MXPA04010880A - Sintesis en un solo reactor de polioles acabados en koh basados en intermedios sinterizados con dmc. - Google Patents
Sintesis en un solo reactor de polioles acabados en koh basados en intermedios sinterizados con dmc.Info
- Publication number
- MXPA04010880A MXPA04010880A MXPA04010880A MXPA04010880A MXPA04010880A MX PA04010880 A MXPA04010880 A MX PA04010880A MX PA04010880 A MXPA04010880 A MX PA04010880A MX PA04010880 A MXPA04010880 A MX PA04010880A MX PA04010880 A MXPA04010880 A MX PA04010880A
- Authority
- MX
- Mexico
- Prior art keywords
- dmc
- koh
- processes
- single reactor
- capped polyols
- Prior art date
Links
- 229920005862 polyol Polymers 0.000 title abstract 4
- 150000003077 polyols Chemical class 0.000 title abstract 4
- 239000000543 intermediate Substances 0.000 title abstract 2
- 230000015572 biosynthetic process Effects 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000006386 neutralization reaction Methods 0.000 abstract 2
- 229920005830 Polyurethane Foam Polymers 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- -1 coatings Substances 0.000 abstract 1
- 238000007599 discharging Methods 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 abstract 1
- 239000000806 elastomer Substances 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000011496 polyurethane foam Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000000565 sealant Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2663—Metal cyanide catalysts, i.e. DMC's
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/185—Catalysts containing secondary or tertiary amines or salts thereof having cyano groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4866—Polyethers having a low unsaturation value
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2648—Alkali metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/269—Mixed catalyst systems, i.e. containing more than one reactive component or catalysts formed in-situ
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2696—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the process or apparatus used
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Toxicology (AREA)
- Polyethers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyurethanes Or Polyureas (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/699,951 US7005552B2 (en) | 2003-11-03 | 2003-11-03 | Single reactor synthesis of KOH-capped polyols based on DMC-synthesized intermediates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MXPA04010880A true MXPA04010880A (es) | 2005-12-06 |
Family
ID=34423459
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MXPA04010880A MXPA04010880A (es) | 2003-11-03 | 2004-11-03 | Sintesis en un solo reactor de polioles acabados en koh basados en intermedios sinterizados con dmc. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7005552B2 (enExample) |
| EP (1) | EP1528073B1 (enExample) |
| JP (1) | JP5062951B2 (enExample) |
| KR (1) | KR101173690B1 (enExample) |
| CN (1) | CN1636989B (enExample) |
| BR (1) | BRPI0404789A (enExample) |
| CA (1) | CA2486337C (enExample) |
| MX (1) | MXPA04010880A (enExample) |
| RU (1) | RU2004131631A (enExample) |
| SG (1) | SG111284A1 (enExample) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7186867B2 (en) * | 2004-04-21 | 2007-03-06 | Basf Aktiengesellschaft | Process for preparing reactive polyether polyols having an ethylene oxide end block |
| EP3919543A3 (en) | 2005-04-22 | 2022-03-16 | Mitsubishi Chemical Corporation | Biomass-resource-derived polyester and production process thereof |
| US7323605B2 (en) * | 2005-11-09 | 2008-01-29 | Bayer Materialscience Llc | Double metal cyanide-catalyzed, low unsaturation polyethers from boron-containing starters |
| US20080255378A1 (en) * | 2007-04-16 | 2008-10-16 | Bayer Materialscience Llc | High productivity process for non-phenolic ethoxylates |
| DE102007044148A1 (de) | 2007-09-15 | 2009-03-26 | Evonik Goldschmidt Gmbh | Neuartige siloxanhaltige Blockcopolymere, Verfahren zu deren Herstellung und deren Verwendung für Schmiermittel |
| DE102008011683A1 (de) * | 2008-02-28 | 2009-09-03 | Bayer Materialscience Ag | Verfahren zur Herstellung von Polyolen |
| CN101412798B (zh) * | 2008-11-21 | 2011-08-10 | 优洁(亚洲)有限公司 | 软质聚氨酯低回弹泡沫及其制备方法 |
| JP5549945B2 (ja) * | 2009-10-05 | 2014-07-16 | 旭硝子株式会社 | 軟質ポリウレタンフォームの製造方法 |
| TW201120094A (en) * | 2009-10-05 | 2011-06-16 | Asahi Glass Co Ltd | Polyethers and method for producing the same |
| JPWO2011043345A1 (ja) * | 2009-10-05 | 2013-03-04 | 旭硝子株式会社 | 軟質ポリウレタンフォームおよびその製造方法、ならびに自動車用シートクッション |
| US8492988B2 (en) * | 2009-10-07 | 2013-07-23 | Lutron Electronics Co., Inc. | Configurable load control device for light-emitting diode light sources |
| KR20130094688A (ko) * | 2010-04-30 | 2013-08-26 | 아사히 가라스 가부시키가이샤 | 폴리옥시알킬렌폴리올, 폴리머 분산 폴리올, 및 연질 폴리우레탄폼, 그리고 이들의 제조 방법 |
| US9169185B2 (en) * | 2010-12-20 | 2015-10-27 | Bayer Intellectual Property Gmbh | Method for the preparation of polyether polyols |
| KR101404702B1 (ko) | 2011-03-08 | 2014-06-17 | 에스케이이노베이션 주식회사 | 에테르 결합 단위체를 함유한 이산화탄소/에폭사이드 공중합체의 제조 방법 |
| KR20140025350A (ko) * | 2011-03-30 | 2014-03-04 | 아사히 가라스 가부시키가이샤 | 폴리에테르폴리올 및 연질 폴리우레탄 폼의 제조 방법, 그리고 시트 |
| CA2873847C (en) * | 2012-05-18 | 2020-06-30 | Basf Se | An encapsulated particle |
| US9944568B2 (en) | 2012-11-16 | 2018-04-17 | Basf Se | Encapsulated fertilizer particle containing pesticide |
| US9051412B2 (en) * | 2013-03-14 | 2015-06-09 | Bayer Materialscience Llc | Base-catalyzed, long chain, active polyethers from short chain DMC-catalyzed starters |
| CN104109234B (zh) * | 2014-08-06 | 2016-06-15 | 山东蓝星东大化工有限责任公司 | 高分子量低不饱和度高伯羟基含量聚醚多元醇的制备方法 |
| WO2016064698A1 (en) * | 2014-10-22 | 2016-04-28 | Dow Global Technologies Llc | Dual catalyst system for high primary hydroxyl polyols |
| KR102575283B1 (ko) | 2015-06-30 | 2023-09-07 | 다우 글로벌 테크놀로지스 엘엘씨 | 이중 금속 시아나이드 촉매를 사용한 프로필렌 옥사이드/에틸렌 옥사이드 코폴리머를 제조하는 방법 및 그렇게 제조된 코폴리머 |
| EP3138865A1 (de) | 2015-09-07 | 2017-03-08 | Basf Se | Verfahren zur herstellung von polyetherpolyolen |
| US9994506B2 (en) * | 2016-04-20 | 2018-06-12 | Covestro Llc | Process for transitioning reactors from base-catalyzed polyol production to DMC-catalyzed polyol production |
| CN109071795B (zh) * | 2016-05-13 | 2021-08-31 | 科思创德国股份有限公司 | 制备聚氧化烯多元醇的方法 |
| KR101842670B1 (ko) * | 2016-05-23 | 2018-03-27 | 미쓰이케미칼앤드에스케이씨폴리우레탄 주식회사 | 폴리우레탄의 제조를 위한 바이오 기반의 폴리올 |
| CN110964191B (zh) * | 2018-09-29 | 2021-02-02 | 杭州普力材料科技有限公司 | 一种混合酸改性的锌钴双金属氰化物催化剂及其制备方法 |
| EP3947522B1 (en) * | 2019-03-25 | 2025-10-15 | Huntsman International LLC | Process for providing a homogeneous polyether polyol composition, reaction mixture comprising a composition obtained by the process, and polyurethane products obtained from the reaction mixture |
| US11572440B2 (en) | 2020-02-18 | 2023-02-07 | Covestro Llc | Methods for purifying polyols containing oxyalkylene units to reduce 2-methyl-2-pentenal content |
| US20230147479A1 (en) * | 2021-11-05 | 2023-05-11 | Covestro Llc | Processes and production plants for producing polyols |
| KR20240100895A (ko) | 2022-12-23 | 2024-07-02 | 주식회사 삼주공업 | 연료전지용 백금합금 촉매 전구체 용액 합성장치 |
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| US5144093A (en) | 1991-04-29 | 1992-09-01 | Olin Corporation | Process for purifying and end-capping polyols made using double metal cyanide catalysts |
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| US6008263A (en) | 1998-04-03 | 1999-12-28 | Lyondell Chemical Worldwide, Inc. | Molded and slab polyurethane foam prepared from double metal cyanide complex-catalyzed polyoxyalkylene polyols and polyols suitable for the preparation thereof |
| CN1174022C (zh) * | 1998-07-10 | 2004-11-03 | 旭硝子株式会社 | 环氧烷开环聚合用催化剂及其制造方法和用途 |
| KR100873594B1 (ko) * | 2001-07-18 | 2008-12-11 | 아사히 가라스 가부시키가이샤 | 폴리올 및 폴리머 분산 폴리올의 제조방법 |
| US20040064001A1 (en) * | 2002-09-30 | 2004-04-01 | Stephan Ehlers | Processes for preparing ethylene oxide-capped polyols |
-
2003
- 2003-11-03 US US10/699,951 patent/US7005552B2/en not_active Expired - Lifetime
-
2004
- 2004-10-19 EP EP04024809.8A patent/EP1528073B1/en not_active Expired - Lifetime
- 2004-10-29 CA CA2486337A patent/CA2486337C/en not_active Expired - Fee Related
- 2004-11-02 RU RU2004131631/04A patent/RU2004131631A/ru not_active Application Discontinuation
- 2004-11-02 SG SG200406368A patent/SG111284A1/en unknown
- 2004-11-02 KR KR1020040088221A patent/KR101173690B1/ko not_active Expired - Fee Related
- 2004-11-03 BR BR0404789-3A patent/BRPI0404789A/pt not_active IP Right Cessation
- 2004-11-03 MX MXPA04010880A patent/MXPA04010880A/es active IP Right Grant
- 2004-11-03 CN CN2004100883792A patent/CN1636989B/zh not_active Expired - Fee Related
- 2004-11-04 JP JP2004320672A patent/JP5062951B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| KR20050042451A (ko) | 2005-05-09 |
| KR101173690B1 (ko) | 2012-08-13 |
| CA2486337C (en) | 2012-06-05 |
| CN1636989A (zh) | 2005-07-13 |
| JP2005163022A (ja) | 2005-06-23 |
| RU2004131631A (ru) | 2006-04-20 |
| BRPI0404789A (pt) | 2005-07-19 |
| SG111284A1 (en) | 2005-05-30 |
| CN1636989B (zh) | 2011-04-13 |
| US20050096488A1 (en) | 2005-05-05 |
| US7005552B2 (en) | 2006-02-28 |
| CA2486337A1 (en) | 2005-05-03 |
| EP1528073B1 (en) | 2019-12-11 |
| JP5062951B2 (ja) | 2012-10-31 |
| EP1528073A1 (en) | 2005-05-04 |
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