fee Related
- 2003-12-18 WO PCT/US2003/040474 patent/WO2004079777A2/en active IP Right Grant
- 2003-12-18 EP EP03808489A patent/EP1597788B1/en not_active Expired - Lifetime
- 2003-12-18 AU AU2003303985A patent/AU2003303985A1/en not_active Abandoned
- 2003-12-18 MX MXPA05008953A patent/MXPA05008953A/es unknown
- 2003-12-18 RU RU2005127055/09A patent/RU2005127055A/ru unknown
- 2003-12-18 JP JP2004569220A patent/JP4738816B2/ja not_active Expired - Fee Related
- 2003-12-18 DE DE60308734T patent/DE60308734T2/de not_active Expired - Lifetime
- 2003-12-18 KR KR1020057015919A patent/KR20050102149A/ko not_active Application Discontinuation
- 2003-12-18 BR BR0318143-0A patent/BR0318143A/pt not_active IP Right Cessation
-
2007
- 2007-03-20 US US11/725,881 patent/US7666237B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP1597788A2 (en) | 2005-11-23 |
US20070189938A1 (en) | 2007-08-16 |
CN100356622C (zh) | 2007-12-19 |
US20040170874A1 (en) | 2004-09-02 |
WO2004079777A3 (en) | 2005-02-17 |
JP2006514416A (ja) | 2006-04-27 |
RU2005127055A (ru) | 2006-02-10 |
DE60308734T2 (de) | 2007-08-16 |
BR0318143A (pt) | 2006-02-07 |
CN1757131A (zh) | 2006-04-05 |
KR20050102149A (ko) | 2005-10-25 |
AU2003303985A1 (en) | 2004-09-28 |
EP1597788B1 (en) | 2006-09-27 |
US7666237B2 (en) | 2010-02-23 |
WO2004079777A2 (en) | 2004-09-16 |
CA2516891A1 (en) | 2004-09-16 |
DE60308734D1 (de) | 2006-11-09 |
US7192460B2 (en) | 2007-03-20 |
JP4738816B2 (ja) | 2011-08-03 |
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