MXPA03008002A - Proceso para la remocion de azufre de liquidos de hidrocarburo. - Google Patents
Proceso para la remocion de azufre de liquidos de hidrocarburo.Info
- Publication number
- MXPA03008002A MXPA03008002A MXPA03008002A MXPA03008002A MXPA03008002A MX PA03008002 A MXPA03008002 A MX PA03008002A MX PA03008002 A MXPA03008002 A MX PA03008002A MX PA03008002 A MXPA03008002 A MX PA03008002A MX PA03008002 A MXPA03008002 A MX PA03008002A
- Authority
- MX
- Mexico
- Prior art keywords
- liquid
- sulfur removal
- hydrocarbon liquids
- alloy
- sulfur
- Prior art date
Links
- 239000007788 liquid Substances 0.000 title abstract 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title abstract 4
- 229910052717 sulfur Inorganic materials 0.000 title abstract 4
- 239000011593 sulfur Substances 0.000 title abstract 4
- 239000004215 Carbon black (E152) Substances 0.000 title abstract 2
- 229930195733 hydrocarbon Natural products 0.000 title abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 229910045601 alloy Inorganic materials 0.000 abstract 2
- 239000000956 alloy Substances 0.000 abstract 2
- 238000006477 desulfuration reaction Methods 0.000 abstract 2
- 230000023556 desulfurization Effects 0.000 abstract 2
- 229910000990 Ni alloy Inorganic materials 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 230000008929 regeneration Effects 0.000 abstract 1
- 238000011069 regeneration method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J25/00—Catalysts of the Raney type
- B01J25/04—Regeneration or reactivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J25/00—Catalysts of the Raney type
- B01J25/02—Raney nickel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/04—Metals, or metals deposited on a carrier
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
- Y10S502/515—Specific contaminant removal
- Y10S502/517—Sulfur or sulfur compound removal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/8995—Catalyst and recycle considerations
- Y10S585/90—Rehabilitation of H acceptor
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/8995—Catalyst and recycle considerations
- Y10S585/904—Catalyst rehabilitation by reversion from different compound
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Physical Water Treatments (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
La presente invencion esta dirigida a un metodo de desulfuracion de un liquido de hidrocarburo cargado con azufre que comprende poner en contacto el liquido con una aleacion de metal de niquel esponjosa, remover el liquido libre de azufre, regeneracion de la aleacion mediante contacto con una solucion acuosa de un oxidante y reutilizar la aleacion para desulfuracion del liquido cargado con azufre adicional.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/833,602 US6558533B2 (en) | 2001-04-13 | 2001-04-13 | Process for sulfur removal from hydrocarbon liquids |
PCT/US2002/010031 WO2002083818A2 (en) | 2001-04-13 | 2002-03-28 | Process for sulfur removal from hydrocarbon liquids |
Publications (1)
Publication Number | Publication Date |
---|---|
MXPA03008002A true MXPA03008002A (es) | 2004-04-02 |
Family
ID=25264842
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MXPA03008002A MXPA03008002A (es) | 2001-04-13 | 2002-03-28 | Proceso para la remocion de azufre de liquidos de hidrocarburo. |
Country Status (14)
Country | Link |
---|---|
US (1) | US6558533B2 (es) |
EP (2) | EP1923450A3 (es) |
JP (2) | JP3963839B2 (es) |
KR (1) | KR100861516B1 (es) |
CN (2) | CN1269936C (es) |
AT (1) | ATE520759T1 (es) |
AU (1) | AU2002258675B2 (es) |
CA (1) | CA2443898C (es) |
DK (1) | DK1401989T3 (es) |
ES (1) | ES2369900T3 (es) |
MX (1) | MXPA03008002A (es) |
NO (1) | NO20034540L (es) |
TW (1) | TWI260994B (es) |
WO (1) | WO2002083818A2 (es) |
Families Citing this family (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2470079A1 (en) * | 2001-12-13 | 2003-06-26 | Lehigh University | Oxidative desulfurization of sulfur-containing hydrocarbons |
US7375053B2 (en) * | 2003-04-07 | 2008-05-20 | W. R. Grace & Co.- Conn. | Nickel and cobalt plated sponge catalysts |
US7309416B2 (en) * | 2003-07-11 | 2007-12-18 | Aspen Products Group, Inc. | Methods and compositions for desulfurization of hydrocarbon fuels |
US6984124B2 (en) * | 2003-09-18 | 2006-01-10 | Midco International, Inc. | High temperature rise makeup air unit |
JP4521172B2 (ja) * | 2003-09-26 | 2010-08-11 | 出光興産株式会社 | 脱硫剤及びこれを用いた脱硫方法 |
US20050100494A1 (en) | 2003-11-06 | 2005-05-12 | George Yaluris | Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking |
US20050100493A1 (en) * | 2003-11-06 | 2005-05-12 | George Yaluris | Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking |
US20050232839A1 (en) * | 2004-04-15 | 2005-10-20 | George Yaluris | Compositions and processes for reducing NOx emissions during fluid catalytic cracking |
US7304011B2 (en) * | 2004-04-15 | 2007-12-04 | W.R. Grace & Co. -Conn. | Compositions and processes for reducing NOx emissions during fluid catalytic cracking |
CA2606249C (en) | 2005-04-27 | 2013-07-23 | W.R. Grace & Co.-Conn. | Compositions and processes for reducing nox emissions during fluid catalytic cracking |
US20060278568A1 (en) * | 2005-06-08 | 2006-12-14 | Catalytic Distillation Technologies | Method of removing oxygenated sulfur compounds from hydrocarbons |
WO2007096709A2 (en) * | 2005-12-30 | 2007-08-30 | Abb Research Ltd. | Improved method for on-line removal of corrosive components of transformer oil |
JP4922783B2 (ja) * | 2006-02-24 | 2012-04-25 | コスモ石油株式会社 | 炭化水素用脱硫剤 |
JP4912767B2 (ja) * | 2006-06-28 | 2012-04-11 | 株式会社コロナ | スポンジメタル触媒の反応器への充填方法 |
KR100882259B1 (ko) * | 2006-10-12 | 2009-02-09 | 주식회사 코캣 | 탈질, 탈황, 함산소 화합물 제조를 위한 탄화수소 기질의선택산화 방법 |
US7871501B2 (en) * | 2006-11-15 | 2011-01-18 | King Fahd University Of Petroleum And Minerals | Laser-based method for removal of sulfur (DMDBT) in hydrocarbon fuels |
US7811474B2 (en) * | 2008-12-04 | 2010-10-12 | Uop Llc | Simultaneous warm gas desulfurization and CO-shift for improved syngas cleanup |
JP5368883B2 (ja) * | 2009-05-29 | 2013-12-18 | 住友化学株式会社 | 塩素製造用触媒の賦活方法および塩素の製造方法 |
US20110011772A1 (en) * | 2009-07-15 | 2011-01-20 | Stephen Raymond Schmidt | Nickel and Cobalt Plated Sponge Catalysts |
US20110054227A1 (en) * | 2009-08-26 | 2011-03-03 | Chevron Phillips Chemical Company Lp | Process to Protect Hydrogenation and Isomerization Catalysts Using a Guard Bed |
TWI490034B (zh) | 2009-11-17 | 2015-07-01 | Basf Se | 製備具有增強氫化活性之經承載氫化觸媒之方法 |
US20110220550A1 (en) * | 2010-03-15 | 2011-09-15 | Abdennour Bourane | Mild hydrodesulfurization integrating targeted oxidative desulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds |
US9296960B2 (en) * | 2010-03-15 | 2016-03-29 | Saudi Arabian Oil Company | Targeted desulfurization process and apparatus integrating oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds |
US8658027B2 (en) * | 2010-03-29 | 2014-02-25 | Saudi Arabian Oil Company | Integrated hydrotreating and oxidative desulfurization process |
SG188753A1 (en) * | 2011-09-30 | 2013-04-30 | Bharat Petroleum Corp Ltd | Sulphur reduction catalyst additive composition in fluid catalytic cracking and method of preparation thereof |
CN104136551B (zh) | 2011-10-24 | 2016-09-21 | 埃迪亚贝拉努沃有限公司 | 生产碳黑的改进工艺 |
US8906227B2 (en) | 2012-02-02 | 2014-12-09 | Suadi Arabian Oil Company | Mild hydrodesulfurization integrating gas phase catalytic oxidation to produce fuels having an ultra-low level of organosulfur compounds |
RU2635808C2 (ru) | 2012-03-30 | 2017-11-16 | Адитиа Бирла Сайенс Энд Текнолоджи Компани Лтд. | Способ получения порошка технического углерода с пониженным содержанием серы |
CN103566976B (zh) * | 2012-08-06 | 2016-04-20 | 中国石油化工股份有限公司 | 一种负载型催化剂及其制备方法 |
KR101918775B1 (ko) * | 2012-08-23 | 2018-11-15 | 에스케이이노베이션 주식회사 | 탄화수소의 산화 탈황방법 |
US8920635B2 (en) | 2013-01-14 | 2014-12-30 | Saudi Arabian Oil Company | Targeted desulfurization process and apparatus integrating gas phase oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds |
CN103045291B (zh) * | 2013-01-15 | 2014-11-05 | 西安嘉宏石化科技有限公司 | 一种硫化物脱除剂及其脱硫方法 |
CN104888808B (zh) * | 2014-03-07 | 2018-08-17 | 中国石油化工股份有限公司 | 一种复合型催化剂及其制备方法 |
US10822549B2 (en) | 2019-01-18 | 2020-11-03 | Baker Hughes Holdings Llc | Methods and compounds for removing non-acidic contaminants from hydrocarbon streams |
US11491466B2 (en) | 2020-07-24 | 2022-11-08 | Baker Hughes Oilfield Operations Llc | Ethyleneamines for regenerating adsorbent beds for sulfur compound removal |
US11331649B2 (en) | 2020-07-24 | 2022-05-17 | Baker Hughes Oilfield Operations Llc | Regenerated adsorbent beds for sulfur compound removal |
CN113559819A (zh) * | 2021-06-30 | 2021-10-29 | 开滦(集团)有限责任公司 | 一种用于芳烃超深度脱硫的吸附剂及制备方法和脱硫方法 |
CN114011433B (zh) * | 2021-12-13 | 2023-12-19 | 万华化学集团股份有限公司 | 一种粉末雷尼催化剂的制备方法 |
Family Cites Families (33)
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NL96087C (es) * | ||||
US1628190A (en) | 1926-05-14 | 1927-05-10 | Raney Murray | Method of producing finely-divided nickel |
US1915473A (en) | 1930-12-31 | 1933-06-27 | Raney Murray | Method of preparing catalytic material |
US2139602A (en) | 1935-06-17 | 1938-12-06 | Raney Murray | Method of reclaiming catalytic material from spent catalytic material |
US2381659A (en) | 1941-12-18 | 1945-08-07 | Phillips Petroleum Co | Regeneration of catalytic material |
US2461396A (en) | 1945-07-25 | 1949-02-08 | Raney Murray | Method of producing finely divided metals |
US2585490A (en) * | 1949-03-31 | 1952-02-12 | Sun Oil Co | Continuous adsorption process |
BE561250A (es) | 1956-10-15 | |||
US2951034A (en) | 1957-04-09 | 1960-08-30 | Sun Oil Co | Desulfurization of hydrocarbons with a mixture of a group viii metal and group viii metal oxide or sulfide |
US2977327A (en) | 1958-09-26 | 1961-03-28 | Raney Catalyst Company Inc | Process of producing nickel catalysts |
US3098816A (en) | 1960-10-10 | 1963-07-23 | British Petroleum Co | Removal of metals from petroleum fractions |
US3351495A (en) | 1966-11-22 | 1967-11-07 | Grace W R & Co | Battery separator |
US3674707A (en) * | 1970-10-21 | 1972-07-04 | Grace W R & Co | Regeneration of sulfur-poisoned raney nickel catalyst |
AU454487B2 (en) * | 1971-08-25 | 1974-10-31 | C. Sr. Chemicals Limited | Improvements in or relating to catalytic regeneration |
US3907710A (en) | 1973-04-18 | 1975-09-23 | Grace W R & Co | Hollow ceramic pellets for catalyst support |
US3904551A (en) | 1973-12-19 | 1975-09-09 | Grace W R & Co | Process for preparing an auto exhaust catalytic converter |
JPS5144592A (en) | 1974-10-15 | 1976-04-16 | Toyo Soda Mfg Co Ltd | Nitsukerushokubaino saiseihoho |
US4188285A (en) | 1978-12-20 | 1980-02-12 | Chevron Research Company | Selective process for removal of thiophenes from gasoline using a silver-exchanged faujasite-type zeolite |
SU862969A1 (ru) * | 1979-08-16 | 1981-09-15 | Казахский Ордена Трудового Красного Знамени Государственный Университет Им.С.М.Кирова | Способ устранени пирофорности никелевого скелетного катализатора |
US4957892A (en) | 1980-07-29 | 1990-09-18 | Uop | Process for combusting solid sulfur containing material |
US4510263A (en) | 1983-10-17 | 1985-04-09 | W. R. Grace & Co. | Catalyst with high geometric surface area alumina extrudate and catalyst with high geometric surface area |
US4790982A (en) | 1986-04-07 | 1988-12-13 | Katalistiks International, Inc. | Metal-containing spinel composition and process of using same |
FR2609710B1 (fr) | 1987-01-21 | 1989-04-21 | Sopar Sa Nv | Procede de purification du benzene |
US4957718A (en) | 1987-11-24 | 1990-09-18 | Uop | Process for reducing emissions of sulfur oxides and composition useful in same |
US4895994A (en) | 1988-04-14 | 1990-01-23 | W. R. Grace & Co.-Conn. | Shaped catalysts and processes |
US4826799A (en) | 1988-04-14 | 1989-05-02 | W. R. Grace & Co.-Conn. | Shaped catalyst and process for making it |
FR2650759B1 (fr) * | 1989-08-08 | 1991-10-31 | Inst Francais Du Petrole | Masse de captation a base de nickel pour l'elimination de l'arsenic et du phosphore contenus dans les coupes d'hydrocarbures liquides, sa preparation et son utilisation |
US5376608A (en) | 1993-01-27 | 1994-12-27 | W. R. Grace & Co.-Conn. | Sulfur reduction in FCC gasoline |
US5516334A (en) | 1994-01-28 | 1996-05-14 | Easton; Gregory D. | Interactive exercise monitor |
KR960003807A (ko) * | 1994-07-20 | 1996-02-23 | 홍해준 | 니켈계 폐촉매의 재생 및 제조방법 |
US5928498A (en) * | 1996-08-23 | 1999-07-27 | Exxon Research And Engineering Co. | Desulfurization and ring opening of petroleum streams |
US5843300A (en) * | 1997-12-29 | 1998-12-01 | Uop Llc | Removal of organic sulfur compounds from FCC gasoline using regenerable adsorbents |
US6254766B1 (en) * | 1999-08-25 | 2001-07-03 | Phillips Petroleum Company | Desulfurization and novel sorbents for same |
-
2001
- 2001-04-13 US US09/833,602 patent/US6558533B2/en not_active Expired - Fee Related
-
2002
- 2002-03-28 CA CA2443898A patent/CA2443898C/en not_active Expired - Fee Related
- 2002-03-28 WO PCT/US2002/010031 patent/WO2002083818A2/en active Application Filing
- 2002-03-28 DK DK02728631.9T patent/DK1401989T3/da active
- 2002-03-28 EP EP07023992A patent/EP1923450A3/en not_active Withdrawn
- 2002-03-28 ES ES02728631T patent/ES2369900T3/es not_active Expired - Lifetime
- 2002-03-28 CN CNB028081749A patent/CN1269936C/zh not_active Expired - Fee Related
- 2002-03-28 JP JP2002582157A patent/JP3963839B2/ja not_active Expired - Fee Related
- 2002-03-28 CN CNB2006100958181A patent/CN100572505C/zh not_active Expired - Fee Related
- 2002-03-28 MX MXPA03008002A patent/MXPA03008002A/es active IP Right Grant
- 2002-03-28 KR KR1020037013201A patent/KR100861516B1/ko not_active IP Right Cessation
- 2002-03-28 AU AU2002258675A patent/AU2002258675B2/en not_active Ceased
- 2002-03-28 EP EP02728631A patent/EP1401989B1/en not_active Expired - Lifetime
- 2002-03-28 AT AT02728631T patent/ATE520759T1/de active
- 2002-04-08 TW TW091106978A patent/TWI260994B/zh not_active IP Right Cessation
-
2003
- 2003-10-09 NO NO20034540A patent/NO20034540L/no not_active Application Discontinuation
-
2007
- 2007-04-17 JP JP2007108088A patent/JP4564980B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN100572505C (zh) | 2009-12-23 |
WO2002083818A3 (en) | 2004-01-29 |
AU2002258675B2 (en) | 2006-12-07 |
JP2007224313A (ja) | 2007-09-06 |
CN1896185A (zh) | 2007-01-17 |
EP1401989B1 (en) | 2011-08-17 |
ATE520759T1 (de) | 2011-09-15 |
KR100861516B1 (ko) | 2008-10-02 |
EP1923450A2 (en) | 2008-05-21 |
CN1269936C (zh) | 2006-08-16 |
EP1401989A2 (en) | 2004-03-31 |
TWI260994B (en) | 2006-09-01 |
JP4564980B2 (ja) | 2010-10-20 |
KR20030087067A (ko) | 2003-11-12 |
NO20034540D0 (no) | 2003-10-09 |
US6558533B2 (en) | 2003-05-06 |
NO20034540L (no) | 2003-12-15 |
JP3963839B2 (ja) | 2007-08-22 |
CA2443898A1 (en) | 2002-10-24 |
US20030019794A1 (en) | 2003-01-30 |
JP2005509043A (ja) | 2005-04-07 |
DK1401989T3 (da) | 2011-10-17 |
WO2002083818A2 (en) | 2002-10-24 |
EP1923450A3 (en) | 2008-07-23 |
ES2369900T3 (es) | 2011-12-09 |
CA2443898C (en) | 2010-10-19 |
CN1520454A (zh) | 2004-08-11 |
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Date | Code | Title | Description |
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FG | Grant or registration |